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At least 91 records · Page 5

On the applicability of the Redlich-Kister framework for viscosity estimation of molten halide salt mixtures

For molten halide salt mixtures already being utilized or under consideration for carbon-free energy production systems, it is crucial that their viscosity is well understood so that system thermal hydraulics can be reliably assessed. Because of the difficulty in accurately measuring molten halide viscosity and the sheer size of the matrix of possible higher order salt mixtures that may be of interest to the energy industry, there are several gaps in the quantified understanding of molten halide viscosity across this matrix. As such, both first-principles and semi-empirical modeling techniques may be crucial for rapidly assessing this broad, complex compositional domain. Herein, the Redlich-Kister framework is applied to assess the feasibility of broadly interpolating and estimating the viscosity of several pseudobinary and pseudoternary molten halide salt systems that may be of key interest to the energy industry. The framework is based on the assumption that an ideal component and a nonideal component collectively describe the viscosity as a function of composition and temperature for a given molten halide system. Three different ideal models were considered for the ideal component, including Grunburg-Nissan, Katti-Chaudhri, and Gambill methods. Regarding the pseudobinary interpolations, the Redlich-Kister models with either the Grunburg-Nissan or Katti-Chaudhri models as the ideal component resulted in either highly (average error less than 5%) or reasonably (average error less than 15%) accurate interpolations of pseudobinary halide viscosity; BeF 2 - or UF 4 -bearing salts tended to result in reasonably accurate interpolations, whereas other pseudobinary mixtures tended to show high accuracy. Regarding the pseudoternary extrapolations, the Redlich-Kister framework shows reasonable success at estimating the extent to which a pseudoternary system may indicate deviations from ideal Grunburg-Nissan mixing, where discrepancies with comparative experimental data generally stay within 30%. Finally, the primary reasons identified for such discrepancies are (1) inaccuracy in the underlying experimental data, (2) different complexation behavior in the higher order systems compared to the pseudobinary subsystems, and (3) extrapolation into temperatures too far out of the domain, which is valid for the underlying experimental data feeding the Redlich-Kister model.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Viscosity of transient glass-forming melt and its relation to foaming during batch-to-glass conversion

Primary foam, which affects the heat transfer into the glass batch and the final glass quality, occurs when a sufficient quantity of transient glass-forming melt evolves with viscosity low enough to close the open porosity of the reacting glass batch. To better understand how the fraction of transient melt and its viscosity affect the primary foam temperature range, we determined, with x-ray diffraction, the fraction and composition of the transient glass-forming melt in a heated waste glass melter feed as a function of temperature. Then we prepared a set of transient melts that occurred within the foaming temperature interval and measured their viscosities with spindle and falling sphere viscometers. Further, the results agree with the Adam-Gibbs and VFT viscosity-composition models, even for transient melt compositions outside of the models compositional validity range. As silica and other refractory particles dissolved in the predominantly borate transient melt while temperature increased, viscosity increased from the initial value of ~500 Pa s at the onset of foaming (~650°C) to a maximum of ~770 Pa s when silica dissolution was almost complete (~700°C). As temperature increased further, transient melt viscosity decreased to ~220 Pa s (~850°C) when the primary foam collapsed.

36 MATERIALS SCIENCE↗

Distinct Gas-Particle Partitioning and Viscosity Characteristics of Secondary Organic Aerosols Derived from α-Pinene versus Ocimene

Secondary organic aerosols (SOA) have complex, multicomponent composition that controls particle viscosity and gas-particle partitioning, key factors to their atmospheric evolution. This study investigates the chemical composition, volatility and viscosity of SOA formed by ozonolysis of cyclic α-pinene (PSOA) and acyclic ocimene (OSOA) monoterpenes. Using Temperature-Programmed Desorption combined with Direct Analysis in Real-Time ionization and High-Resolution Mass Spectrometry, we determined the molecular composition and saturation mass concentration of individual SOA constituents. These data enabled gas-particle partitioning and viscosity estimates under varied atmospheric conditions. PSOA, composed of higher molecular weight and less oxidized species, shows higher condensability and viscosity under high total organic mass (tOM) loadings. Here, in contrast, OSOA, consisting of more oxidized, lower molecular weight species, exhibits greater sensitivity to tOM, with viscosity increasing significantly upon dilution. Poke-flow experiments support this trend, indicating that OSOA undergoes more dynamic compositional and phase changes during atmospheric aging. These observations reveal distinct dynamic trends in the atmospheric transformations and reactivity of SOA from cyclic and acyclic monoterpenes, with the latter showing greater compositional changes during aging that alter viscosity and diffusion. This highlights the importance of incorporating such dynamic transformations into atmospheric models to improve predictions of SOA atmospheric loadings, lifetimes, and impacts.

