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EPCAPE-PT-LANL Measurements: Scanning Mobility Particle Sizer

Coastal cities offer a unique environment for studying aerosol-cloud interactions and the effects of urban emissions on cloud properties. As part of the Eastern Pacific Cloud Aerosol Precipitation Experiment (EPCAPE), the Partitioning Thrust by Los Alamos National Laboratory (EPCAPE-PT-LANL) was conducted. Our campaign focused on measuring the optical and chemical properties of aerosols and their interactions within marine stratocumulus clouds in La Jolla, California. EPCAPE-PT-LANL enhances the primary goals of EPCAPE through innovative observations of vapor-phase transitions between aerosols and cloud droplets, the impact of black carbon on aerosol-cloud dynamics, and the effects of cloud processing on aerosol optical properties. Instrument: Scanning Mobility Particle Sizer (TSI), DMA Classifier Model 3082 + CPC Detector Model 3752. Data Notes: The SMPS dataset is limited due to necessary instrument maintenance and subsequent extensive downtime. Data is only available from October 21 to November 8, 2023. Post November 22, 2023, the NanoScan instrument provided coverage for the latter half of the campaign. To ensure consistency, the data was resampled into uniform size bins ranging from 15 nm to 667 nm. This adjustment was required due to changes in size bins and the maximum diameter that occurred after maintenance and repairs. Multiple Charge Correction applied, Nanoparticle Agglomerate Mobility Analysis not applied, and Diffusion Correction applied. Header: - List [15 nm to 667 nm] middle of the size bin in nanometers: Data reports the concentration particles in this size bin per cubic centimeter, dN/dLog(dp). - CVI_Flag[bool]: A boolean flag indicating whether the Counterflow Virtual Impactor (CVI) was active (true) or inactive (false) during the measurement.

54 ENVIRONMENTAL SCIENCES↗

The Vera C. Rubin Observatory Data Preview 1

We present Rubin Data Preview 1 (DP1), the first data from the National Science Foundation–Department of Energy Vera C. Rubin Observatory, comprising raw and calibrated single-epoch images, coadds, difference images, detection catalogs, and ancillary data products. DP1 is based on 1792 optical–near-infrared exposures acquired over 48 distinct nights by the Rubin Commissioning Camera (LSSTComCam) on the Simonyi Survey Telescope at the Summit Facility on Cerro Pachón, Chile in late 2024. DP1 covers ∼15 deg 2 distributed across seven roughly equal-sized noncontiguous fields, each independently observed in six broad photometric bands, ugrizy. The median FWHM of the point-spread function across all bands is approximately 1"14, with the sharpest images reaching about 0." 58. The 5σ point-source depths for coadded images in the deepest field, the Extended Chandra Deep Field South, are u = 24.55, g = 26.18, r = 25.96, i = 25.71, z = 25.07, and y = 23.1. Other fields are no more than 2.2 mag shallower in any band, where they have nonzero coverage. DP1 contains approximately 2.3 million distinct astrophysical objects, of which 1.6 million are extended in at least one band in coadds, and 431 solar system objects, of which 93 are new discoveries. DP1 is approximately 3.5 TB in size and is available to Vera C. Rubin Observatory data rights holders via the Rubin Science Platform, a cloud-based environment for the analysis of petascale astronomical data. While small compared to future LSST releases, its high quality and diversity of data support a broad range of early science investigations ahead of full operations in 2026.

Ground-based astronomy↗

Weather radar utility in hazard detection and response

Publicly accessible weather radar data have significant capabilities for meteorological measurements and predictions and, further, have the potential to measure nonmeteorological events that include smoke, ash, and debris plumes as well as explosions. The ability to identify and track nonmeteorological events can be of assistance in emergency response, hazard mitigation, and related activities in locations where radar coverage both exists and is recorded and accessible to the user. Here, in this study, events from multiple locations in the United States that are reported in news outlets are assessed using a manual inspection process of Level 2 weather radar data to identify anthropogenic and nonbiological returns. Explosive events are also identified, and a large high-altitude debris cloud from the intentional destruction of the SpaceX Starship is tracked across a wide area. Finally, future efforts using a machine learning model are discussed as a means of automating the process and potentially enabling near-real-time nonmeteorological event identification in the same areas where the data are accessible. Using weather radar data can be a valuable new tool for Department of Defense systems to aid in military awareness, and for interagency emergency response and forensic mission experts to consider national weather service data in their mission profiles. Radar data can be effective in detecting several common types of emergencies and inform and aid response personnel.

