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At least 91 records · Page 5

Application of Two-Phase CFD to the Design and Analysis of a Subscale Motor Experiment to Evaluate Propellant Slag Production

The redesigned solid rocket motor (RSRM) Pressure Perturbation Investigation Team concluded that the cause of recent pressure spikes during both static and flight motor burns was the expulsion of molten aluminum oxide slag from a pool which collects in the aft end of the motor around the submerged nozzle nose during the last half of motor operation. It is suspected that some motors produce more slag than others due to differences in aluminum oxide agglomerate particle sizes which may relate to subtle differences in propellant ingredient characteristics such as particle size distribution, contaminants, or processing variations. In order to determine the effect of suspect propellant ingredient characteristics on the propensity for slag production in a real motor environment, a subscale motor experiment was designed. An existing 5 inch ballistic test motor was selected as the basic test vehicle due to low cost and quick turn around times. The standard converging/diverging nozzle was replaced with a submerged nozzle nose design to provide a positive trap for the slag which would increase both the quantity and repeatability of measured slag weights. Computational fluid dynamics (CFD) was used to assess a variety of submerged nose configurations to identify the design which possessed the best capability to reliably collect slag. CFD also was used to assure that the final selected nozzle design would result in flow field characteristics such as dividing streamline location, nose attach point, and separated flow structure which would have similtude with the RSRM submerged nozzle nose flow field. It also was decided to spin the 5 inch motor about its longitudinal axis to further enhance slag collection quantities. Again, CFD was used to select an appropriate spin rate along with other considerations, including the avoidance of burn rate enhancement from radial acceleration effects.

Whitesides, R. Harold↗

Predicting Slag Generation in Sub-Scale Test Motors Using a Neural Network

Generation of slag (aluminum oxide) is an important issue for the Reusable Solid Rocket Motor (RSRM). Thiokol performed testing to quantify the relationship between raw material variations and slag generation in solid propellants by testing sub-scale motors cast with propellant containing various combinations of aluminum fuel and ammonium perchlorate (AP) oxidizer particle sizes. The test data were analyzed using statistical methods and an artificial neural network. This paper primarily addresses the neural network results with some comparisons to the statistical results. The neural network showed that the particle sizes of both the aluminum and unground AP have a measurable effect on slag generation. The neural network analysis showed that aluminum particle size is the dominant driver in slag generation, about 40% more influential than AP. The network predictions of the amount of slag produced during firing of sub-scale motors were 16% better than the predictions of a statistically derived empirical equation. Another neural network successfully characterized the slag generated during full-scale motor tests. The success is attributable to the ability of neural networks to characterize multiple complex factors including interactions that affect slag generation.

Wiesenberg, Brent↗

The Influence of Phosphorous Additions on Phase Evolution in Molten Coal Slag

Carbon feedstocks used in power, chemical and metallurgical industries typically contain numerous minerals or impurities that liquefy during high temperature processing to form slag as a byproduct. Slags have many industrial applications, for example, as construction materials and for element recovery. In addition to other variables, the extent of slag utilization is dependent on its composition and post treatments. In this work, the influence of temperature and phosphorus additions on phase evolution in coal slag was investigated. Synthetic slag mixtures with varying AlPO<sub>4</sub> contents (0–14 wt%) were heated from 1380–1470 °C in air, then water-quenched to preserve the phases formed. SEM/EDS, XRF and XRD analyses were performed before/after testing to gain insight about slag chemistry and phases present. It was found that coal slag exhibited a large solubility of phosphorous, affecting morphology of mullite formed under the conditions studied. Results obtained and their significance are discussed.

