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At least 91 records · Page 5

Vibrational characterization of a diiron bridging hydride complex – a model for hydrogen catalysis

A diiron complex containing a bridging hydride and a protonated terminal thiolate of the form [(m,k 2 - bdtH)(m-PPh 2 )(m-H)Fe 2 (CO) 5 ] + has been investigated through 57 Fe nuclear resonance vibrational spectroscopy (NRVS) and interpreted using density functional theory (DFT) calculations. We report the Fe–mH–Fe wagging mode, and indications for Fe–mD stretching vibrations in the D-isotopologue, observed by 57 Fe-NRVS. Our combined approach demonstrates an asymmetric sharing of the hydride between the two iron sites that yields two nondegenerate Fe–mH/D stretching vibrations. The studied complex provides an important model relevant to biological hydrogen catalysis intermediates. The complex mimics proposals for the binuclear metal sites in [FeFe] and [NiFe] hydrogenases. It is also an appealing prototype for the ‘Janus intermediate’ of nitrogenase, which has been proposed to contain two bridging Fe–H–Fe hydrides and two protonated sulfurs at the FeMo-cofactor. The significance of observing indirect effects of the bridging hydride, as well as obstacles in its direct observation, is discussed in the context of biological hydrogen intermediates.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Control-Affine Schrödinger Bridge and Generalized Bohm Potential

From a stochastic control perspective, the Schrödinger bridge is a density-valued continuous curve parameterized by time that connects a given pair of initial and terminal probability densities via minimum effort controlled Brownian motion. The control-affine Schrödinger bridge extends this idea to a generic control-affine Itô diffusion, possibly with an additive state cost. Here, in this letter, we recast the necessary conditions of optimality for the control-affine Schrödinger bridge problem as a two point boundary value problem for a quantum mechanical Schrödinger PDE with complex potential. This complex-valued potential is a generalization of the real-valued Bohm potential in quantum mechanics. Our derived potential is akin to the optical potential in nuclear physics where the real part of the potential encodes elastic scattering (transmission of wave function), and the imaginary part encodes inelastic scattering (absorption of wave function). The key takeaway is that the process noise that drives the evolution of probability densities induces an absorbing medium in the evolution of wave function. These results make new connections between control theory and non-equilibrium statistical mechanics through the lens of quantum mechanics.

Markov processes↗

Residual Stress Limits Gridline Bridging in Cracked Solar Cells

Cracks in solar cells can be generated in various ways, but this does not mean immediate power loss. Previous studies showed that gridlines bridge cracked silicon cells, and the bridging behavior decreases during the contact and separation of gridlines within bare cells. In this study, we investigate bridging behavior in laminated monocrystalline cells. We characterize the behavior with Weibull analysis of critical crack opening distance (COD), at which the gridline is completely separated. The Weibull analysis of the laminated cell shows a good agreement with bare cells at the first cycle. However, we observe different behavior during cyclic bending. Bare cells show gradual decay of critical COD, while laminated cells show instant decay and plateau. We hypothesize that the difference is due to residual stress, squeezing gridlines, and causing plastic deformation. This is justified by the correlation between critical COD and gridline morphology. In the presentation, we shall present a Weibull analysis of the cyclic bending of a laminated cell with a reduced residual stress effect.

bending↗

(U) The Effects of Impurities on Detonator Bridge Performance

The primary route for impurities to impact bridge performance is through an increase in resistivity leading to premature bridge burst resulting in both decreased burst time and burst current. Changes in burst time could increase timing error while a decrease in burst current could reduce the firing margin. The most consistent results may be achieved by the minimization of impurities. However, since complete elimination is not practical, a practical production specification approach is presented. Further, since specification limits should be based on performance, a practical approach to estimate and simulate the effects of impurities is also provided using the existing Davis Bridge Burst Model.

