Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “SMD”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 91 records · Page 5

Results from the Lunar Reconnaissance Orbiter Mission and Plans for the Extended Science Mission

The Lunar Reconnaissance Orbiter spacecraft (LRO), launched on June 18,2009, began with the goal of seeking safe landing sites for future robotic missions or the return of humans to the Moon as part of NASA's Exploration Systems Mission Directorate (ESMD). In addition, LRO's objectives included the search for surface resources and the measurement of the lunar radiation environment. After spacecraft commissioning, the ESMD phase of the mission began on September 15, 2009 and was completed on September 15, 2010 when operational responsibility for LRO was transferred to NASA's Science Mission Directorate (SMD). The SMD mission was scheduled for 2 years and completed in September of 2012. Under SMD, the Science Mission focused on a new set of goals related to understanding the history of the Moon, its current state, and what it can tell us about the evolution of the Solar System. Having recently marked the completion of the two-year Science Mission, we will review here the major results from the LRO for both exploration and science and discuss plans and objectives for the Extended Science that will last until September, 2014. Some results from the LRO mission are: the development of comprehensive high resolution maps and digital terrain models of the lunar surface; discoveries on the nature of hydrogen distribution, and by extension water, at the lunar poles; measurement of the daytime and nighttime temperature of the lunar surface including temperature down below 30 K in permanently shadowed regions (PSRs); direct measurement of Hg, H2, and CO deposits in the PSRs; evidence for recent tectonic activity on the Moon; and high resolution maps of the illumination conditions at the poles.

Vondrak, Richard R.↗

2016 Science Mission Directorate Technology Highlights

The role of the Science Mission Directorate (SMD) is to enable NASA to achieve its science goals in the context of the nation's science agenda. SMD's strategic decisions regarding future missions and scientific pursuits are guided by agency goals, input from the science community including the recommendations set forth in the National Research Council (NRC) decadal surveys and a commitment to preserve a balanced program across the major science disciplines. Toward this end, each of the four SMD science divisions -- Heliophysics, Earth Science, Planetary Science, and Astrophysics -- develops fundamental science questions upon which to base future research and mission programs.

TECHNOLOGY↗

2018 Science Mission Directorate Technology Highlights

The role of the Science Mission Directorate (SMD) is to enable NASA to achieve its science goals in the context of the nation's science agenda. SMD's strategic decisions regarding future missions and scientific pursuits are guided by agency goals, input from the science community including the recommendations set forth in the National Research Council (NRC) decadal surveys and a commitment to preserve a balanced program across the major science disciplines. Toward this end, each of the four SMD science divisions -- Heliophysics, Earth Science, Planetary Science, and Astrophysics -- develops fundamental science questions upon which to base future research and mission programs.

Technology↗

Using Arcane Data: Past Performance in NASA Science’s Principal Investigator (PI) Development Programs and Improving Future Peer Review for Space Flight Missions

This panel will explore challenges and initial findings from three qualitative studies that use the National Aeronautics and Space Administration's (NASA) Science Mission Directorate's(SMD) internal administrative data to begin to assess program effectiveness and document outputs and outcomes. SMD has funded both at and outside NASA, projects that promotethe development of SMD's future principal investigators (PI) workforce and science and technology investigations on space flight missions that advance the high priority science,technology, and exploration objectives. NASA's internal administrative data are arcane because they developed outside of relational databases. The studies reveal unique challenges to locating and using these data to document effective program processes, i.e.,peer review criteria for large flight missions, and results from the PI-development projects,e.g. the Hands-On Project Experience (HOPE) Training Opportunity solicitations limited to NASA Centers the Jet Propulsion Laboratory; and graduate student/postdoctoral opportunities at higher education institutions.

