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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS2016

The Formation of Nucleobases from the Irradiation of Purine in Astophysical Ices and Comparisons with Meteorites.

N-heterocycles have been identified in meteorites and their extraterrestrial origins are suggested by isotopic ratio measurements. Although small N- heterocycles have not been detected in the interstellar medium (ISM), recent experiments in our lab have shown that the irradiation of the aromatic molecules like benzene (C6H6) and naphthalene (C10H8) in mixed molecular ices leads to the formation of O- and N-heterocyclic molecules. Among the class of N-heterocycles are the nucleobases, which are of astrobiological interest because they are the information bearing units of DNA and RNA. Nucleobases have been detected in meteorites [3-5], with isotopic signatures that are also consistent with an extraterrestrial origin. Three of the biologically relevant nucleobases (uracil, cytosine, and guanine) have a pyrimidine core structure while the remaining two (adenine and guanine) possess a purine core. Previous experiments in our lab have demonstrated that all of the bio-logical nucleobases (and numerous other molecules) with a pyrimidine core structure can be produced by irradiating pyrimidine in mixed molecular ices of several compositions [6-8]. In this work, we study the formation of purine-based molecules, including the nucleobases adenine, and guanine, from the ultraviolet (UV) irradiation of purine in ices consisting mixtures of H2O and NH3 at low temperature. The experiments are designed to simulate the astrophysical conditions under which these species may be formed in dense molecular clouds, protoplanetary disks, or on the surfaces of icy bodies in planetary systems.

Astrochemistry↗
NASA NTRS1999

MESSENGER, MErcury: Surface, Space ENvironment, GEochemistry, and Ranging; A Mission to Orbit and Explore the Planet Mercury

MESSENGER is a scientific mission to Mercury. Understanding this extraordinary planet and the forces that have shaped it is fundamental to understanding the processes that have governed the formation, evolution, and dynamics of the terrestrial planets. MESSENGER is a MErcury Surface, Space ENvironment, GEochemistry and Ranging mission to orbit Mercury for one Earth year after completing two flybys of that planet following two flybys of Venus. The necessary flybys return significant new data early in the mission, while the orbital phase, guided by the flyby data, enables a focused scientific investigation of this least-studied terrestrial planet. Answers to key questions about Mercury's high density, crustal composition and structure, volcanic history, core structure, magnetic field generation, polar deposits, exosphere, overall volatile inventory, and magnetosphere are provided by an optimized set of miniaturized space instruments. Our goal is to gain new insight into the formation and evolution of the solar system, including Earth. By traveling to the inner edge of the solar system and exploring a poorly known world, MESSENGER fulfills this quest.

Source record↗
NASA NTRS2004

Hybrid Inflatable Pressure Vessel

Figure 1 shows a prototype of a large pressure vessel under development for eventual use as a habitable module for long spaceflight (e.g., for transporting humans to Mars). The vessel is a hybrid that comprises an inflatable shell attached to a rigid central structural core. The inflatable shell is, itself, a hybrid that comprises (1) a pressure bladder restrained against expansion by (2) a web of straps made from high-strength polymeric fabrics. On Earth, pressure vessels like this could be used, for example, as portable habitats that could be set up quickly in remote locations, portable hyperbaric chambers for treatment of decompression sickness, or flotation devices for offshore platforms. In addition, some aspects of the design of the fabric straps could be adapted to such other items as lifting straps, parachute straps, and automotive safety belts. Figure 2 depicts selected aspects of the design of a vessel of this type with a toroidal configuration. The bladder serves as an impermeable layer to keep air within the pressure vessel and, for this purpose, is sealed to the central structural core. The web includes longitudinal and circumferential straps. To help maintain the proper shape upon inflation after storage, longitudinal and circumferential straps are indexed together at several of their intersections. Because the web is not required to provide a pressure seal and the bladder is not required to sustain structural loads, the bladder and the web can be optimized for their respective functions. Thus, the bladder can be sealed directly to the rigid core without having to include the web in the seal substructure, and the web can be designed for strength. The ends of the longitudinal straps are attached to the ends of the rigid structural core by means of clevises. Each clevis pin is surrounded by a roller, around which a longitudinal strap is wrapped to form a lap seam with itself. The roller is of a large diameter chosen to reduce bending of the fibers in the strap. The roller also serves to equalize the load in the portions of the strap on both sides of the clevis pin. The lap seam is formed near the clevis by use of a tapered diamond stitch: This stitch is designed specifically to allow fibers in the stitch and strap to relax under load in such a manner that the load becomes more nearly evenly distributed among all fibers in the stitch region. Thus, the tapered diamond stitch prevents load concentrations that could cause premature failure of the strap and thereby increases the strength of the strap/structural-core joint. The lap seam can be rated at >90 percent of the strength of the strap material.

