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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Hybrid BaTiO 3 /SiN x /AlGaN/GaN lateral Schottky barrier diodes with low turn-on and high breakdown performance

In this Letter, we demonstrate hybrid GaN lateral Schottky barrier diodes with enhanced breakdown characteristics and a low turn-on voltage. These diodes incorporate a lateral Schottky barrier in combination with a high permittivity material beneath the field plate, enabling high average breakdown fields and a low turn-on voltage. Average electric fields up to 2.38 MV/cm were achieved for devices with an anode–cathode spacing of 4 μm, while maintaining with a turn-on voltage of 0.48 V. In contrast, SiN x /AlGaN/GaN control lateral Schottky diodes displayed an average breakdown field of ~0.7 MV/cm for devices with similar dimensions with a turn-on voltage of 0.46 V. The use of a high-permittivity dielectric can more effectively utilize the high breakdown fields in wide bandgap materials by proper management of the electric field. This demonstration provides an innovative way to integrate high-permittivity materials with GaN lateral devices for improved breakdown and resistance characteristics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Impact of power flow on Z-pinch loads

Magnetically insulated transmission lines (MITLs) are used to deliver tens of MA to a Z-pinch load. The MITLs suffer current losses due to contaminant plasma located in the anode–cathode gap which is swept toward the load along the power flow. The swept up contaminant plasma can deposit mass and energy onto the load resulting in deformations or the seeding of macroscopic instabilities. This paper discusses 2D fully kinetic simulations of the contaminant plasma evolution which predict the current losses and the flux of mass and energy onto the load. Furthermore, the effects of a dynamic, i.e., imploding, load are shown to increase both the current loss and the mass and energy flux. The MITL used is a conical, radially converging design which is a feature common to MA-scale Z-pinch accelerators.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Power flow in magnetically insulated transmission lines with ion backscatter effects

Ion backscattering off of surfaces in magnetically insulated transmission lines (MITLs) is often ignored in kinetic simulations of MITL power flow. Backscattering reduces ion current losses and the surface impact heating, which dictates the rate at which surface-adsorbed contaminants are liberated into the anode–cathode gap. Backscatter probabilities are difficult to implement in a kinetic code because there are limited data for incident ion energies less than a few keV. This paper presents an analytic model based on the Rutherford scattering formula that reproduces the measured backscatter probabilities at high incident energies and transitions to the highly reflective behavior expected at low incident energies. The backscatter model is implemented in power flow simulations, which are validated with current loss experiments conducted on the 0.4 TW Mykonos accelerator at Sandia National Laboratories. This simulation setup is then used in a high-current Z-machine shot. In conclusion, backscatter effects are found to be unimportant in the low-current Mykonos regime but significantly reduce current losses at the Z-machine scale.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Improved internal short circuit models for thermal runaway simulations in lithium-ion batteries

Thermal runaway (TR) modeling is one of the primary tools that can be used to overcome challenges associated with lithium-ion battery (LIB) safety. Among all LIB accidents that have occurred over the past decade, Internal Short Circuit (ISC) remains the most common trigger mechanism. Many available models in the literature either use a simplified approach to simulate ISC or completely ignore its contribution. The aim of this study is to understand the nature of the heat released for different types of ISC scenarios, including aluminum-anode, anode–cathode, and copper-cathode ISC. We study ISC behavior using a coupled electrochemical–thermal model with an integrated TR chemical kinetics solver built in the COMSOL Multiphysics framework. The time duration of heat release and the magnitude of the peak ISC current are studied as functions of parameters such as the size of the penetrating filament and the capacity of the cell. The numerical results are used to build an empirical model validated against the published experimental TR propagation data. Our model can be successfully used as a viable low-cost substitute in lower order (lumped) TR simulations to enable TR prevention and mitigation.

Singh, Bakhshish Preet (ORCID:0000000264751992)↗
DOE OSTI2026

Single-shot ultrafast dynamics of nanosecond pulsed plasmas: Transition from ps–ns nonequilibrium to near-full ionization

