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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS1994

The Diurnal Variation of Hydrogen, Nitrogen, and Chlorine Radicals: Implications for the Heterogeneous Production of HNO2

In situ measurements of hydrogen, nitrogen, and chlorine radicals obtained through sunrise and sunset in the lower stratosphere during SPADE are compared to results from a photochemical model constrained by observed concentrations of radical precursors and environmental conditions. Models allowing for heterogeneous hydrolysis of N205 on sulfate aerosols agree with measured concentrations of NO, NO2, and ClO throughout the day, but fail to account for high concentrations of OH and H02 observed near sunrise and sunset. The morning burst of [OH] and [HO2] coincides with the rise of [NO] from photolysis of N02, suggesting a new source of HO, that photolyzes in the near UV (350 to 400 nm) spectral region. A model that allows for the heterogeneous production of HN02 results in an excellent simulation of the diurnal variations of [OH] and [HO2].

Salawitch, R. J.↗
NASA NTRS2002

Near IR Photolysis of HO2NO2: Supplemental Material

MkIV measurements of the volume mixing ratio (VMR) of HO2NO2 at 35 deg N, sunset on Sept. 25, 1993 are given. Measurements of HO2NO2 made between approx. 65 and 70 deg N, sunrise on May 8, 1997 are listed. The uncertainties given are 1 sigma estimates of the measurement precision. Uncertainty in the HO2NO2 line strengths is estimated to be 20%; this is the dominant contribution to the systematic error of the HO2NO2 measurement. Model inputs for the simulations are given. The albedos were obtained from Total Ozone Mapping Spectrometer reflectively data (raw data at ftp://jwocky.gsfc.nasa.gov) for the time and place of observation. Profiles of sulfate aerosol surface area ("Surf. Area") were obtained from monthly, zonal mean profiles measured by SAGE II [Thomason et al., 1997 updated via private communication]. The profile of Be(y) is based on the Wamsley et al. relation with N2O, using MkIV measurements of N20O. All other model inputs given are based on direct MkIV measurements. Finally, we note the latitude of the MkIV tangent point varied considerably during sunrise on May 8, 1997. The simulations shown here were obtained using different latitudes for each altitude.

Source record↗
NASA NTRS2004

Application of Satellite-Derived Land Surface Temperature to Minimum Temperature Forecasting

Satellite-derived land surface temperature (LST) is studied for the purpose of understanding regional skin temperature dependency and variability, and its relationship to corresponding, site-specific air temperature. Skin temperature is highly correlated with surface-air temperature although it differs depending on land surface characteristics, terrain, and atmospheric conditions on a diurnal and seasonal scale. The high temporal resolution of the Geostationary Operational Environmental Satellite (GOES) -12 sounder is used to compare the diurnal cycles of LST and surface-air temperature. The minimum for both temperatures occurs near sunrise and LST is found to agree closely with surface-air temperatures a period of hours before sunrise on clear sky nights. The Moderate Resolution Imaging Spectroradiometer (MODIS)-derived LST renders more horizontal temperature structure - with its high spatial resolution (1 km at nadir) compared to the GOES-12 sounder (10 km). Nighttime MODIS-derived LST is extrapolated to the time of minimum temperature for a number of case study days and these are grouped by season and atmospheric conditions. These composites show that the variation in LST mirror the variation in minimum surface-air temperature under similar conditions.

Jones, P. R.↗
NASA NTRS2009

Cloud Imagers Offer New Details on Earth's Health

A stunning red sunset or purple sunrise is an aesthetic treat with a scientific explanation: The colors are a direct result of the absorption or reflectance of solar radiation by atmospheric aerosols, minute particles (either solid or liquid) in the Earth s atmosphere that occur both naturally and because of human activity. At the beginning or end of the day, the Sun s rays travel farther through the atmosphere to reach an observer s eyes and more green and yellow light is scattered, making the Sun appear red. Sunset and sunrise are especially colorful when the concentration of atmospheric particles is high. This ability of aerosols to absorb and reflect sunlight is not just pretty; it also determines the amount of radiation and heat that reaches the Earth s surface, and can profoundly affect climate. In the atmosphere, aerosols are also important as nuclei for the condensation of water droplets and ice crystals. Clouds with fewer aerosols cannot form as many water droplets (called cloud particles), and consequently, do not scatter light well. In this case, more sunlight reaches the Earth s surface. When aerosol levels in clouds are high, however, more nucleation points can form small liquid water droplets. These smaller cloud particles can reflect up to 90 percent of visible radiation to space, keeping the heat from ever reaching Earth s surface. The tendency for these particles to absorb or reflect the Sun s energy - called extinction by astronomers - depends on a number of factors, including chemical composition and the humidity and temperature in the surrounding air; because cloud particles are so small, they are affected quickly by minute changes in the atmosphere. Because of this sensitivity, atmospheric scientists study cloud particles to anticipate patterns and shifts in climate. Until recently, NASA s study of atmospheric aerosols and cloud particles has been focused primarily on satellite images, which, while granting large-scale atmospheric analysis, limited scientists ability to acquire detailed information about individual particles. Now, experiments with specialized equipment can be flown on standard jets, making it possible for researchers to monitor and more accurately anticipate changes in Earth s atmosphere and weather patterns.