Sladek, Mary Frances↗

Leveraging Partnerships, Science Content, Special Events, and NASA Assets to Help Girl Scouts Earn Space Science Badges

Throughout 2019, NASA celebrated historic anniversaries and announced bold new programs generating excitement about earth and space exploration. One of the most notable events was the celebration of the 50th anniversary of Apollo 11 historic first steps on the Moon. Complementing this anniversary event were the additional activities and events conducted across the agency that highlighted the many science achievements that were attained across all of NASA’s Science Mission Directorate (SMD) Divisions (earth, planetary, heliophysics, and astrophysics). Further excitement was generated through NASA’s Artemis program which plans to send the first woman and next man to the surface of the Moon. NASA continues to inspire the public including learners of all ages around the world. Building on this momentum, in October 2019, the Astromaterials Research and Exploration Science (ARES) Science Engagement team partnered with the Lunar and Planetary Institute (LPI) and the Girl Scouts of San Jacinto to host an event that enabled Girl Scouts to earn recently released space science badges developed by the Reach for the Stars: NASA Science for Girls Scouts Program. The event celebrated SMD science and highlighted Earth’s Moon and International Observe the Moon Night (InOMN) while facilitating the earning of the NASA inspired space science badges. This event was coordinated and led by the ARES Science Engagement team as part of their collaborative work and involvement in NASA’s SMD Science Activation Program.

Graff, P. V.↗

Science Mission Directorate TechPort Records for 2019 STI-DAA Release

The role of the Science Mission Directorate (SMD) is to enable NASA to achieve its science goals in the context of the Nation's science agenda. SMD's strategic decisions regarding future missions and scientific pursuits are guided by Agency goals, input from the science community including the recommendations set forth in the National Research Council (NRC) decadal surveys and a commitment to preserve a balanced program across the major science disciplines. Toward this end, each of the four SMD science divisions -- Heliophysics, Earth Science, Planetary Science, and Astrophysics -- develops fundamental science questions upon which to base future research and mission programs.

Seablom, Michael S.↗

2020 SCIENCE MISSION DIRECTORATE TECHNOLOGY HIGHLIGHTS

The role of the Science Mission Directorate (SMD) is to enable NASA to achieve its science goals in the context of the nation's science agenda. SMD's strategic decisions regarding future missions and scientific pursuits are guided by agency goals, input from the science community including the recommendations set forth in the National Research Council (NRC) decadal surveys and a commitment to preserve a balanced program across the major science disciplines. Toward this end, each of the four SMD science divisions -- Heliophysics, Earth Science, Planetary Science, and Astrophysics -- develops fundamental science questions upon which to base future research and mission programs.

Michael S Seablom↗

NASA Science Mission Directorate Overview for CLD Utilization Forum

This presentation is a set of charts presented at the CLD Utilization Forum for Science Mission Directorate External Payloads. These charts provide an overview of SMD Science themes and organization, description of SMD Science, ISS and other hosted payload opportunities, and future demand of SMD External Payloads on CLDs. This presentation was presented and recorded on Aug 17, 2023 at the CLD Utilization Forum.

