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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Systematic evaluation of structure–property relationships in heteroacene – diketopyrrolopyrrole molecular donors for organic solar cells

Improved understanding of fundamental structure–property relationships, particularly the effects of molecular shape and intermolecular packing on film morphology and active layer charge transport characteristics, enables more rational synthesis of new p-type small molecules. Here we investigate a series of small molecules consisting of an acene-based electron-rich core flanked by one or two electron-deficient diketopyrrolopyrrole (DPP) moieties. Through minor changes in the molecule structures, measurable variations in the crystal structure and sizable differences in macroscopic properties are achieved. The molecular symmetry as well as the conformation of the side chains affects the unit cell packing density and strength of the intermolecular electronic coupling in single crystals of all molecules in this series. Here, the addition of a second DPP unit to the benzodithiophene (BDT) core increases molecular planarity leading to decreased reorganization energy, strong cofacial coupling, and moderate hole mobility (2.7 × 10 –4 cm 2 V –1 s –1 ). Increasing the length of the acene core from benzodithiophene to naphthodithiophene (NDT) results in a further reduction in reorganization energy and formation of smaller crystalline domains (~11 nm) when mixed with PCBM. Decreasing the aspect ratio of the core using a “zig-zag” naphthodithiophene (zNDT) isomer results in the highest hole mobility of 1.3 × 10 –3 cm 2 V –1 s –1 due in part to tight lamellar (d = 13.5 Å) and π–π stacking (d = 3.9 Å). The hole mobility is directly correlated with the short-circuit current (11.7 mA cm –2 ) and solar cell efficiency (4.4%) of the highest performing zNDT:PCBM device. For each of these small molecules the calculated π-coupling constant is correlated with the hole mobility as a function of crystal structure and orientation indicating the importance of designing molecules that create extended crystalline networks with maximal π-orbital overlap.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Analysis of Planar-Cavity Receiver Reactor for Solar Thermochemical Dry-Reforming

Concentrating solar thermal (CST) systems can be leveraged to provide not only heat for power generation, but also for energy storage and thermochemical fuel production. Such solar thermochemical processes have been studied conceptually, from solar thermochemical hydrogen production (STCH) and thermochemical energy storage (TCES), to gasification, reforming, and fuel upgrading by various means. The solar receiver and reactor are critical components in the conversion of solar energy into chemical energy in the form of 'solar fuels'. For effective conversion of solar energy within a coupled solar receiver-reactor, extremely high temperatures are required, thereby demanding a high solar concentration ratio (CR) for efficient operation. This creates a design challenge for the receiver-reactor, as many thermochemical processes involve gas or gas-solid systems that are limited by low heat transfer coefficients. A unique receiver design is proposed that has the potential to incorporate various high-temperature thermochemical processes such as TCES-assisted power generation, methane reforming, or STCH processes. Modeling this receiver and its potential applications requires a full three-dimensional model that accurately captures the interconnected effects of receiver geometry, spatial solar irradiance, complex radiation, reaction kinetics, fluid dynamics, and heat transfer. In this paper we analyze a CST system integrated with this unique planar-cavity receiver-reactor design using the developed model. The model presented in this paper showed where improved thermal management was needed to achieve suitable receiver performance when a dry-methane reforming process is implemented.

14 SOLAR ENERGY↗
DOE OSTI2022

Design of a Combined Proportional Integral Derivative Controller to Regulate the Temperature Inside a High-Temperature Tubular Solar Reactor

Solar fuels are proven to be promising candidates for thermochemical energy storage. However, the transient nature of solar radiation is an obstacle to maintaining a stable operational temperature inside a solar reactor. To overcome this challenge, the temperature of a solar reactor can be regulated by controlling the incoming solar radiation or the feedstock flowrate inside the reactor. In this work, a combined proportional integral derivative (PID) controller is implemented to regulate the temperature inside a high-temperature tubular solar reactor with counter-current flowing gas/particles. The control model incorporates two control systems to regulate incoming solar radiation and gas flow simultaneously. The design of the controller is based on a reduced-order numerical model of a high-temperature tubular solar reactor that is vertically oriented with an upward gas flow and downward particle flow. The reactor receives heat circumferentially through its wall over a finite segment of its length. Formulation of the heat transfer model is presented by applying the energy balance for the reactor tube and considering heat and mass transfer inside. A set of governing differential equations are solved numerically by using the finite volume method to obtain reactor wall, particles, and gas temperatures along the reactor length with various boundary conditions. Simulation results are used to tune the PID controller parameters by utilizing the Ziegler–Nichols tuning method. Both the simulation results and the controller performance are visualized on the LABVIEW platform. The controller is challenged to track different temperature setpoints with different scenarios of transient solar radiation. Here, the performance of the PID controller was compared to experimental results obtained from an industrial PID controller embedded in a 7 kW electric furnace. Results show that the combined PID controller is successful in maintaining a stable temperature inside the reactor by regulating the incoming solar radiation and the flowrate via small steady-state error and reasonable settling time and overshoot.