Source record↗
NASA NTRS2009

Continuous Lidar Monitoring of Polar Stratospheric Clouds at the South Pole

Polar stratospheric clouds (PSC) play a primary role in the formation of annual ozone holes over Antarctica during the austral sunrise. Meridional temperature gradients in the lower stratosphere and upper troposphere, caused by strong radiative cooling, induce a broad dynamic vortex centered near the South Pole that decouples and insulates the winter polar airmass. PSC nucleate and grow as vortex temperatures gradually fall below equilibrium saturation and frost points for ambient sulfate, nitrate, and water vapor concentrations (generally below 197 K). Cloud surfaces promote heterogeneous reactions that convert stable chlorine and bromine-based molecules into photochemically active ones. As spring nears, and the sun reappears and rises, photolysis decomposes these partitioned compounds into individual halogen atoms that react with and catalytically destroy thousands of ozone molecules before they are stochastically neutralized. Despite a generic understanding of the ozone hole paradigm, many key components of the system, such as cloud occurrence, phase, and composition; particle growth mechanisms; and denitrification of the lower stratosphere have yet to be fully resolved. Satellite-based observations have dramatically improved the ability to detect PSC and quantify seasonal polar chemical partitioning. However, coverage directly over the Antarctic plateau is limited by polar-orbiting tracks that rarely exceed 80 degrees S. In December 1999, a NASA Micropulse Lidar Network instrument (MPLNET) was first deployed to the NOAA Earth Systems Research Laboratory (ESRL) Atmospheric Research Observatory at the Amundsen-Scott South Pole Station for continuous cloud and aerosol profiling. MPLNET instruments are eye-safe, capable of full-time autonomous operation, and suitably rugged and compact to withstand long-term remote deployment. With only brief interruptions during the winters of 2001 and 2002, a nearly continuous data archive exists to the present.

OZONE DESTRUCTION↗
NASA NTRS1967

Television observations from Surveyor III

Surveyor III landed on the lunar surface at 00:04 GMT, on Day 110, 1967, approximately 23 hr after local sunrise on the Moon. The first pictures were taken by the television camera at 01:02 GMT. The camera was operated extensively for the first period of lunar visibility from the Goldstone Tracking Station of the Deep Space Network and, except on Day 115, on each successive Goldstone pass of the Moon until the Sun set over the Surveyor III landing site on Day 123. During this period, the Sun rose from an elevation angle of 11° in the east to within 3° of the zenith and then sank almost due west of the spacecraft. Many pictures were obtained of the illuminated eastern horizon in the period immediately preceding sunset. In addition to those received at the Goldstone Station, some were obtained at the Canberra, Australia, station of the Deep Space Network. There were 6315 television pictures taken during the first lunar day of the Surveyor III mission.

Surveyor III spacecraft↗
NASA NTRS1972

Design, testing, fabrication and launch support of a liquid chemical barium release payload (utilizing the liquid fluorine-barium salt/hydrazine system)

A payload was designed which included a cryogenic oxidizer tank, a fuel tank, and burner section. Release of 30 lb of chemicals was planned to occur in 2 seconds at the optimum oxidizer to fuel ratio. The chemicals consisted of 17 lb of liquid fluorine oxidizer and 13 lb of hydrazine-barium salt fuel mixture. The fuel mixture was 17% barium chloride, 16% barium nitrate, and 67% hydrazine, and contained 2.6 lb of available barium. Two significant problem areas were resolved during the program: explosive valve development and burner operation. The release payload was flight tested, from Wallops Island, Virginia. The release took place at an altitude of approximately 260 km. The release produced a luminous cloud which expanded very rapidly, disappearing to the human eye in about 20 seconds. Barium ion concentration slowly increased over a wide area of sky until measurements were discontinued at sunrise (about 30 minutes).

Stokes, C. S.↗
NASA NTRS1972

Energetic ion bursts on the nightside of the moon.