Hawa, Hani↗

The Integration of Plant Sample Analysis, Laboratory Studies, and Thermodynamic Modeling to Predict Slag-Matte Equilibria in Nickel Sulfide Converting

The Kalgoorlie Nickel Smelter (KNS) produces low Fe, low Cu nickel matte in its Peirce–Smith converter operations. To inform process development in the plant, new fundamental data are required on the effect of CaO in slag on the distribution of arsenic between slag and matte. A combination of plant sample analysis, high-temperature laboratory experiments, and thermodynamic modeling was carried out to identify process conditions in the converter and to investigate the effect of slag composition on the chemical behavior of the system. The high-temperature experiments involved re-equilibration of industrial matte-slag-lime samples at 1498 K (1225 °C) and P(SO{sub 2}) = 0.12 atm on a magnetite/quartz substrate, rapid quenching in water, and direct measurement of phase compositions using electron probe X-ray microanalysis (EPMA) and laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS). A private thermodynamic database for the Ca-Cu-Fe-Mg-Ni-O-S-Si-(As) system was used together with the FactSage software package to assist in the analysis. Thermodynamic predictions combined with plant sample characterization and the present experimental data provide a quantitative basis for the analysis of the effect of CaO fluxing on the slag-matte thermochemistry during nickel sulfide converting, in particular on the spinel liquidus and the distribution of elements between slag and matte as a function of CaO addition.

36 MATERIALS SCIENCE↗

Kinetic Investigations of SiMn Slags From Different Mn Sources

The kinetics of MnO and SiO 2 reduction were investigated for Silicomanganese (SiMn) slags using a Thermogravimetric analysis (TGA) between 1773 K and 1923 K (1500 °C and 1650 °C) under CO atmospheric pressure. The charge materials were based on Assmang ore and HC FeMn Slag. Rate models for MnO and SiO 2 reduction were applied to describe the metal-producing rates, as shown by the following equations: r MnO =k MnO ×A×(a MnO -((a Mn )/(K{sub T})))r SiO 2 =k SiO 2 ×A×(a SiO 2 -((a Si )/(K T ))).The results show that the choice of raw materials in the charge considerably affected the reduction rate of MnO and SiO 2 . The highest reduction rate was found to be from charges using HC FeMn slag. The difference in the driving forces was insignificant among the SiMn slags, and the similar slag viscosities could not explain the different reduction rates. Instead, the difference is attributed to small amounts of sulfur and the amount of iron in the charge. In addition, the rate models were applicable to describe the reduction of MnO and SiO 2 in SiMn slags.

36 MATERIALS SCIENCE↗

Effect of Iron Redox Equilibrium on the Foaming Behavior of MgO-Saturated Slags

In this study, the foaming index of CaO-SiO{sub 2}-Fe{sub t}O and CaO-SiO{sub 2}-Fe{sub t}O-Al{sub 2}O{sub 3} slags saturated with MgO was measured to understand the relationship between their foaming behavior and physical properties. The foaming index of MgO-saturated slags increases with the Fe{sub t}O content due to the redox equilibrium of Fe{sub t}O. Experimental results indicated that MgO-saturated slag has relatively high ferric ion concentration, and the foaming index increases due to the effect of ferric ion. Therefore, the foaming behavior of MgO-saturated slag is more reasonably explained by considering the effect of ferric ion on the estimation of slag properties such as viscosity, surface tension, and density. Specifically, the estimation of slag viscosity was additionally verified by NBO/T, and this is experimentally obtained through Raman spectroscopy.

36 MATERIALS SCIENCE↗

Viscosity of TiO{sub 2}-FeO-Ti{sub 2}O{sub 3}-SiO{sub 2}-MgO-CaO-Al{sub 2}O{sub 3} for High-Titania Slag Smelting Process

The present study demonstrates the dependence of viscosity on chemical composition and temperature of high-titania slag, a very important raw material for producing titanium dioxide. The results indicated that completely molten high-titania slag exhibits a viscosity of less than 1 dPa s with negligible dependence on temperature. However, it increases dramatically with decreasing temperature slightly below the critical temperature, i.e., the solidus temperature of the slag. Above the critical temperature, the slag samples displayed the same order of viscosity at 0.6 dPa s, regardless of their compositional variation. However, the FeO, CaO, and MgO were confirmed to decrease viscosity, while SiO{sub 2} and Ti{sub 2}O{sub 3} increase it. The apparent activation energy for viscosity-temperature relation and liquidus temperature based on experiments and thermodynamic calculations are also presented. Conclusively, the critical temperatures of the slags are on average 15 K below their corresponding calculated liquidus temperatures. The increase in FeO content was found to considerably lower the critical temperature, while the increase in both Ti{sub 2}O{sub 3} and TiO{sub 2} contents increases it. The main phases of the slag in solid state, as indicated by X-ray diffraction, are (Fe, Mg){sub x}Ti{sub y}O{sub 5} (x + y = 3, pseudobrookite) and rutile.

