Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “breakup reactions”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

87 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Halo Nuclei from Ab Initio Nuclear Theory

A realistic description of halo nuclei, characterized by low-lying breakup thresholds, requires a proper treatment of continuum effects. We have developed an ab initio approach, the No-Core Shell Model with Continuum (NCSMC), capable of describing both bound and unbound states in light nuclei in a unified way. With chiral two- and three-nucleon interactions as the only input, we can predict the structure and dynamics of halo and other light nuclei and, by comparing to available experimental data, test the quality of chiral nuclear forces. We review NCSMC calculations of weakly bound states and resonances of the exotic halo nuclei 6He, 8B, 11Be, and 15C. For the latter, we discuss its production in the capture reaction 14C(n,𝛾 )15C. We highlight the challenges of a description of 6He as a Borromean n-n-4He system. Finally, we present our calculations of excited states in 10Be exhibiting a one-neutron halo structure and a large scale No-Core Shell Model investigation of 11Li as a precursor of a full n-n-9Li NCSMC study.

Navrátil, Petr↗
NASA NTRS1989

Investigation of an excited jet diffusion flame at elevated pressure

Experiments are carried out for studying the relationship between flow structure, flow excitation, and the reaction process in the near field of a low-speed coflowing jet diffusion flame. The effect of axial forcing and increasing pressure on the structure and controllability of the flame is studied to elucidate some of the underlying control mechanisms. The experiments are conducted in a variable-pressure flow facility permitting the study of reacting flows in the 10-1000 kPa (0.1-10 atm) pressure range. The flame is excited by a small-amplitude periodic fluctuation added to the central fuel jet exit velocity. Among the varied excitation frequencies employed, a narrow band is found in which several of the flow instabilities seem to be in coincidence, causing periodic breakup of the flame into a series of distinct eddies. This is called the strongly-coupled state. Effects of excitation frequencies at and above the strongly-coupled range are presented.

Strawa, Anthony W.↗
DOE OSTI2023

Atomic autoionization in the photo-dissociation of super-excited deuterated water molecules fragmenting into D + + O + + D

We present the relaxation dynamics of deuterated water molecules via autoionization, initiated by the absorption of a 61 eV photon, producing the very rare D + + O + + D breakup channel. We employ the COLd target recoil ion momentum spectroscopy method to measure the 3D momenta of the ionic fragments and emitted electrons from the dissociating molecule in coincidence. We interpret the results using the potential energy surfaces extracted from multi-reference configuration interaction calculations. The measured particle energy distributions can be related to a super-excited monocationic state located above the double ionization threshold of D 2 O. The autoionized electron energy shows a sharp distribution centered around 0.5 eV, which is a signature of the atomic oxygen autoionization occurring in the direct and sequential dissociation processes of D 2 O + * at a large internuclear distance. In this way, an O + radical fragment and a low-energy electron are created, both of which can trigger secondary reactions in their environment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1988

Nonlinear Tollmien-Schlichting/vortex interaction in boundary layers

The nonlinear reaction between two oblique 3-D Tollmein-Schlichting (TS) waves and their induced streamwise-vortex flow is considered theoretically for an imcompressible boundary layer. The same theory applies to the destabilization of an incident vortex motion by subharmonic TS waves, followed by interaction. The scales and flow structure involved are addressed for high Reynolds numbers. The nonlionear interaction is powerful, starting at quite low amplitudes with a triple-deck structure for the TS waves but a large-scale structure for the induced vortex, after which strong nonlinear amplification occurs. This includes nonparallel-flow effects. The nonlinear interaction is governed by a partial differential system for the vortex flow coupled with an ordinary-differential one for the TS pressure. The solution properties found sometimes produce a breakup within a finite distance and sometimes further downstream, depending on the input amplitudes upstream and on the wave angles, and that then leads to the second stages of interaction associated with higher amplitudes, the main second stages giving either long-scale phenomena significantly affected by nonparallelism or shorter quasi-parallel ones governed by the full nonlinear triple-deck response.