The ultrafast multi-stage evolution of state-defining properties in atmospheric-pressure nanosecond pulsed plasmas is quantified using single-discharge, jitter-free, continuous streak-sweep spectroscopy of N 2 (C → B) molecular and N + /O + ionic species with a single-shot time resolution as short as ∼160 ps. An early period of extreme nonequilibrium is observed with vibrational temperatures [T V (C)] dropping from ∼8000 K at <200 ps after plasma breakdown to <4000 K within ∼1 ns, with near-ambient rotational temperatures [T R (C)] ∼ 300 K due to limited collisional energy transfer. This early-time T V (C) trend is representative of a direct and unquenched look into the high-energy tail of the electron energy distribution function; thus, it tracks real-time changes in the mean electron energy via the N2(C) emission signatures. This is followed by the rapid onset of N + /O + ionic emission after a distinct time delay of ∼14.9 ns due to multistep chemical kinetics. The ionic emission enables determination of electron densities (n e ) >2 × 10 19 cm −3 and electron temperatures (T e ) >36 000 K, indicating the transition to a nearly fully ionized regime. The ps–ns temporal dynamics are also compared between air and N 2 plasmas to assess the influence of collisional partners, as well as across the anode, cathode, and central gap regions to identify spatial variations in plasma behavior. Finally, this work demonstrates versatile continuously probing approach capable of spectro-temporal and spatially resolved single-shot measurements of key state variables in the ps–ns evolution of atmospheric-pressure nanosecond pulsed plasmas.

Electric discharges↗
DOE OSTI2022

Multi-channel front-end ASIC for a 3D position-sensitive detector

Arrays of 3D position-sensitive detectors (3DPSD), operating at room temperature and using cadmium zinc telluride (CZT) and thallium bromide (TIBr) sensors, are suitable for gamma-ray spectrometry in many applications. One detector configuration, the 3D position-sensitive Virtual Frisch-Grid detector (VFG), is particularly advantageous for integrating into large area arrays. The signals generated inside each detector of the array are captured with the anode, cathode and four pads that enable the reconstruction of the position and energy of the ionizing interaction by measurements of amplitude and timing of the signals. For these applications, a low-noise front-end ASIC has been developed, capable of processing bipolar signals (needed because of AC-coupling of certain electrodes). The ASIC can be coupled to an ADC in order to form a compound “waveform digitizer” capable of post-processing the analog signals and determining amplitude and timing information. This paper describes a 32-channel front-end ASIC that is suitable for reading out a 3 × 3 or 4 × 4 element matrix in the VFG configuration. Each channel is composed of a low-noise charge amplifier with an adaptive continuous reset feedback circuit suitable for both positive and negative charge, a first order shaper and a single-to-differential converter output stage. Voltage and current references are all internally generated by 10-bit DACs and the chip is fully controllable with the I 2 C communication protocol. The readout channel response has been verified using the implemented injection circuit. Linear behavior up to ~75 ke ± with the gain of ~80 mV/fC, and up to ~200 ke ± with the gain of ~30 mV/fC was demonstrated. In conclusion, the first test result waveforms using a 137 Cs radioactive source on a 5 × 5 × 12 mm 3 TIBr crystal are reported.

47 OTHER INSTRUMENTATION↗
DOE OSTI2022

Three-Dimensional Particle-in-Cell Analysis of Mechanical Design Tolerances of the Scorpius Injector With Warp

Here, this article examines the mechanical design tolerances for the Scorpius injector using a 3-D particle-in-cell (PIC) code. In order to meet its objective as a high-fidelity, multipulse flash X-ray source, the accelerator has requirements for the electron beam in order to minimize the spot size of the beam focused onto a foil target to create high fluence X-rays at energies greater than 10 MeV. The requirements for alignment of the cathode, anode beam pipe, focusing solenoids, and transport solenoids specified using Trak and AMBER are independently verified using a 3-D electrostatic/magnetostatic model of the Scorpius injector, including transverse magnetic field errors that arise from mechanical alignment errors. It is predicted that the injector will meet the performance requirements for radiographic operation and has a design margin to correct for potentially unforeseen operating conditions.

42 ENGINEERING↗
DOE OSTI2024

Methods for Quantitative Thermal Analysis of Lithium Solid-State and Beyond Battery Safety

The use of differential scanning calorimetry (DSC) to measure the thermal behavior of individual components and electrolyte/electrode combinations is common. However, here we focus on DSC tests on an anode, cathode, and electrolyte (ACE) component combination over a temperature range that includes many of the phase transitions and key reactions (i.e., to 500 °C) that contribute to thermal runaway. This method can help quantify the complex reaction network in a full cell, thereby informing potential safety issues. Here, we used DSC heat flow data from a solid-state Li 0.43 CoO 2 +C+PVDF | LLZO | Li metal ACE sample and its components to quantify key factors affecting results. We focused on three areas: (1) ACE sample preparation and assembly in DSC pans, (2) DSC measurement parameters, and (3) heat flow analysis. Key points include the choice of component ratios (e.g., commercially relevant N:P capacity ratio), the importance of conductive carbon and binder, type of pan used, DSC ramp rate, and integration method used when dealing with broad and overlapping exothermic peaks. This work deepens the scientific basis and best practices for obtaining heat flow data from ACE samples for early-stage evaluation of solid-state and beyond battery safety.

