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Hidden Spin-Valley Locking Stabilizes Nanosecond Spin Polarization in 2D Perovskites

Room-temperature spin control in semiconductors is fundamental to spin-optoelectronics. Although inversion symmetry breaking offers one path for spin control in semiconductors, strong spin dephasing at elevated temperatures remains a persistent limitation. Hidden spin polarization without global symmetry breaking provides another promising material design strategy, but robust spin stabilization from this effect has yet to be experimentally realized. Here we show spin stabilization at room temperature in two-dimensional hybrid organic-inorganic perovskites through hidden spin-valley locking. We use functional non-primary ammonium cations to induce symmetry-breaking distortions in the metal-halide layers, producing giant local spin splitting while preserving global inversion symmetry. Time-resolved circular dichroism measurements reveal optically generated spin-polarized carriers that persist for 686 ps in (AzOH)2PbI4 and 4.7 ns in the lead-free analogue (AzOH)2SnI4 at room temperature, without an external magnetic field. First-principles calculations suggest that these long lifetimes arise from hidden spin valleys, enhanced dielectric screening and reduced spin-orbit-induced scattering in the Sn-based compound. Our design paradigm unlocks inversion-symmetric semiconductors with ultralong spin lifetimes, broadening the materials options for light-driven spin control.

14 SOLAR ENERGY

Attitude stability of spinning flexible spacecraft

The stability of spinning flexible satellites in a force-free environment was analyzed. The satellite was modeled as a rigid core having attached to it a flexible appendage idealized as a collection of particles (point masses) interconnected by springs. Both Liapunov and Routh-Hurwitz stability procedures are used. In the former, the Hamiltonian of the system, constrained through the angular momentum integral so as to admit complete damping, is used as a testing function. Equations of motion are written using the hybrid coordinate formulation, which readily accepts a modal coordinate transformation ultimately allowing truncation to a level amenable to literal stability analysis. Closed form stability criteria are generated for the first mode of a restricted appendage model lying in a plane containing the system center of mass and orthogonal to the spin axis. The effects of spin on flexible bodies are discussed by considering a very elementary particle model. Control of passively unstable spacecraft is briefly considered.

Likins, P. W.

Attitude stability of spinning satellites

Some problems of attitude stability of spinning satellites are treated in a rigorous manner. With certain restrictions, linearized stability analysis correctly predicts the attitude stability of spinning satellites, even in the critical cases of the Liapunov-Poincare stability theory.

Caughey, T. K.

Attitude Ground System (AGS) For The Magnetospheric Multi-Scale (MMS) Mission

The Magnetospheric Multiscale (MMS) mission is a Solar-Terrestrial Probe mission consisting of four identically instrumented spin-stabilized spacecraft flying in an adjustable pyramid-like formation around the Earth. The formation of the MMS spacecraft allows for three-dimensional study of the phenomenon of magnetic reconnection, which is the primary objective of the mission. The MMS spacecraft were launched early on March 13, 2015 GMT. Due to the challenging and very constricted attitude and orbit requirements for performing the science, as well as the need to maintain the spacecraft formation, multiple ground functionalities were designed to support the mission. These functionalities were incorporated into a ground system known as the Attitude Ground System (AGS). Various AGS configurations have been used widely to support a variety of three-axis-stabilized and spin-stabilized spacecraft missions within the NASA Goddard Space Flight Center (GSFC). The original MMS operational concept required the AGS to perform highly accurate predictions of the effects of environmental disturbances on the spacecraft orientation and to plan the attitude maneuvers necessary to stay within the science attitude tolerance. The orbit adjustment requirements for formation control drove the need also to perform calibrations that have never been done before in support of NASA GSFC missions. The MMS mission required support analysts to provide fast and accurately calibrated values of the inertia tensor, center of mass, and accelerometer bias for each MMS spacecraft. During early design of the AGS functionalities, a Kalman filter for estimating the attitude, body rates, center of mass, and accelerometer bias, using only star tracker and accelerometer measurements, was heavily analyzed. A set of six distinct filters was evaluated and considered for estimating the spacecraft attitude and body rates using star tracker data only. Four of the six filters are closely related and were compared during support of the Time History of Events and Macroscale Interactions during Substorms (THEMIS) and Space Technology-5 (ST-5) missions. These analyses exposed high dependency and sensitivity on the knowledge of the spacecraft inertia tensor for both body rates and accelerometer bias estimation. The conclusion of the analysis led to the design of an inertia tensor calibration technique using only star tracker data. The second most important result of the analysis was the design of two separate Kalman filters to estimate the spacecraft attitude and body rates and the accelerometer bias instead of a single combined filter. In this paper, the calibration results of the mass properties, as well as the performance of the spacecraft attitude and body rates filters using flight data are presented and compared against the mission requirements.

