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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

On the kinetics of volatile loss from chondrites

Data by Lipschutz and coworkers (1975, 1976, 1977) on thermal release of Tl, Bi, and In from primitive chondrites are reexamined to obtain information on the nature and activation energy (E) of release processes: desorption, volume diffusion, and decomposition of the host phase. For the Allende C3 chondrite, the main release for Bi and Tl between 400 and 700 C is shown to be apparently due to desorption of a surface layer, coupled with grain boundary diffusion as the slow step. Further, the main release of In above 600 C and the small tails of Bi and Tl between 700 and 1000 C are observed to represent probably volume diffusion. Results for Abee and other primitive meteorites were found to be essentially similar, except for a very abrupt 500 C release of Tl from Krymka (81%) and Bi from Tieschitz (70%). It is suggested that this release may represent decomposition of a thermolabile phase in a late condensate, such as organic matter or phyllosilicates.

Alaerts, L.↗
NASA NTRS1983

The thermoluminescence carrier in the Dhajala chondrite

It is pointed out that the type 3 (unequilibrated) ordinary chondrites provide a major source of information on the early solar system. However, the interpretation of the data is difficult because all but a few display signs of metamorphic alteration. The present investigation is concerned with the thermoluminescence (TL) sensitivity measurements on 58 chondrules separated from the Dhajala meteorites. The data were discussed briefly by Sparks and Sears (1982). In the current investigation particular attention is given to the constraints placed by these data on the mechanism by which metamorphism is related to TL sensitivity. Dhajala-normalized TL sensitivity of the separated chondrules is plotted against chondrule mass, and a histogram of the CaO contents of 15 chondrules is presented. Histograms showing the TL sensitivity of chondrules separated from the Dhajala meteorite are also provided.

Sparks, M. H.↗
NASA NTRS1984

Studies of an artificially shock-loaded H group chondrite

SEM and TEM, together with thermoluminescence (TL), are used to study five samples of the naturally unshocked Kernouve (H6) meteorite that were shock-loaded to pressures of 70, 165, 270, and 390 kbar. Attention is given to olivine and orthopyroxene deformation mechanisms at these pressure levels. The microhardness of the kamacite in the samples increases with shock pressure, and it is noted that annealed kamacite displays incipient crystallinity, while alpha-martensite and taenite sometimes contain slip lines. At pressures over 200 kbar, there was a systematic decrease in both natural TL and TL sensitivity. Changes in the ratio of these two values for various regions of the TL glow curve suggest that two processes were effective during shock: thermal drainage of electron traps and a reduction in the effective trap density. Thermal effects with widespread annealing are noted in the case of a sample subjected to shock pulse.

Sears, D. W.↗
NASA NTRS1984

Thermoluminescence and the shock and reheating history of meteorites. II - Annealing studies of the Kernouve meteorite

Samples of the unshocked, equilibrated chondrite, Kernouve (H6), have been annealed for 1-100 hours at 500-1200 C, their thermoluminescence sensitivity measured and Na, K, Mn, Ca, and Sc determined by instrumental neutron activation analysis. The TL sensitivity decreased with temperature until by 1000 C it had fallen by 40 percent. The process responsible has an activation energy of 8 kcal/mole and probably involves diffusion. Samples annealed 1000-1200 C had TL sensitivities 0.01 times the unannealed values, most of the decrease occurring at 1100 C. This process has an activation energy of 100 kcal/mole and is probably related to the melting of the TL phosphor, feldspar, with some decomposition and loss of Cs, Na and K. Meteorites whose petrography indicates heating above 1100 C by natural shock heating events (shock facies d-f), have TL sensitivities similar to samples annealed above 1100 C.

Sears, D. W. G.↗
NASA NTRS1986

Chemical and physical studies of type 3 chondrites. VII - Annealing studies of the Dhajala H3.8 chondrite and the thermal history of chondrules and chondrites

Samples of the Dhajala meteorite were annealed at 600-1000 C for 1, 2, 10, 20 and 100 h and their thermoluminescence (TL) properties were measured. After annealing at less than 900 deg, the TL sensitivity decreased by a factor of two; at higher temperatures, it fell by an order of magnitude. Data indicate that the annealing treatment caused the low-temperature feldspar in Dhajala to be converted to feldspar of a high-temperature (disordered) form. Low-temperature feldspar was found in the meteorite's TL-sensitive chondrules which comprised about 20 percent of those separated. It is suggested that these chondrules suffered greater crystallization of their mesostasis than the other chondrules, and equilibrated to lower temperatures. Based on TL data, there appears to be no relationship between post-metamorphic cooling rate and petrologic type for the 3.5-3.9 chondrites.