25 ENERGY STORAGE↗
DOE OSTI2020

Diagnosing Field Strengths and Plasma Conditions in Magnetically Insulated Transmission Lines Using Active Dopant Spectroscopy

Experimental validation data is needed to inform simulations of large pulsed power devices which are in development to understand and improve existing accelerators and inform future pulsed power capabilities. Using current spectroscopic techniques on the Z-machine, we have been unable to reliably diagnose plasma conditions and electric and magnetic fields within power flow regions. Laser ablation of a material produces a low density plasma, resulting in narrow spectroscopic line widths. By introducing a laser ablated plasma to the anode cathode gap of the Mykonos accelerator, we can monitor how the line shapes change due the current pulse by comparing these line shapes to spectral measurements taken without power flow. In this report we show several examples of measurements conducted on Mykonos on various dopant materials. We also show a negligible effect on power flow due to the presence of the ablation plasma for a range of parameters.

43 PARTICLE ACCELERATORS↗
DOE OSTI2020

Characterization of Self-Magnetic Pinch (SMP) Radiographic Diode Performance on RITS-6 at Sandia National Laboratories

The goals of an electron beam-driven radiographic source are the focusing of high current at high voltage to a minimal spot size with excellent shot-to-shot reproducibility. The Self-Magnetic Pinch (SMP) diode makes use of such an intense electron beam impinging on a high-atomic weight (tantalum) converter, a counter-streaming ion beam to help minimize the spot size, and operation in a magnetic field-free diode region which further encourages small spot size. Through a series of diode development experiments, output voltages up to 12.5 MV and output currents up to 225 kA have been characterized, with resulting spot sizes below ~ few mm. Scaling studies with parameter variation, such as diode aspect ratio and anode-cathode (A-K) gap variation, give systematic validation to what has heretofore been noted anecdotally by other research groups. While the lack of an imbedded magnetic field helps minimize the SMP spot size, a secondary result may be the generation of beam instabilities which can terminate the radiation pulse. There is anecdotal evidence that in-situ DC heating of the diode region can help stabilize the beam pinch. Clear experimental evidence exists that DC heating/RF cleaning results in better control over the counter-streaming ion population. Expanded use of spatial dose-rate detection is shown to yield new insights into electron beam dynamics in the SMP diode. An attendant study of the SMP diode as a load for an Inductive Voltage Adder (IVA) driver leads to insights into the behavior of the IVA-SMP diode configuration, viewed as a total system, and yields constraints on the overall impedance behavior of the SMP diode load.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Development of High-Capacity Cathodes and Robust Solid Electrolytes

In Phase 1, the University of Texas at Austin explored many methods of cathode design, synthesis, and modification, while also developing an understanding of the relationships among the cathode, anode, and electrolyte. Some of the major accomplishments are highlighted in this report.

25 ENERGY STORAGE↗
DOE OSTI2024

Quantification of Commercially Planned Battery Component Supply in North America through 2035

There is the potential for rapid growth in battery manufacturing in North America in the coming years, as indicated by investment plans which companies have announced. Argonne National Laboratory is tracking these investment announcements to understand the availability of domestically produced battery cells and battery components over the next decade. We find that companies have made announcements for over 1,300 GWh/year of lithium-ion battery cell production by 2030, enough to conservatively supply ten million electric vehicles and expected growth in stationary grid storage. From 2021 to 2032, battery cell production is modeled to grow 28-fold. For each of the core battery components of lithium-ion batteries (cathodes, anodes, separators, electrolytes, and foils), we describe the current announced capacities for materials with respect to cell production and end-use demand, finding similar rapid growth for each.

25 ENERGY STORAGE↗
DOE OSTI2023

Development of a colinear Second-Harmonic Orthogonal Polarization (SHOP) interferometer for electron areal density measurements in Magnetically Insulated Transmission Lines (MITLs)

