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At least 91 records · Page 5

Experimental investigation of the excess charge and time constant of minority carriers in the thin diffused layer of 0.1 Ohm-cm silicon solar cells

The observed low open-circuit voltage in 0.1 Ohm-cm solar cells is probably related to an excessively high diode saturation current. Theoretical studies conducted by Lindholm et al. (1975) and by Godlewski et al. (1975) have shown that a high saturation current could be produced by either high recombination rates or bandgap narrowing effects. A description is given of an investigation which shows that bandgap narrowing effects have a first order significance in determining the charge carrier transport controlling the open-circuit voltage of 0.1 Ohm-cm silicon solar cells.

Godlewski, M. P.↗

Design Analysis of the Ares 1 Pogo Accumulator

Several accumulator designs and gas charge systems are considered in order to suppress POGO within the Ares I vehicle Upper Stage Liquid Ox ygen System. The thermodynamic and flow analysis completed to evaluat e candidate designs are presented and the results are used to evaluat e the ability of each concept to meet the levied suppression requirements. One annular accumulator design meets all suppression requirement s while also providing manufacturability and operability advantages. Of the two proposed charge systems to provide and maintain gas within the accumulator, a passive level control design meets the charge req uirements and maximizes reliability.

Swanson, Luke A.↗

Working Group Reports and Presentations: Cis-lunar

Space agencies are committed to the "safe, sustained, affordable human and robotic exploration of the Moon, Mars, and beyond." However, we recommend that they explicitly define our ultimate goal and motivation in order to portray a sense of purpose to the public. Our goal is sustainable human settlement of the Moon and Mars and our motivation is to preserve the human race. All secondary exploration and science objectives flow from this main goal and are still imperative to our success. As an economic guiding principle, governments should be limited to those areas where only government can perform the activity and should recognize and coordinate with the larger private and military sectors. Also, space agencies must continue to fund the interdisciplinary science necessary to characterize environmental hazards associated with dust, radiation, surface charging, topology, and meteorites in order to make our first attempts at extraterrestrial living viable.

Laubscher, Bryan↗

A Closer Look at Solar Wind Sputtering of Lunar Surface Materials

Solar-wind induced potential sputtering of the lunar surface may be a more efficient erosive mechanism than the "standard" kinetic (or physical) sputtering. This is partly based on new but limited laboratory measurements which show marked enhancements in the sputter yields of slow-moving, highly-charged ions impacting oxides. The enhancements seen in the laboratory can be orders of magnitude for some surfaces and highly charged incident ions, but seem to depend very sensitively on the properties of the impacted surface in addition to the fluence, energy and charge of the impacting ion. For oxides, potential sputtering yields are markedly enhanced and sputtered species, especially hydrogen and light ions, show marked dependence on both charge and dose.

Barghouty, A. F.↗

Thin electrostatically self-focusing electron streams.

Study of 30 to 380 microampere, 50 to 550 V, 1 to 2 mm, electrostatically self-focusing electron streams (50 cm long) drifting through mercury vapor (at 50 microtorr to 2 millitorr) in a tube with a radius of 6.6 cm. The inside surface of the tube is coated with a transparent layer whose resistivity is 50 ohm-cm per centimeter. In order to determine the charged-particle densities and the potential profile in and around the beam without disturbing the system, a multigrid electrostatic charged particle energy analyzer was used to study separately the energy distributions of both ions and electrons ejected radially from the beam. The results show two energy groupings for electrons. The energy distribution of the high-energy group is produced by ionizing collisions between beam electrons and neutral gas atoms; a group of flow-energy electrons becomes trapped in the potential well within and around the beam, subsequently escaping by collisional mechanisms.

Mccorkle, R. A.↗

Improved multiple-shot gun for use as a combustion stability rating device

A program was conducted to develop and experimentally evaluate an improved version of a modified machine gun for use as a device for rating the relative combustion stability of various rocket combustors. Following the results of a previous study involving a caliber .30 machine gun, a caliber .50 machine gun was modified in order to extend the charge-size range of the device. Nitrocellulose charge sizes ranging from 1.004 to 9.720 grams were fired at rates up to four shots per second. Shock pressures up to 25,512 kN/sq m were measured near the end of a shortened gun barrel. A minimal resistance type of check valve permitted the gun to fire into pressurized regions; back pressures up to 3448 kN/sq m abs were tested. The final modified assembly was evaluated during combustion stability tests on rocket combustors burning a FLOX-methane propellant combination.