CLD↗

Modeling the influence of nozzle-generated turbulence on diesel sprays

The physical mechanisms governing spray breakup in direct injection engines, such as aerodynamic induced instabilities and nozzle-generated cavitation and turbulence, are not well understood due to the experimental and computational limitations in resolving these processes. Recent x-ray and visible extinction measurements have been con-ducted with a targeted interest in the spray formation region in order to characterize the distribution of droplet sizes throughout the spray. Detailed analysis of these measurements shows promise of yielding insight into likely mechanisms governing atomization, which can inform the improvement of spray models for engine computational fluid dynamic (CFD) codes. In order to investigate potential atomization mechanisms, we employ a joint experimental and computational approach to characterize the structure of the spray formation region using the Engine Combustion Network Spray D injector. X-ray tomography, radiography and ultra-small angle x-ray scattering measurements conducted at the Advanced Photon Source at Argonne National Laboratory quantify the injector geometry, liquid fuel mass and Sauter mean diameter (SMD) distributions under non-vaporizing conditions. Diffused back-illumination imaging measurements, conducted at the Georgia Institute of Technology, characterize the asymmetry of the spray structure. The selected range of injection pressures (50 – 150 MPa) and ambient densities (1.2 – 22.8 kg/m3) allow for the influence of aerodynamic forces on the spray to be studied in a controlled and systematic manner, while isolating the atomization process from the effects of vaporization. In comparison to high ambient density conditions, the spray is observed to be more asymmetric at low ambient density conditions. Although several mechanisms may cause asymmetries in the nozzle exit flow conditions and ultimately the spray distribution, irregularities in the internal nozzle geometry were identified, suggesting an increased sensitivity of the spray structure to internal nozzle surface finish imperfections at such conditions. The presence of these asymmetries may influence the ability to interpret line-of-sight measurements and their derived SMD values and trends from a single viewing angle of the spray. With this consideration in mind, the measured local sensitivities to ambient density suggest that for ambient densities less than 2.4 kg/m3, aerodynamic effects are likely suppressed, allowing the influence of turbulent-induced breakup to be isolated. In concert with the experimental measurements, we utilize three-dimensional, CFD Lagrangian-Eulerian spray simulations in CONVERGE to evaluate the details of the predicted spray structure. In particular, we compare measured and predicted sensitivities of the SMD distribution to changes in injection and ambient conditions from three different atomization models, namely Kelvin Helmholtz (KH), KH Aerodynamics Cavitation Turbulence (KH-ACT), and the newly developed KH-Faeth hybrid model. While none of the existing hybrid spray models were able to replicate the experimentally observed sensitivities, it was found that the scales characterizing the KH-Faeth model show promise of capturing the experimentally observed trends if the effects of secondary droplet breakup are neglected. These results inform recommendations for future experiments and computational studies that can guide the development of an improved spray breakup model.

33 ADVANCED PROPULSION SYSTEMS↗

Science Office for Mission Assessments Overview

The Science Office for Mission Assessments (SOMA) at NASA Langley Research Center (LaRC) supports the Science Mission Directorate (SMD) at NASA Headquarters in the acquisition of competed, Principal Investigator-led, Earth and space science missions and instruments. SOMA Acquisition Managers work with SMD Program Scientists to develop Announcement of Opportunity (AO) solicitations, and to lead the Technical, Management, and Cost (TMC) evaluations of proposals received in response to the AO solicitations and Phase A concept studies. The SOMA proposal evaluation process is described, along with examples of space science missions that SOMA personnel have worked on.

SOMA↗

Reconstruction of Central European daily weather types back to 1763

Weather type classifications (WTCs) are a simple tool to analyse variations in weather patterns. Long series of WTCs could be used to address decadal changes in weather as a basis for studying changes in variability or extremes or for addressing contributions of sea-surface temperature or external forcings using climate models. However, there is no long series of daily objective weather types (WTs). A new method (Shortest Mahalanobis Distance, SMD) using daily European weather data is developed to reconstruct WTCs back in time. Here the SMD method is applied on the Cluster Analysis of Principal Components (CAP9) classification used by MeteoSwiss. The CAP9 daily WT time series (computed with ERA-40) is used as reference over the 1958–1998 period. Daily data (temperature, mean sea level pressure and pressure tendency) from 13 European stations covering the period 1763–2009 are used for the reconstruction. The reference CAP9 is reduced from nine to seven types so the new daily WTC is called CAP7. As an assessment, CAP7 is compared to the original classification CAP9 and to the same WTs computed with the Twentieth Century Reanalysis (20CR and 20CRv2c). Over the reference period up to 90% of all the daily WTs can be correctly reproduced in the new WTC compared to the original series, with higher reliability in winter than in summer. In addition, the reliability of the classification is increasing from 1763 onward. The annual occurrence of each type reveals some trends, mostly a decrease in the number of cyclonic days and an increase of cyclonic days.