cyclic and acyclic monoterpenes↗

High-Throughput Screening and Accurate Prediction of Ionic Liquid Viscosities Using Interpretable Machine Learning

Ionic liquids (ILs) are a novel group of green solvents with great promise for various industrial applications, including carbon capture and lignocellulosic biomass deconstruction. However, the use of ILs at the industrial scale remains challenging due to their high viscosities at ambient temperatures. To develop ILs with lower viscosities, a systematic study of their quantitative structure–property relationship (QSPR) is desirable. Here, we developed four machine learning (ML) models to predict viscosity at various temperature and pressure ranges, trained over a wide range of ILs consisting of various cationic and anionic families. ML methods including two-factor polynomial regression (two-factor PR), support vector regression (SVR), feed-forward neural networks (FFNN), and categorical boosting (CATBoost) were developed based on features that have proven useful in previous ML studies: COSMO-RS (conductor-like screening model for real solvents)-derived surface screening charge densities (sigma profiles). FFNN and CATBoost were the most accurate in predicting IL viscosities with lower average absolute relative deviation and higher R2 values on the test set. Tanimoto similarity scores were calculated to characterize the chemical space and structural similarity of the investigated ions. Furthermore, SHapley Additive exPlanation (SHAP) analysis was employed to interpret the ML results. Temperature, the polar area of ILs, and the nonpolar regions of ions are key features that influence the viscosity predictions. Importantly, the IL viscosity prediction here is the most accurate reported to date.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

High-throughput small-angle X-ray scattering reveals effective structure factor transitions linked to high-concentration antibody viscosity

High-concentration monoclonal antibody (mAb) formulations are often constrained by elevated viscosity, largely driven by protein–protein interactions, which complicates manufacturing and limits subcutaneous delivery. Early viscosity risk assessment is essential during discovery, yet traditional measurements require large sample volumes, and lack high-throughput capability. Here, we develop a high-throughput small-angle X-ray scattering (SAXS) protocol to detect mAb self-association at dilute concentrations, enabling early predictive insights into high-concentration viscosity. Synchrotron SAXS measurements were conducted for 21 mAbs formulated in a histidine buffer at pH 6.0. An initial subset of 10 mAbs analyzed across 1–150 mg/mL revealed that effective structure factor transitions in the low-q region, indicative of interparticle interactions, consistently emerged below 25 mg/mL. Subsequently, 11 additional mAbs were analyzed at 1–25 mg/mL using automated liquid handling and flow cells to enable high-throughput screening. High-viscosity mAbs exhibited detectable low-q upturns at concentrations ≤10 mg/mL, whereas low-viscosity mAbs showed downturns. A classification criterion based on effective structure factor transitions accurately classified all high- and low-viscosity mAbs at 150 mg/mL, offering a scalable, sample-efficient alternative to conventional methods. These results extend recent findings on the concentration-dependent sensitivity of SAXS to short-range attractions, demonstrating that they can emerge at lower concentrations than previously reported. This study presents the most comprehensive and diverse SAXS dataset for mAbs reported to date within a single formulation, providing a valuable resource for developing and validating coarse-grained models that can more accurately capture intermolecular interactions governing high-concentration solution behavior, thereby enabling rational antibody engineering and improved developability.

