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NASA NTRS1997

Spectral and temporal properties of the black hole candidate systems

Observations of Galactic, and extragalactic black hole candidates show that their spectra can be fitted by the thermal Comptonization spectra in the hard state and two components in the soft state. The first component is a black body shape spectrum and the second component is an extended power law with a spectral index of between 1 and 2. The spectral formation of Comptonized spectra in the presence of thermal and bulk motion is considered. In the soft state, when the disk luminosity is high, the emission region temperature is low. In the limit of low plasma temperature, the theoretical spectrum consists of two components: the soft input photons escaping without significant energy change, and a power law that extends to high energies. The spectral index is in the range between 1 and 2, depending on the mass accretion rate. The extended power law is the result of upscattering of soft disk photons in the bulk flow which takes place in the vicinity of the black hole. In the hard state, the disk luminosity is low, the electron temperature of the emission region is high and the thermal Comptonization is the dominant process in the formation of the resulting spectrum.

Titarchuk, Lev↗

NASA NTRS2005

Synthesis, Characterization and Decomposition Studies of Tris(N,N-dibenzyldithiocarbamato) Indium(III): Chemical Spray Deposition of Polycrystalline CuInS2 on Copper Films

Tris(bis(phenylmethyl)carbamodithioato-S,S ), commonly referred to as tris(N,Ndibenzyldithiocarbamato) indium(III), In(S2CNBz2)3, was synthesized and characterized by single crystal X-ray crystallography. The compound crystallizes in the triclinic space group P1 bar with two molecules per unit cell. The material was further characterized using a novel analytical system employing the combined powers of thermogravimetric analysis, gas chromatography/mass spectrometry and Fourier-Transform infrared spectroscopy to investigate its potential use as a precursor for the chemical vapor deposition (CVD) of thin film materials for photovoltaic applications. Upon heating, the material thermally decomposes to release CS2 and benzyl moieties in to the gas phase, resulting in bulk In2S3. Preliminary spray CVD experiments indicate that In(S2CNBz2)3 decomposed on a Cu substrate reacts to produce stoichiometric CuInS2 films.

Hehemann, David G.↗

NASA NTRS2012

NASA Tech Briefs, August 2012

Topics covered include: Mars Science Laboratory Drill; Ultra-Compact Motor Controller; A Reversible Thermally Driven Pump for Use in a Sub-Kelvin Magnetic Refrigerator; Shape Memory Composite Hybrid Hinge; Binding Causes of Printed Wiring Assemblies with Card-Loks; Coring Sample Acquisition Tool; Joining and Assembly of Bulk Metallic Glass Composites Through Capacitive Discharge; 670-GHz Schottky Diode-Based Subharmonic Mixer with CPW Circuits and 70-GHz IF; Self-Nulling Lock-in Detection Electronics for Capacitance Probe Electrometer; Discontinuous Mode Power Supply; Optimal Dynamic Sub-Threshold Technique for Extreme Low Power Consumption for VLSI; Hardware for Accelerating N-Modular Redundant Systems for High-Reliability Computing; Blocking Filters with Enhanced Throughput for X-Ray Microcalorimetry; High-Thermal-Conductivity Fabrics; Imidazolium-Based Polymeric Materials as Alkaline Anion-Exchange Fuel Cell Membranes; Electrospun Nanofiber Coating of Fiber Materials: A Composite Toughening Approach; Experimental Modeling of Sterilization Effects for Atmospheric Entry Heating on Microorganisms; Saliva Preservative for Diagnostic Purposes; Hands-Free Transcranial Color Doppler Probe; Aerosol and Surface Parameter Retrievals for a Multi-Angle, Multiband Spectrometer LogScope; TraceContract; AIRS Maps from Space Processing Software; POSTMAN: Point of Sail Tacking for Maritime Autonomous Navigation; Space Operations Learning Center; OVERSMART Reporting Tool for Flow Computations Over Large Grid Systems; Large Eddy Simulation (LES) of Particle-Laden Temporal Mixing Layers; Projection of Stabilized Aerial Imagery Onto Digital Elevation Maps for Geo-Rectified and Jitter-Free Viewing; Iterative Transform Phase Diversity: An Image-Based Object and Wavefront Recovery; 3D Drop Size Distribution Extrapolation Algorithm Using a Single Disdrometer; Social Networking Adapted for Distributed Scientific Collaboration; General Methodology for Designing Spacecraft Trajectories; Hemispherical Field-of-View Above-Water Surface Imager for Submarines; and Quantum-Well Infrared Photodetector (QWIP) Focal Plane Assembly.