54 ENVIRONMENTAL SCIENCES↗

Stellar population models based on the SDSS-IV MaStar library of stellar spectra – I. Intermediate-age/old models

ABSTRACT We use the first release of the SDSS/MaStar stellar library comprising ∼9000, high S/N spectra, to calculate integrated spectra of stellar population models. The models extend over the wavelength range 0.36–1.03 µm and share the same spectral resolution ($R\sim 1800$) and flux calibration as the SDSS-IV/MaNGA galaxy data. The parameter space covered by the stellar spectra collected thus far allows the calculation of models with ages and chemical composition in the range $\rm {\mathit{ t}\gt 200 \,Myr, -2 \lt = [Z/H] \lt = + 0.35}$, which will be extended as MaStar proceeds. Notably, the models include spectra for dwarf main-sequence stars close to the core H-burning limit, as well as spectra for cold, metal-rich giants. Both stellar types are crucial for modelling λ > 0.7 µm absorption spectra. Moreover, a better parameter coverage at low metallicity allows the calculation of models as young as 500 Myr and the full account of the blue horizontal branch phase of old populations. We present models adopting two independent sets of stellar parameters (Teff, log g, [Z/H]). In a novel approach, their reliability is tested ‘on the fly’ using the stellar population models themselves. We perform tests with Milky Way and Magellanic Clouds globular clusters, finding that the new models recover their ages and metallicities remarkably well, with systematics as low as a few per cent for homogeneous calibration sets. We also fit a MaNGA galaxy spectrum, finding residuals of the order of a few per cent comparable to the state-of-art models, but now over a wider wavelength range.

Maraston, C.↗

Global Simulations Suggest Biomass Burning Aerosol Emissions From Grassland Fires Could Be Important Ice Nucleating Particles

Ice nucleating particles (INP) capable of nucleating ice crystals via immersion freezing at temperatures above approximately −35°C may strongly influence cloud glaciation, with implications for global precipitation and climate feedback. In addition to mineral dust, soil dust, and marine organics, laboratory and field measurements suggest biomass burning aerosols (BBA) can act as immersion-mode INP between around −30°C and −15°C. However, the contribution of BBA to the global INP budget remains poorly understood due to poor knowledge of which fuels yield INPs, uncertainties in global coverage of those fuels, and unknown size distributions of the INPs in the BBA. Nonetheless, with some understanding of these uncertainties from sensitivity studies, the relative importance of ice nucleation activity of BBA compared to other INP sources can be quantified. In this work, we investigate the potential global importance of BBA as INP using a global aerosol-climate model, specifically the UK Met Office Unified Model (UM). We evaluate the model using field campaign data sets. We examine potential uncertainties in fuel types and particle sizes on BBA-based INP concentrations. Averaged over June–September between 15°S and 50°S, BBA is a more important INP than dust and marine INP about 30% of the time at altitudes with temperatures between −30°C and −20°C. Our simulations therefore suggest BBA INPs may be at least as important as mineral dust and marine INP over the atmospheric regions and seasons where grassland fires are frequent.

Gohil, Kanishk [Carnegie Mellon University, Pittsb↗

Coastal-Fog Microphysics Using In-Situ Observations and GOES-R Retrievals

Here, the objective of this work is to evaluate GOES-R based fog conditions occurred during the C-FOG (Toward Improving Coastal Fog Prediction) field campaign. C-FOG is designed to advance understanding of fog formation, development, and dissipation over coastal environments to improve its predictability. The project took place along coastlines and open water environments of Eastern Canada (Nova Scotia, NS and the Island of Newfoundland, NL) during August-October of 2018 where environmental conditions play an important role for late season’s fog formation. During the C-FOG field campaign, instruments were located at the Ferryland Supersite, NL, with 2 main sites, and five satellite sites, as well as on the Research Vessel (R/V) Hugh R. Sharp. Key measurement instruments included a Gondola carrying a CDP (cloud droplet probe) and a BCP (backscatter cloud probe) was used for measuring droplet spectra from 1-75 µm on the R/V. A LPM (laser precipitation monitor) with 100 µm-1 cm size range and an OPC (optical particle counter) with 0.3-17 µm at 16 spectral channels provided information for fog and drizzle discrimination. Remote sensing platforms (e.g. profiling microwave radiometer, PMWR), Ceilometer, Lidar), meteorological towers, tethered balloons, and GOES-R products (e.g. fog coverage and droplet size and liquid water path) were used to evaluate fog over horizontal and vertical dimensions. Results suggest that effective radius, phase, liquid water path, and liquid water content values obtained from GOES-R and PMWR were comparable to ground based in-situ observations. It is concluded that integration of observations and nowcasting products may help improve short term local fog predictions.