36 MATERIALS SCIENCE↗

CONSTRAINTS ON THE VISCOSITY AND MAGNETIC FIELD IN HOT ACCRETION FLOWS AROUND BLACK HOLES

The magnitude of the viscosity and magnetic field parameters in hot accretion flows is investigated in low luminosity active galactic nuclei (LLAGNs). Theoretical studies show that a geometrically thin, optically thick disk is truncated at mass accretion rates less than a critical value by mass evaporated vertically from the disk to the corona, with the truncated region replaced by an advection dominated accretion flow (ADAF). The critical accretion rate for such a truncation is a function of the viscosity and magnetic field. Observations of X-ray photon indices and spectral fits of a number of LLAGNs published in the literature provide an estimate of the critical rate of mass accretion and the truncation radius, respectively. By comparing the observational results with theoretical predictions, the viscosity and magnetic field parameters in the hot accretion flow region are estimated. Specifically, the mass accretion rates inferred in different sources constrain the viscosity parameter, whereas the truncation radii of the disk, as inferred from spectral fits, further constrain the magnetic field parameter. It is found that the value of the viscosity parameter in the corona/ADAF ranges from 0.17 to 0.5, with values clustered about 0.2-0.3. Magnetic pressure is required by the relatively small truncation radii for some LLAGNs and is found to be as high as its equipartition value with the gas pressure. The inferred values of the viscosity parameter are in agreement with those obtained from the observations of non-stationary accretion in stellar mass black hole X-ray transients. This consistency provides support for the paradigm that a geometrically thin disk is truncated by means of a mass evaporation process from the disk to the corona at low mass accretion rates.

79 ASTRONOMY AND ASTROPHYSICS↗

Critical viscosity of a fluctuating superconductor

We consider a fluctuating superconductor in the vicinity of the transition temperature, T c . The fluctuation shear viscosity is calculated. In two dimensions, the leading correction to viscosity is negative and scales as δη(T) ∝ ln(T–T c ). Critical hydrodynamics of the fluctuating superconductor involves two fluids: a fluid of fluctuating pairs and a quasiparticle fluid of single-electron excitations. The pair viscosity (Aslamazov-Larkin) term is shown to be zero. The (density of states) correction to viscosity of single-electron excitations is negative, which is due to fluctuating pairing that results in a reduction of electron density. Scattering of electrons off of the fluctuations gives rise to an enhanced quasiparticle scattering and another (Maki-Thomson) negative correction to viscosity. Furthermore, our results suggest that fluctuating superconductors provide a promising platform to investigate low-viscosity electronic media and may potentially host fermionic/electronic turbulence. Some experimental probes of two-fluid critical hydrodynamics are proposed such as time-of-flight measurement of turbulent energy cascades in critical cold atom superfluids and magnetic dynamos in three-dimensional fluctuating superconductors.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Bulk viscosity of nuclear matter with pions in the neutrino-trapped regime

Recent work has shown that a population of thermal pions could modify the equation of state and transport properties of hot and dense neutron-rich matter and introduce new reaction pathways to change the proton fraction. In this article we study their impact on the bulk viscosity of dense matter, focusing on the neutrino-trapped regime that would be realized in neutron star mergers and supernovae. We find that the presence of a thermal population of pions alters the bulk viscosity by modifying the EoS (via the susceptibilities) and by providing new reaction pathways to achieve beta equilibrium. In neutron star merger conditions, the bulk viscosity in neutrino-trapped npeμ matter (without pions) has its peak at temperatures of at most a couple MeV and is quite small at temperatures of tens of MeV. We find that thermal pions enhance the low-temperature peak of the bulk viscosity by a factor of a few and shift it to slightly lower temperatures. At higher temperatures, where the pion abundance is large but the bulk viscosity is traditionally small, pions can increase the bulk viscosity by an order of magnitude or more, although it is still orders of magnitude smaller than its peak value.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Viscosity Meaurement Technique for Metal Fuels