54 ENVIRONMENTAL SCIENCES↗

Toward Quantum Chemical Free Energy Simulations of Platinum Nanoparticles on Titania Support

Platinum nanoparticles (Pt-NPs) supported on titania surfaces are costly but indispensable heterogeneous catalysts because of their highly effective and selective catalytic properties. Therefore, it is vital to understand their physicochemical processes during catalysis to optimize their use and to further develop better catalysts. However, simulating these dynamic processes is challenging due to the need for a reliable quantum chemical method to describe chemical bond breaking and bond formation during the processes but, at the same time, fast enough to sample a large number of configurations required to compute the corresponding free energy surfaces. Density functional theory (DFT) is often used to explore Pt-NPs; nonetheless, it is usually limited to some minimum-energy reaction pathways on static potential energy surfaces because of its high computational cost. In this work, we report a combination of the density functional tight binding (DFTB) method as a fast but reliable approximation to DFT, the steered molecular dynamics (SMD) technique, and the Jarzynski equality to construct free energy surfaces of the temperature-dependent diffusion and growth of platinum particles on a titania surface. In particular, we present the parametrization for Pt-X (X = Pt, Ti, or O) interactions in the framework of the second-order DFTB method, using a previous parametrization for titania as a basis. The optimized parameter set was used to simulate the surface diffusion of a single platinum atom (Pt 1 ) and the growth of Pt 6 from Pt 5 and Pt 1 on the rutile (110) surface at three different temperatures (T = 400, 600, 800 K). The free energy profile was constructed by using over a hundred SMD trajectories for each process. We found that increasing the temperature has a minimal effect on the formation free energy; nevertheless, it significantly reduces the free energy barrier of Pt atom migration on the TiO 2 surface and the transition state (TS) of its deposition. In a concluding remark, the methodology opens the pathway to quantum chemical free energy simulations of Pt-NPs’ temperature-dependent growth and other transformation processes on the titania support.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Prediction of Redox Potentials for Ac, Th, and Pa in Aqueous Solution

Density functional theory in conjunction with small core pseudopotentials and the associated basis sets was used to calculate potentials for multiple redox couples, covering a range of oxidation states for Ac (0 to III), Th (0 to IV), and Pa (0 to V) in aqueous solution. Solvation effects were incorporated using a supermolecule-continuum approach, with 30 water molecules representing two solvation shells, and the COSMO and SMD implicit solvation models. The calculated geometries for Ac(III), Th(IV), and Pa(V) were in reasonable agreement with the available experimental data. Using the COSMO model with the B3LYP functional, the calculated redox potentials were within ± 0.2 V from experiment for most redox couples. Several pathways were explored for the Pa(V/IV) redox couple for different forms of Pa(V) and Pa(IV). Most Pa(V/IV) redox couples have very similar potentials, ranging from 0 to -0.4 V up to a pH of 1.4. At pH = 1.4, the potentials shift to values that are more negative than -0.7 V, reflecting the growing unfavorable nature of the redox process at higher pH levels. The calculated values for An(III/II) potentials were consistent with prior estimates and the available experimental data. The predicted redox potentials for An(II/I) were highly negative, as expected. For An(I/0) potentials, Th and Pa exhibited positive values, contrasting with the negative values calculated for Ac. Furthermore, the An +m /An(0) potentials agreed better with the experimental data when using the COSMO solvation model as compared to the SMD model.

Chemical calculations↗

Prediction of Redox Potentials for the Late Actinides Cm to Lr Using Electronic Structure Methods

Our previously developed computational method for calculating the aqueous redox potentials of the early actinides has been extended to the later elements in the actinide series: Cm, Bk, Cf, Es, Fm, Md, No, and Lr in multiple oxidation states. These calculations were performed using density functional theory with small-core pseudopotentials and their associated basis sets. Solvation effects were considered via a supermolecule-continuum approach, with 30 water molecules representing two solvation shells. Both the COSMO and SMD implicit solvation models were utilized. The structural parameters and hydration numbers for Cm(III), Bk(III), Bk(IV), and Cf(III) are in reasonable agreement with the available experimental data. For redox processes involving atomic cations in solution, the B3LYP/COSMO approach predicted redox potentials to within ±0.2 V of experiment for most redox couples, consistent with our prior work. Inclusion of spin-orbit corrections in specific redox pairs, especially those with the later actinides in high oxidation states, yields improved results relative to calculations including only scalar-relativistic corrections. The An +m /An(0) redox potentials were calculated using a Born-Haber cycle incorporating sublimation, ionization, and hydration energies. Due to a lack of experimental data, three sets of ionization energies were used for the Born-Haber cycle. The calculated An(III/0) potentials showed better agreement with experimental data when using the COSMO solvation model and the test set comprising the NIST recommended ionization energies. Furthermore, the Md(II/0) potential was better described with the SMD model, whereas No(II/0) was not well described by all methods. Finally, the computational approach was able to predict redox potentials that for most cases agreed with the current available experimental or estimated data.