54 ENVIRONMENTAL SCIENCES↗

Shortwave Array Spectroradiometer-Hemispheric (SAS-He): design and evaluation

A novel ground-based radiometer, referred to as the Shortwave Array Spectroradiometer-Hemispheric (SAS-He), is introduced. This radiometer uses the shadow-band technique to report total irradiance and its direct and diffuse components frequently (every 30 s) with continuous spectral coverage (350–1700 nm) and moderate spectral (~2.5 nm ultraviolet–visible and ~6 nm shortwave-infrared) resolution. The SAS-He's performance is evaluated using integrated datasets collected over coastal regions during three field campaigns supported by the US Department of Energy's Atmospheric Radiation Measurement (ARM) program, namely the (1) Two-Column Aerosol Project (TCAP; Cape Cod, Massachusetts), (2) Tracking Aerosol Convection Interactions Experiment (TRACER; in and around Houston, Texas), and (3) Eastern Pacific Cloud Aerosol Precipitation Experiment (EPCAPE; La Jolla, California). We compare (i) aerosol optical depth (AOD) and total optical depth (TOD) derived from the direct irradiance, as well as (ii) the diffuse irradiance and direct-to-diffuse ratio (DDR) calculated from two components of the total irradiance. As part of the evaluation, both AOD and TOD derived from the SAS-He direct irradiance are compared to those provided by a collocated Cimel sunphotometer (CSPHOT) at five (380, 440, 500, 675, 870 nm) and two (1020, 1640 nm) wavelengths, respectively. Additionally, the SAS-He diffuse irradiance and DDR are contrasted with their counterparts offered by a collocated multifilter rotating shadowband radiometer (MFRSR) at six (415, 500, 615, 675, 870, 1625 nm) wavelengths. Overall, reasonable agreement is demonstrated between the compared products despite the challenging observational conditions associated with varying aerosol loadings and diverse types of aerosols and clouds. For example, the AOD- and TOD-related values of root mean square error remain within 0.021 at 380, 440, 500, 675, 870, 1020, and 1640 nm wavelengths during the three field campaigns.

47 OTHER INSTRUMENTATION↗

Processed Surface Imagery & Raster Imagery taken onboard TigerShark (U3) UAS

Land-surface orthomosaic imagery derived from the images collected using the Micasense Altum Imager on board the UAS TigerShark (U3) on March 11th, 2021 at an altitude of 2000 ft. The Altum takes images of the land surface across five visible bands and one long wave infrared thermal band. The photogrametry software Agisoft PhotoScan v 1.4 is used to align and stitch the images into a larger composet image using the technique of structure from motion image capture to construct a dense cloud and 3-D model of the surface, which is used to produce a digital elevation model of the terraine surveyed and orthomosaic imagery. This dataset contains the raster calculated orthomosaics of various vegetative indicies, which are used to indicate plant health and land surface characteristics, including Normalized Difference Vegetation Index (NDVI), Green Normalized Difference Vegetation Index (GNDVI), Normalized Difference Water Index (NDWI), surface temperature, and Enhanced_vegetation_index (EVI). These orthomosaics were collected west of the Starkville, MS, airport, and include natural, agricultural, and industrial land coverage. The images have a resolution of 0.2 m/pix.