36 MATERIALS SCIENCE↗

Wetting Behavior of TiO{sub 2} by Calcium Ferrite Slag at 1523 K

The wetting behaviors of a TiO{sub 2} substrate by calcium ferrite (CF) series slags were investigated using an improved sessile drop method at 1523 K (1250 °C). The initial contact angles were in the range 35 to 50 deg, the final equilibrium apparent contact angles were < 20 deg, and the spreading durations were in the range 75 to 180 seconds. The CF-TiO{sub 2} system showed reactive wetting, which was categorized into four dynamic stages. Stage I: physical spreading, stage II: slow linear spreading, stage III: fast linear spreading, and stage IV: equilibrium. Interfacial reactions yielded CaTiO{sub 3} during reactive spreading, thereby transitioning TiO{sub 2} wetting into CaTiO{sub 3} wetting and then forming Fe{sub 2}TiO{sub 5} and FeTiO{sub 3} owing to the excess Fe{sub 2}O{sub 3} and FeO that had accumulated in the interfacial zone. Although stage III spreading was faster than stage II spreading, adding MgO to the slag slowed stage III spreading. The interfacial microstructure of the residual slag was roughly divided into three layers owing to the different densities of the slag and solid products. The top layer was composed of CaTiO{sub 3} and Fe{sub 2}O{sub 3}, the middle one was composed of CaTiO{sub 3} and Fe{sub 2}TiO{sub 5}, and the bottom one was composed of Fe{sub 2}TiO{sub 5} and FeTiO{sub 3}. Adding TiO{sub 2} to the slag produced a dense CaTiO{sub 3}-containing interfacial layer, resulting in CF being detected in the residual slag.

36 MATERIALS SCIENCE↗

Characterization and Recovery of Copper from Converter Copper Slag Via Smelting Separation

Converter copper slag can be viewed as an important secondary resource for valuable metals, considering its high commercial value. The current research investigates the recycling of copper by a combination of theoretical and experimental methods. Based on a modified Stokes equation, it was determined that copper droplets in the molten slag exhibited a low terminal settling velocity of 2.140 × 10{sup −6} m/s. The copper particles will collide with each other during settling, resulting in particle growth. The results from high temperature experimentation, scanning electron microscopy, and energy-dispersive spectroscopy confirm that in the absence of reducing agents, copper droplets are encased in magnetite to form composite ‘Cu droplet–magnetite’ particles. Other copper droplets adhere to magnetite particles which are suspended in the slag in a short-range-ordered array. The study also confirms that in the presence of increasing amounts of anthracite as a reducing agent, the magnetite content of the slag is progressively decreased and the recovery of copper from the slag is significantly improved. Based on the findings from this work, a new processing route is proposed to treat copper slag for the recovery of copper.

36 MATERIALS SCIENCE↗

Molecular Dynamics Simulation on the Effect of MgO/Al{sub 2}O{sub 3} Ratio on Structure and Properties of Blast Furnace Slag Under Different Basicity Conditions

The SiO{sub 2}-Al{sub 2}O{sub 3}-CaO-MgO is the basic structural system of blast furnace slag and the composition directly affects the performance of the slag. Molecular dynamics simulations were carried out to analyze the local structure, structural unit, bond angle, transport properties, and enthalpy of the slag with the increase of MgO/Al{sub 2}O{sub 3} mass ratio under different basicity conditions. It was found that the change of MgO/Al{sub 2}O{sub 3} ratio does not affect the short-range order structure, but it will reduce the overall stability of the network structure. Through the analysis of the structural unit of the slag, it was found that the polymerization degree of the system decreases with the increase of MgO/Al{sub 2}O{sub 3} ratio, indicating that the complex network structure of the system is partially depolymerized. Besides, the self-diffusion coefficients of each ion were concluded and the magnitudes were observed to be in the following order: Mg{sup 2+}>Ca{sup 2+}>Al{sup 3+}>O{sup 2-}>Si{sup 4+}. The diffusivity of the slag increases with the increase of MgO/Al{sub 2}O{sub 3} ratio and the corresponding viscosity decreases. And the enthalpy of the slag is increased with the increase of MgO/Al{sub 2}O{sub 3} ratio or basicity, therefore the fuel consumption should also be properly adjusted during the operation of blast furnace to ensure the target temperature.