Source record↗

NASA NTRS2015

Dormancy and Recovery Testing for Biological Wastewater Processors

Bioreactors, such as aerated membrane type bioreactors have been proposed and studied for a number of years as an alternate approach for treating wastewater streams for space exploration. Several challenges remain before these types of bioreactors can be used in space settings, including transporting the bioreactors with their microbial communities to space, whether that be the International Space Station or beyond, or procedures for safing the systems and placing them into dormant state for later start-up. Little information is available on such operations as it is not common practice for terrestrial systems. This study explored several dormancy processes for established bioreactors to determine optimal storage and recovery conditions. Procedures focused on complete isolation of the microbial communities from an operational standpoint and observing the effects of: 1) storage temperature, and 2) storage with or without the reactor bulk fluid. The first consideration was tested from a microbial integrity and power consumption standpoint; both room temperature (25 C) and cold (4 C) storage conditions were studied. The second consideration was explored; again, for microbial integrity as well as plausible real-world scenarios of how terrestrially established bioreactors would be transported to microgravity and stored for periods of time between operations. Biofilms were stored without the reactor bulk fluid to simulate transport of established biofilms into microgravity, while biofilms stored with the reactor bulk fluid simulated the most simplistic storage condition to implement operations for extended periods of nonuse. Dormancy condition did not have an influence on recovery in initial studies with immature biofilms (48 days old), however, a lengthy recovery time was required (20+ days). Bioreactors with fully established biofilms (13 months) were able to recover from a 7-month dormancy period to steady state operation within 4 days (approximately 1 residence cycle). Results indicate a need for future testing on biofilm age and health and further exploration of dormancy length.

Dormancy↗

NASA NTRS2015

Dormancy and Recovery Testing for Biological Wastewater Processors

Bioreactors, such as the aerated hollow fiber membrane type, have been proposed and studied for a number of years as an alternate approach for treating wastewater streams for space exploration. Several challenges remain to be resolved before these types of bioreactors can be used in space settings, including transporting the bioreactors with intact and active biofilms, whether that be to the International Space Station or beyond, or procedures for safing the systems and placing them into a dormant state for later start-up. Little information is available on such operations as it is not common practice for terrestrial systems. This study explored several dormancy processes for established bioreactors to determine optimal storage and recovery conditions. Procedures focused on complete isolation of the microbial communities from an operational standpoint and observing the effects of: 1) storage temperature, and 2) storage with or without the reactor bulk fluid. The first consideration was tested from a microbial integrity and power consumption standpoint; both ambient temperature (25 C) and cold (4 C) storage conditions were studied. The second consideration was explored; again, for microbial integrity as well as plausible real-world scenarios of how terrestrially established bioreactors would be transported to microgravity and stored for periods of time between operations. Biofilms were stored without the reactor bulk fluid to simulate transport of established biofilms into microgravity, while biofilms stored with the reactor bulk fluid simulated the most simplistic storage condition to implement operations for extended periods of nonuse. Dormancy condition did not have an influence on recovery in initial studies with immature biofilms (48 days old), however a lengthy recovery time was required (20+ days). Bioreactors with fully established biofilms (13 months) were able to recover from a 7-month dormancy period to steady state operation within 4 days (approx. 1 residence cycle). Results indicate a need for future testing on biofilm age and health and further exploration of dormancy length.

Recovery Testing↗

NASA NTRS1999

Type I Cosmic Spherules: Key to a Major, But Poorly Sampled, Asteroid Population?