54 ENVIRONMENTAL SCIENCES↗

Transition of Large-Scale Environmental Conditions and Characteristics of Four Rainfall Types Observed by S-PolKa During the MJO-1 Active Phase of DYNAMO/CINDY/AMIE

Analyses of National Center for Atmospheric Research (NCAR) S-PolKa dual-polarization radar data and ERA5 reanalysis fields indicate gradual changes in convection characteristics and large-scale environmental conditions during a central Indian Ocean Madden-Julian Oscillation (MJO) event observed by the DYNAMO/CINDY/AMIE field campaigns in late October 2011 (MJO-1). Examination of four rainfall types (isolated convective cores, convective, mixed, and stratiform) reveals a transition of convection characteristics (i.e., areal coverage and depth) between distinct 5-day environmental periods at the beginning and end of this ~2-week MJO active phase. A shift toward less frequent rainfall covering less of the radar domain for all four rainfall types occurs when large-scale lower-tropospheric dry air advects into the region with the westerly wind burst (WWB). Drier and warmer lower-free-tropospheric conditions associated with the WWB contribute to increased large-scale surface-based convective inhibition (CIN), surface-based convective available potential energy (CAPE), and cloud base heights. A thermodynamic budget analysis indicates reduced surface heat fluxes contribute to the increased surface-based CAPE. Greater CAPE at the end of MJO-1 coincides with deeper 50-dBZ convective echoes, while decreased 10-dBZ depth for all rainfall types corresponds in time with WWB-related dry-air advection. Increased (decreased) reflectivity values in the lower-level vertical reflectivity distribution of convective (stratiform) precipitation indicate increased (decreased) convective (stratiform) intensities when the WWB is present. The opposite depth changes for convective echoes and opposite shifts in convective and stratiform precipitation intensities underscore how the WWB can have differing impacts at different reflectivity thresholds and stages of the deep convection lifecycle.

54 ENVIRONMENTAL SCIENCES↗

Evaluation of a Stochastic Mixing Scheme in the Deep Convective Gray Zone Using a Tropical Oceanic Deep Convection Case Study

Abstract A stochastic horizontal subgrid‐scale mixing scheme is evaluated in ensemble simulations of a tropical oceanic deep convection case using a horizontal grid spacing (Δ h ) of 3 km. The stochastic scheme, which perturbs the horizontal mixing coefficient according to a prescribed spatiotemporal autocorrelation scale, is found to generally increase mesoscale organization and convective intensity relative to a non‐stochastic control simulation. Perturbations applied at relatively short autocorrelation scales induce differences relative to the control that are more systematic than those from perturbations applied at relatively long scales that yield more variable outcomes. A simulation with mixing enhanced by a constant factor of 4 significantly increases mesoscale organization and convective intensity, while turning off horizontal subgrid‐scale mixing decreases both. Total rainfall is modulated by a combination of mesoscale organization, areal coverage of convection, and convective intensity. The stochastic simulations tend to behave more similarly to the constant enhanced mixing simulation owing to greater impacts from enhanced mixing as compared to reduced mixing. The impacts of stochastic mixing are robust, ascertained by comparing the stochastic mixing ensembles with a non‐stochastic mixing ensemble that has grid‐scale noise added to the initial thermodynamic field. Compared to radar observations and a higher resolution Δ h = 1 km simulation, stochastic mixing seemingly degrades the simulation performance. These results imply that stochastic mixing produces non‐negligible impacts on convective system properties and evolution but does not lead to an improved representation of convective cloud characteristics in the case studied here.

54 ENVIRONMENTAL SCIENCES↗

Multi-scale integration of satellite remote sensing improves characterization of dry-season green-up in an Amazon tropical evergreen forest

In tropical forests, leaf phenology-particularly the pronounced dry-season green-up-strongly regulates biogeochemical cycles of carbon and water fluxes. However, uncertainties remain in the understanding of tropical forest leaf phenology at different spatial scales. Phenocams accurately characterize leaf phenology at the crown and ecosystem scales but are limited to a few sites and time spans of a few years. Time-series satellite observations might fill this gap, but the commonly used satellites (e.g. MODIS, Landsat and Sentinel-2) have resolutions too coarse to characterize single crowns. To resolve this observational challenge, we used the PlanetScope constellation with a 3m resolution and near daily nadir-view coverage. We first developed a rigorous method to cross-calibrate PlanetScope surface reflectance using daily BRDF-adjusted MODIS as the reference. We then used linear spectral unmixing of calibrated PlanetScope to obtain dry-season change in the fractional cover of green vegetation (GV) and non-photosynthetic vegetation (NPV) at the PlanetScope pixel level. We used the Central Amazon Tapajos National Forest k67 site, as all necessary data (from field to phenocam and satellite observations) was available. For this proof of concept, we chose a set of 22 dates of PlanetScope measurements in 2018 and 16 in 2019, all from the six drier months of the year to provide the highest possible cloud-free temporal resolution. Our results show that MODIS-calibrated dry-season PlanetScope data (1) accurately assessed seasonal changes in ecosystem-scale and crown-scale spectral reflectance; (2) detected an increase in ecosystem-scale GV fraction (and a decrease in NPV fraction) from June to November of both years, consistent with local phenocam observations with R 2 around 0.8; and (3) monitored large seasonal trend variability in crown-scale NPV fraction. Finally, our results highlight the potential of integrating multi-scale satellite observations to extend fine-scale leaf phenology monitoring beyond the spatial limits of phenocams.