Estimation

Pointing and control for planetary spacecraft - The first twenty years

The evolution of guidance and control systems for United States planetary and unmanned lunar spacecraft over the last 20 years is traced. The characteristics of the guidance and control systems used on spacecraft from the Range lunar impactor to the planned Galileo Jupiter orbiter and entry probe are surveyed, with attention given to the uses of three-axis stabilized, spin-stabilized and dual-spin designs. System performance trends that have evolved to meet the increasing science and mission requirements of the spacecraft are considered in the areas of attitude references, control consumables, dynamics and system modeling, thrust vector control, optical navigation, manuever turns, maneuver velocity control, instrument pointing, and antenna pointing. Hardware trends in optical sensors, inertial sensors, processing electronics, electromechanical devices, and system testing and reliability are also reviewed. The achievements represented by these advances are emphasized, and it is predicted that future developments will be in the areas of increased control system autonomy and performance requirements.

Pace, G. D.

Free vibration analysis of spinning structural systems.

This article presents an efficient digital computer procedure, along with the complete listing of the associated computer program, which may be conveniently utilized for the accurate solution of a wide range of practical eigenvalue problems. Important applications of the present work are envisaged in the natural frequency analysis of spinning structures discretized by the finite element technique, and in the determination of transfer functions associated with the dynamic blocks of control systems of spacecraft utilizing gas jets or reaction wheels for attitude control, as well as of spin-stabilized and dual-spin-stabilized satellites. The validity of the Sturm sequence property is first established for the related matrix formulation involving Hermitian and real symmetric, positive-definite matrices, both being usually of highly banded configuration. A numerically stable algorithm based on the Sturm sequence method is then developed which fully exploits the banded form of the associated matrices.

Gupta, K. K.

System design of the Pioneer Venus spacecraft. Volume 9: Attitude control/mechanisms subsystems studies

The Pioneer Venus mission study was conducted for a probe spacecraft and an orbiter spacecraft to be launched by either a Thor/Delta or an Atlas/Centaur launch vehicle. Both spacecraft are spin stabilized. The spin speed is controlled by ground commands to as low as 5 rpm for science instrument scanning on the orbiter and as high as 71 rpm for small probes released from the probe bus. A major objective in the design of the attitude control and mechanism subsystem (ACMS) was to provide, in the interest of costs, maximum commonality of the elements between the probe bus and orbiter spacecraft configurations. This design study was made considering the use of either launch vehicle. The basic functional requirements of the ACMS are derived from spin axis pointing and spin speed control requirements implicit in the acquisition, cruise, encounter and orbital phases of the Pioneer Venus missions.

Neil, A. L.

Spacecraft attitude and articulation control systems for future planetary missions

Comparative evaluations of the major types of control systems, such as three-axis-active, spin-stabilized, dual spin, and momentum basis, are performed to determine their applicability for planetary missions in the early 1990s. The key requirements that determine control system selection are science functional, mission orbital, and vehicle configuration characteristics. Five functional groups are given for preliminary control system selection: (1) preliminary survey; (2) detailed remote observation; (3) close scrutiny - deep space; (4) close scrutiny - near sun; (5) sample return. Requirements affecting the selection of attitude/articulation control methods, comparison of the performance capabilities of competing control concepts, criteria for selecting competing methods, comparison of relative complexity, and identification of hardware needs and trends that may affect control system selection are considered.

Mcglinchey, L. F.