Actinides↗

Calculating Free Energy Changes in Continuum Solvation Models

We recently showed for a large dataset of pK a s and reduction potentials that free energies calculated directly within the SMD continuum model compares very well with corresponding thermodynamic cycle calculations in both aqueous and organic solvents (Phys. Chem. Chem. Phys. 2015, 17, 2859). In this paper, we significantly expand the scope of our study to examine the suitability of this approach for the calculation of general solution phase kinetics and thermodynamics, in conjunction with several commonly used solvation models (SMDM062X, SMD-HF, CPCM-UAKS, and CPCM-UAHF) for a broad range of systems and reaction types. This includes cluster-continuum schemes for pK a calculations, as well as various neutral, radical and ionic reactions such as enolization, cycloaddition, hydrogen and chlorine atom transfer, and bimolecular SN2 and E2 reactions. On the basis of this benchmarking study, we conclude that the accuracies of both approaches are generally very similar – the mean errors for Gibbs free energy changes of neutral and ionic reactions are approximately 5 kJ mol -1 and 25 kJ mol -1 respectively. In systems where there are significant structural changes due to solvation, as is the case for certain ionic transition states and amino acids, the direct approach generally afford free energy changes that are in better agreement with experiment. The results indicate that when appropriate combinations of electronic structure methods are employed, the direct approach provides a reliable alternative to the thermodynamic cycle calculations of solution phase kinetics and thermodynamics across a broad range of organic reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Pioneer Design of Non-contact Synchronized Measurement Devices Using Electric and Magnetic Field Sensors

Here, traditional synchrophasors rely on CTs and PTs physically connected to transmission lines or buses to acquire input signals for phasor measurement. However, it is challenging to install and maintain traditional phasor measurement units in some remote areas due to lack of facilities. Since transmission lines naturally generate alternating electrical and magnetic fields in the surrounding atmosphere, this paper presents two innovative designs for non-contact synchronized measurement devices (NCSMD), including an electric field sensor based non-contact SMD (E-NCSMD) and a magnetic field sensor based non-contact SMD (M-NCSMD). Compared with conventional synchrophasors, E-NCSMD and M-NCSMD are much more flexible to be deployed and have much lower costs, making E-NCSMDs and M-NCSMD highly accessible and useful for a wide array of phasor measurement applications. Laboratory and field experiment results verified the effectiveness of the designs of both E-NCSMD and M-NCSMD.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Interaction of Long-lived Reactive Species from Cold Atmospheric Pressure Plasma with Polymers: Chemical Modification by Ozone and Reactive Oxygen-Nitrogen Species

Atmospheric pressure plasma (APP) sources are able to generate a variety of reactive species that have different effects on materials, such as functionalization, etching and deposition. In this article, we study the effect of long-lived reactive neutral species on polymers using a model plasma-surface interaction (PSI) system that consists of ultra-thin (~10 nm) polystyrene (PS) films and a surface micro-discharge (SMD) reactor operated with various N 2 /O 2 working gas mixtures. We characterized and quantified the reactive species generated by SMD using IR and UV absorption, and we found that O 3 , N 2 O 5 , N 2 O and HNO 3 are the dominant long-lived reactants near the target surface. When exposing PS films to these reactive species, we observed material responses including film thickness expansion, surface and bulk oxidation, and surface organic nitrate formation. The quantity of these changes varied with the N 2 /O 2 working gas composition. By correlating material response with gas phase species, we find that the chemical modification of PS strongly depends on the density of O 3 in the gas phase, which is indicative of an essential role of O 3 in the remote APP treatment of polymers. Our results show that O 3 causes polymer surface oxidation, participates in the diffusion-reaction process in the polymer bulk, and results in aromatic ring cleavage and the formation of carbonyl groups. In contrast, we did not find a correlation between surface organic nitrate and individual long-lived reactive species mentioned above. This indicates that surface organic nitrate formation on polymer surfaces might result from the interaction of multiple reactive species, including O 3 and nitrogen containing species. A model for the interphase mass transfer of reactive species from gas to solid was also described.