Keck, B. D.↗
NASA NTRS1986

A thermoluminescence study of experimentally shock-loaded oligoclase and bytownite

The thermoluminescence (TL) properties of a terrestrial oligoclase and a bytownite shock-loaded to pressures of 10.5-45 GPa are measured. Glow curves and TL sensitivity levels for the oligoclase and bytownite samples are presented and analyzed; it is detected that shock causes a decrease in the TL sensitivity and changes the shape of the glow curve. The causes of the decrease in TL sensitivity and peak temperature and width variations are examined. Shock-induced disordering of the Al, Si chain, and ordinary chondrite shocks are studied.

Hartmetz, Christopher P.↗
NASA NTRS1991

Chemical and physical studies of type 3 chondrites. XI - Metamorphism, pairing, and brecciation of ordinary chondrites

The present study reports recent measurements of the induced thermoluminescence (TL) properties of 69 type-3 ordinary chondrites, bringing to 125 the number of type-3 ordinary chondrites for which TL data are available. The samples include several of the particularly low petrographic type and many breccias, some of them gas-rich. The significance of the data with respect to the physical conditions affecting metamorphism is discussed. The TL data, olivine heterogeneity, carbon content, and inert-gas content were used to assign the samples to petrologic types. Twelve meteorites were identified as being type 3.0-3.2, and 10 of the breccias were found to contain material that may also be of this type. The temperature and width of the induced TL peak are also related to thermal history, with type 3.2-3.4 chondrites tending to have narrower peaks at lower glow curve temperatures than the type 3.6-3.9 chondrites. Type 3 H chondrites were found to be a higher petrographic type than the type 3 L and LL chondrites.

Sears, D. W. G.↗
NASA NTRS1992

Observation of alloy solidification using high-speed video

A high-speed video instrumentation system was used to observe solidification of undercooled Ti-51 at. pct Al. The camera system developed by Battelle is capable of operation at rates up to 12,000 frames per second. The system digitizes and stores video images acquired by a 64 x 64 pixel silicon photodiode array. In a joint effort with Vanderbilt University the camera was used to observe three transformations of the undercooled alloys, using containerless processing by electromagnetic levitation. The first was solidification where nucleation was induced at an undercooling of 9 percent Tl, where Tl is the liquidus temperature of the alloy, and the second was solidification where nucleation was spontaneous at an undercooling of 15 percent Tl. The third event was a solid-state nucleation and growth transformation following the solidification at an undercooling of 15 percent Tl.

Bassler, B. T.↗
NASA NTRS1994

The natural thermoluminescence of meteorites. 7: Ordinary chondrites from the Elephant Moraine region, Antarctica

We report natural and induced thermoluminescence (TL) measurements for meteorites from the Elephant Moraine region (76 deg 17 min S, 157 deg 20 min E) of Antarctica. We use our data to identify fragmented meteorites (i.e., 'pairings'); our dataset of 107 samples represents at most 73 separate meteorite falls. Pairing groups are generally confined to single icefields, or to adjacent icefields, but a small proportion cross widely separated icefields in the region, suggesting that the fields can be considered as a single unit. Meteorites from this region have high natural TL levels, which indicates that they have small terrestrial surface exposure ages (less than 12,500 years). There do not appear to be significant differences in natural TL levels (and hence surface exposure ages) between individual blue icefields in the region. The proportion of reheated meteorites from the Elephant Moraine region is similar to that of other Antarctic sites and modern falls, consistent with the uniformity of the meteoritic flux in this regard. An unusual subset of H-chondrites, with high induced TL peak temperatures, is absent among the data for meteorites collected in the Elephant Moraine region, which stresses their similarity to modern falls. We suggest that the Elephant Moraine region, which stresses their similarity to modern falls. We suggest that the Elephant Moraine icefields formed through shallow ablation of the ice. Unlike the Allan Hills sites to the south, lateral transport is probably less important relative to the infall of meteorites in concentrating meteorites on these icefields.

Benoit, P. H.↗
NASA NTRS1996

The Thermal and Radiation Exposure History of Lunar Meteorites

We have measured the natural and induced thermoluminescence (TL) of seven lunar meteorites in order to examine their crystallization, irradiation, and recent thermal histories. Lunar meteorites have induced TL properties similar to Apollo samples of the same provenance (highland or mare), indicating similar crystallization and metamorphic histories. MacAlplne Hills 88104/5 has experienced the greatest degree of impact/regolith processing among the highland-dominated meteorites. The basaltic breccia QUE 94281 is dominated by mare component but may also contain a significant highland component. For the mare-dominated meteorites, EET 87521 may have a significant highland impact-melt component, while Asuka 881757 and Y-793169 have been heavily shocked. The thermal history of Y-793169 included slow cooling, either during impact processing or during its initial crystallization. Our natural TL data indicate that most lunar meteorites have apparently been irradiated in space a few thousand years, with most less than 15,000 a. Elephant Moraine 87521 has the lowest irradiation exposure time, being less than 1,000 a. Either the natural TL of ALHA81005, Asuka 881757 and Y-82192 was only partially reset by lunar ejection or these meteorites were in small perihelia orbits (less than or equal to 0.7 AU).