Sokolowski, D. E.↗

Elemental composition of solar energetic particles in 1977 and 1978

The elemental composition of energetic nuclei from seven major solar flare events were measured wit the cosmic ray detector systems aboard the Voyager 1 and 2 spacecraft. The energetic nuclei abundances differ significantly from those of photospheric material. They are enhanced relative to the photonsphere by a factor which is the ratio of abundance of an energetic nuclei species (relative to oxygen) over the corresponding abundance of photospheric material. This factor is common to all events and has a nonmonochromatic characteristic dependence on nuclear charge. This factor is roughly ordered by first ionization potential into two groups of elements, metallics and volatiles.

Cook, W. R.↗

Structure-activity correlations for organophosphorus ester anticholinesterases. Part 2: CNDO/2 calculations applied to ester hydrolysis rates

Quantitative structure-activity relationships are presented for the hydrolysis of organophosphorus esters, RR'P(O)X, where R and R' are alkyl and/or alkoxy groups and X is fluorine, chlorine or a phenoxy group. CNDO/2 calculations provide values for molecular parameters that correlate with alkaline hydrolysis rates. For each subset of esters with the same leaving group, X, the CNDO-derived net atomic charge at the central phosphorus atom correlates well with the alkaline hydrolysis rate constants. For the whole set of esters with different leaving groups, equations are derived that relate charge, orbital energy and bond order to the hydrolysis rate constants.

Johnson, H.↗

Effects of non-Maxwellian electron velocity distribution functions and nonspherical geometry on minor ions in the solar wind

A previous model has shown that in order to account for the charge state distribution in the low-speed solar wind, a high coronal temperature is necessary and that this temperature peak goes together with a peak of nx/np in the corona. In the present paper, one of the assumptions made previously, i.e., that coronal electrons are Maxwellian, is relaxed, and a much cooler model is presented, which could account for the same oxygen charge states in the solar wind due to the inclusion of non-Maxwellian electrons. Also, due to a different choice of the coronal magnetic field geometry, this model would show no enhancement of the coronal nx/np. Results of the two models are then compared, and observational tests to distinguish between the two scenarios are proposed: comparison of directly measured coronal Te to charge state measurements in the solar wind, determination of the coronal nx/np measurement of ion speeds in the acceleration region of the solar wind, and measurement of the frozen-in silicon charge state distribution.

Burgi, A.↗

Secondary Li battery incorporating 12-Crown-4 ether

A rechargeable lithium battery which utilizes a polyethylene oxide (PEO) solid polymeric electrolyte complexed with a lithium salt is disclosed. The conductivity is increased an order of magnitude and interfacial charge transfer resistance is substantially decreased by incorporating a minor amount of 12-Crown-4 ether in the PEO-lithium salt solid electrolyte film. Batteries containing the improved electrolyte permit operation at a lower temperature with improved efficiency.

Nagasubramanian, Ganesan↗

The (FHCl)- molecular anion - Structural aspects, global surface, and vibrational eigenspectrum

State of the art ab initio electronic structure methods have been used to investigate the (FHCl)- molecular anion. It is proposed that the geometric structure and binding energies of the complex are r(e)(H-F) = 0.963 +/- 0.003 A, R(e)(H-Cl) = 1.925 +/- 0.015 A, and D0(HF + Cl(-)) = 21.8 +/- 0.4 kcal/mol. A Morokuma decomposition of the ion-molecular bonding give the following electrostatic, polarization, exchange repulsion, dispersion, and charge-transfer plus higher-order mixing components of the vibrationless complexation energy: -27.3, -5.2, +18.3, -4.5, and -5.0 kcal/mol, respectively. A couples cluster single and doubles global surface is constructed from 208 and 228 energy points for linear and bent configurations, respectively, these being fit to rms errors of only 3.9 and 9.3/cm, respectively, below 8000/cm. Converged J = 0 and J = 1 variational eigenstates of the (FHCl)- surface to near the HF + Cl(-) dissociation threshold are determined. The fundamental vibrational frequencies are found to be nu1 = 247/cm, nu2 = 876/cm, and nu3 = 2884/cm. The complete vibrational eigenspectrum is analyzed.