Recurrent bursts of positive ions are a persistent feature of the data from the Apollo 12 and Apollo 14 Alsep suprathermal ion detectors. Most remarkable is the occasional occurrence of these events when the Alsep is deep in the lunar night. One such series of bursts seen during December 1969 starting approximately 4.7 days before sunrise at the Apollo 12 Alsep site is reported. These bursts have durations ranging up to 14 min and recur with a highly variable frequency. The ions have differential energy spectra with narrow peaks. The peak energies range from 10 to 1250 eV but are found most frequently in the vicinity of 250 to 500 eV. They can be seen when the field of view of the detector looks as close as 16 deg to the antisolar direction. Data from the ion-mass analyzer indicate that, unlike some similar events seen on other occasions, these ions have mass per unit charge less than 10 amu/q, and hence, are probably of solar-wind origin.

Freeman, J. W., Jr.↗
NASA NTRS1972

Vacuum measurements on the lunar surface.

Results of measurements of neutral gas pressure on the lunar surface made with a cold cathode ionization gauge carried to the moon by Apollo 14. The vacuum quality at the landing site is much influenced by the adsorption of rocket gases and their later release. During surface operations by the astronauts, the pressure was near 10 to the minus 8th torr. No data were obtained between the time of the surface operations and lunar sunset about 12 days later, at which time the temperature fell rapidly to the vicinity of 100 K. The pressure was about 10 to the minus 12th torr shortly after sunset, but intermittent releases of gas, perhaps from within the moon itself, occasionally raised the pressure by less than an order of magnitude for as long as a day or two at a time and on one occasion to about 10 to the minus 10th torr for about an hour. At lunar sunrise, as the surface was warmed rapidly to about 300 K, the pressure rose rapidly to about 10 to the minus 10th torr, most likely due to the release of absorbed gases in the immediate landing area or on the landing module itself. For comparison with interplanetary vacuum conditions, the directed pressure of the solar wind is usually less than 10 to the minus 11th torr and the pressure of random gas motion within the solar wind, less than 10 to the minus 13th torr.

Johnson, F. S.↗
NASA NTRS1972

Photoelectron emission from Io as the cause of enhancements of the Jovian decametric radiation.

A theoretical explanation for the dependence of the Jovian decametric radiation on the position of its satellite Io is advanced in terms of electrostatic instabilities created by injection into the hot natural plasma of cold photoelectrons from Io. This may be tested with appropriately positioned and presently planned deep-space probes that search for variations of the Jovian decametric radiation at times following local sunset and sunrise at Io.

Mozer, F. S.↗
NASA NTRS1972

Suprathermal ion detector results from Apollo missions.

This paper reviews briefly the knowledge of the ion environment of the moon as obtained from the Apollo Lunar Surface Experiments Package, Suprathermal Ion Detector Experiment. Topics to be discussed include: an interplanetary shock as seen from the lunar surface; bow shock and magnetosheath ions; magnetotail plasma seen during a magnetic disturbance; suprathermal ions seen during passage of the sunset and sunrise terminators; and ions associated with neutral gas clouds in the vicinity of the moon, and in particular the low energy mono-energetic spectrum of these ions. It is believed that these low energy spectra and some terminator ions can be explained by ion acceleration by the interplanetary electric field. This paper serves as catalog to references to these and other related phenomena.

Freeman, J. W., Jr.↗
NASA NTRS1972

Suprathermal ions near the moon.

This paper reports some preliminary results from the suprathermal ion detectors deployed on the lunar surface by the Apollo 12 and 14 astronauts. Salient features of these results include: the possible observation of sporadic venting of gas from the lunar surface; evidence for a prompt ionization and acceleration mechanism operating in the lunar exosphere; and a preliminary measurement yielding approximately 1 month for the e-folding decay time for the heavier components of the exhaust gases from the Apollo lunar landing systems. Prominent phenomena from which these results have been derived are: (1) ion bursts of low to moderate energy seen in conjunction with lunar sunrise and sunset; (2) solar wind energy ions detected on the night side of the moon; (3) ions of several keV energy seen during the lunar sunset to midnight quadrant of the moon's orbit; (4) magnetosheath ion flux enhancements; (5) ion bursts generated by the lunar impact of the Apollo 13 Saturn upper stage; and (6) geomagnetic storm associated ion flux variations in the earth's magnetotail.

Freeman, J. W., Jr.↗
NASA NTRS1972

Comparative analyses of observations of lunar transient phenomena.

From the author's collection of more than 900 reports of lunar transient phenomena (LTP) covering the period 1540-1970, 771 positive plus 112 negative observations (several times more than any previously published analyses) with sufficient ancillary data were analyzed for five hypotheses of causes. Treated as two groups they were divided into four categories (gaseous, reddish, bluish, and brightenings) and were analyzed separately and combined with respect to the hypotheses. The five hypotheses involved effects of tides, sunrise, low-angle illumination, earth's magnetic tail, and solar particles.

Cameron, W. S.↗