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At least 91 records · Page 5

Oxidation Behavior of Copper Concentrate, Gold Concentrate, and Their Mixtures Between 1173 K (900 °C) and 1373 K (1100 °C)

Gold is typically extracted from ores using a cyanidation process. However, environmental regulations and low productivity are the main drawbacks of cyanide usage. Alternative technologies for gold extraction are being studied although development of any new technology necessitates additional investments. In South Korea, recovery of gold and silver is performed by the local copper producer by feeding gold concentrate into a smelter. An integrated copper-making process might be an efficient and feasible alternative for the extraction of precious metals without the use of toxic cyanide. Installed exhaust gas cleaning system of copper smelter would minimize the toxic effects of hazardous elements (arsenic, bismuth, antimony, etc.) contained in gold concentrates. A kinetic and thermodynamic understanding of the effects of gold concentrates on copper metallurgy is necessary for the operation. The effects of various parameters on the oxidation kinetics of sulfides were investigated.

36 MATERIALS SCIENCE↗

Amazon boundary layer aerosol concentration sustained by vertical transport during rainfall

The nucleation of atmospheric vapours is an important source of new aerosol particles that can subsequently grow to form cloud condensation nuclei in the atmosphere. Most field studies of atmospheric aerosols over continents are influenced by atmospheric vapours of anthropogenic origin and, in consequence, aerosol processes in pristine, terrestrial environments remain poorly understood. The Amazon rainforest is one of the few continental regions where aerosol particles and their precursors can be studied under near-natural conditions, but the origin of small aerosol particles that grow into cloud condensation nuclei in the Amazon boundary layer remains unclear. Here we present aircraft- and ground-based measurements under clean conditions during the wet season in the central Amazon basin. We find that high concentrations of small aerosol particles (with diameters of less than 50 nanometres) in the lower free troposphere are transported from the free troposphere into the boundary layer during precipitation events by strong convective downdrafts and weaker downward motions in the trailing stratiform region. Lastly, this rapid vertical transport can help to maintain the population of particles in the pristine Amazon boundary layer, and may therefore influence cloud properties and climate under natural conditions.

54 ENVIRONMENTAL SCIENCES↗

Effect of plasma on gas flow and air concentration in the effluent of a pulsed cold atmospheric pressure helium plasma jet

In this work, we report on the flow effects induced by a nanosecond pulsed helium cold atmospheric pressure plasma jet impinging on a glass substrate. Herein, gas temperature measurements have been performed using optical emission spectroscopy including rotational spectra of OH(A-X) (0,0) and N 2 (C-B) (0,0) and resonance broadening of a helium emission line at 667.8 nm. The measured increase in gas temperature was less than 15 K. We have measured the air concentration distribution in the jet effluent by means of Rayleigh scattering exploiting the large difference in Rayleigh cross-section of air and helium. The obtained results show that the plasma causes a broadening of the helium channel suggesting an enhanced gas velocity and mixing with the ambient air. The impact of the plasma on the jet effluent is polarity dependent and is larger in the case of positive applied voltage pulses. Using an estimation of the increased gas velocity required to obtain the observed air concentrations, we have shown that both gas heating and electrohydrodynamic (EHD) forces related to the propagation of an ionization front are not causing the observed phenomena. The surface charge which can exist for a much longer time than the duration of the applied voltage pulse is the primary cause of the EHD forces on the bulk charges which lead to significant different air concentration profiles in the jet effluent for plasma on and off.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Recovery of Rare Earth Oxides from Flotation Concentrates of Bastnaesite Ore by Ultra-Fine Centrifugal Concentration

Historically, the ability to effectively separate carbonate gangue from bastnaesite via flotation has frequently proven to be challenging without sacrificing significant rare earth oxide (REO) grade or recovery. However, in light of the fact that the rare earth bearing minerals often exhibit higher specific gravities than the carbonate gangue, the possibility exists that the use of gravity separation could be used to achieve such a selective separation. This however is complicated by the fact that, in cases such as this study when the liberation size is finer than 50 microns, most traditional gravity separation methods become increasingly challenging. The aim of this study is to determine the applicability of centrifugal concentrators to beneficiate ultra-fine (UF) bastnaesite and calcite bearing flotation concentrates. By using a UF Falcon, it was possible to achieve initial gravity REO recoveries exceeding 90% while rejecting on the order of 25% to 35% of the total calcium from an assortment of rougher and cleaner flotation concentrates. Additionally, when additional stages of cleaner UF Falcon gravity separation were operated in an open circuit configuration, it was possible, from an original fine feed of 35 microns containing 50.5% REO and 5.5% Ca, to upgrade up to approximately 59% REO and 2.0% calcium. While not the goal of this study, these results also support previous limited data to suggest that UF Falcons are potentially capable of treating a wider range of materials than they were originally designed for, including feeds rich in heavy mineral content.