42 ENGINEERING↗

43-0434 Bridge Inspection Report 2022

This report covers the inspection findings for the Routine Inspection of the Omega Bridge conducted on September 23-25, 2022 and the Fracture Critical Member (FCM) Inspection conducted on June 26-27, 2021. Note that due to complications with the under-bridge access unit, portions of the Routine Inspection and the entire FCM Inspection could not be completed in 2022. As a result, the superstructure condition reported herein is based on the 2021 inspection whereas the deck and substructure conditions are based on the 2022 inspection. The superstructure condition will be updated when the inspection is completed in 2023. The inspections were completed according to the standards referenced in EXHIBIT “D” SCOPE OF WORK AND TECHNICAL SPECIFICATIONS including the National Bridge Inspection Standards (23 CFR Part 650, dated 12/14/2004) and other FHWA, NMDOT, and AASHTO codes and standards.

42 ENGINEERING↗

Routine & Nonredundant Steel Tension Member (NSTM) Inspection Report (Final): Property ID No. 43-0434 - Los Alamos Canyon Bridge

This report covers the inspection findings for the Routine and Nonredundant Steel Tension Member (NSTM) Inspection of the Los Alamos Canyon Bridge over Omega Rd conducted on June 7-9, 2024. The inspections were completed according to the standards referenced in DOE O 437.1 Bridge and Tunnel Management including the National Bridge Inspection Standards (23 CFR Part 650, dated 12/14/2004) and other Federal Highway Administration (FHWA), New Mexico Department of Transportation (NMDOT), and American Association of State Highway and Transportation Officials (AASHTO) codes and standards.

42 ENGINEERING↗

The CO Emission in the Taffy Galaxies (UGC 12914/15) at 60 pc Resolution. I. The Battle for Star Formation in the Turbulent Taffy Bridge

We present Atacama Large Millimeter/submillimeter Array observations at a spatial resolution of $0^{"}_{.}2$ (60 pc) of CO emission from the Taffy galaxies (UGC 12914/5). The observations are compared with narrowband Paα, mid-IR, radio continuum and X-ray imaging, plus optical spectroscopy. The galaxies have undergone a recent head-on collision, creating a massive gaseous bridge that is known to be highly turbulent. The bridge contains a complex web of narrow molecular filaments and clumps. The majority of the filaments are devoid of star formation, and fall significantly below the Kennicutt–Schmidt relationship for normal galaxies, especially for the numerous regions undetected in Paα emission. Within the loosely connected filaments and clumps of gas we find regions of high velocity dispersion that appear gravitationally unbound for a wide range of likely values of X CO . Like the "Firecracker" region in the Antennae system, they would require extremely high external dynamical or thermal pressure to stop them dissipating rapidly on short crossing timescales of 2–5 Myr. We suggest that the clouds may be transient structures within a highly turbulent multiphase medium that is strongly suppressing star formation. Despite the overall turbulence in the system, stars seem to have formed in compact hotspots within a kiloparsec-sized extragalactic H ii region, where the molecular gas has a lower velocity dispersion than elsewhere, and shows evidence for a collision with an ionized gas cloud. Like the shocked gas in the Stephan's Quintet group, the conditions in the Taffy bridge shows how difficult it is to form stars within a turbulent, multiphase, gas.

79 ASTRONOMY AND ASTROPHYSICS↗

A method for detecting structural deterioration in bridges

The problem of detecting deterioration in bridge structures is studied with the use of Randomdec analysis. Randomdec signatures, derived from the ambient bridge vibrations in the acoustic range, were obtained for a girder bridge over a period of a year to show the insensitivity of the signatures to environmental changes. A laboratory study was also conducted to show the sensitivity of signatures to fatigue cracks on the order of a centimeter in length in steel beams.