36 MATERIALS SCIENCE↗

Process Anomaly Detection for Sparsely Labeled Events in Nuclear Power Plants

An essential aspect of online monitoring, subtle anomaly detection increases the detection lead time for equipment failure and enables a nuclear power plant (NPP) to mitigate unexpected partial or full outages, resulting in significant cost saving to the plant. Once an anomaly is detected by plant staff, its cause and severity are investigated. Because the vast majority of anomalies require some level of investigation, including some that require time-consuming examination, before they are passed over to the engineering organization for further analysis, plants are often equipped with tools to assist the staff in performing anomaly detection. Those tools operate as a black box and are often based on statistical methods that establish sensor correlations using preconfigured mathematical models and flag correlation deviations as anomalies. Due to the number of anomalies detected at a given NPP on a daily basis, a significant number of flagged anomalies usually await examination for days or weeks. A primary cause of this backlog is that the methods used by the tools generate many false positives. Though this is usually attributed to oversensitive model settings due to very narrow normal operation bands, it can also be associated with the model development being inadequate for the process being monitored, or with missing model inputs that could have explained misclassified positives. The performance of anomaly detection tools impacts their plant acceptance and utilization, especially when the effort to address false positives generated by the tool depletes the value or cost saved by using that tool. Thus, means to advance anomaly detection performance have been investigated by the Department of Energy’s Light Water Reactor Sustainability program. Previous and ongoing efforts have targeted unsupervised machine-learning (ML) methods, which do not require the labeling of any data fed into the ML model. By contrast, in supervised anomaly detection methods, every data point is labeled as either a normal or abnormal process condition, and the model is trained to replicate the classification process. Supervised methods usually outperform unsupervised methods, due to the added value in differentiating normal from anomalous states of the monitored process. An NPP’s corrective action program requires it to track and document, via a dedicated report, the resolution of any issues that occur within the plant. Once created, each report is reviewed by a plant screening committee, and several classifications and decisions are made. Recently, a collaborating NPP developed an artificial intelligence and ML-based classifier to categorize a condition report (CR) into classes that can serve to label the data as normal or anomalous. Applying CRs as labels represents a semi-supervised use case. Semi-supervised ML assumes that labels exist for some data points (i.e., labeled anomalies, in this case) but not for the rest. In this effort, semi-supervised ML methods were used to fuse data from CRs with anomaly detection methods in order to test the hypothesis that partially labeled anomalies would improve the accuracy of the anomaly detection methods. Specifically, two methods were used. The first is the deep Semi-supervised Anomaly Detection (deep SAD) method, which can handle labels ranging from fully unsupervised to fully supervised cases. The second is a newly designed ML method developed specifically for this effort and referred to as the high-order feature (HOF)-based method. To evaluate these two methods in controlled environments, synthetic data generators were developed and used. The first datasets used a spring-mass-damper (SMD) system simulator commonly found in mechanical engineering references. This was used to create two use cases: a one- and a three-mass system. Anomalies were introduced by changing the spring and damper coefficients while the system was actuated by random forces. The second datasets used the commercial Dymola-Modelica software to build a simplified nuclear reactor model. Anomalies were added in the form of corrupted sensor readings and/or control commands. The deep SAD method was tested using the SMD system, while the HOF method was tested using both datasets. Application of the deep SAD semi-supervised ML method demonstrated that labels can generate increased confidence in detecting true anomalies. This helped increase the number of true positives and decrease the number of false negatives—something that would aid in addressing the backlog of possible anomalies. Application of the HOF method demonstrated that labels can aid in down selecting from a candidate set of features to a more optimal subset in order to better differentiate between normal and anomalous conditions.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