Herzog et al. have determined Fe, Ni, and Cr abundances in Type I cosmic spherules recovered from the deep sea, and also the isotopic fractionation of these elements during passage of the spherules through the terrestrial atmosphere. Isotopic fractionation for all three elements is typically large, approx. 16%/amu, corresponding to evaporative mass losses of approx. 80 - 85%, assuming Rayleigh distillation from an open system. The corrected, pre-atmospheric, Cr/Ni and Fe/Ni ratios, are compared to ratios in bulk chondrites and chondritic metal. Although the calculated pre-atmospheric Fe/Ni ratio for the spherules is relatively constant at 19 +/- 4 (sigma(sub mean)) the calculated pre-atmospheric Cr/Ni ratios vary by about two orders of magnitude. The Cr/Ni ratios are thus powerful discriminators for possible modes of origin of the spherules. For example, iron meteorites typically have low Cr contents and low Cr/Ni ratios, less or = 3 x 10(exp -4). Thus, Type I spherules do not appear to be ablation products of iron meteorites, in contrast to an earlier suggestion.

Nyquist, L. E.↗

NASA NTRS2010

Large-Flow-Area Flow-Selective Liquid/Gas Separator

This liquid/gas separator provides the basis for a first stage of a fuel cell product water/oxygen gas phase separator. It can separate liquid and gas in bulk in multiple gravity environments. The system separates fuel cell product water entrained with circulating oxygen gas from the outlet of a fuel cell stack before allowing the gas to return to the fuel cell stack inlet. Additional makeup oxygen gas is added either before or after the separator to account for the gas consumed in the fuel cell power plant. A large volume is provided upstream of porous material in the separator to allow for the collection of water that does not exit the separator with the outgoing oxygen gas. The water then can be removed as it continues to collect, so that the accumulation of water does not impede the separating action of the device. The system is designed with a series of tubes of the porous material configured into a shell-and-tube heat exchanger configuration. The two-phase fluid stream to be separated enters the shell-side portion of the device. Gas flows to the center passages of the tubes through the porous material and is then routed to a common volume at the end of the tubes by simple pressure difference from a pumping device. Gas flows through the porous material of the tubes with greater ease as a function of the ratio of the dynamic viscosity of the water and gas. By careful selection of the dimensions of the tubes (wall thickness, porosity, diameter, length of the tubes, number of the tubes, and tube-to-tube spacing in the shell volume) a suitable design can be made to match the magnitude of water and gas flow, developed pressures from the oxygen reactant pumping device, and required residual water inventory for the shellside volume.

Vasquez, Arturo↗

NASA NTRS2009

Synthesis, Characterization, and Processing of Copper, Indium, and Gallium Dithiocarbamates for Energy Conversion Applications

Ten dithiocarbamate complexes of indium(III) and gallium(III) have been prepared and characterized by elemental analysis, infrared spectra and melting point. Each complex was decomposed thermally and its decomposition products separated and identified with the combination of gas chromatography/mass spectrometry. Their potential utility as photovoltaic materials precursors was assessed. Bis(dibenzyldithiocarbamato)- and bis(diethyldithiocarbamato)copper(II), Cu(S2CN(CH2C6H5)2)2 and Cu(S2CN(C2H5)2)2 respectively, have also been examined for their suitability as precursors for copper sulfides for the fabrication of photovoltaic materials. Each complex was decomposed thermally and the products analyzed by GC/MS, TGA and FTIR. The dibenzyl derivative complex decomposed at a lower temperature (225-320 C) to yield CuS as the product. The diethyl derivative complex decomposed at a higher temperature (260-325 C) to yield Cu2S. No Cu containing fragments were noted in the mass spectra. Unusual recombination fragments were observed in the mass spectra of the diethyl derivative. Tris(bis(phenylmethyl)carbamodithioato-S,S'), commonly referred to as tris(N,N-dibenzyldithiocarbamato)indium(III), In(S2CNBz2)3, was synthesized and characterized by single crystal X-ray crystallography. The compound crystallizes in the triclinic space group P1(bar) with two molecules per unit cell. The material was further characterized using a novel analytical system employing the combined powers of thermogravimetric analysis, gas chromatography/mass spectrometry, and Fourier transform infrared (FT-IR) spectroscopy to investigate its potential use as a precursor for the chemical vapor deposition (CVD) of thin film materials for photovoltaic applications. Upon heating, the material thermally decomposes to release CS2 and benzyl moieties in to the gas phase, resulting in bulk In2S3. Preliminary spray CVD experiments indicate that In(S2CNBz2)3 decomposed on a Cu substrate reacts to produce stoichiometric CuInS2 films.