Cole, H. A., Jr.↗

Thermocapillary convection in a liquid bridge

Results from experiments on thermocapillary flow in a vertical liquid bridge are reported. Data on surface velocities are presented for four different silicone oils at several values of the temperature difference across the liquid bridge and for three different average temperatures. Also, axial velocity measured as a function of radial position in the bridge is reported. A theoretical model of the velocity and temperature fields in the system is formulated and solved by finite differences. The experimental data on surface velocities are nondimensionalized, and are found to collapse on a single line when plotted against the Marangoni number. Scaled velocities are relatively insensitive to changes in the value of the Marangoni number from 20 to 290, and the Prandtl number from 1460 to 7120. The data are in reasonable accord with predictions from theory.

Mcneil, Thomas J.↗

Implementation of thermal residual stresses in the analysis of fiber bridged matrix crack growth in titanium matrix composites

In this research, thermal residual stresses were incorporated in an analysis of fiber-bridged matrix cracks in unidirectional and cross-ply titanium matrix composites (TMC) containing center holes or center notches. Two TMC were investigated, namely, SCS-6/Timelal-21S laminates. Experimentally, matrix crack initiation and growth were monitored during tension-tension fatigue tests conducted at room temperature and at an elevated temperature of 200 C. Analytically, thermal residual stresses were included in a fiber bridging (FB) model. The local R-ratio and stress-intensity factor in the matrix due to thermal and mechanical loadings were calculated and used to evaluate the matrix crack growth behavior in the two materials studied. The frictional shear stress term, tau, assumed in this model was used as a curve-fitting parameter to matrix crack growth data. The scatter band in the values of tau used to fit the matrix crack growth data was significantly reduced when thermal residual stresses were included in the fiber bridging analysis. For a given material system, lay-up and temperature, a single value of tau was sufficient to analyze the crack growth data. It was revealed in this study that thermal residual stresses are an important factor overlooked in the original FB models.

Bakuckas, John G., Jr.↗

Experimental design for the evaluation of high-T(sub c) superconductive thermal bridges in a sensor satellite

Infrared sensor satellites, which consist of cryogenic infrared sensor detectors, electrical instrumentation, and data acquisition systems, are used to monitor the conditions of the earth's upper atmosphere in order to evaluate its present and future changes. Currently, the electrical connections (instrumentation), which act as thermal bridges between the cryogenic infrared sensor and the significantly warmer data acquisition unit of the sensor satellite system, constitute a significant portion of the heat load on the cryogen. As a part of extending the mission life of the sensor satellite system, the researchers at the National Aeronautics and Space Administration's Langley Research Center (NASA-LaRC) are evaluating the effectiveness of replacing the currently used manganin wires with high-temperature superconductive (HTS) materials as the electrical connections (thermal bridges). In conjunction with the study being conducted at NASA-LaRC, the proposed research is to design a space experiment to determine the thermal savings on a cryogenic subsystem when manganin leads are replaced by HTS leads printed onto a substrate with a low thermal conductivity, and to determine the thermal conductivities of HTS materials. The experiment is designed to compare manganin wires with two different types of superconductors on substrates by determining the heat loss by the thermal bridges and providing temperature measurements for the estimation of thermal conductivity. A conductive mathematical model has been developed and used as a key tool in the design process and subsequent analysis.

Scott, Elaine P.↗

Dynamics and statics of nonaxisymmetric liquid bridges

We finished the construction of the experimental apparatus and the design and testing of some of the visualization and data acquisition techniques. Experimental work focused on three areas: force measurements, loss of stability to nonaxisymmetric bridges, and vibration behavior. The experimental work is summarized in section 2. Selected results from our force measurement experiments are outlined in section 3. In addition we worked on the theory of the dynamic stability of axisymmetric bridges and undertook numerical simulation of the effects of inclined gravity vectors on the minimum volume stability limit for static bridges. The results and status of our theoretical work and numerical simulation are described in section 4. Papers published and in preparation, conference presentations, etc., are described in section 5. Work planned for the third year is discussed in section 6. References cited in the report are listed in section 7.