36 MATERIALS SCIENCE↗

Oxygen Potential of High-Titania Slag from the Smelting Process of Ilmenite

Oxygen potential of TiO{sub 2}-FeO-Ti{sub 2}O{sub 3} ternary slags was determined by the electromotive force (EMF) method based on the solid electrolyte oxygen sensor at 2003 K (1730 °C). The effect of FeO content and Ti{sup 3+}/Ti{sup 4+} mass ratio on the oxygen potential of the high-titania slag was also studied. At a fixed Ti{sup 3+}/Ti{sup 4+} mass ratio of 3.11, the oxygen potential increased with increasing FeO content. Increase of Ti{sup 3+}/Ti{sup 4+} mass ratio from 2.29 to 3.60 caused a significant decrease in the oxygen potential of the slag. Comparing measured oxygen potential with the calculated values indicated that the oxygen potential of the slag might be determined by FeO/Fe equilibrium reaction rather than TiO{sub 2}/Ti{sub 2}O{sub 3} reaction. In addition, the experimentally measured oxygen potential values were modeled by multiple linear regression analysis, and a semi-empirical mathematical correlation was established between the oxygen potential and slag compositions. The iso-oxygen potential distribution diagram based on the mathematical model was obtained for the high-titania slag.

36 MATERIALS SCIENCE↗

Phosphorus Removal from Si-Fe Alloy Using SiO{sub 2}-Al{sub 2}O{sub 3}-CaO Slag

Phosphorus removal from silicon using a combination of solvent and slag refining, with lower carbon footprint and lower energy requirement than the current industrial process, is investigated by evaluating the distribution of phosphorus between Si-Fe alloy and SiO{sub 2}-Al{sub 2}O{sub 3}-CaO slag. An alloy with the composition of silicon-20 wt pct iron was treated with a slag of CaO-Al{sub 2}O{sub 3}-SiO{sub 2} at 1600 °C. The effects of slag basicity and oxygen potential on the distribution of phosphorus were studied via changing the slag composition. The critical oxygen potential, at which the maximum removal of phosphorus is obtained, was calculated as 6.3 × 10{sup −18} atm. Normalized distribution and phosphate capacity values were calculated for each slag composition with the purpose of isolating the effect of basicity. In a separate experiment, calcium was also added to the alloy with the purpose of improving the removal efficiency of phosphorus. Results show that the addition of calcium can almost double the partition ratio of phosphorus. The removal rate of phosphorus was quantified via kinetics calculations, and the total mass-transfer rate of phosphorus was estimated to be 8.58 × 10{sup −7} cm/s.

36 MATERIALS SCIENCE↗

Characterization of Roughness, Porosity and Thermal Resistances of Continuous Casting Mold Slag Layers Devitrified and Crystallized in Laboratory

This paper presents an experimental investigation about the variation, with temperature, of surface roughness, porosity, degree of crystallization and microstructure, occurring in solid layers of a commercial mold powder slag used for casting medium carbon steel thin slabs. Characterization is done with samples devitrified and crystallized at 698 K, 823 K, 898 K and 973 K (425 °C, 550 °C, 625 °C and 700 °C) for 10,800 seconds, in the furnace of a high-temperature confocal laser scanning microscope. As well as, with slag disks devitrified non-isothermally in a heat flow apparatus based on the application of Fourier's law in steady state conditions, where the high temperature surface is maintained at selected values, between 927 K and 1241 K (654 °C and 968 °C). Surface roughness and porosity determinations are performed by image analysis of confocal laser scanning and scanning electron micrographs, respectively. For the time considered and temperatures ≥ 823 K (550 °C) the slag crystallizes completely, and variations of roughness and porosity with temperature are associated with changes in size and packing of the primary crystalline-phase grains. Crystallization induced porosity is significant and causes slag layer expansion. Hence crystallization does not lead to gap formation with a neighboring surface (e.g., mold wall) by shrinkage. Instead, surface separation arises from development of roughness, and measurements with the heat flow apparatus confirm that interfacial thermal resistance between a slag layer and a metallic wall can be estimated from the sum of the means of maximum peak to valley height of their surfaces. Furthermore, the results establish that slag layers roughness and porosity increase with temperature and reveal effective thermal conductivities in the range of ~ 0.3 to ~ 0.5 W/m K. Low effective thermal conductivities must be a consequence of porous bands, whose porosity depends on temperature and reaches values as high as ~ 0.20 and ~ 0.50.

