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At least 91 records · Page 5

Stress- and interface-compatible red phosphorus anode for high-energy and durable sodium-ion batteries

Sodium-ion battery is a promising candidate for energy storage application, but the absence of high-capacity and low-cost anode materials significantly limit their practical specific energy and cost. Red phosphorus (RP) possesses a high theoretical specific capacity but suffers from large volume change, low electronic conductivity and unstable solid-electrolyte interphase (SEI). Herein, a hierarchical micro/nanostructured antimony-doped RP/carbon anode was developed, which demonstrate extraordinary electrochemical performance with high initial Coulombic efficiency of ~90%, high areal (~1.7 mAh cm-2) capacity together with good cycle stability and rate capability. Combined experimental and computational studies consistently revealed that such a unique structural design can dramatically accommodate the mechanical stress and moreover effectively restrain the undesired decomposition of electrolyte solvents regardless of electrolytes formulation, resulting in superior structural integrity and thin/robust SEI formation during cycling. The present finding has offered an alternative strategy for stress management and interface engineering on high-capacity alloying-based anode materials.

Liu, Xiang↗

A Unified Framework to Reconcile Different Approaches of Modeling Transpiration Response to Water Stress: Plant Hydraulics, Supply Demand Balance, and Empirical Soil Water Stress Function

Plant responses to water stress is a major uncertainty to predicting terrestrial ecosystem sensitivity to drought. Different approaches have been developed to represent plant water stress. Empirical approaches (the empirical soil water stress (or Beta) function and the supply-demand balance scheme) have been widely used for many decades; more mechanistic based approaches, that is, plant hydraulic models (PHMs), were increasingly adopted in the past decade. However, the relationships between them—and their underlying connections to physical processes—are not sufficiently understood. This limited understanding hinders informed decisions on the necessary complexities needed for different applications, with empirical approaches being mechanistically insufficient, and PHMs often being too complex to constrain. Here we introduce a unified framework for modeling transpiration responses to water stress, within which we demonstrate that empirical approaches are special cases of the full PHM, when the plant hydraulic parameters satisfy certain conditions. We further evaluate their response differences and identify the associated physical processes. Finally, we propose a methodology for assessing the necessity of added complexities of the PHM under various climatic conditions and ecosystem types, with case studies in three typical ecosystems: a humid Midwestern cropland, a semi-arid evergreen needleleaf forest, and an arid grassland. Notably, Beta function overestimates transpiration when VPD is high due to its lack of constraints from hydraulic transport and is therefore insufficient in high VPD environments. With the unified framework, we envision researchers can better understand the mechanistic bases of and the relationships between different approaches and make more informed choices.

54 ENVIRONMENTAL SCIENCES↗

On the correlation between the stress exponent for creep determined by nanoindentation and the mechanism of action enabling stress relief in indium

Instrumented indentation performed at room temperature with a Berkovich and 10 μm radius sphere has been used to measure the stress exponent for creep before and after the strain burst observed in well-annealed, high-purity indium. Before the strain burst, the measured values are successfully rationalized using a new model based on stress directed diffusional flow along the interface between the indenter tip and test specimen. After the strain burst, the measured stress exponents are found to be representative of dislocation glide and climb assisted glide. Here these results are compared and contrasted to the previous experimental investigations and modeling efforts of Feng et al., Lucas et al., and Li et al. Collectively, the experimental observations and rationalization presented here provide significant new insight into the mechanisms of action that control the competition for stress relief in small, constrained volumes of crystalline metals subjected to high homologous temperatures.

36 MATERIALS SCIENCE↗

Stress analysis and stress intensity factors for finite geometry solids containing rectangular surface cracks

The line method of analysis is applied to the Navier-Cauchy equations of elastic equilibrium to calculate the displacement field in a finite geometry bar containing a variable depth rectangular surface crack under extensionally applied uniform loading. The application of this method to these equations leads to coupled sets of simultaneous ordinary differential equations whose solutions are obtained along sets of lines in a discretized region. Using the obtained displacement field, normal stresses and the stress intensity factor variation along the crack periphery are calculated for different crack depth to bar thickness ratios. Crack opening displacements and stress intensity factors are also obtained for a through-thickness, center cracked bar with variable thickness. The reported results show a considerable potential for using this method in calculating stress intensity factors for commonly encountered surface crack geometries in finite solids.