Benoit, Paul H.↗
NASA NTRS2015

Acoustically Tailored Composite Rotorcraft Fuselage Panels

A rotorcraft roof sandwich panel has been redesigned to optimize sound power transmission loss (TL) and minimize structure-borne sound for frequencies between 1 and 4 kHz where gear meshing noise from the transmission has the most impact on speech intelligibility. The roof section, framed by a grid of ribs, was originally constructed of a single honeycomb core/composite face sheet panel. The original panel has coincidence frequencies near 700 Hz, leading to poor TL across the frequency range of 1 to 4 kHz. To quiet the panel, the cross section was split into two thinner sandwich subpanels separated by an air gap. The air gap was sized to target the fundamental mass-spring-mass resonance of the double panel system to less than 500 Hz. The panels were designed to withstand structural loading from normal rotorcraft operation, as well as 'man-on-the-roof' static loads experienced during maintenance operations. Thin layers of VHB 9469 viscoelastomer from 3M were also included in the face sheet ply layups, increasing panel damping loss factors from about 0.01 to 0.05. Measurements in the NASA SALT facility show the optimized panel provides 6-11 dB of acoustic transmission loss improvement, and 6-15 dB of structure-borne sound reduction at critical rotorcraft transmission tonal frequencies. Analytic panel TL theory simulates the measured performance quite well. Detailed finite element/boundary element modeling of the baseline panel simulates TL slightly more accurately, and also simulates structure-borne sound well.

Hambric, Stephen↗
NASA NTRSDate not supplied

Development of Acoustic Mufflers for Cabin Noise Reduction in Orion Spacecraft

Controlling cabin acoustic noise levels in the Crew Module (CM) of the Orion spacecraft is critical to ensure adequate speech intelligibility, to avoid fatigue, and prevent any possibility of temporary and permanent hearing loss to the crew. The primary source of cabin noise for the on-orbit phase of the mission is from the Environmental Control and Life Support System (ECLSS) which recycles and conditions breathing air and maintains cabin pressurization through its duct network and components. Unfortunately, as a side effect, noise from the ECLSS fans propagates through theses ducts and emanate into the cabin habitable volume via the ECLSS inlet and outlets. To mitigate excessive duct-borne noise, two ECLSS mufflers have been designed to provide significant acoustic transmission loss (TL) so that the cabin noise requirements can be met. Each muffler is meant to be installed in the ducting of the ECLSS air inlet and outlet sides, respectively. Packaging constraints and tight volume requirements necessitated the mufflers to be of complex geometry and compatible with the bends of the ECLSS duct layout. To design and characterize the acoustic performance of the inlet and outlet mufflers, computational acoustic models were developed using the Finite Element Method (FEM) with 𝑤𝑎𝑣𝑒଺ vibroacoustic software. Characterization of the acoustic material and perforations in the mufflers were addressed with poroelastic theory. Once the mufflers were designed on paper and its TL predicted, prototypes of these mufflers were created using additive manufacturing. The muffler prototypes were subsequently tested for acoustic TL in the laboratory with various con-figurations of acoustic materials. Comparing the analytical predictions to the test performance yielded excellent correlation for acoustic TL and demonstrated significant broadband noise attenuation. The ECLSS mufflers are currently scheduled to be installed on the Artemis II Crew Module (CM) of the Orion spacecraft and will provide significant cabin comfort to crew during the mission.

Indranil Dandaroy↗
NASA NTRS1975

The effect of air flow, panel curvature, and internal pressurization on field-incidence transmission loss

In the context of sound transmission through aircraft fuselage panels, equations for the field-incidence transmission loss (TL) of a single-walled panel are derived that include the effects of external air flow, panel curvature, and internal fuselage pressurization. These effects are incorporated into the classical equations for the TL of single panels, and the resulting double integral for field-incidence TL is numerically evaluated for a specific set of parameters.