Klepeis, Neil E.↗

Boson localization and universality in YBa2Cu(3-x)M(x)O(7-delta)

We consider a two component mixture of charged fermions on neutralizing background with all sign combinations and arbitrarily small mass ratios. In the two impurity limit for the heavier component we show that the pair forms a bound state for all charge combinations. In the lowest order approximation we derive a closed form expression Veff(r) for the binding potential which has short-range repulsion followed by attraction. In the classical limit, when the mass of embedded particles is large m2 much greater than m, we can calculate from Veff(r) also the cohesive energy E and the bond length R of a metallic crystal such as lithium. The lowest order result is R = 3.1 A, E = -0.9 eV, not entirely different from the experimental result for lithium metal. The same interaction for two holes on a parabolic band with m2 greater than m gives the quantum mechanical bound state which one may interpret as a boson or local pair in the case of high-Te and heavy fermion superconductors. We also show that for compounds of the type YBa2Cu(3 - x)M(x)O(7 - delta) one can understand most of the experimental results for the superconducting and normal states with a single temperature dependent boson breaking function f(T) for each impurity content x governing the decay of bosons into pairing fermions. In the normal state f(T) turns out to be a linear, universal function, independent of the impurity content I and the oxygen content delta. We predict with universality a depression in Tc(x) with slight down bending in agreement with experiment. As a natural consequence of the model the bosons become localized slightly above Tc due to the Wigner crystallization, enhanced with lattice local field minima. The holes remain delocalized with a linearly increasing concentration in the normal state, thus explaining the rising Hall density. The boson localization temperature T(sub BL) shows up as a minimum in the Hall density R(sub ab)(exp -1). We also give explanation for very recently observed scaling of temperature dependent Hall effect in La(2 - x)Sr(x)CuO4.

Kallio, A.↗

Spacecraft Charging Calculations: NASCAP-2K and SEE Spacecraft Charging Handbook

For fifteen years NASA and the Air Force Charging Analyzer Program for Geosynchronous Orbits (NASCAP/GEO) has been the workhorse of spacecraft charging calculations. Two new tools, the Space Environment and Effects (SEE) Spacecraft Charging Handbook (recently released), and Nascap-2K (under development), use improved numeric techniques and modern user interfaces to tackle the same problem. The SEE Spacecraft Charging Handbook provides first-order, lower-resolution solutions while Nascap-2K provides higher resolution results appropriate for detailed analysis. This paper illustrates how the improvements in the numeric techniques affect the results.

Davis, V. A.↗

Asymptotic Energies and QED Shifts for Rydberg States of Helium

This paper reviews progress that has been made in obtaining essentially exact solutions to the nonrelativistic three-body problem for helium by a combination of variational and asymptotic expansion methods. The calculation of relativistic and quantum electrodynamic corrections by perturbation theory is discussed, and in particular, methods for the accurate calculation of the Bethe logarithm part of the electron self energy are presented. As an example, the results are applied to the calculation of isotope shifts for the short-lived 'halo' nucleus He-6 relative to He-4 in order to determine the nuclear charge radius of He-6 from high precision spectroscopic measurements carried out at the Argonne National Laboratory. The results demonstrate that the high precision that is now available from atomic theory is creating new opportunities to create novel measurement tools, and helium, along with hydrogen, can be regarded as a fundamental atomic system whose spectrum is well understood for all practical purposes.