Metallic fuels have exceptional transient behavior, excellent thermal conductivity, and a more straightforward reprocessing path, which does not separate out pure plutonium from the process stream. Fabrication of fuel containing minor actinides and rare earth (RE) elements for irradiation tests, for instance, U-20Pu-3Am-2Np-1.0RE-15Zr samples at the Idaho National Laboratory, is generally done by melt casting in an inert atmosphere. For the design of a casting system and further scale up development, computational modeling of the casting process is needed to provide information on melt flow and solidification for process optimization. Therefore, there is a need for melt viscosity data, the most important melt property that controls the melt flow. The goal of the project was to develop a measurement technique that uses fully sealed melt sample with no Americium vapor loss to determine the viscosity of metallic melts and at temperatures relevant to the casting process. The specific objectives of the project were to: develop mathematical models to establish the principle of the measurement method, design and build a viscosity measurement prototype system based on the established principle, and calibrate the system and quantify the uncertainty range. The result of the project indicates that the oscillation cup technique is applicable for melt viscosity measurement. Detailed mathematical models of innovative sample ampoule designs were developed to not only determine melt viscosity, but also melt density under certain designs. Measurement uncertainties were analyzed and quantified. The result of this project can be used as the initial step toward the eventual goal of establishing a viscosity measurement system for radioactive melts.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Viscosity Control Experiment Feasibility Study

Turbulent mix has been invoked to explain many results in Inertial Confinement Fusion (ICF) and High Energy Density (HED) physics, such as reduced yield in capsule implosions. Many ICF capsule implosions exhibit interfacial instabilities seeded by the drive shock, but it is not clear that fully developed turbulence results from this. Many simulations use turbulent mix models to help match simulation results to data, but this is not appropriate if turbulence is not present. It would be useful to have an experiment where turbulent mixing could be turned on or off by design. The use of high-Z dopants to modify viscosity and the resulting influence on turbulence is considered here. A complicating factor is that the plasma in some implosions can become strongly coupled, which makes the Spitzer expression for viscosity invalid. We first consider equations that cover a broad parameter space in temperature and density to address regimes for various experimental applications. Next, a previous shock-tube and other ICF experiments that investigate viscosity or use doping to examine the effects on yield are reviewed. How viscosity and dopants play a role in capsule yield depends on the region and process under consideration. Experiments and simulations have been performed to study the effects of viscosity on both the hot spot and the fuel/ablator mix. Increases in yield have been seen for some designs, but not all. We then discuss the effect of adding krypton dopant to the gas region of a typical OMEGA and a 2-shock NIF implosion to determine approximately the effect of adding dopant on the computed Reynolds number. Recommendations for a path forward for possible experiments using high-Z dopants to affect viscosity and turbulence are made.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Evolution of eddy viscosity in the wake of a wind turbine

The eddy viscosity hypothesis is a popular method in wind turbine wake modeling for estimating turbulent Reynolds stresses. We document the downstream evolution of eddy viscosity in the wake of a wind turbine from experimental and large-eddy-simulation data. Wake eddy viscosity is isolated from its surroundings by subtracting the inflow profile, and the driving forces are identified in each wake region. Eddy viscosity varies in response to changes in turbine geometry and nacelle misalignment with larger turbines generating stronger velocity gradients and shear stresses. We propose a model for eddy viscosity based on a Rayleigh distribution. Model parameters are obtained from scaling the eddy viscosity hypothesis and demonstrate satisfactory agreement with the reference data. The model is implemented in the curled wake formulation in the FLOw Redirection and Induction in Steady State (FLORIS) framework and assessed through comparisons with the previous formulation. Our approach produced more accurate flow field estimates with lower total error for the majority of cases.

17 WIND ENERGY↗

Reinventing Design Principles for Developing Low-Viscosity Carbon Dioxide-Binding Organic Liquids for Flue Gas Clean Up