Long Term Missions at the Sun-Earth Libration Point L1: ACE, SOHO, and WIND

Three heliophysics missions -- the Advanced Composition Explorer (ACE), Solar Heliospheric Observatory (SOHO), and the Global Geoscience WIND -- have been orbiting the Sun-Earth interior libration point L1 continuously since 1997, 1996, and 2004, respectively. ACE and WIND (both NASA missions) and SOHO (an ESA-NASA joint mission) are all operated from the NASA Goddard Space Flight Center (GSFC). While ACE and SOHO have been dedicated libration point orbiters since their launches, WIND has had also a remarkable 10-year career flying a deep-space, multiple lunar-flyby trajectory prior to 2004. That era featured 36 targeted lunar flybys with excursions to both L1 and L2 before its final insertion in L1 orbit. A figure depicts the orbits of the three spacecraft, showing projections of the orbits onto the orthographic planes of a solar rotating ecliptic frame of reference. The SOHO orbit is a quasi-periodic halo orbit, where the frequencies of the in-plane and out-of-plane motions are practically equal. Such an orbit is seen to repeat itself with a period of approximately 178 days. For ACE and WIND, the frequencies of the in-plane and out-of-plane motions are unequal, giving rise to the characteristic Lissajous motion. ACE's orbit is of moderately small amplitude, whereas WIND's orbit is a large-amplitude Lissajous of dimensions close to those of the SOHO halo orbit. As motion about the collinear points is inherently unstable, stationkeeping maneuvers are necessary to prevent orbital decay and eventual escape from the L1 region. Though the three spacecraft are dissimilar (SOHO is a 3-axis stabilized Sun pointer, WIND is a spin-stabilized ecliptic pole pointer, and ACE is also spin-stabilized with its spin axis maintained between 4 and 20 degrees of the Sun), the stationkeeping technique for the three is fundamentally the same. The technique consists of correcting the energy of the orbit via a delta-V directed parallel or anti-parallel to the Spacecraft-to-Sun line. SOHO achieves this using thrusters oriented in line with the solar direction. WIND achieves the delta-V via pulsing radial thrusters when aligned with the Sun. ACE uses axial thrusters to apply delta-V with a component that is 94% or more aligned with the ACE-Sun line. Sunward thrust adds energy to the orbit preventing decay back toward Earth. Thrust directed anti-Sunward takes energy out of the L1 orbit, thereby preventing escape from the Earth-Moon system into independent heliocentric orbit. Libration point orbit stationkeeping delta-V costs grow exponentially with time elapsed from the last maneuver performed. The doubling time constant is approximately 16 days. For the sake of fuel conservation, and for limiting the absolute magnitude of propulsion performance errors, stationkeeping maneuvers should be performed before the delta-V grows too large; for our purposes 'too large' is considered to be greater than 0.5 m/sec. In practice, the typical interval between burns for this trio is about three months, and the typical delta-V is much smaller than 0.5 m/sec. Typical annual stationkeeping costs have been around 1.0 m/sec for ACE and WIND, and much less than that for SOHO. All three spacecraft have ample fuel remaining; barring contingencies all three could, in principle, be maintained at L1 for decades to come. This paper will review the L1 orbits and the mission history of ACE, WIND, and SOHO, and describe the stationkeeping techniques and orbit maneuver experience. The Lissajous phase control that was practiced for ACE during the period from 1999 to 2001 will also be briefly discussed. The final section will consider the future of these ongoing missions.

Roberts, Craig E.

Stabilizing a spinning Skylab

The results are presented of a study of the dynamics of a spinning Skylab space station. The stability of motion of several simplified models with flexible appendages was investigated. A digital simulation model that more accurately portrays the complex Skylab vehicle is described, and simulation results are compared with analytically derived results.

Seltzer, S. M.

Stabilizing a spinning Skylab.

This paper presents the results of a study of the dynamics of a spinning Skylab space station. The stability of motion of several simplified models with flexible appendages was investigated. A digital simulation model that more accurately portrays the complex Skylab vehicle is described, and simulation results are compared with analytically derived results.

Seltzer, S. M.

A Computational Investigation for Determining the Natural Frequencies and Damping Effects of Diaphragm-Implemented Spacecraft Propellant Tanks

Spin-stabilization maneuvers are typically performed by spacecraft entering low-earth orbit to maintain attitude stability. These maneuvers induce periodic fluid movement inside the spacecraft's propellant tank known as fuel slosh, which is responsible for creating forces and moments on the sidewalls of the propellant tank. These forces and moments adversely affect spin-stabilization and risk jeopardizing the mission of the spacecraft. Therefore, propellant tanks are designed with propellant management devices (PMD's) such as barnes or diaphragms which work to counteract the forces and moments associated with fuel slosh. However, despite the presence of PMD's, the threat of spin-stabilization interference still exists should the propellant tank be excited at its natural frequency. When the fluid is excited at its natural frequency, the forces and moments acting on the propellant tank are amplified and may result in destabilizing the spacecraft. Thus, a computational analysis is conducted concerning diaphragm-implemented propellant tanks excited at their natural frequencies. Using multi-disciplinary computational fluid dynamics (CFD) software, computational models are developed to reflect potential scenarios that spacecraft propellant tanks could experience. By simulating the propellant tank under a wide array of parameters and variables including fill-level, gravity and diaphragm material and shape, a better understanding is gained as to how these parameters individually and collectively affect liquid propellant tanks and ultimately, spacecraft attitude dynamics.