Alexander, J. Iwan D.↗

Dynamics and Statics of Nonaxisymmetric Liquid Bridges

Theoretical and experimental investigation of the stability of nonaxisymmetric and nonaxisymmetric bridges contained between equal and unequal radii disks as a function of Bond and Weber number with emphasis on the transition from unstable axisymmetric to stable nonaxisymmetric shapes, are conducted. Numerical analysis of the stability of nonaxisymmetric bridges between unequal disks for various orientations of the gravity vector is performed. Experimental and theoretical investigation of large (nonaxisymmetric) oscillations and breaking of liquid bridges are also conducted.

Alexander, J. Iwan D.↗

Stability Limits and Dynamics of Nonaxisymmetric Liquid Bridges

Theoretical and experimental investigation of the stability of nonaxisymmetric and axisymmetric bridges contained between equal and unequal radii disks as a function of Bond and Weber number with emphasis on the transition from unstable axisymmetric to stable nonaxisymmetric shapes. Numerical analysis of the stability of nonaxisymmetric bridges between unequal disks for various orientations of the gravity vector Experimental and numerical investigation of bridge stability (nonaxisymmetric and axisymmetric), large amplitude (nonaxisymmetric) oscillations and breaking.

Alexander, J. Iwan D.↗

A Conversion of Wheatstone Bridge to Current-Loop Signal Conditioning for Strain Gages

Current loop circuitry replaced Wheatstone bridge circuitry to signal-condition strain gage transducers in more than 350 data channels for two different test programs at NASA Dryden Flight Research Center. The uncorrected test data from current loop circuitry had a lower noise level than data from comparable Wheatstone bridge circuitry, were linear with respect to gage-resistance change, and were uninfluenced by varying lead-wire resistance. The current loop channels were easier for the technicians to set up, verify, and operate than equivalent Wheatstone bridge channels. Design choices and circuit details are presented in this paper in addition to operational experience.

Anderson, Karl F.↗

Stability Limits and Dynamics of Nonaxisymmetric Liquid Bridges

Theoretical and experimental investigation of the stability of nonaxisymmetric and nonaxisymmetric bridges contained between equal and unequal radii disks as a function of Bond and Weber number with emphasis on the transition from unstable axisymmetric to stable nonaxisymmetric shapes. Numerical analysis of the stability of nonaxisymmetric bridges for various orientations of the gravity vector for equal and unequal disks. Experimental and theoretical investigation of large (nonaxisymmetric) oscillations and breaking of liquid bridges. This project involves both experimental and theoretical work. Static and dynamic experiments are conducted in a Plateau tank which makes a range of static Bond numbers accessible.

Alexander, J. Iwan D.↗

A Bridge Health Monitoring Method Using the Hilbert-Huang Transform: A Case Study

We have developed a new method for nondestructive instrument method to monitor the health of a bridge. This new method is based on a transient test load and simple data collection. The nuclear of the method is the new invented nonstationary and nonlinear time series analysis method, the Empirical Mode Decomposition and Hilbert Spectral Analysis. The final decision on the health of the bridge structure is based on the nonlinear characteristic of the data, and on the comparison between the free and the forced vibration frequencies. Thus this alternative method enjoys many advantages: (1) no a priori data required, (2) simple data collection, and (3) minimum traffic disruption. Results from a case study of the Shing-Nan Bridge in Hou-Wei will be reported.

Huang, Norden E.↗

Rarefied Transitional Bridging of Blunt Body Aerodynamics

The bridging procedures discussed provide an accurate engineering method for predicting rarefied transitional aerodynamics of spherically-blunted cone entry vehicles. The single-point procedure offers a way to improve the bridging procedures while minimizing the computational effort. However, the accuracy of these procedures ultimately depends on accurate knowledge of the aerodynamics in the free-molecular and continuum limits. The excellent agreement shown for DSMC predictions and bridging relations with the Viking flight data in transitional regime enhance the coincidence in these procedures.

Wilmoth, R. G.↗