Gyekenyesi, J. P.↗

Stress analysis and stress-intensity factors for finite geometry solids containing rectangular surface cracks

The line method of analysis is applied to the Navier-Cauchy equations of elastic equilibrium to calculate the displacement field in a finite geometry bar containing a variable depth rectangular surface crack under extensionally applied uniform loading. The application of this method to these equations leads to coupled sets of simultaneous ordinary differential equations whose solutions are obtained along sets of lines in a discretized region. Using the obtained displacement field, normal stresses, and the stress-intensity factor variation along the crack periphery are calculated for different crack depth to bar thickness ratios. Crack opening displacements and stress-intensity factors are also obtained for a through-thickness, center-cracked bar with variable thickness. The reported results show a considerable potential for using this method in calculating stress-intensity factors for commonly encountered surface crack geometries in finite solids

Gyekenyesi, J. P.↗

Influence of precracked specimen configuration and starting stress intensity on the stress corrosion cracking of 4340 steel

Since the pioneer work of Brown (1966), precracked specimens and related fracture mechanics analyses have been extensively used to study stress corrosion cracking. Certain questions arose in connection with initial attempts to prepare standardized recommended practices by ASTM Committee G-1 on Corrosion of Metals. These questions were related to adequacy of test control as it pertains to acceptable limits of variability, and to validity of expressions for stress intensity and crack-surface displacements for both specimen configurations. An interlaboratory test program, was, therefore, planned with the objective to examine the validity of KIscc testing for selected specimen configurations, materials,and environmental systems. The results reported in the present paper include details of a single laboratory test program. The program was conducted to determine if the threshold value of stress intensity for onset and arrest of stress corrosion cracking was independent for the two specimen configurations examined.

Lisagor, W. B.↗

Investigation of stress concentration factor - Stress intensity factor interaction for flaws in filleted rods

To predict the fatigue life of machine parts which contain flaws in regions of stress concentration, the engineer needs to treat a series of crack sizes and/or shapes quickly and economically. In this paper the stress intensity factor distributions for circular surface flaws in the roots of fillets in rods loaded by remote tension are presented and examined. The examination reveals insight into the interaction of cracks with other stress concentrating discontinuities, and based on this it is suggested that weight function methods used in conjunction with known crack solutions may provide needed, efficient stress intensity factor prediction methods for such three-dimensional geometries.

Springfield, C. W., Jr.↗

Evaluation of finite-element models and stress-intensity factors for surface cracks emanating from stress concentrations

A re-evaluation of the 3-D finite-element models and methods used to analyze surface crack at stress concentrations is presented. Previous finite-element models used by Raju and Newman for surface and corner cracks at holes were shown to have ill-shaped elements at the intersection of the hole and crack boundaries. Improved models, without these ill-shaped elements, were developed for a surface crack at a circular hole and at a semi-circular edge notch. Stress-intensity factors were calculated by both the nodal-force and virtual-crack-closure methods. Comparisons made between the previously developed stress-intensity factor equations and the results from the improved models agreed well except for configurations with large notch-radii-to-plate-thickness ratios. Stress-intensity factors for a semi-elliptical surface crack located at the center of a semi-circular edge notch in a plate subjected to remote tensile loadings were calculated using the improved models.

Tan, P. W.↗

Comparative Stress Corrosion Cracking and General Corrosion Resistance of Annealed and Hardened 440 C Stainless Steel - New Techniques in Stress Corrosion Testing

The corrosion and stress corrosion cracking (SCC) characteristics of annealed and hardened 440C stainless steel were evaluated in high humidity and 3.5-percent NaCl solution. Corrosion testing consisted of an evaluation of flat plates, with and without grease, in high humidity, as well as electrochemical testing in 3.5-percent NaCl. Stress corrosion testing consisted of conventional, constant strain, smooth bar testing in high humidity in addition to two relatively new techniques under evaluation at MSFC. These techniques involve either incremental or constant rate increases in the load applied to a precracked SE(B) specimen, monitoring the crack-opening-displacement response for indications of crack growth. The electrochemical corrosion testing demonstrated an order of magnitude greater general corrosion rate in the annealed 440C. All techniques for stress corrosion testing showed substantially better SCC resistance in the annealed material. The efficacy of the new techniques for stress corrosion testing was demonstrated both by the savings in time and the ability to better quantify SCC data.

Mendreck, M. J.↗

High-Temperature Slow Crack Growth of Silicon Carbide Determined by Constant-Stress-Rate and Constant-Stress Testing

High-temperature slow-crack-growth behaviour of hot-pressed silicon carbide was determined using both constant-stress-rate ("dynamic fatigue") and constant-stress ("static fatigue") testing in flexure at 1300 C in air. Slow crack growth was found to be a governing mechanism associated with failure of the material. Four estimation methods such as the individual data, the Weibull median, the arithmetic mean and the median deviation methods were used to determine the slow crack growth parameters. The four estimation methods were in good agreement for the constant-stress-rate testing with a small variation in the slow-crack-growth parameter, n, ranging from 28 to 36. By contrast, the variation in n between the four estimation methods was significant in the constant-stress testing with a somewhat wide range of n= 16 to 32.