Norgren, Alex↗

Concentrations of trace elements and compounds in the airborne suspended particulate matter in Cleveland, Ohio, from August 1971 to August 1972 and their dependence on wind direction: Complete data listing and concentration roses

Concentrations of 75 chemical constituents in the airborne particulate matter were measured in Cleveland, Ohio during 1971 and 1972. Daily values, maxima, geometric means and their standard deviations covering a 1-year period (45 to 50 sampling days) at each of 16 sites are presented on microfiche for 60 elements, and for a lesser number of days for 10 polycyclic aromatic hydrocarbon compounds (PAH), the aliphatic hydrocarbon compounds (AH) as a group and carbon. In addition, concentration roses showing directional properties are presented for 39 elements, 10 PAH and the AH as a group. The elements (except carbon) are shown both in terms of concentration and percentage of the suspended particulate matter.

King, R. B.↗

Design of nonimaging concentrators as second stages in tandem with image-forming first-stage concentrators

The paper discusses the paraboloidal mirror as a tracking solar concentrator, fitting a nonimaging second stage to the paraboloidal mirror, other image-forming systems as first stages, and tracking systems in two-dimensional geometry. Because of inherent aberrations, the paraboloidal mirror cannot achieve the thermodynamic limit. It is shown how paraboloidal mirrors of short focal ratio and similar systems can have their flux concentration enhanced to near the thermodynamic limit by the addition of nonimaging compound elliptical concentrators.

Winston, R.↗

Concentration of off-axis radiation by solar concentrators for space power

Four types of off-axis radiation are discussed. These are: (1) small off-axis angles during walk-off, (2) large off-axis angles, (3) an extended off-axis source such as Earth albedo, and (4) miscellaneous off-axis sources including radio frequency sources and local point sources. A code named OFFSET has been developed to represent the solar concentrator being developed for Space Station Freedom. It is a detailed, ray-tracing model which represents 50 ray originating points on the Sun and reflections from 10 points on each of the 456 concentrator facets. Results of this code are generally similar to the PIXEL results although there are small differences due to the more detailed representations of the Sun and concentrator that were used in the OFFSET code.

Jefferies, Kent S.↗

The response of C1O radical concentrations to variations in NO2 radical concentrations in the lower stratosphere

The respose of ClO concentrations to changes in NO2 concentrations has been inferred from simultaneous observations of (ClO), (NO), (NO2) and (O3) in the midlatitude lower stratosphere. This analysis demonstrates that (ClO) is inversely correlated with (NO2), consistent with formation and photolysis of (ClONO2). A factor of ten range in the concentration if NO2 was sampled (0.1 to 1 x 10(exp 9) mol/cu cm), with a comparable range in the ratio of (ClO) to total available inorganic chlorine (1% less than or equal to (ClO)/(Cl(sub y)) less than or equal to 5%. This analysis leads to an estimate of (ClONO2)/(Cl(sub y)) = 0.12 (x/2), in the mid-latitude, lower-stratospheric air masses sampled.

Stimfle, R. M.↗

The Response of ClO Radical Concentrations to Variations in NO2 Radical Concentrations in the Lower Stratosphere

The response of ClO concentrations to changes in NO2 concentrations has been inferred from simultaneous observations of [ClO], [NO], [NO2] and [O3] in the mid-latitude lower stratosphere. This analysis demonstrates that [ClO] is inversely correlated with [NO2], consistent with formation and photolysis of [ClONO2]. A factor of ten range in the concentration of NO2 was sampled (0.1 to 1 x 10(exp 9) mol/cc), with a comparable range in the ratio of [ClO] to total available inorganic chlorine (1% <= [ClO]/[Cl(sub y)] <= 5%). This analysis leads to an estimate of [ClONO2]/[Cl(sub y)] = 0.12 (x/divided by 2), in the mid-latitude, lower-stratospheric air masses sampled.