Experimental measurements of low density plasmas forming in Magnetically Insulated Transmission Line (MITL) regions are desired to improve our understanding of current loss and power flow. Therefore, a new optical interferometer diagnostic was commissioned via this LDRD project. To measure the expected 10 13 - 10 17 cm -3 electron densities inside the 0.5 - 6 mm Anode-Cathode (A-K) gaps, a colinear SHOP interferometer diagnostic was constructed. The diagnostic was initially fielded on the University of New Mexico (UNM) Helicon-Cathode (HelCat) plasma device which provided a highly repeatable and well understood plasma source for which the colinear SHOP interferometer’s functionality could be verified and measured. Utilizing the highly repeatable plasma source and shot averaging, the interferometer was able to achieve an areal density sensitivity of 1×10 14 cm -2 . This work at UNM lead to a Review of Scientific Instruments (RSI) publication [20], DOI:10.1063/5.0101687. After the diagnostic’s capability was proven at UNM, the colinear SHOP interferometer was commissioned for use on the Sandia National Laboratories (SNL) Mykonos accelerator. Here, it provided the first temporal areal density measurements of plasma formation in a parallel plate MITL. The diagnostic was able to achieve a single shot (no multi-shot averaging like at UNM) areal density sensitivity of 1×10 15 cm -2 along a ~ 2mm probing path length, which provided adequate capability to conduct fundamental physics research of MITL plasma formation. CHICAGO and ALEGRA simulations support the diagnostics experimental findings. More experimental and computational work will continue, likely leading to another publication(s). The smaller scale Mykonos accelerator work has also provided justification that the colinear SHOP interferometer is a capable diagnostic for measuring plasma areal densities in the inner MITL and convolute regions of larger TW-class accelerators like SNL’s Z machine.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

New Simulations for Ion-Production and Back-Bombardment in GaAs Photo-guns

GaAs-based DC high voltage photo-guns used at accelerators with extensive user programs must exhibit long photocathode operating lifetime. Achieving this goal represents a significant challenge for proposed high average current facilities that must operate at tens of milliamperes or more. Specifically, the operating lifetime is dominated by ion back-bombardment of the photocathode from ionized residual gas. While numerous experiments have been performed to characterize the operating lifetime under various conditions, detailed simulations of the ion back-bombardment mechanism that explains these experiments are lacking. Recently, a new user routine was implemented using the code General Particle Tracer (GPT) to simulate electron impact ionization of residual beam line gas and simultaneously track the incident electron, the ejected electron, and the newly formed ion. This new routine was benchmarked against analytical calculations and then applied to experiments performed at the CEBAF injector at the Thomas Jefferson National Accelerator Facility to study the effectiveness of limiting ions from entering the cathode-anode gap using a positively biased anode. These simulations were performed using detailed 3D field maps produced with CST Microwave Studio describing the photo-gun electrostatics. Discussion of the experiment and the application of this new GPT routine to model the experiments will be presented at the workshop.

Yoskowitz, Joshua↗
DOE OSTI2025

Study of the Design and Characteristics of a Modified Pulsed Plasma Thruster with Graphite and Tungsten Trigger Electrodes

The paper presents experimental results for a modified pulsed plasma thruster (PPT) with solid propellant, using a coaxial anode–cathode design. Graphite from pencil leads served as propellant, and a tungsten trigger electrode was tested to reduce carbonization effects. Experiments were performed in a vacuum chamber at 0.001 Pa, employing diagnostics such as discharge current/voltage recording, power measurement, ballistic pendulum, time-of-flight (TOF) method, and a Faraday cup. Current and voltage waveforms matched an oscillatory RLC circuit with variable plasma channel resistance. Key discharge parameters were measured, including current pulse duration/amplitude and plasma channel formation/decay dynamics. Impulse bit values, obtained with a ballistic pendulum, reached up to 8.5 μN·s. Increasing trigger capacitor capacitance reduced thrust due to unstable “pre-plasma” formation and partial pre-discharge energy loss. Using TOF and Faraday cup diagnostics, plasma front velocity, ion current amplitude, current density, and ion concentration were determined. Tungsten electrodes produced lower charged particle concentrations than graphite but offered better adhesion resistance, minimal carbonization, and stable long-term performance. The findings support optimizing trigger electrode materials and PPT operating modes to extend lifetime and stabilize thrust output.

Faraday cup↗
DOE OSTI2020

Electrochemical Impedance Spectroscopy and Cyclic Voltammetry Methods for Monitoring SmCl 3 Concentration in Molten Eutectic LiCl-KCl

Molten salt solutions consisting of eutectic LiCl-KCl and concentrations of samarium chloride (0.5 to 3.0 wt%) at 500 C were analyzed using both cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The CV technique gave the average diffusion coefficient for Sm 3+ over the concentration range. Equipped with Sm 3+ diffusion coefficient, the Randles-Sevcik equation predicted Sm 3+ concentration values that agree with the given experimental values. From CV measurements; the anodic, cathodic, and half-peak potentials were identified and subsequently used as a parameter to acquire EIS spectra. A six-element Voigt model was used to model the EIS data in terms of resistance-time constant pairs. The lowest resistances were observed at the half-peak potential with the associated resistance-time constant pairs characterizing the reversible reaction between Sm 3+ and Sm 2+ . By extrapolation, the Voigt model estimated the polarization resistance and established a polarization resistance-concentration relationship.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