14 SOLAR ENERGY↗
DOE OSTI2017

Variations in Solar Parameters and Cosmic Rays with Solar Magnetic Polarity

The sunspot number varies with the 11-year Schwabe cycle, and the solar magnetic polarity reverses every 11 years approximately at the solar maximum. Because of polarity reversal, the difference between odd and even solar cycles is seen in solar activity. In this study, we create the mean solar cycle expressed by phase using the monthly sunspot number for all solar cycles 1–23. We also generate the mean solar cycle for sunspot area, solar radio flux, and cosmic ray flux within the allowance of observational range. The mean solar cycle has one large peak at solar maximum for odd solar cycles and two small peaks for most even solar cycles. The odd and even solar cycles have the statistical difference in value and shape at a confidence level of at least 98%. For solar cycles 19–23, the second peak in the even solar cycle is larger than the first peak. This result is consistent with the frequent solar events during the declining phase after the solar maximum. The difference between odd and even solar cycles can be explained by a combined model of polarity reversal and solar rotation. In the positive/negative polarity, the polar magnetic field introduces angular momentum in the same/opposite direction as/to the solar rotation. Thus the addition/subtraction of angular momentum can increase/decrease the motion of plasma to support the formation of sunspots. Since the polarity reverses at the solar maximum, the opposite phenomenon occurs in the declining phase.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRSDate not supplied

Attitude Control System for the Solar Cruiser and Future Solar Sail Missions

NASA’s Marshall Space Flight Center (MSFC) is developing the Solar Cruiser solar sail mission to continue to mature solar sail propulsion. Solar Cruiser is a 95kg spacecraft capable of deploying a 1654 square meter solar sail. Solar Cruiser will demonstrate science observation capabilities and navigation in sub Lagrange Point (L1) halo-orbits. Solar Cruiser sail technology can be scaled to larger solar sail missions, including attitude control system and sail membrane and boom technology. Larger solar sails could be used to image the solar poles, enabling Solar Polar Imager (SPI) missions currently prohibitively expensive for propellant-based propulsion methods. Similarly, solar sails can be used to create artificial equilibria and indefinite station-keeping at locations sunward of Lagrange Point one, L1, along the Sun-Earth line (SEL), which can provide space-weather monitor and prediction and reveal discoveries about our Sun and solar system. To achieve the high characteristic acceleration required for larger solar sail missions such as SPI, a solar sail area of approximately 7000 square-meters would be needed. In comparison, the largest solar sail flown to date is the JAXA’s IKAROS mission with a 196 square-meters sail. Attitude control an SPI-size sail poses challenges, including station keeping under solar sail induced torques and thrust vector pointing. In this study, the scalability of the Solar Cruiser sail attitude control architecture to larger sails is studied, such as pointing control performance, mass and power requirements. Solar Cruiser attitude control actuators include propellant-based, such as ion engines, and propellantless options which create differential solar pressures to generate spacecraft torques. Propellantless attitude control includes active translation of the center of mass, Reflectivity Control Devices (RCDs), and tip vanes. The study summarizes the scalability characteristics of the different attitude control architectures for larger solar sail missions.

Solar Sail Propulsion↗
DOE OSTI2016

The environmental and public health benefits of achieving high penetrations of solar energy in the United States

Here, we estimate the environmental and public health benefits that may be realized if solar energy cost reductions continue until solar power is competitive across the U.S. without subsidies. Specifically, we model, from 2015 to 2050, solar power–induced reductions to greenhouse gas (GHG) emissions, air pollutant emissions, and water usage. To find the incremental benefits of new solar deployment, we compare the difference between two scenarios, one where solar costs have fallen such that solar supplies 14% of the nation's electricity by 2030 and 27% by 2050, and a baseline scenario in which no solar is added after 2014. We monetize benefits, where credible methods exist to do so. We find that under these scenarios, solar power reduces GHG and air pollutants by ~10%, from 2015 to 2050, providing a discounted present value of 56–789 billion USD (central value of ~250 billion USD, equivalent to ~2 ¢/kWh-solar) in climate benefits and 77–298 billion USD (central value of 167 billion USD, or ~1.4 ¢/kWh-solar) in air quality and public health benefits. The ranges reflect uncertainty within the literature about the marginal impact of emissions of GHG and air pollutants. Solar power is also found to reduce water withdrawals and consumption by 4% and 9%, respectively, including in many drought-prone states.