54 ENVIRONMENTAL SCIENCES↗

DSCOVR/EPIC-derived global hourly and daily downward shortwave and photosynthetically active radiation data at 0.1° × 0.1° resolution

Downward shortwave radiation (SW) and photosynthetically active radiation (PAR) play crucial roles in Earth system dynamics. Spaceborne remote sensing techniques provide a unique means for mapping accurate spatiotemporally continuous SW–PAR, globally. However, any individual polar-orbiting or geostationary satellite cannot satisfy the desired high temporal resolution (sub-daily) and global coverage simultaneously, while integrating and fusing multisource data from complementary satellites/sensors is challenging because of co-registration, intercalibration, near real-time data delivery and the effects of discrepancies in orbital geometry. The Earth Polychromatic Imaging Camera (EPIC) on board the Deep Space Climate Observatory (DSCOVR), launched in February 2015, offers an unprecedented possibility to bridge the gap between high temporal resolution and global coverage and characterize the diurnal cycles of SW–PAR globally. In this study, we adopted a suite of well-validated data-driven machine-learning models to generate the first global land products of SW–PAR, from June 2015 to June 2019, based on DSCOVR/EPIC data. The derived products have high temporal resolution (hourly) and medium spatial resolution (0.1°×0.1°), and they include estimates of the direct and diffuse components of SW–PAR. We used independently widely distributed ground station data from the Baseline Surface Radiation Network (BSRN), the Surface Radiation Budget Network (SURFRAD), NOAA's Global Monitoring Division and the U.S. Department of Energy's Atmospheric System Research (ASR) program to evaluate the performance of our products, and we further analyzed and compared the spatiotemporal characteristics of the derived products with the benchmarking Clouds and the Earth's Radiant Energy System Synoptic (CERES) data. We found both the hourly and daily products to be consistent with ground-based observations (e.g., hourly and daily total SWs have low biases of -3.96 and -0.71 W m -2 and root-mean-square errors (RMSEs) of 103.50 and 35.40 W m -2 , respectively). The developed products capture the complex spatiotemporal patterns well and accurately track substantial diurnal, monthly, and seasonal variations in SW–PAR when compared to CERES data. They provide a reliable and valuable alternative for solar photovoltaic applications worldwide and can be used to improve our understanding of the diurnal and seasonal variabilities of the terrestrial water, carbon and energy fluxes at various spatial scales.

54 ENVIRONMENTAL SCIENCES↗

A Near-infrared Chemical Inventory of the Atmosphere of 55 Cancri e

We present high-resolution near-infrared spectra taken during eight transits of 55 Cancri e, a nearby low-density super-Earth with a short orbital period (<18 hr). While this exoplanet’s bulk density indicates a possible atmosphere, one has not been detected definitively. Our analysis relies on the Doppler cross-correlation technique, which takes advantage of the high spectral resolution and broad wavelength coverage of our data, to search for the thousands of absorption features from hydrogen-, carbon-, and nitrogen-rich molecular species in the planetary atmosphere. Although we are unable to detect an atmosphere around 55 Cancri e, we do place strong constraints on the levels of HCN, NH{sub 3}, and C{sub 2}H{sub 2} that may be present. In particular, at a mean molecular weight of 5 amu, we can rule out the presence of HCN in the atmosphere down to a volume mixing ratio (VMR) of 0.02%, NH{sub 3} down to a VMR of 0.08%, and C{sub 2}H{sub 2} down to a VMR of 1.0%. If the mean molecular weight is relaxed to 2 amu, we can rule out the presence of HCN, NH{sub 3}, and C{sub 2}H{sub 2} down to VMRs of 0.001%, 0.0025%, and 0.08%, respectively. Our results reduce the parameter space of possible atmospheres consistent with the analysis of Hubble Space Telescope/WFC3 observations by Tsiaras et al. and indicate that if 55 Cancri e harbors an atmosphere, it must have a high mean molecular weight or clouds.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Extraordinary March 2022 East Antarctica “Heat” Wave. Part II: Impacts on the Antarctic Ice Sheet