Raboin, Jasen↗
NASA NTRS1988

Experimental studies in vortex pair motion coincident with a liquid reaction

An experimental examination of the coincidence of a liquid reaction (acid/base) with the formation of a vortex pair structure is described in which emphasis is placed on the evolution of the strained diffusion layer and reacted core structures. Flow visualization of the reaction process is achieved via the technique of chemically sensitive LIF. The observed growth of reacted core structures associated with each vortex is compared with theoretically predicted behavior (Marble, 1983; Karagozian and Marble, 1986). Vortex pair separation is also compared with theoretical correlations, and the relevance of the analogy between a fast liquid reaction and a gaseous reaction is discussed.

Karagozian, A. R.↗
DOE OSTI2022

Coupling to short linear motifs creates versatile PME-1 activities in PP2A holoenzyme demethylation and inhibition

Protein phosphatase 2A (PP2A) holoenzymes target broad substrates by recognizing short motifs via regulatory subunits. PP2A methylesterase 1 (PME-1) is a cancer-promoting enzyme and undergoes methylesterase activation upon binding to the PP2A core enzyme. Here, we showed that PME-1 readily demethylates different families of PP2A holoenzymes and blocks substrate recognition in vitro. The high-resolution cryoelectron microscopy structure of a PP2A-B56 holoenzyme–PME-1 complex reveals that PME-1 disordered regions, including a substrate-mimicking motif, tether to the B56 regulatory subunit at remote sites. They occupy the holoenzyme substrate-binding groove and allow large structural shifts in both holoenzyme and PME-1 to enable multipartite contacts at structured cores to activate the methylesterase. B56 interface mutations selectively block PME-1 activity toward PP2A-B56 holoenzymes and affect the methylation of a fraction of total cellular PP2A. The B56 interface mutations allow us to uncover B56-specific PME-1 functions in p53 signaling. Our studies reveal multiple mechanisms of PME-1 in suppressing holoenzyme functions and versatile PME-1 activities derived from coupling substrate-mimicking motifs to dynamic structured cores.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2022

Physical characterization of fault rocks within the Opalinus Clay formation

Near-surface disposal of radioactive waste in shales is a promising option to safeguard the population and environment. However, natural faults intersecting these geological formations can potentially affect the long-term isolation of the repositories. This paper characterizes the physical properties and mineralogy of the internal fault core structure intersecting the Opalinus Clay formation, a host rock under investigation for nuclear waste storage at the Mont Terri Laboratory (Switzerland). We have performed porosity, density, microstructural and mineralogical measurements in different sections of the fault, including intact clays, scaly clays and fault gouge. Mercury intrusion porosimetry analysis reveal a gouge that has a pore network dominated by nanopores of less than 10 nm, yet a high-porosity (21%) and low grain density (2.62 g/cm 3 ) when compared to the intact rock (14.2%, and 2.69 g/cm 3 ). Thus, a more permeable internal fault core structure with respect to the surrounding rock is deduced. Further, we describe the OPA fault gouge as a discrete fault structure having the potential to act as a preferential, yet narrow, and localized channel for fluid-flow if compared to the surrounding rock. Since the fault gouge is limited to a millimetres-thick structure, we expect the barrier property of the geological formation is almost not affected.