Duraj, S. A.↗

NASA NTRS2000

Crystal Growth of ZnSe and Related Ternary Compound Semiconductors by Vapor Transport

Interest in optical devices which can operate in the visible spectrum has motivated research interest in the II-VI wide band gap semiconductor materials. The recent challenge for semiconductor opto-electronics is the development of a laser which can operate at short visible wavelengths. In the past several years, major advances in thin film technology such as molecular beam epitaxy and metal organic chemical vapor deposition have demonstrated the applicability of II-VI materials to important devices such as light-emitting diodes, lasers, and ultraviolet detectors. With an energy gap of 2.7 eV at room temperature, and an efficient band- to-band transition, ZnSe has been studied extensively as the primary candidate for a blue light emitting diode for optical displays, high density recording, and military communications. By employing a ternary or quaternary system, the energy band gap of II-VI materials can be tuned to a specific range. While issues related to the compositional inhomogeneity and defect incorporation are still to be fully resolved, ZnSe bulk crystals and ZnSe-based heterostructures such as ZnSe/ZnSeS, ZnSe/ZnCdSe and ZnCdSe/ZnSeS have showed photopumped lasing capability in the blue-green region at a low threshold power and high temperatures. The demonstration of its optical bistable properties in bulk and thin film forms also make ZnSe a possible candidate material for the building blocks of a digital optical computer. Despite this, developments in the crystal growth of bulk H-VI semiconductor materials has not advanced far enough to provide the low price, high quality substrates needed for the thin film growth technology.

Su, Ching-Hua↗

NASA NTRS2007

Foods for a Mission to Mars: Investigations of Low-Dose Gamma Radiation Effects

Food must be safe, nutritious, and acceptable throughout a long duration mission to maintain the health, well-being, and productivity of the astronauts. In addition to a developing a stable pre-packaged food supply, research is required to better understand the ability to convert edible biomass into safe, nutritious, and acceptable food products in a closed system with many restrictions (mass, volume, power, crew time, etc.). An understanding of how storage conditions encountered in a long-term space mission, such as elevated radiation, will impact food quality is also needed. The focus of this project was to contribute to the development of the highest quality food system possible for the duration of a mission, considering shelf-stable extended shelf-life foods, bulk ingredients, and crops to be grown in space. The impacts of space-relevant radiation doses on food, bulk ingredient, and select candidate crop quality and antioxidant capacity were determined. Interestingly, increasing gamma-radiation doses (0 to 1000 Gy) did not always increase dose-related effects in foods. Intermediate radiation doses (10 to 800Gy) often had significantly larger impact on the stability of bulk ingredient oils than higher (1000Gy) radiation doses. Overall, most food, ingredient, and crop systems investigated showed no significant differences between control samples and those treated with 3 Gy of gamma radiation (the upper limit estimated for a mission to Mars). However, this does not mean that all foods will be stable for 3-5 years, nor does it mean that foods are stable to space radiation comprising more than gamma rays.

Gandolph, J.↗

NASA NTRS1994

Strength characteristics and crack growth behavior of a composite with well aligned fibers

Continuous fiber composites have shown tremendous promise in industrial applications. Their microstructures, however, are very complex and in many instances difficult to characterize. In this project, the fracture characteristics of a specially made fiber reinforced composite with different fiber spacing are investigated. The experimental results so far have shown that after an initial transient phase the crack speed reaches a steady phase, i.e., independent of the crack length. Within the steady crack growth phase debonding along the fibers in the bridging zone grows in a self-similar manner. During the steady phase the energy dissipation per cycle is constant. Afterwards, an increase of the energy dissipation is observed that is accompanied by a decrease in crack speed. This latter trend is presumed to be the result of relatively large amounts of energy dissipated in the bulk of the specimen. Using appropriate Green's function and computer simulations, the stress intensity factor at the crack tip is evaluated for various cases of bridging stresses. In this way the effects of specimen size and fiber spacing on the overall fracture behavior of the composite system are analyzed. The steady crack speed and the steady rate of debonding have a similar power dependence on stress level. Dimensional analysis demonstrates that the particular fracture process is not governed by dimensional invariance but on the detailed micromechanisms in the bridging zone.