Abstract Between 15 and 19 March 2022, East Antarctica experienced an exceptional heat wave with widespread 30°–40°C temperature anomalies across the ice sheet. In Part I, we assessed the meteorological drivers that generated an intense atmospheric river (AR) that caused these record-shattering temperature anomalies. Here, we continue our large collaborative study by analyzing the widespread and diverse impacts driven by the AR landfall. These impacts included widespread rain and surface melt that was recorded along coastal areas, but this was outweighed by widespread high snowfall accumulations resulting in a largely positive surface mass balance contribution to the East Antarctic region. An analysis of the surface energy budget indicated that widespread downward longwave radiation anomalies caused by large cloud-liquid water contents along with some scattered solar radiation produced intense surface warming. Isotope measurements of the moisture were highly elevated, likely imprinting a strong signal for past climate reconstructions. The AR event attenuated cosmic ray measurements at Concordia, something previously never observed. Last, an extratropical cyclone west of the AR landfall likely triggered the final collapse of the critically unstable Conger Ice Shelf while further reducing an already record low sea ice extent. Significance Statement Using our diverse collective expertise, we explored the impacts from the March 2022 heat wave and atmospheric river across East Antarctica. One key takeaway is that the Antarctic cryosphere is highly sensitive to meteorological extremes originating from the midlatitudes and subtropics. Despite the large positive temperature anomalies driven from strong downward longwave radiation, this event led to huge amounts of snowfall across the Antarctic interior desert. The isotopes in this snow of warm airmass origin will likely be detectable in future ice cores and potentially distort past climate reconstructions. Even measurements of space activity were affected. Also, the swells generated from this storm helped to trigger the final collapse of an already critically unstable Conger Ice Shelf while further degrading sea ice coverage.

Wille, Jonathan D.↗

TRACER Carbonaceous Aerosols Thrust – University of California, Davis Field Campaign Report

The broader U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility’s TRacking Aerosol Convection interactions ExpeRiment (TRACER) campaign aims to increase our understanding of convective cloud life cycles and aerosol-convection interactions. Our TRACER Carbonaceous Aerosols Thrust-University of California, Davis (TRACER-CAT-UCDavis) study complemented these broader aims by characterizing and quantifying the optical properties and composition of carbonaceous aerosols during part of the TRACER intensive sampling period (July 1- July 31, 2022) at the first ARM Mobile Facility (AMF1) main site (M1) in La Porte, Texas. Our measurements complemented the suite of instrumentation already provided by the AMF1, expanding the capabilities through deployment of unique, state-of-the-science instrumentation. The instrumentation included: (i) two cavity-attenuated phase shift spectroscopy single-scatter albedo (CAPS-SSA) instruments operating at 530 nm and 630 nm, and that were modified to characterize particle light absorption, extinction, and scattering at elevated humidities; (ii) the UC Davis dual-wavelength cavity ringdown-photoacoustic spectrometer (CRD-PAS), which characterizes dry particle extinction and absorption at 405 nm and 532 nm; (iii) a soot particle aerosol mass spectrometer (SP-AMS) that operated in “laser only” mode that characterized the size-dependent compositions of black carbon (BC)-containing particles; (v) a thermal denuder, to remove coatings on particles; and (vi) a scanning electrical mobility sizer (SEMS), to characterize particle mobility diameters from 10-1300 nm. Our measurements occurred alongside complementary observations made by Los Alamos National Laboratory (LANL) during the TRACER-CAT-LANL study, including a humidified CAPS-SSA instrument operating at 450 nm. Our primary scientific interest is in understanding the relationship between particle composition and light absorption, with a particular focus on the influence of water uptake. While it is known that coatings on BC can enhance absorption, the extent to which this occurs in the atmosphere and the specific role that water plays as a coating remain unclear. The TRACER-CAT-UCDavis measurements were made with near-complete coverage for the CRD-PAS, SP-AMS, and SEMS throughout the intensive period. The UC Davis humidified CAPS-SSA instruments had significant challenges with operation owing to the demanding conditions (large temperature fluctuations, high humidity), exacerbated by supply chain issues that delayed resolution of these challenges. However, the humidified CAPS-SSA instrument operated by LANL operated throughout the intensive period with near-complete coverage. The dry light extinction measurements from the CRD-PAS measurements and the LANL CAPS-SSA exhibited a good correlation, although the CAPS-SSA systematically measured greater extinction values than expected. While all instruments, with the exception of an aerodynamic particle sizer (APS), measured behind a common particulate matter (PM)2.5 μm cyclone, the greater extinction measured by the LANL CAPS-SSA compared to the CRD-PAS may have resulted from different losses of larger particles in the sampling lines from the cyclone to the instruments; the tubing length was shorter from the cyclone to the LANL CAPS-SSA, consistent with this idea. A summary of the TRACER-CAT-UCDavis measurements, along with some of the TRACER-CAT-LANL measurements, are shown in the figure below. Notably, there were periods when the contributions of presumed dust were substantial and even dominated the observed light extinction and absorption. Also, there was a clear shift in the behavior of submicron particles from before July 16, 2022 to after, with the prior period exhibiting regular episodes of new particle formation and the latter period exhibiting rapid variations in the concentrations of small particles.