58 GEOSCIENCES↗
NASA NTRS2004

[Relationship Between Core Convective Structure and Intensity Change in Tropical Cyclones]

Tropical Storm Chantal during August 2001 was a storm that failed to intensify over the few days prior to making landfall on the Yucatan Peninsula. An observational study of Tropical Storm Chantal is presented using a diverse data set including remote and in situ measurements from the NASA ER-2 and DC-8 and the NOAA WP-3D N42RF aircraft and satellite data. The authors discuss the storm structure from the larger scale environment down to the convective scale. Large vertical shear (850-200 hPa shear magnitude range 8-15 m/s) plays a very important role in preventing Chantal from intensifying. The storm had a poorly defined vortex that only extended up to 5-6 km altitude, and an adjacent intense convective region that comprised an Mesoscale Convective System (MCS). The entire low-level circulation center was in the rain-free western side of the storm, about 80 km to the west-southwest of the MCS. The MCS appears to have been primarily the result of intense convergence between large scale, low-level easterly flow with embedded downdrafts, and the cyclonic vortex flow. The individual cells in the MCS such as Cell 2 during the period of the observations, were extremely intense with reflectivity core diameters of 10 km and peak updrafts exceeding 20 m/s. Associated with this MCS were two broad subsidence (warm) regions both of which had portions over the vortex. The first layer near 700 hPa was directly above the vortex and covered most of it. The second layer near 500 hPa was along the forward and right flanks of Cell 2 and undercut the anvil divergence region above. There was not much resemblance of these subsidence layers to typical upper level warm cores in hurricanes that are necessary to support strong surface winds and a low central pressure. The observations are compared to previous studies of weakly sheared storms and modeling studies of shear effects and intensification. The configuration of the convective updrafts, low-level circulation, and lack of vertical coherence between the upper and low level warming regions, likely inhibited intensification of Chantal. This configuration is consistent with modeling of vortices in sheared environments, which suggest strongest convection and rain in the downshear left quadrant of the storm, and subsidence in the upshear right quadrant. The vertical shear profile is however different from what was assumed in previous modeling in that the winds are strongest in the lowest levels and the deep tropospheric vertical shear is on the order of 10-12 m/s.

Source record↗
DOE OSTI2023

Core-shell structured tow-pregs enabled additive manufacturing of continuously reinforced thermoset composites

One of the major challenges in thermally curable polymer composite additive manufacturing is the slow curing time of thermally curable resins, coupled with a significant drop in thermoset viscosity upon heating, making the formation of complex shapes difficult. To tackle these issues, we have introduced a novel rapid composite preformation strategy called Tow-Preg Cladding (TPC). This technique involves the use of a thin and rapidly curable dual-cure resin, which combines a thermally curable resin (such as epoxy) with a fast photo-curable resin. The dual-cure resin is applied as a coating over a thermally curable resin tow-preg, enabling the formation of a rigid cladding that supports and shapes the tow-pregs into the desired geometries and patterns. The key advantage of this approach lies in the sequential formation of an interpenetrating polymer network (IPN) at the interlayer between laminates, resulting from the curing of the photocurable resin and the thermally curable resin sequentially. This IPN formation enhances interlaminar bonding in the composite, contributing to its overall strength and performance. The composites produced using this technique exhibited impressive mechanical properties, including longitudinal tensile strength of 1058.2 MPa, longitudinal tensile modulus of 74.2 GPa, flexural strength of 1080.4 MPa, and flexural modulus of 41.7 GPa. Overall, our Tow-Preg Cladding approach shows great promise in overcoming the challenges associated with thermally curable polymer composite additive manufacturing. It offers a viable solution to creating strong, shape-specific thermoset composites efficiently with enhanced mechanical properties.