Anthropogenic carbon dioxide (CO 2 ) emission from point sources, such as coal fired-power plants, account for the majority of the green houses gasses in the atmosphere. Capture, storage and utilization are required to mitigate adverse environmental effects. Aqueous amine-based CO 2 capture solvents are currently considered the industry standard, but deployment to market is limited by their high regeneration energy demand. In that context, energy efficient and less-viscous water-lean transformational solvent systems known as CO 2 Binding Organic Liquids (CO 2 BOLs) are being developed in our group to advance this technology to commercialization. Herein, we present a logical design approach based on fundamental concepts of organic chemistry and computer simulations aimed at lowering solvent viscosity. Conceptually, viscosity reduction would be achieved by systemmatic methods such as introduction of steric hindrance on the anion to minimize the intermolecular cation-anion interactions, fine tuning the electronics, hydrogen bonding orientation and strength, and charge solvation. Conventional standard trial-and-error approaches while effective, are time consuming and economically expensive. Herein, we rethink the metrics and design principles of low-viscosity CO 2 capture solvents using a combined synthesis and computational modeling approach. We critically study the impacts of modyfying factors such as as orientation of hydrogen bonding, introduction of higher degrees of freedom and cation or anion charge solvation and assess if or how each factor impacts viscosity of CO 2 BOL CO 2 capture solvents. Ultimately, we found that hydrogen bond orientation and strength is predominantly influencing the viscosity in CO 2 BOL solvents. With this knowledge, a new 1-MEIPADM-2-BOL CO 2 BOL variant was synthesized and tested, resulting in a solvent that is approximately 60% less viscous at 25 mol% CO 2 loading with respect to our base compound 1-IPADM-2-BOL. The insights gained from the current study redefines the fundamental concepts and understanding of what influences viscosity in concentrated organic CO 2 capture solvents.

54 ENVIRONMENTAL SCIENCES↗

Optimization of matrix viscosity improves polypropylene fiber dispersion and properties of engineered cementitious composites

Engineered cementitious composites (ECC) is a durable cementitious material with high tensile ductility and strain-hardening characteristics. Although considered as a cost-effective fiber for ECC, polypropylene (PP) fiber is reportedly difficult to disperse in mortar matrix due to its high aspect ratio and hydrophobicity. In this study, the matrix viscosity of a low-carbon ECC based on limestone calcined clay cement was tailored as a variable to improve PP fiber dispersion under a pre-determined mixing protocol. The effect of matrix viscosity on the composite fresh and hardened properties was investigated experimentally. Results suggested an optimal range of matrix viscosity (10.3–11.5 Pa . s) favors the composite tensile strength and strain capacity at 28 days. At the optimal state with a 0.1 % viscosity modifying admixture (VMA)-to-binder mass ratio, PP-ECC achieved 7.0 % tensile strain capacity and 3.5 MPa ultimate tensile strength. When matrix viscosity falls outside the desired range, both ultimate tensile strength and strain capacity were diminished. By tailoring the VMA dosage, the matrix viscosity can be adjusted for desired fiber dispersion, workability, and mechanical properties. Finally, the findings of this study provide a technical reference for the practical design and application of PP-ECC.

36 MATERIALS SCIENCE↗

Impact of melt viscosity on filler dispersion in elastomeric nanocomposites

Compounding of commercial nanocomposites usually involves the addition of viscosity enhancers such as binder resins in ink jet inks, and paints. Contrary to this, plasticizers such as process oils are added to reduce the melt viscosity and ease processability of reinforced elastomers. Nanofillers such as silica and carbon black are typically added to reinforce rubber and enhance performance of automotive tire treads. Filler dispersion has traditionally been qualitatively (indirectly) assessed by measuring the properties of reinforced elastomers. While dispersion can be quantified by examining filler agglomeration through surface roughness measurements and microscopy, the size-scale dependence for these hierarchical fillers has usually been ignored. Here, we have recently devised a method to quantify nano-scale dispersion of fillers using Ultra small-angle X-ray scattering (USAXS) techniques. This method is advantageous since it directly links the controllable processing/compounding parameters such as the mixing speed, mixer geometry, residence time (or mixing duration), melt density, flow gap distance, and melt viscosity to nano-scale dispersion. While our previous studies have explored the impact of different processing parameters, this study specifically investigates the impact of melt viscosity on nano-scale filler dispersion in elastomer compounds. Commercially available polybutadienes with different Mooney viscosities were used in conjunction with different grades and amounts of process oils to modify the melt viscosity.