54 ENVIRONMENTAL SCIENCES↗

CHESS 2025: Waveform LiDAR data from NEON AOP surveys

This dataset provides Level 1 (L1) full-waveform light detection and ranging (LiDAR) data collected for the 2025 Colorado Headwaters Ecological Spectroscopy Study (CHESS). These data were acquired to enable characterization of vegetation structure and other three-dimensional features of the land surface, and to evaluate structural changes that may have occurred between a prior LiDAR acquisition in 2018 and the 2025 overflight. Waveform LiDAR data can provide more detailed information about objects on the ground than discrete point clouds typically do, and they are often used for granular target segmentation and characterization of subcanopy vegetation. The data were acquired over three study domains in the Upper Gunnison river basin: the upper East River watershed (CRBU); Almont Triangle and Taylor Canyon (ALMO); and Upper Taylor River watershed (UPTA) between 2025-06-13 and 2025-07-15. LiDAR data were acquired using the Optech Galaxy Prime Airborne LiDAR Terrain Mapper onboard the National Ecological Observatory Network (NEON) Airborne Observation Platform (AOP). These are the primary waveform LiDAR data delivered by NEON and are provided per flightline in compressed Pulsewaves format, an open-source binary file standard. A Pulsewaves object comprises a two files: a pulse (.pls) file, which stores the geographic origin, outgoing vector, and metadata for every laser pulse emitted by the scanner, and a wave file (.wvs), which stores the sequential amplitude samples of the outgoing pulse and the returning signals. The files are published here in their compressed forms (.plz, .wvz). All waveform data were processed following the theoretical workflow described in the NEON L0-to-L1 Waveform LiDAR Algorithm Theoretical Basis Document (Krause and Goulden 2022a); however, the Pulsewaves output format differs from a legacy format described in that document. Waveform amplitude samples are recorded at 1 nanosecond intervals. All coordinates are provided in meters. Horizontal coordinates are referenced in Universal Transverse Mercator (UTM) zone 13N and the World Geodetic System (WGS) 1984 ensemble datum. Elevations are referenced to Geoid12A. Waveform data for the UPTA survey area were collected without incident and the published records are complete. However, both the ALMO and CRBU collections experienced issues that resulted in incomplete data for those areas. On collection day 2018-06-16 a hardware failure caused the waveform digitizer to lose data from the eastern edge of the ALMO site (Figure 22). The waveform data for flightlines 2–20 could not be extracted from the digitizer, and the data proved unrecoverable. As a result, a portion of the site does not have coverage with waveform data. Although no hardware failure was observed during collection over the CRBU area, final waveform files generated by vendor software contained only ~25% of the expected number of return pulses. After discovery, NEON initiated troubleshooting with the vendor. The root cause of the data ablation had not been identified at the time of publication. Additional data will be published in an update to this package if further recovery proves successful. CHESS Project Description: The Colorado Headwaters Ecological Spectroscopy Study (CHESS) comprised a multi-week airborne remote sensing and field observation campaign in the Upper Gunnison Basin, Colorado, conducted in June and July of 2025. Airborne remote sensing was conducted by the National Ecological Observatory Network Airborne Observation Platform (NEON AOP), concurrent with a field campaign run by the Rocky Mountain Biological Laboratory (RMBL), the Lawrence Berkeley National Laboratory (LBNL) and SLAC National Accelerator Laboratory Watershed Function Science Focus Area (SFA), and NASA-JPL (Jet Propulsion Laboratory) Earth Surface Mineral Dust Source Investigation (EMIT) program. Between June 10 and July 18, 2025, the NEON AOP flight team collected high-resolution aerial imaging spectroscopy and Light Detection and Ranging (LiDAR) data over three domains: the Upper East River (CRBU), Almont Triangle (ALMO), and the Upper Taylor Basin (UPTA). In coordination with the flights, a field campaign acquired ground-truth observations, including observations of vegetation composition, foliar traits, forest demography, and subsurface properties in 18 core sampling areas within the domains. Additional surface water observations were taken at over 380 point locations. All CHESS campaign datasets can be found within the CHESS ESS-DIVE data portal: https://data.ess-dive.lbl.gov/portals/chess. Funding Acknowledgement: Field and remote-sensing data acquisition was performed under a grant from the National Aeronautics and Space Administration (80NSSC24K1005). This work was also supported by the Watershed Function Science Focus Area at Lawrence Berkeley National Laboratory funded by the US Department of Energy, Office of Science, Biological and Environmental Research under Contract No. DE-AC02-05CH11231.