Koval, L. R.↗
NASA NTRS1975

Heavy element affinities in Apollo 17 samples

Pb-204, Bi, Tl, and Zn in samples from the Apollo 17 site exhibit relationships not found in samples from other sites. Pb-204, Tl, and Zn in residues remaining after dilute acid leaching are correlated with one another. Orange soil 74220, which is enriched in Pb-204, Tl, and Zn, is included in these relationships. In addition, the submicron metallic phase generally associated with agglutinate formation is correlated with all three of these elements; this relationship has already been reported for Pb-204 in other samples. Thus, orange soil and agglutinates appear to be involved in concentrating heavy volatile metals. A process other than mixing is required to account for this. As a consequence of the isolation of the landing site by the surrounding massifs, local supply and recycling of volatile trace elements in soils may account for some of the interelement relations.

Allen, R. O., Jr.↗
NASA NTRS1975

On sound transmission into a thin cylindrical shell under 'flight conditions'

A mathematical model for sound transmission into a thin cylindrical shell is used to study sound transmission under flight conditions, i.e., under conditions of external air flow past a pressurized cylinder at flight altitude. Numerical results for different incidence angles are presented for a typical narrow-bodied jet in cruising flight at 10,660 m with interior pressure at 2440 m. A comparison is made between no-flow sound transmission at standard conditions on the ground to sound transmission under flight conditions. It is shown that at M = 0, the cylinder transmission loss (TL) has dips at the cylinder ring frequency (fR) and the critical frequency (fc) for a flat panel of same material and thickness as shell. Between fR and fc, cylinder TL follows a mass-law behavior. Flow provides a modest increase in TL in the mass-law region, and strongly interacts with the cylinder resonances below fR.

Koval, L. R.↗
NASA NTRS1976

On sound transmission into a stiffened cylindrical shell under flight conditions

In the context of airborne-noise transmission through an aircraft fuselage, a mathematical model is presented for sound transmission into a stiffened cylindrical shell. The stiffening effect of the ring frames and stringers is approximated by a 'smeared'-stiffener theory which includes the eccentricity of the stiffeners. Numerical results are presented for a typical narrow-bodied jet in cruising flight. A comparison is made between noise transmission into a monococque shell and into a stiffened shell. The stiffeners are shown to greatly increase TL for small incidence angles, so that the effective 'window' for noise transmission is restricted to the neighborhood of normal incidence. Flow is shown to increase TL for sound waves propagating 'upstream' against the flow. Stiffeners are also shown to raise the ring frequency at which a dip in cylinder TL occurs. Limitations of the 'smeared'-stiffener theory are also discussed.

Koval, L. R.↗
NASA NTRS1978

Volatile elements in chondrites - Metamorphism or nebular fractionation

Three of the most highly metamorphosed meteorites of their respective classes, Shaw (LL7), Karoonda (C5), and Coolidge (C4), were analyzed by radiochemical neutron activation analysis for Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Ni, Os, Pd, Rb, Re, Sb, Se, Te, Tl, U, and Zn. Comparison with data by Lipschutz and coworkers (1977) on artificially heated primitive meteorites shows that the natural metamorphism of meteorites cannot have taken place in a system open to volatiles. Shaw, metamorphosed at 1300 C for more than 1 million yr, is less depleted in In, Bi, Ag, Te, Zn, and Tl than Krymka heated at 1000 C for 1 week. Karoonda, metamorphosed at 600 C for many millennia, is less depleted in Bi and Tl than Allende heated at 600 C for 1 week. Data on primordial noble gases also show that the volatile-element patterns of ordinary and carbonaceous chondrites were established by nebular condensation and changed little, if at all, during metamorphism. For enstatite chondrites, the evidence is still incomplete but seems to favor a nebular origin of the volatile pattern.

Takahashi, H.↗
NASA NTRS1979

Thermal metamorphism of primitive meteorites. VIII - Noble gases, carbon and sulfur in Allende /C3/ meteorite heated at 400-1000 C

Noble gases, C and S, are lost from Allende samples heated for 1 week at temperatures of 400-1000 C in a low pressure environment. In the extreme, losses of He-3 and He-4 are about 100 x while for C, S and Ne, Ar and Kr isotopes and Xe-132 these are less than or equal to 10 x. Except for He, these losses are less severe than those of Bi or Tl from samples heated in the same runs. Significant He, Ne and Ar isotopic fractionation during heating indicates preferential outgassing of specific reservoirs. Next to He, Ar-40 is the most labile of those species considered here but still less so than Bi or Tl. L-group (but not H- or LL-group) chondrites may have lost mobile elements like Tl while being outgassed after late impact-associated heating. A less likely alternative involving a collateral relation between condensation conditions and depth in a parent object may also explain the L-group trend.

Herzog, G. F.↗