14 SOLAR ENERGY↗
DOE OSTI2016

Midmarket Solar Policies in the United States: A Guide for Midsized Solar Customers

The midscale market for solar photovoltaics (PV) has not experienced the same high growth rate as residential- or utility-scale market segments in the past five years when solar PV deployment increased rapidly. Midscale solar can be defined as behind-the-meter solar PV between 50 kilowatts and 2 megawatts adopted by multi-housing residential, commercial, industrial, non-profit, and other entities. A number of challenges face the midscale segment, including difficulties in contracting, mismatch between tenant lease and PV financing terms, high transaction costs relative to project sizes, and inefficiencies in matching prospective projects with capital. The changing policy landscape across U.S. states provides both opportunities and challenges to midmarket solar. Some states, such as California, are expanding system capacity limits for policies such as net metering, thus enabling a wider range of customers to benefit from excess generation. A number of states and utilities are making changes to rate design to introduce new or higher user fees for solar customers or reduced tariffs for net metering, which decrease the value of solar generation. An understanding of these policies relative to project feasibility and economics is important for prospective customers to make informed decisions to adopt solar PV. This guide complements existing solar policy resources to help potential customers navigate through the policy landscape in order to make informed decisions for their solar investment. The first part of this guide introduces the key solar policies necessary for policy-based decision-making, which involves using knowledge of a solar policy to improve project economics and efficiency. Policies that could result in policy-based decisions include interconnection standards, net metering, user fees, incentives, and third-party ownership policies. The goal of this section is to equip prospective customers and project developers with the tools necessary to understand and use solar policies in a dynamic policy environment. The second part of this guide provides a complete, state-by-state inventory of midmarket solar policies for potential customers and developers to use as reference when making policy-based decisions. Although solar policies are dynamic, the profiles provide a framework for assessing policies to build the parameters that could be used to determine feasibility and structure of a solar PV system for midmarket customers and developers.

14 SOLAR ENERGY↗
DOE OSTI2024

Solar Energy Technical Publications Catalog: Solar Thermal Technology

The research and development described in these documents was conducted within the U.S . Department of Energy's (DOE) Solar Thermal Technology Program. The goal of this program is to advance the engineering and scientific understanding of solar thermal technology and to establish the technology base from which private industry can develop solar thermal power production options for introduction into the competitive energy market. Solar thermal technology concentrates the solar flux using tracking mirrors or lenses onto a receiver where the solar energy is absorbed as heat and converted into electricity or incorporated into products as process heat. The two primary solar thermal technologies, central receivers and distributed receivers, employ various point and line-focus optics to concentrate sunlight. Current central receiver systems use fields of heliostats (two-axis tracking mirrors) to focus the sun's radiant energy onto a single, tower- mounted receiver. Point focus concentrators up to 17 meters in diameter track the sun in two axes and use parabolic dish mirrors or Fresnel lenses to focus radiant energy onto a receiver. Troughs and bowls are line-focus tracking reflectors that concentrate sunlight onto receiver tubes along their focal lines. Concentrating collector modules can be used alone or in a multimodule system. The concentrated radiant energy absorbed by the solar thermal receiver is transported to the conversion process by a circulating work fluid. Receiver temperatures range from l00 degrees C in low-temperature troughs to over 1500 degrees C in dish and central receiver systems. The Solar Thermal Technology Program is directing efforts to advance and improve each system concept through solar thermal materials, components, and subsystems research and development and by testing and evaluation. These efforts are carried out with the technical direction of DOE and its network of field laboratories that works with private industry. Together they have established a comprehensive, goal-directed program to improve performance and provide technically proven options for eventual incorporation into the nation's energy supply. To successfully contribute to an adequate energy supply at reasonable cost, solar thermal energy must be economically competitive with a variety of other energy sources. The Solar Thermal Technology Program has developed components and system-level performance targets as quantitative program goals. These targets are used in planning research and development activities, measuring progress, assessing alternative technology options, and developing optimal components. These targets are pursued vigorously to ensure a successful program. This catalog represents part of an effort to provide information on publications about solar thermal research and development activities conducted by DOE's laboratories. Publications listed include technical and research reports and special publications. The following national laboratories are represented in this edition: Sandia National Laboratories, Solar Energy Research Institute, Jet Propulsion Laboratory. This catalog is a product of the DOE Solar Technical Information Program, which is dedicated to providing information to scientific and industrial users in ways most convenient and useful to them. This catalog focuses on solar thermal technologies, and its purpose is to keep the scientific and industrial communities informed of the latest developments in federally sponsored research in this technology.