Choi, Sung H.↗

Nonlinear Reduced-Order Simulation Using Stress-Free and Pre-Stressed Modal Bases

A study is undertaken to determine the advantages and disadvantages associated with application of stress-free and pre-stressed modal bases in a reduced-order finite-element-based nonlinear simulation. A planar beam is chosen as an application example and its response due to combined thermal and random pressure loadings is examined. Combinations of two random pressure levels and two thermal conditions are investigated. The latter consists of an ambient temperature condition and an elevated temperature condition in the post-buckled regime. It is found that stress-free normal modes establish a broadly applicable modal basis yielding accurate results for all the loading regimes considered. In contrast, the range of applicability for a thermally pre-stressed modal basis is found to be limited. The behavior is explained by scrutinizing the coupling found in the linear stiffness and the effect this coupling has on the structural response characteristics under the range of loading conditions considered.

Przekop, Adam↗

Stress Promotion of the 1958 Mw∼7.8 Fairweather Fault Earthquake and Others in Southeast Alaska by Glacial Isostatic Adjustment and Inter-earthquake Stress Transfer

We assess how recent glacial isostatic adjustment (GIA) and inter-earthquake stress transfer modulated the state of stress on major faults in Southeast Alaska, and how these effects may have influenced recent large and moderate earthquakes. The Glacier Bay Icefield has lost >3,000 km3 of ice since ca. 1770, with ice thinning up to 1.5 km, and the rest of southeast Alaska has been deglaciating since ca. 1900. The resulting GIA response in the solid earth produces present-day surface uplift rates of up to ∼4 cm/yr, among the fastest on Earth. This rapid deformation occurs directly alongside and atop the Fairweather Fault, which accommodates 4–5 cm/yr of right-lateral motion through slip in frequent large earthquakes, recently including a Mw∼7.8 earthquake in 1958. We find that the 1958 earthquake nucleated very close to the location of maximum GIA-induced Coulomb stress increase on the Fairweather Fault between 1770 and 1958 (estimated at ∼0.2–0.6 MPa), on the only section of fault where GIA-induced stress changes had involved both right-lateral shearing and unclamping. The September 10, 1899 Mw∼8.1 Yakutat Bay earthquake also promoted failure on at least the northwest part of the eventual 1958 rupture. In turn, the 1899 and 1958 earthquakes and GIA promoted failure along the St. Elias compressional margin, the site of a Mw∼7.4 event in 1979. While rapid tectonic loading is very likely the main driver of earthquakes in southeast Alaska, we estimate that 23 of 30 instrumentally constrained Mw ≥ 5.0 earthquakes in this region were also promoted by post-1770 GIA.

Chris Rollins↗

The Importance of Vane Configuration on Yield Stress Measurements of Cement Slurry

Vane methods combined with direct shear tests are widely applied to measure the yield stress $τ_0$ in concentrated suspensions such as cement slurries. This report reviews three different vanes with different shapes and sizes, and examines the relationship between the yield stress versus the torque and the shear rate versus the angular velocity. This research shows that vanes with conical shapes or reduced height/diameter ratio $(H/D)$ result in larger yield stress values.

36 MATERIALS SCIENCE↗

On the role of constant-stress surfaces in the problem of minimizing elastic stress concentration

Cases involving antiplane shear deformation, axisymmetric torsion, and plane strain theory, with surfaces of constant stress magnitude optimal in terms of minimizing stress, are investigated. Results for the plane theory refer to exterior doubly connected domains. Stresses generated by torsion of an elastic solid lying within a radially convex region of revolution with plane ends, body force absent, and lateral surface traction-free, are examined. The unknown portion of the boundary of such domains may involve a hole, fillet, or notch.

Wheeler, L.↗

Use of two-dimensional transmission photoelastic models to study stresses in double-lap bolted joints: Load transfer and stresses in the inner lap

The determination of the stress distribution in the inner lap of double-lap, double-bolt joints using photoelastic models of the joint is discussed. The principal idea is to fabricate the inner lap of a photoelastic material and to use a photoelastically sensitive material for the two outer laps. With this setup, polarized light transmitted through the stressed model responds principally to the stressed inner lap. The model geometry, the procedures for making and testing the model, and test results are described.

Hyer, M. W.↗

Boundary-layer effects in composite laminates. I - Free-edge stress singularities. II - Free-edge stress solutions and basic characteristics

The fundamental nature of the boundary-layer effect in fiber-reinforced composite laminates is formulated in terms of the theory of anisotropic elasticity. The basic structure of the boundary-layer field solution is obtained by using Lekhnitskii's stress potentials (1963). The boundary-layer stress field is found to be singular at composite laminate edges, and the exact order or strength of the boundary layer stress singularity is determined using an eigenfunction expansion method. A complete solution to the boundary-layer problem is then derived, and the convergence and accuracy of the solution are analyzed, comparing results with existing approximate numerical solutions. The solution method is demonstrated for a symmetric graphite-epoxy composite.

Wang, S. S.↗