Hall, P.↗
NASA NTRS1989

Nonlinear a Tollmien-Schlichting/vortex interaction in boundary layers

The nonlinear reaction between two oblique three-dimensional Tollmien-Schlichting (TS) waves and their induced streamwise-vortex flow is considered theoretically for an incompressible boundary layer. The same theory applies to the destabilization of an incident vortex motion by subharmonic TS waves, followed by interaction. The scales and flow structure involved are addressed for high Reynolds numbers. The nonlinear interaction is powerful, starting at quite low amplitudes with a triple-deck structure for the TS waves but a large-scale structure for the induced vortex, after which strong nonlinear amplification occurs. This includes nonparallel-flow effects. The nonlinear interaction is governed by a partial differential system for the vortex flow coupled with an ordinary-differential one for the TS pressure. The solution properties found sometimes produce a breakup within a finite distance and sometimes further downstream, depending on the input amplitudes upstream and on the wave angles, and that then leads to the second stages of interaction associated with higher amplitudes, the main second stages giving either long-scale phenomena significantly affected by nonparallelism or shorter quasi-parallel ones governed by the full nonlinear triple-deck response.

Hall, P.↗
DOE OSTI2024

Quantifying electron transport in aggregated colloidal suspensions in the strong flow regime

Electron transport in complex fluids, biology, and soft matter is a valuable characteristic in processes ranging from redox reactions to electrochemical energy storage. These processes often employ conductor–insulator composites in which electron transport properties are fundamentally linked to the microstructure and dynamics of the conductive phase. While microstructure and dynamics are well recognized as key determinants of the electrical properties, a unified description of their effect has yet to be determined, especially under flowing conditions. In this work, the conductivity and shear viscosity are measured for conductive colloidal suspensions to build a unified description by exploiting both recent quantification of the effect of flow-induced dynamics on electron transport and well-established relationships between electrical properties, microstructure, and flow. These model suspensions consist of conductive carbon black (CB) particles dispersed in fluids of varying viscosities and dielectric constants. In a stable, well-characterized shear rate regime where all suspensions undergo self-similar agglomerate breakup, competing relationships between conductivity and shear rate were observed. To account for the role of variable agglomerate size, equivalent microstructural states were identified using a dimensionless fluid Mason number, Mn f , which allowed for isolation of the role of dynamics on the flow-induced electron transport rate. At equivalent microstructural states, shear-enhanced particle–particle collisions are found to dominate the electron transport rate. This work rationalizes seemingly contradictory experimental observations in literature concerning the shear-dependent electrical properties of CB suspensions and can be extended to other flowing composite systems.

Science & Technology - Other Topics↗
NASA NTRS1996

Atomization and Dispersion of a Liquid Jet Injected Into a Crossflow of Air

In recent years, environmental regulations have become more stringent, requiring lower emissions of mainly nitrogen oxides (NOx), as well as carbon monoxide (CO) and unburned hydrocarbons (UHC). These regulations have forced the gas turbine industry to examine non-conventional combustion strategies, such as the lean burn approach. The reasoning behind operating under lean conditions is to maintain the temperature of combustion near and below temperatures required for the formation of thermal nitric oxide (NO). To be successful, however, the lean processes require careful preparation of the fuel/air mixture to preclude formation of either locally rich reaction zones, which may give rise to NO formation, or locally lean reaction zones, which may give rise to inefficient fuel processing. As a result fuel preparation is crucial to the development and success of new aeroengine combustor technologies. A key element of the fuel preparation process is the fuel nozzle. As nozzle technologies have developed, airblast atomization has been adopted for both industrial and aircraft gas turbine applications. However, the majority of the work to date has focused on prefilming nozzles, which despite their complexity and high cost have become an industry standard for conventional combustion strategies. It is likely that the new strategies required to meet future emissions goals will utilize novel fuel injector approaches, such as radial injection. This thesis proposes and demonstrates an experiment to examine, on a mechanistic level (i.e., the physics of the action), the processes associated with the atomization, evaporation, and dispersion of a liquid jet introduced, from a radial, plain-jet airblast injector, into a crossflow of air. This understanding requires the knowledge not only of what factors influence atomization, but also the underlying mechanism associated with liquid breakup and dispersion. The experimental data acquired identify conditions and geometries for improved performance of radial airblast injectors.