140000* -- Solar Energy↗
NASA NTRS2007

Solar Cycle #24 and the Solar Dynamo

We focus on two solar aspects related to flight dynamics. These are the solar dynamo and long-term solar activity predictions. The nature of the solar dynamo is central to solar activity predictions, and these predictions are important for orbital planning of satellites in low earth orbit (LEO). The reason is that the solar ultraviolet (UV) and extreme ultraviolet (EUV) spectral irradiances inflate the upper atmospheric layers of the Earth, forming the thermosphere and exosphere through which these satellites orbit. Concerning the dynamo, we discuss some recent novel approaches towards its understanding. For solar predictions we concentrate on a solar precursor method, in which the Sun s polar field plays a major role in forecasting the next cycle s activity based upon the Babcock- Leighton dynamo. With a current low value for the Sun s polar field, this method predicts that solar cycle #24 will be one of the lowest in recent times, with smoothed F10.7 radio flux values peaking near 130+ 30 (2 4, in the 2013 timeframe. One may have to consider solar activity as far back as the early 20th century to find a cycle of comparable magnitude. Concomitant effects of low solar activity upon satellites in LEO will need to be considered, such as enhancements in orbital debris. Support for our prediction of a low solar cycle #24 is borne out by the lack of new cycle sunspots at least through the first half of 2007. Usually at the present epoch in the solar cycle (-7+ years after the last solar maximum), for a normal size following cycle, new cycle sunspots would be seen. The lack of their appearance at this time is only consistent with a low cycle #24. Polar field observations of a weak magnitude are consistent with unusual structures seen in the Sun s corona. Polar coronal holes are the hallmarks of the Sun s open field structures. At present, it appears that the polar coronal holes are relatively weak, and there have been many equatorial coronal holes. This appears consistent with a weakening polar field, but coronal hole data must be scrutinized carefully as observing techniques have changed. We also discuss new solar dynamo ideas, and the SODA (Solar Dynamo Amplitude) index, which provides the user with the ability to track the Sun s hidden, dynamo magnetic fields throughout the various stages of the Sun s cycle. Our solar dynamo ideas are a modernization and rejuvenation of the Babcock-Leighton original idea of a shallow solar dynamo, using modem observations that appear to support their shallow dynamo viewpoint. We are in awe of being able to see an object the size of the Sun undergoing as dramatic a change as our model provides in a few short years. The Sun, however, has undergone changes as rapid as this before! The weather on the Sun is at least as fickle as the weather on the Earth.

Pesnell, W. Dean↗
NASA NTRS2007

Solar Cycle #24 and the Solar Dynamo

We focus on two solar aspects related to flight dynamics. These are the solar dynamo and long-term solar activity predictions. The nature of the solar dynamo is central to solar activity predictions, and these predictions are important for orbital planning of satellites in low earth orbit (LEO). The reason is that the solar ultraviolet (UV) and extreme ultraviolet (EUV) spectral irradiances inflate the upper atmospheric layers of the Earth, forming the thermosphere and exosphere through which these satellites orbit. Concerning the dynamo, we discuss some recent novel approaches towards its understanding. For solar predictions we concentrate on a solar precursor method, in which the Sun's polar field plays a major role in forecasting the next cycle s activity based upon the Babcock-Leighton dynamo. With a current low value for the Sun s polar field, this method predicts that solar cycle #24 will be one of the lowest in recent times, with smoothed F10.7 radio flux values peaking near 130 plus or minus 30 (2 sigma), in the 2013 timeframe. One may have to consider solar activity as far back as the early 20th century to find a cycle of comparable magnitude. Concomitant effects of low solar activity upon satellites in LEO will need to be considered, such as enhancements in orbital debris. Support for our prediction of a low solar cycle #24 is borne out by the lack of new cycle sunspots at least through the first half of 2007. Usually at the present epoch in the solar cycle (approx. 7+ years after the last solar maximum), for a normal size following cycle, new cycle sunspots would be seen. The lack of their appearance at this time is only consistent with a low cycle #24. Polar field observations of a weak magnitude are consistent with unusual structures seen in the Sun s corona. Polar coronal holes are the hallmarks of the Sun's open field structures. At present, it appears that the polar coronal holes are relatively weak, and there have been many equatorial coronal holes. This appears consistent with a weakening polar field, but coronal hole data must be scrutinized carefully as observing techniques have changed. We also discuss new solar dynamo ideas, and the SODA (SOlar Dynamo Amplitude) index, which provides the user with the ability to track the Sun's hidden, dynamo magnetic fields throughout the various stages of the Sun's cycle. Our solar dynamo ideas are a modernization and rejuvenation of the Babcock-Leighton original idea of a shallow solar dynamo, using modern observations that appear to support their shallow dynamo viewpoint. We are in awe of being able to see an object the size of the Sun undergoing as dramatic a change as our model provides in a few short years. The Sun, however, has undergone changes as rapid as this before! The weather on the Sun is at least as fickle as the weather on the Earth.

Schatten, Kenneth↗