Lenahen, Brian

A Globally Stable Lyapunov Pointing and Rate Controller for the Magnetospheric MultiScale Mission (MMS)

The Magnetospheric MultiScale Mission (MMS) is scheduled to launch in late 2014. Its primary goal is to discover the fundamental plasma physics processes of reconnection in the Earth's magnetosphere. Each of the four MMS spacecraft is spin-stabilized at a nominal rate of 3 RPM. Traditional spin-stabilized spacecraft have used a number of separate modes to control nutation, spin rate, and precession. To reduce the number of modes and simplify operations, the Delta-H control mode is designed to accomplish nutation control, spin rate control, and precession control simultaneously. A nonlinear design technique, Lyapunov's method, is used to design the Delta-H control mode. A global spin rate controller selected as the baseline controller for MMS, proved to be insufficient due to an ambiguity in the attitude. Lyapunov's design method was used to solve this ambiguity, resulting in a controller that meets the design goals. Simulation results show the advantage of the pointing and rate controller for maneuvers larger than 90 deg and provide insight into the performance of this controller.

Shah, Neerav

Decomposition-aggregation stability analysis of the spinning Skylab

Stability of an 11-th order linear model of the spinning Skylab is determined by the decomposition-aggregation method based upon the comparison principle and vector Liapunov functions. To reduce the inherent conservativeness of the method an optimization problem is formulated and resolved producing the optimum comparison system. The system provides the best estimate of the stability region of the important structural parameter - asymmetry in the boom settings.

Cuk, S. M.

Utilizing the Precessing Orbit of TRMM to Produce Hourly Corrections of Geostationary Infrared Imager Data with the VIRS Sensor

Accurate characterization of the Earth's radiant energy is critical for many climate monitoring and weather forecasting applications. For example, groups at the NASA Langley Research Center rely on stable visible- and infrared-channel calibrations in order to understand the temporal/spatial distribution of hazardous storms, as determined from an automated overshooting convective top detection algorithm. Therefore, in order to facilitate reliable, climate-quality retrievals, it is important that consistent calibration coefficients across satellite platforms are made available to the remote sensing community, and that calibration anomalies are recognized and mitigated. One such anomaly is the infrared imager brightness temperature (BT) drift that occurs for some Geostationary Earth Orbit satellite (GEOsat) instruments near local midnight. Currently the Global Space-Based Inter-Calibration System (GSICS) community uses the hyperspectral Infrared Atmospheric Sounding Interferometer (IASI) sensor as a common reference to uniformly calibrate GEOsat IR imagers. However, the combination of IASI, which has a 21:30 local equator crossing time (LECT), and hyperspectral Atmospheric Infrared Sounder (AIRS; 01:30 LECT) observations are unable to completely resolve the GEOsat midnight BT bias. The precessing orbit of the Tropical Rainfall Measuring Mission (TRMM) Visible and Infrared Scanner (VIRS), however, allows sampling of all local hours every 46 days. Thus, VIRS has the capability to quantify the BT midnight effect observed in concurrent GEOsat imagers. First, the VIRS IR measurements are evaluated for long-term temporal stability between 2002 and 2012 by inter-calibrating with Aqua-MODIS. Second, the VIRS IR measurements are assessed for diurnal stability by inter-calibrating with Meteosat-9 (Met-9), a spin-stabilized GEOsat imager that does not manifest any diurnal dependency. In this case, the Met-9 IR imager is first adjusted with the official GSICS calibration coefficients. Then VIRS is used as a diurnal calibration reference transfer to produce hourly corrections of GEOsat IR imager BT. For the 9 three-axis stabilized GEO imagers concurrent with VIRS, the midnight effect increased the BT on average by 0.5 K (11 microns) and 0.4 K (12 microns), with a peak at approx.01:00 local time. As expected, the spin-stabilized GEOsats revealed a smaller diurnal temperature cycle (mostly < 0.2 K) with inconsistent peak hours.

Scarino, Benjamin