Seay, J. E.↗
DOE OSTI2021

Investigation of the background in coherent J/ψ production at the EIC

Understanding various fundamental properties of nucleons and nuclei is among the most important scientific goals at the upcoming Electron-Ion Collider (EIC). With the unprecedented opportunity provided by the next-generation machine, the EIC might provide definitive answers to many standing puzzles and open questions in modern nuclear physics. We investigate one of the golden measurements proposed at the EIC, which is to obtain the spatial gluon density distribution within a lead (Pb) nucleus. The proposed experimental process is the exclusive J/ψ vector-meson production off the Pb nucleus: e + Pb → e' + J/ψ + Pb'. The Fourier transformation of the momentum transfer |t| distribution of the coherent diffraction is the transverse gluon spatial distribution. In order to measure it, the experiment has to overcome an overwhelmingly large background arising from the incoherent diffractive production, where the nucleus Pb' mostly breaks up into fragments of particles in the far-forward direction close to the hadron-going beam rapidity. We systematically study the rejection of incoherent J/ψ production by vetoing products from these nuclear breakups—protons, neutrons, and photons—which is based on the BeAGLE event generator and the most up-to-date EIC Far-forward Interaction Region design. The achieved vetoing efficiency, the ratio between the numbers of vetoed events and total incoherent events, ranges from about 80% to 99% depending on |t|. Assuming a 5% smearing applied to the reconstructed |t| resolution in the Sar t re model, this vetoing efficiency can suppress the incoherent background to at least the first minimum of the coherent |t| distribution. Experimental and accelerator machine challenges as well as potential improvements are discussed herein.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2025

Growth of Hexagonal Boron Nitride from Molten Nickel Solutions: A Reactive Molecular Dynamics Study

Metal flux methods are excellent for synthesizing high-quality hexagonal boron nitride (hBN) crystals, but the atomic mechanisms of hBN nucleation and growth in these systems are poorly understood and difficult to probe experimentally. Here, we harness classical reactive molecular dynamics (ReaxFF) to unravel the mechanisms of hBN synthesis from liquid nickel solvent over time scales up to 30 ns. These simulations mimic experimental conditions by including relatively large liquid nickel slabs containing dissolved boron and a molecular nitrogen gas phase. Overall, the reaction takes place almost exclusively on the surface of the liquid nickel, owing to the low solubility of nitrogen in bulk nickel and the intermediate species’ preference for the metal–gas interface. The formation of hBN invariably begins by reaction of dinitrogen with nickel-solvated boron atoms at the surface, forming intermediate N–N–B species, which typically evolve into B–N–B units through a short-lived intermediate where a single nitrogen atom is coordinated by one nitrogen and two boron atoms. The resulting B–N–B units, in turn, coalesce with growing hBN nuclei and carry nitrogen between hBN nanocrystals in an Ostwald ripening process. The amount of hBN produced on the tens of nanosecond time scale depends critically on the boron concentration, while having a much weaker dependence on the N 2 pressure for the regime considered (N 2 pressures of 2.5–10 MPa, Ni–B solutions with 6–12% boron by atom fraction). The highest rate of hBN formation occurs at the lowest temperature considered (1750 K, just above the melting point of nickel), while no hBN sheets are formed at 2000 K or above. An analysis of the transition pathways for nitrogen atoms shows that the final step, incorporation of small B–N motifs into larger hBN sheets, is the rate-limiting step in the regimes considered. While raising the temperature from 1750 to 2000 K has little effect on the formation of intermediates (N–N–B, B–N–B, etc.), the lack of large hBN sheets at temperatures >1900 K is explained by decreased probability of the final step and increased probability of breakup of hBN into B–N motifs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Impact of nitrogen molecular breakup on divertor conditions in JET L-mode plasmas using SOLPS-ITER