Botsis, John↗

NASA NTRS1985

Profiles of fatigue damage in graphite/epoxy composites from ultrasonic transmission power spectra

Early fatigue damage in non-unidirectional multi-ply graphite/epoxy composites is manifested by a distribution of cracks and disbonds through the bulk of the material. Such damage is subtle and is difficult to detect with conventional ultrasonic technology. Consequently, a new ultrasonic measurement technique called phase-insensitive tone-burst spectroscopy has been developed. The new technique eliminates problems associated with phase cancellation and pulse shape artifacts inherent to conventional broadband ultrasonic spectral measurement systems and produces clean spectral information irrespective of specimen inhomogeneity or irregularities in surface geometry. Application of the new technique to measurements of graphite/epoxy composites has yielded frequency-domain profiles that show distinct differences in ultrasonic attenuation, attenuation slope, and velocity for each specimen experiencing a different level of fatigue damage.

Cantrell, J. H., Jr.↗

NASA NTRS1985

Measurement of wind near the surface

A survey is presented of instrumentation suitable for measurement of wind near the surface of the earth by using in-situ techniques and further restricted to sensors that are operational. In this case, a sensor is deemed to be operational if it is commercially available. There is no discussion here of the systems that might be used to acquire, process, display, and store the sensor data. It is assumed that some sort of automatic data logging equipment would be used. Without special requirements such as need for high frequency response, low power consumption, etc., this treatment must be quite general and provides little detail. Also, without special restrictions, emphasis must be placed on conventional sensors that provide the bulk of wind data today.

Brock, Fred V.↗

NASA NTRS1999

Type I Cosmic Spherules: Key to a Major, But Poorly Sampled, Asteroid Population

Fe, Ni, and Cr abundances in Type I cosmic spherules recovered from the deep sea, and also the isotopic fractionation of these elements during passage of the spherules through the terrestrial atmosphere was determined. Isotopic fractionation for all three elements is typically large, approx. 16%o/amu, corresponding to evaporative mass losses of approx. 80-85%, assuming Rayleigh distillation from an open system. The corrected, pre-atmospheric, Cr/Ni and Fe/Ni ratios are shown, where they are compared to these ratios in bulk chondrites and chondritic metal. Although the calculated pre-atmospheric Fe/Ni ratio for the spherules is relatively constant at 19 plus or minus 4 (sigma (sub mean)), the calculated pre-atmospheric Cr/Ni ratios vary by about two orders of magnitude. The Cr/Ni ratios are thus powerful discriminators for possible modes of origin of the spherules. For example, iron meteorites typically have low Cr contents and low Cr/Ni ratios, less than or equal to 3 x 10(exp -4). Thus, Type I spherules do not appear to be ablation products of iron meteorites, in contrast to an earlier suggestion..

Nyquist, Larry E.↗

NASA NTRS2000

Type 1 Cosmic Spherules: Key to a Major, But Poorly Sampled, Asteroid Population?

Herzog et al. have determined Fe, Ni, and Cr abundances in Type I cosmic spherules recovered from the deep sea, and also the isotopic fractionation of these elements during passage of the spherules through the terrestrial atmosphere. Isotopic fractionation for all three elements is typically large, approx.16%(sigma)/amu, corresponding to evaporative mass losses of approx.80-85%, assuming Rayleigh distillation from an open system. The corrected, pre-atmospheric, Cr/Ni and Fe/Ni ratios are shown in Figure 1, where they are compared to these ratios in bulk chondrites and chondritic metal. Although the calculated pre-atmospheric Fe/Ni ratio for the spherules is relatively constant at 19+/-4 (sigma(sub mean), the calculated pre-atmospheric Cr/Ni ratios vary by about two orders of magnitude. The Cr/Ni ratios are thus powerful discriminators for possible modes of origin of the spherules. For example, iron meteorites typically have low Cr contents and low Cr/Ni ratios,:less than or equal to 3 x 10(exp -4). Thus, Type I spherules do not appear to be ablation products of iron meteorites, in contrast to an earlier suggestion.