36 MATERIALS SCIENCE↗

Cationic Effect of Ferrous Ions on Sulfide Capacity of CaO-Fe{sub t}O-Al{sub 2}O{sub 3}-SiO{sub 2} Slag System

The cationic effect of ferrous ions on the sulfide capacity of CaO-Fe{sub t}O-Al{sub 2}O{sub 3}-SiO{sub 2} slags was studied from the viewpoint of the ionic structure in the slag using micro-Raman spectroscopy. In the cation-excess region (M{sup 2+}/2(Fe{sup 3+} + Al{sup 3+}) > 1.0), the sulfide capacity was directly proportional to the basicity of the slags, owing to the S{sup 2−} stabilizing effect of excess cations. However, in the cation-deficient region (M{sup 2+}/2(Fe{sup 3+} + Al{sup 3+}) < 1.0), the sulfide capacity was independent of the basicity of the slags owing to the deficiency of cations required for charge compensation with Al{sup 3+} and Fe{sup 3+}. The cation-substitution effect on the sulfide capacity of the CaO-rich slags (Fe{sub t}O/(Fe{sub t}O + CaO < 0.5) exhibited a linear relationship with the Fe{sup 2+} content because Fe{sup 2+} had a stronger affinity with S{sup 2−} compared to that with Ca{sup 2+}. However, in the Fe{sub t}O-rich slags (Fe{sub t}O/(Fe{sub t}O + CaO > 0.5), the sulfide capacity decreased with the increase of the Fe{sup 2+} content owing to the Q{sup n} unit affinity of the Fe{sup 2+} ion. The sulfide capacity was determined by the competition between the Q{sup n} unit affinity and stability of the S{sup 2−} ion, depending on the type of cation. Therefore, the partial covalent bonding between the M{sup 2+} cations (M: Ca, Fe) and aluminosilicate affected the ionic interactions with the S{sup 2−} ions.

36 MATERIALS SCIENCE↗

Electromagnetic Wave-Absorbing Properties of Steel Slag

This research explores the electromagnetic radiation protection function of steel slag for use as a building material. Scanning electron microscopy, x-ray diffraction, x-ray photoelectron spectroscopy and Mössbauer spectroscopy were used to analyze the chemical composition and mineralogical phase of steel slag powder. Electromagnetic parameters of the samples were analyzed and discussed in detail for the frequency range of 1-18 GHz. We found that steel slag had the electromagnetic wave-absorbing property due to electric components (such as FeO and carbon powder) and magnetic components [such as magnetite (Fe{sub 3}O{sub 4}) and hematite (α-Fe{sub 2}O{sub 3})]; electric loss was far greater than magnetic loss. With the increasing milling time, the electric and magnetic properties were increased. The calculated reflectivity curve of steel slag powder epoxide resin–matrix composite at a thickness of 10 mm had several interference peaks, and the absorbing properties increased gradually with increasing frequency. Moreover, the minimum reflectivity was − 21 dB (Decibel) at 13 GHz (Gigahertz). The steel slag powder cement-based composite showed electromagnetic wave-absorbing properties at 10-18 GHz, and the greatest absorption of the 25 mm sample reached 11.5 dB; therefore, the steel slag shows promise as a building material for electromagnetic protection.