42 ENGINEERING↗
DOE OSTI2024

Novel intrinsic helical cores and MHD dynamo flux pumping evidence in DIII-D

Evidence of a MHD dynamo brought about by intrinsic helical core structures in negative triangularity (NT) and ITER baseline scenario (IBS) plasmas demonstrates paths to operating tokamaks without seeds for deleterious global MHD modes. A stationary sawtooth- and edge localized mode-free state maintains high performance for long durations in a strong NT shape in the DIII-D tokamak. Disparity between minimum safety factor values predicted by magnetic flux diffusion theory and derived from experiment suggests anomalous flux diffusion by an MHD dynamo, driven by flows associated with quasi-interchange modes. Stability calculations with the GATO code find NT and IBS experimental equilibria unstable to quasi-interchange modes, in agreement with observed saturated activity. IBS discharges with similar magnetic winding structure occupy robust helical core states following a transition from sawtooth instabilities. These states agree with prior modeling of helical core bifurcation thresholds with the VMEC equilibrium code.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

The narrative arc: Revealing core narrative structures through text analysis

Scholars across disciplines have long debated the existence of a common structure that underlies narratives. Using computer-based language analysis methods, several structural and psychological categories of language were measured across ~40,000 traditional narratives (e.g., novels and movie scripts) and ~20,000 nontraditional narratives (science reporting in newspaper articles, TED talks, and Supreme Court opinions). Across traditional narratives, a consistent underlying story structure emerged that revealed three primary processes: staging, plot progression, and cognitive tension. No evidence emerged to indicate that adherence to normative story structures was related to the popularity of the story. Last, analysis of fact-driven texts revealed structures that differed from story-based narratives.

60 APPLIED LIFE SCIENCES↗
NASA NTRS2004

[Relationship Between Core Convective Structure and Intensity Change in Tropical Cyclones]

The downshear reformation of Tropical Storm Gabrielle (2001) was investigated using radar reflectivity and lightning data that were nearly continuous in time, as well as frequent aircraft reconnaissance fights. Initially the storm was a marginal tropical storm in an environment with strong 850-200 hPa vertical wind shear of 12-13 m/s and an approaching upper tropospheric trough. Both the observed outflow and an adiabatic balance model calculation showed that the radial-vertical circulation increased with time as the trough approached. Convection was highly asymmetric, with almost all radar return located in one quadrant left of downshear in the storm. Reconnaissance data show that an intense mesovortex formed downshear of the original center. This vortex was located just south of: rather than within, a strong downshear left lightning outbreak, consistent with tilting of the horizontal vorticity associated with the vertical wind shear. The downshear mesovortex contained a 972 hPa minimum central pressure, 20 hPa lower than minimum pressure in the original vortex just three hours earlier. The mesovortex became the new center of the storm, but weakened somewhat prior to landfall. It is argued that dry air carried around the storm from the region of upshear subsidence, as well as the direct effects of the shear, prevented the reformed vortex from continuing to intense.

Source record↗
NASA NTRS2005

[Summary of Research on Relationship Between Core Convective Structure and Intensity Change in Tropical Cyclones]

The downshear reformation of Tropical Storm Gabrielle (2001) was investigated using radar reflectivity and lightning data that were nearly continuous in time, as well as frequent aircraft reconnaissance flights. Initially the storm was a marginal tropical storm in an environment with strong 850-200 hPa vertical wind shear of 12-13 meters per second and an approaching upper tropospheric trough. Both the observed outflow and an adiabatic balance model calculation showed that the radial-vertical circulation increased with time as the trough approached. Convection was highly asymmetric, with almost all radar return located in one quadrant left of downshear in the storm. Reconnaissance data show that an intense mesovortex formed downshear of the original center. This vortex was located just south of, rather than within, a strong downshear left lightning outbreak, consistent with tilting of the horizontal vorticity associated with the vertical wind shear. The downshear mesovortex contained a 972 hPa minimum central pressure, 20 hPa lower than minimum pressure in the original vortex just three hours earlier. The mesovortex became the new center of the storm, but weakened somewhat prior to landfall. It is argued that dry air carried around the storm from the region of upshear subsidence, as well as the direct effects of the shear, prevented the reformed vortex from continuing to intensify. Despite the subsequent weakening of the reformed center, it reached land with greater intensity than the original center. It is argued that this intensification process was set into motion by the vertical wind shear in the presence of an environment with upward motion forced by the upper tropospheric trough. In addition, the new center formed much closer to the coast and made landfall much earlier than predicted. Such vertical shear-induced intensity and track fluctuations are important to understand, especially in storms approaching the coast. The structures of the highly sheared tropical storm Chantal During CAMEX-4 is also discussed.

Source record↗