2018 NEON and 2025 CHESS Campaigns↗

CSAPR2 cell-tracking data collected during TRACER

One of the challenges of analyzing convective cell properties is quick evolution of the individual convective cells. While the operational radar data provide great a data set to analyze the evolution of radar observables of convective precipitation clouds statistically, previous studies also suggested that, because of the quick evolution of cell life cycle, conventional radar volume scan strategies taking ~5-7 minutes might not capture the detailed evolution. The TRACER campaign deployed CSAPR2, which performed frequent update of RHI and sector PPI scans to track convective cells every < 2 minutes guided by a new cell-tracking framework, Multisensor Agile Adaptive Sampling (MAAS; Kollias et al. 2020). This allows for capturing fast-evolving radar observables. The submitted data files are CSAPR2 data in CfRadial format collected during the TRACER field campaign from June to September 2020. The data files include processed radar variables including: noise-masked reflectivity and differential reflectivity corrected for rain attenuation and systematic biases, noise-masked dealiased radial velocity, specific differential phase, locations of target cells (latitude, longitude, radar range), and radar-echo classification.

54 ENVIRONMENTAL SCIENCES↗

Influence of Lake Ice Biases in Reanalysis Data on Downscaled Climate Simulations over the Great Lakes Region

This data package contains observation-based and model-simulated datasets (all provided in NetCDF format) for evaluating how wintertime lake-ice representation affects regional weather and climate over the Laurentian Great Lakes (freshwater lake ecosystem) during the high–ice-cover winter of 2009. The observational component includes: (1) Stage IV gridded precipitation at 4 km, hourly resolution for January–February 2009 over the Great Lakes region (radar–gauge multisensor precipitation analyses); (2) Great Lakes Surface Environmental Analysis (GLSEA) satellite-derived lake-ice coverage at 1.3 km, daily resolution for the 2009 winter months, providing ice coverage over Lakes Superior, Michigan, Huron, Erie, and Ontario; and (3) in situ measurements at the Standard Rock site on Lake Superior from the Great Lakes Evaporation Network (GLEN) at hourly resolution, including near-surface atmospheric variables and sensible and latent heat fluxes (air–lake exchange) at a fixed point location. The modeling component provides corresponding fields from two simulations, both archived at 4 km, hourly resolution: a standalone Weather Research Forecasting model (WRF) run driven by the European Centre for Medium-Range Weather Forecasts (ECMWF) Reanalysis 5 (ERA5), and a two-way coupled model using WRF and the Finite Volume Community Ocean Model (WRF-FVCOM, a 3-D hydrodynamic lake model). These outputs include variables relevant to air–lake interaction and lake-effect processes (e.g., near-surface temperature, humidity, wind, precipitation, and surface turbulent fluxes), enabling direct comparison with the observational datasets. Users can analyze and visualize these NetCDF files with common tools such as Python (e.g., xarray, netCDF4, numpy, pandas), NCO/CDO, Panoply, or ncview; NetCDF variables can also be converted to other formats (e.g., CSV, GeoTIFF) using these utilities.

EARTH SCIENCE > ATMOSPHERE > ATMOSPHERIC TEMPERATU↗