36 MATERIALS SCIENCE↗

Determining the slag fraction, water/binder ratio and degree of hydration in hardened cement pastes

A method for determining the original mix composition of hardened slag-blended cement-based materials based on analysis of backscattered electron images combined with loss on ignition measurements is presented. The method does not require comparison to reference standards or prior knowledge of the composition of the binders used. Therefore, it is well-suited for application to real structures. The method is also able to calculate the degrees of reaction of slag and cement. Results obtained from an experimental study involving sixty samples with a wide range of water/binder (w/b) ratios (0.30 to 0.50), slag/binder ratios (0 to 0.6) and curing ages (3 days to 1 year) show that the method is very promising. The mean absolute errors for the estimated slag, water and cement contents (kg/m{sup 3}), w/b and s/b ratios were 9.1%, 1.5%, 2.5%, 4.7% and 8.7%, respectively. 91% of the estimated w/b ratios were within 0.036 of the actual values. -- Highlights: •A new method for estimating w/b ratio and slag content in cement pastes is proposed. •The method is also able to calculate the degrees of reaction of slag and cement. •Reference standards or prior knowledge of the binder composition are not required. •The method was tested on samples with varying w/b ratios and slag content.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Hydration of potassium citrate-activated BOF slag

Basic Oxygen Furnace (BOF) slag is currently utilized with low-grade applications or landfilled. Here, we investigate a novel route to upgrade BOF slag to a high-performance binder by chemical activation with tri-potassium citrate. The impact of tri-potassium citrate on hydration and phase assemblage of BOF slag is analyzed with a multi-technique approach. Results reveal that the addition of tri-potassium citrate considerably enhances the reactivity of brownmillerite and accelerates the hydration of belite at early ages. The majority of brownmillerite hydrates within 24 h, and the reaction kinetics is controlled by the activator dosage. The main products of BOF slag hydration are siliceous hydrogarnet and C-S-H gel. Acting as a strong water reducer, tri-potassium citrate enables the manufacture of slag pastes with high compressive strength (up to 75 MPa at 28 days) and low porosity. Leaching of heavy metals from the slag pastes fulfills the Dutch Soil Quality Decree limits.

36 MATERIALS SCIENCE↗

Fixation and partitioning of heavy metals in slag after incineration of sewage sludge

Highlights: Black-Right-Pointing-Pointer The contents and partitioning of HMs in slag of sludge incineration were examined. Black-Right-Pointing-Pointer The fixation rate decreases with residential time and finally keeps a constant. Black-Right-Pointing-Pointer Water mass fraction of 55% is optimal for the sediment for Ni, Mn, Zn, Cu and Cr. Black-Right-Pointing-Pointer Water mass fraction of 75% is optimal for the sediment for Pb. Black-Right-Pointing-Pointer We found higher temperature versus lower non-residual fraction except that of Pb. - Abstract: Fixation of heavy metals in the slag produced during incineration of sewage sludge will reduce emission of the metals to the atmosphere and make the incineration process more environmentally friendly. The effects of incineration conditions (incineration temperature 500-1100 Degree-Sign C, furnace residence time 0-60 min, mass fraction of water in the sludge 0-75%) on the fixation rates and species partitioning of Cd, Pb, Cr, Cu, Zn, Mn and Ni in slag were investigated. When the incineration temperature was increased from 500 to 1100 Degree-Sign C, the fixation rate of Cd decreased from 87% to 49%, while the fixation rates of Cu and Mn were stable. The maximum fixation rates for Pb and Zn and for Ni and Cr were reached at 900 and 1100 Degree-Sign C, respectively. The fixation rates of Cu, Ni, Cd, Cr and Zn decreased as the residence time increased. With a 20 min residence time, the fixation rates of Pb and Mn were low. The maximum fixation rates of Ni, Mn, Zn, Cu and Cr were achieved when the mass fraction of water in the sludge was 55%. The fixation rate of Cd decreased as the water mass fraction increased, while the fixation rate of Pb increased. Partitioning analysis of the metals contained in the slag showed that increasing the incineration temperature and residence time promoted complete oxidation of the metals. This reduced the non-residual fractions of the metals, which would lower the bioavailability of the metals. The mass fraction of water in the sludge had little effect on the partitioning of the metals. Correlation analysis indicated that the fixation rates of heavy metals in the sludge and the forms of heavy metals in the incinerator slag could be controlled by optimization of the incineration conditions. These results show how the bioavailability of the metals can be reduced for environmentally friendly disposal of the incinerator slag.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