Drake, G.W.F.↗

Electric propulsion system technology

The work performed in fiscal year (FY) 1991 under the Propulsion Technology Program RTOP (Research and Technology Objectives and Plans) No. (55) 506-42-31 for Low-Thrust Primary and Auxiliary Propulsion technology development is described. The objectives of this work fall under two broad categories. The first of these deals with the development of ion engines for primary propulsion in support of solar system exploration. The second with the advancement of steady-state magnetoplasmadynamic (MPD) thruster technology at 100 kW to multimegawatt input power levels. The major technology issues for ion propulsion are demonstration of adequate engine life at the 5 to 10 kW power level and scaling ion engines to power levels of tens to hundreds of kilowatts. Tests of a new technique in which the decelerator grid of a three-grid ion accelerator system is biased negative of neutralizer common potential in order to collect facility induced charge-exchange ions are described. These tests indicate that this SAND (Screen, Accelerator, Negative Decelerator) configuration may enable long duration ion engine endurance tests to be performed at vacuum chamber pressures an order of magnitude higher than previously possible. The corresponding reduction in pumping speed requirements enables endurance tests of 10 kW class ion engines to be performed within the resources of existing technology programs. The results of a successful 5,000-hr endurance of a xenon hollow cathode operating at an emission current of 25 A are described, as well as the initial tests of hollow cathodes operating on a mixture of argon and 3 percent nitrogen. Work performed on the development of carbon/carbon grids, a multi-orifice hollow cathode, and discharge chamber erosion reduction through the addition of nitrogen are also described. Critical applied-field MPD thruster technical issues remain to be resolved, including demonstration of reliable steady-state operation at input powers of hundreds to thousands of kilowatts, achievement of thruster efficiency and specific impulse levels required for missions of interest, and demonstration of adequate engine life at these input power, efficiency, and specific impulse levels. To address these issues we have designed, built, and tested a 100 kW class, radiation-cooled applied-field MPD thruster and a unique dual-beam thrust stand that enables separate measurements of the applied- and self-field thrust components. We have also initiated the development of cathode thermal and plasma sheath models that will eventually be used to guide the experimental program. In conjunction with the cathode modeling, a new cathode test facility is being constructed. This facility will support the study of cathode thermal behavior and erosion mechanisms, the diagnosis of the near-cathode plasma and the development and endurance testing of new, high-current cathode designs. To facilitate understanding of electrode surface phenomenon, we have implemented a telephoto technique to obtain photographs of the electrodes during engine operation. In order to reduce the background vacuum tank pressure during steady-state engine operation in order to obtain high fidelity anode thermal data, we have developed and are evaluating a gas-dynamic diffuser. A review of experience with alkali metal propellants for MPD thrusters led to the conclusion that alkali metals, particularly lithium, offer the potential for significant engine performance and lifetime improvements. These propellants are also condensible at room temperature, substantially reducing test facility pumping requirements. The most significant systems-level issue is the potential for spacecraft contamination. Subsequent experimental and theoretical efforts should be directed toward verifying the performance and lifetime gains and characterizing the thruster flow field to assess its impact on spacecraft surfaces. Consequently, we have begun the design and development of a new facility to study engine operation with alkali metal propellants.

Brophy, John R.↗

Spacecraft Charging in Low Temperature Environments

Spacecraft charging in plasma and radiation environments is a temperature dependent phenomenon due to the reduction of electrical conductivity in dielectric materials at low temperatures. Charging time constants are proportional to l/conductivity may become very large (on the order of days to years) at low temperatures and accumulation of charge densities in insulators in charging environments traditionally considered benign at ambient temperatures may be sufficient to produce charge densities and electric fields of concern in insulators at low temperatures. Low temperature charging is of interest because a number of spacecraft-primarily infrared astronomy and microwave cosmology observatories-are currently being design, built, and or operated at very cold temperatures on the order of 40K to 100K. This paper reviews the temperature dependence of spacecraft charging processes and material parameters important to charging as a function of temperature with an emphasis on low temperatures regimes.

Parker, Linda N.↗

Single photon X-ray imaging with charge-coupled devices /CCDs/

The paper describes a CCD camera facility designed and built for testing and characterization of CCDs in response to single X-ray photons in the 1-10 keV energy range. Results from the frontside-illuminated Fairchild 211 and 221 area imagers are presented; high quantum efficiency over the 3-6 keV range was verified. In order to avoid the problem of charge spreading at the higher energies, deep-depleted CCDs for soft X-ray imaging have been constructed, and good response was obtained at 6 keV. The present results are a first step toward the demonstration of the CCD as an appropriate device for at least the central part of the focal plane of a large X-ray telescope, e.g., the proposed Advanced X-ray Astrophysics Facility.

Griffiths, R. E.↗

A three-dimensional spacecraft-charging computer code

A computer code is described which simulates the interaction of the space environment with a satellite at geosynchronous altitude. Employing finite elements, a three-dimensional satellite model has been constructed with more than 1000 surface cells and 15 different surface materials. Free space around the satellite is modeled by nesting grids within grids. Applications of this NASA Spacecraft Charging Analyzer Program (NASCAP) code to the study of a satellite photosheath and the differential charging of the SCATHA (satellite charging at high altitudes) satellite in eclipse and in sunlight are discussed. In order to understand detector response when the satellite is charged, the code is used to trace the trajectories of particles reaching the SCATHA detectors. Particle trajectories from positive and negative emitters on SCATHA also are traced to determine the location of returning particles, to estimate the escaping flux, and to simulate active control of satellite potentials.

Rubin, A. G.↗