Carbon black↗

Structure–property reduced order model for viscosity prediction in single-component CO 2 -binding organic liquids

CO2 capture from power generation with aqueous solvents remains energy intensive due to the high water content of the current technology, or the high viscosity of non-aqueous alternatives. Quantitative reduced models, connecting molecular structure to bulk properties, are key for developing structure-property relationships that enable molecular design. In this work, we describe such a model that quantitatively predicts viscosities of CO2 binding organic liquids (CO2BOLs) based solely on molecular structure and the amount of bound CO2. The functional form of the model correlates the viscosity with the CO2 loading and an electrostatic term describing the charge distribution between the CO2-bearing functional group and the proton-receiving amine. Molecular simulations identify the proton shuttle between these groups within the same molecule to be the critical indicator of low viscosity. The model, developed to allow for quick screening of solvent libraries, paves the way towards the rational design of low viscosity non-aqueous solvent systems for post-combustion CO2 capture. Following these theoretical recommendations, synthetic efforts of promising candidates and viscosity measurement provide experimental validation and verification.

Cantu, David C.↗

Reference Correlation for the Viscosity of Carbon Dioxide

A comprehensive database of experimental and computed data for the viscosity of carbon dioxide (CO 2 ) was compiled and a new reference correlation was developed. Literature results based on an ab initio potential energy surface were the foundation of the correlation of the viscosity in the limit of zero density in the temperature range from 100 K to 2000 K. Guided symbolic regression was employed to obtain a new functional form that extrapolates correctly to T → 0 K and to 10 000 K. Coordinated measurements at low density made it possible to implement the temperature dependence of the Rainwater-Friend theory in the linear-in-density viscosity term. The residual viscosity could be formulated with a scaling term ργ/T the significance of which was confirmed by symbolic regression. The final viscosity correlation covers temperatures from 100 K to 2000 K for gaseous CO 2 , and from 220 K to 700 K with pressures along the melting line up to 8000 MPa for compressed and supercritical liquid states. The data representation is more accurate than with the previous correlations, and the covered pressure and temperature range is significantly extended. The critical enhancement of the viscosity of CO 2 is included in the new correlation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Bulk viscosity coefficients due to phonons in superfluid neutron stars

We calculate the three bulk viscosity coefficients as arising from the collisions among phonons in superfluid neutron stars. We use effective field theory techniques to extract the allowed phonon collisional processes, written as a function of the equation of state of the system. The solution of the dynamical evolution of the phonon number density allows us to calculate the bulk viscosity coefficients as function of the phonon collisional rate and the phonon dispersion law, which depends on the neutron pairing gap. Our method of computation is rather general, and could be used for different superfluid systems, provided they share the same underlying symmetries. We find that the behavior with temperature of the bulk viscosity coefficients is dominated by the contributions coming from the collinear regime of the 2↔3 phonon processes. For typical star radial pulsation frequencies of ω ∼ 10{sup 4}s{sup −1}, we obtain that the bulk viscosity coefficients at densities n∼>4n{sub 0} are within 10% from its static value for T∼<10{sup 9} K and for the case of strong neutron superfluidity in the core with a maximum value of the {sup 3}P{sub 2} gap above 1 MeV, while, otherwise, the static solution is not a valid approximation to the bulk viscosity coefficients. Compared to previous results from Urca and modified Urca reactions, we conclude that at T ∼ 10{sup 9}K phonon collisions give the leading contribution to the bulk viscosities in the core of the neutron stars, except for n ∼ 2n{sub 0} when the opening of the Urca processes takes place.

79 ASTRONOMY AND ASTROPHYSICS↗

Hall viscosity of the composite-fermion Fermi seas for fermions and bosons

The Hall viscosity has been proposed as a topological property of incompressible fractional quantum Hall states and can be evaluated as Berry curvature. This paper reports on the Hall viscosities of composite-fermion Fermi seas at ν = 1/m, where m is even for fermions and odd for bosons. A well-defined value for the Hall viscosity is not obtained by viewing the 1/m composite-fermion Fermi seas as the n → ∞ limit of the Jain ν = n/(nm ± 1) states, whose Hall viscosities (±n + m)ℏρ/4 (ρ is the two-dimensional density) approach ±∞ in the limit n → ∞. A direct calculation shows that the Hall viscosities of the composite-fermion Fermi sea states are finite and also relatively stable with system size variation, although they are not topologically quantized in the entire τ space. Here, I find that the ν = 1/2 composite-fermion Fermi sea wave function for a square torus yields a Hall viscosity that is expected from particle-hole symmetry and is also consistent with the orbital spin of 1/2 for Dirac composite fermions. I compare my numerical results with some theoretical conjectures.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