Stimpfle, R. M.↗

Localized High-Concentration Sulfone Electrolytes for High-Efficiency Lithium-Metal Batteries

To enable next-generation high-energy-density lithium (Li) metal batteries (LMBs), an electrolyte that has simultaneous high Li metal Coulombic efficiency (CE) and high anodic stability on cathodes is of significant importance. Sulfones are known for their high dielectric constants, low flammability and in particular strong resistance against oxidation, but their application in LMBs is restricted due to their poor compatibility with Li metal anode. Uncontrolled Li plating in sulfones results in poor Li CE and induces catastrophic battery failure, and their high viscosity and poor wettability towards electrodes and separators introduce serious issues for the practical applications. Here, we demonstrate that stable Li plating/stripping cycles can be achieved in concentrated sulfone-based electrolytes at a high CE over 98%, where nodule instead of dendritic Li deposition occurs. Furthermore, the viscosity and wettability issues of sulfones could be resolved by the addition of a fluorinated ether, which is a poor solvating agent for ionic species but well miscible with sulfones at microscopic scale. This localized high-concentration electrolyte (LHCE) not only provides further improvement in Li CE (to 98.8%), but also remains anodically stable with high voltage cathode and enables LMBs to operate in a wide temperature range. As a result, significantly improved cycling performance of LMBs using sulfone-based LHCE has been realized.

sulfone, concentrated electrolyte, localized high ↗

Evaluating a Concentrating Solar Power Plant as an Extended-Duration Peaking Resource

We explore the ability of a concentrating solar power (CSP) plant with thermal energy storage (TES) to provide peaking capacity. We focus on future power systems, wherein net load patterns may be significantly different than they are today (e.g., due to higher renewable-energy penetrations). We examine 28 locations in the southwestern United States over an 18-year period. The hourly operation of the CSP plants are simulated to determine their potential to provide energy during an eight-hour peak-load window for each day up to 365 days per year. Our result shows that for the large majority of locations and years, CSP plants with certain configurations (i.e., in terms of solar field and TES sizes) can provide nearly 100% peak-load capacity. We examine also the amount of supplemental energy (e.g., by using natural gas as a supplemental thermal-energy source) that would be required to ensure that a CSP plant could serve the eight highest-load hours of every day of the year. We find that in most cases, a CSP plant supplemented with natural gas would require less than 5% of the fuel that is used by a natural-gas fired power plant providing the same level of reliable capacity. A series of sensitivity analyses show that these results are robust to the number of peak-load hours and days that are considered and the configuration of the CSP plant.

14 SOLAR ENERGY↗

Surprising Relationship between Silicon Anode Calendar Aging and Electrolyte Components in a Localized High-Concentration Electrolyte System

Although localized high-concentration electrolytes (LHCEs) have been shown to improve the calendar lifetime of silicon anodes, the roles of the electrolyte constituents in calendar aging are not well understood. Here, in this work, we utilize a voltage hold protocol and an LHCE with varying molar ratios of lithium bis(fluorosulfonyl)imide (LiFSI), tetramethylene sulfone (TMS), and 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether (TTE) to probe the component roles during aging. Interestingly, the estimated calendar lifetime and irreversible lithium losses from the V-hold experiments are independent of the electrolyte formulations. Contrarily, the solid electrolyte interphase (SEI) composition depends on the electrolyte formulation. X-ray photoelectron spectroscopy shows that TMS-coordinated species decompose to form insoluble alkanes and lithium hydroxide (LiOH), while lithium fluoride (LiF) originates from the anion-coordination complex. The SEI composition does not appear to play a significant role in the silicon anode passivity, as measured by parasitic current, suggesting that the SEI-electrolyte interactions dictate the calendar aging mechanisms.

Si anode↗

Estimating the Capacity Value of Concentrating Solar Power Plants: A Case Study of the Southwestern United States

We estimate the capacity value of concentrating solar power (CSP) plants without thermal energy storage in the southwestern U.S. Our results show that CSP plants have capacity values that are between 45% and 95% of maximum capacity, depending on their location and configuration. We also examine the sensitivity of the capacity value of CSP to a number of factors and show that capacity factor-based methods can provide reasonable approximations of reliability-based estimates.

14 SOLAR ENERGY↗