SOLPS-ITER simulations of nitrogen-seeded, low-confinement mode plasmas in the Joint European Torus (JET) predict that the electron temperature in the low-field side (LFS) divertor leg is reduced locally by up to an order of magnitude when nitrogen is assumed to recycle as molecules (N 2 ) instead of atoms using a fixed nitrogen injection rate. The LFS divertor temperature reduction under the assumption of molecular recycling occurs due to a three-step mechanism: (1) the plasma penetration of nitrogen atoms is increased due to the strong triple bond of the N 2 molecule and the kinetic energy release in the dissociation event, both mechanisms contributing equally, (2) the abundance of (particularly multiply-charged) nitrogen ions in the divertor is increased and (3) the electron temperature is reduced due to the increase in radiation (by up to a factor of 4) from nitrogen ions. Setting the volume-integrated nitrogen radiated power to a constant value (0.6 MW) instead of the nitrogen injection rate, SOLPS-ITER predicts under the molecular nitrogen recycling assumption that the peak line-integrated N II, N III and N IV intensities in the LFS divertor are approximately within 15%, 35% and 5%, respectively, of the reference atomic nitrogen recycling case. The predicted peak N II, N III and N IV intensities under either assumption are within 30%, 65% and 5%, respectively, of measurements using the vertically viewing mirror-link divertor spectrometer (Meigs et al., 2010) in nitrogen-seeded JET L-mode plasmas (Lomanowski et al., 2019). ERO2.0 simulations using a constant nitrogen seeding rate on static background plasma solutions from EDGE2D-EIRENE (previously presented in Mäenpää et al., (2022), revised here to include fast reflections) predict that N II to N IV line emission is increased by 20% to 30% when nitrogen is assumed to recycle as molecules, demonstrating the importance of considering the effect of molecular dissociation reactions on the divertor plasma in a self-consistent manner.

Divertor↗
DOE OSTI2026

A stress-based fracture model for reacting metal ejecta

The evolution of reacting metal ejecta continues to be a topic of interest at the forefront of metals in reactive and extreme environments. Ejecta are small particles formed when the surface of a metal undergoes Richtmyer–Meshkov instability from a strong shock. Experiments have shown that in the case where ejecta are in ambient conditions that induce a reaction, the ejecta behave irregularly. The ejecta temperature rises and then plateaus, and the acceleration profile shows unexpected jumps. These variations are assumed to be related to the exothermic heat release and particle mass loss caused by the reaction. To explain this phenomenon, efforts to model this in simulations have increased. While current models can capture many of these physical processes, they currently assign a constant reaction shell thickness with little physical reasoning. This work remedies this problem by assigning a dynamic physically informed shell thickness to the reacting particles, using solid analysis. The shell thickness of the particles impacts the rate of change of reacted mass in the system, as well as the rate at which the particles react. The model is based on a simple stress–strain relationship and gives a dynamic assignment for when the reacting particle should begin to fracture. We compare our model to the previous computational and simulation data to analyze the effects of different model parameters.