Nyquist, L. E.↗

NASA NTRS1978

Meteoroids from periodic comet d'Arrest

The predicted anomalous tail of periodic comet d'Arrest was photographed and photometrically studied. The derived particle-size distribution function varies inversely according to slightly higher than the 4-th power of the size. Particle dimensions span a few orders of magnitude, the mean size being in the general range of 0.01 to 0.1 cm depending on the assumed bulk density. The determination of the amount of the ejected dust is complicated by large uncertainties in the particle albedo. The product of the particle albedo and of the production rate of meteoroids that remain gravitationally bound to the solar system is found to be about 3000 g/s at the time of maximum activity and some 200 g/s when averaged over the comet's revolution period. The contribution of the comet to the interplanetary dust cloud is insignificant, unless the albedo of the debris from the comet is as low as 0.1 percent.

Sekanina, Z.↗

NASA NTRS2008

Application of the CloudSat and NEXRAD Radars Toward Improvements in High Resolution Operational Forecasts

As computational power increases, operational forecast models are performing simulations with higher spatial resolution allowing for the transition from sub-grid scale cloud parameterizations to an explicit forecast of cloud characteristics and precipitation through the use of single- or multi-moment bulk water microphysics schemes. investments in space-borne and terrestrial remote sensing have developed the NASA CloudSat Cloud Profiling Radar and the NOAA National Weather Service NEXRAD system, each providing observations related to the bulk properties of clouds and precipitation through measurements of reflectivity. CloudSat and NEXRAD system radars observed light to moderate snowfall in association with a cold-season, midlatitude cyclone traversing the Central United States in February 2007. These systems are responsible for widespread cloud cover and various types of precipitation, are of economic consequence, and pose a challenge to operational forecasters. This event is simulated with the Weather Research and Forecast (WRF) Model, utilizing the NASA Goddard Cumulus Ensemble microphysics scheme. Comparisons are made between WRF-simulated and observed reflectivity available from the CloudSat and NEXRAD systems. The application of CloudSat reflectivity is made possible through the QuickBeam radiative transfer model, with cautious application applied in light of single scattering characteristics and spherical target assumptions. Significant differences are noted within modeled and observed cloud profiles, based upon simulated reflectivity, and modifications to the single-moment scheme are tested through a supplemental WRF forecast that incorporates a temperature dependent snow crystal size distribution.

Molthan, A. L.↗

NASA NTRS2012

Investigation into Cloud Computing for More Robust Automated Bulk Image Geoprocessing

Geospatial resource assessments frequently require timely geospatial data processing that involves large multivariate remote sensing data sets. In particular, for disasters, response requires rapid access to large data volumes, substantial storage space and high performance processing capability. The processing and distribution of this data into usable information products requires a processing pipeline that can efficiently manage the required storage, computing utilities, and data handling requirements. In recent years, with the availability of cloud computing technology, cloud processing platforms have made available a powerful new computing infrastructure resource that can meet this need. To assess the utility of this resource, this project investigates cloud computing platforms for bulk, automated geoprocessing capabilities with respect to data handling and application development requirements. This presentation is of work being conducted by Applied Sciences Program Office at NASA-Stennis Space Center. A prototypical set of image manipulation and transformation processes that incorporate sample Unmanned Airborne System data were developed to create value-added products and tested for implementation on the "cloud". This project outlines the steps involved in creating and testing of open source software developed process code on a local prototype platform, and then transitioning this code with associated environment requirements into an analogous, but memory and processor enhanced cloud platform. A data processing cloud was used to store both standard digital camera panchromatic and multi-band image data, which were subsequently subjected to standard image processing functions such as NDVI (Normalized Difference Vegetation Index), NDMI (Normalized Difference Moisture Index), band stacking, reprojection, and other similar type data processes. Cloud infrastructure service providers were evaluated by taking these locally tested processing functions, and then applying them to a given cloud-enabled infrastructure to assesses and compare environment setup options and enabled technologies. This project reviews findings that were observed when cloud platforms were evaluated for bulk geoprocessing capabilities based on data handling and application development requirements.

Brown, Richard B.↗