42 ENGINEERING↗
DOE OSTI2022

Step-by-step state-selective tracking of fragmentation dynamics of water dications by momentum imaging

Abstract The double photoionization of a molecule by one photon ejects two electrons and typically creates an unstable dication. Observing the subsequent fragmentation products in coincidence can reveal a surprisingly detailed picture of the dynamics. Determining the time evolution and quantum mechanical states involved leads to deeper understanding of molecular dynamics. Here in a combined experimental and theoretical study, we unambiguously separate the sequential breakup via D + + OD + intermediates, from other processes leading to the same D + + D + + O final products of double ionization of water by a single photon. Moreover, we experimentally identify, separate, and follow step by step, two pathways involving the b 1 Σ + and a 1 Δ electronic states of the intermediate OD + ion. Our classical trajectory calculations on the relevant potential energy surfaces reproduce well the measured data and, combined with the experiment, enable the determination of the internal energy and angular momentum distribution of the OD + intermediate.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2022

Probing the Gluonic Structure of the Deuteron with J / ψ Photoproduction in d + Au Ultraperipheral Collisions

Understanding gluon density distributions and how they are modified in nuclei are among the most important goals in nuclear physics. In recent years, diffractive vector meson production measured in ultraperipheral collisions (UPCs) at heavy-ion colliders has provided a new tool for probing the gluon density. In this Letter, we report the first measurement of J/psi photoproduction off the deuteron in UPCs at the center-of-mass energy root √S-NN = 200 GeV in d + Au collisions. The differential cross section as a function of momentum transfer -t is measured. In addition, data with a neutron tagged in the deuteron-going zero-degree calorimeter is investigated for the first time, which is found to be consistent with the expectation of incoherent diffractive scattering at low momentum transfer. Theoretical predictions based on the color glass condensate saturation model and the leading twist approximation nuclear shadowing model are compared with the data quantitatively. A better agreement with the saturation model has been observed. With the current measurement, the results are found to be directly sensitive to the gluon density distribution of the deuteron and the deuteron breakup process, which provides insights into the nuclear gluonic structure.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2025

Investigation of post-breakup Coulomb acceleration using a trajectory model

Intermediate mass fragments ejected during the deexcitation of excited projectilelike fragments may promptly decay following ejection; the daughter particles that are subsequently produced are subject to interactions with the residual nucleus that affect final-state observables, a process herein referred to as post-breakup Coulomb acceleration. A simple classical Coulomb interaction model was used to study modification of 8 Be (2 + ), 5 Li (3/2 – ), 7 Li (7/2 – ), 7 Be (7/2 – ), and states in 12 B emitted following heavy-ion collisions of 28 Si + 12 C at 35 MeV/nucleon. Here, in contrast to previous work studying 8 Be (2 + ), excellent agreement between simulation and experiment was obtained using only Coulomb forces when either a Lorentzian or R-matrix line shape was used to describe the initial relative energy rather than a Gaussian. In consideration of the obtained results, improvements to the model and evaluation of experimental data are discussed as future directions, but it was concluded that the effects observed in the present data can be accurately described using only elements of classical mechanics and that the process is largely understood for a wide range of state lifetimes and mass and charge (a)symmetries.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2026

Measurement of 𝐷 0 Meson Photoproduction in Ultraperipheral Heavy Ion Collisions

This Letter reports the first measurement of photonuclear 𝐷 0 meson production in ultraperipheral heavy ion collisions. The study is performed using lead-lead collision data, with an integrated luminosity of 1.34 nb −1 , collected by the CMS experiment at a nucleon-nucleon center-of-mass energy of 5.36 TeV. Photonuclear events, where one of the colliding nuclei breaks up and the other remains intact, are selected based on breakup neutron emissions and by requiring no particle activity in a large rapidity interval in the direction of the photon-emitting nucleus. The 𝐷 0 mesons are reconstructed via the 𝐷 0 → 𝐾 −⁢ 𝜋 + decay channel, with the cross section measured as a function of 𝐷 0 meson transverse momentum and rapidity. The results are compared with next-to-leading-order perturbative QCD calculations that employ recent parametrizations of the lead nuclear parton distribution functions, as well as with predictions based on the color glass condensate framework. This measurement is the first photonuclear collision study characterizing parton distribution functions of lead nuclei for parton fractional momenta 𝑥 (relative to the nucleon) ranging approximately from a few 10 −4 to 10 −2 for different hard energy scale 𝑄 2 selections.

charm quark↗