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Use of high-dimensional spectral data to evaluate organic matter, reflectance relationships in soils

Recent breakthroughs in remote sensing technology have led to the development of a spaceborne high spectral resolution imaging sensor, HIRIS, to be launched in the mid-1990s for observation of earth surface features. The effects of organic carbon content on soil reflectance over the spectral range of HIRIS, and to examine the contributions of humic and fulvic acid fractions to soil reflectance was evaluated. Organic matter from four Indiana agricultural soils was extracted, fractionated, and purified, and six individual components of each soil were isolated and prepared for spectral analysis. The four soils, ranging in organic carbon content from 0.99 percent, represented various combinations of genetic parameters such as parent material, age, drainage, and native vegetation. An experimental procedure was developed to measure reflectance of very small soil and organic component samples in the laboratory, simulating the spectral coverage and resolution of the HIRIS sensor. Reflectance in 210 narrow (10 nm) bands was measured using the CARY 17D spectrophotometer over the 400 to 2500 nm wavelength range. Reflectance data were analyzed statistically to determine the regions of the reflective spectrum which provided useful information about soil organic matter content and composition. Wavebands providing significant information about soil organic carbon content were located in all three major regions of the reflective spectrum: visible, near infrared, and middle infrared. The purified humic acid fractions of the four soils were separable in six bands in the 1600 to 2400 nm range, suggesting that longwave middle infrared reflectance may be useful as a non-destructive laboratory technique for humic acid characterization.

Henderson, T. L.

Comparison of in situ and Landsat derived reflectance of Alaskan glaciers

Reflectances calculated from TM data and corrected for atmospheric effects correspond with in situ measured reflectances in the nadir-viewing mode, and are shown to be related to a glacier's mass balance if measured over a period of years. A reflectance of 0.895 for a test site in the Wrangell Mountains, Alaska, was calculated from TM Band 4 (0.76 - 0.90 micron) data and corrected for atmospheric effects. This value was comparable to the in situ reflectance of 0.90 measured in the same 0.76 - 0.90 micron wavelength region. For the same site, a reflectance value of 0.79 derived from integrating over most (0.40 - 3.0 micron) of the reflective portion of the electromagnetic spectrum was quite different from the integrated reflectance of 0.95 calculated for the spectral range 0.40 - 1.0 micron. This demonstrates the importance of using the full reflective energy spectrum for calculating the albedo of snow, and for obtaining a meaningful computation of a glacier's energy and mass balance change.

Hall, D. K.

Method and apparatus for removing unwanted reflections from an interferometer

A device for eliminating unwanted reflections from refractive optical elements in an optical system is provided. The device operates to prevent desired multiple fringe patterns from being obscured by reflections from refractive elements positioned in proximity to a focal plane of the system. The problem occurs when an optical beam is projected into, and reflected back out of, the optical system. Surfaces of the refractive elements reflect portions of the beam which interfere with portions of the beam which are transmitted through the refractive elements. Interference between the reflected and transmitted portions of the beam produce multiple fringe sets which tend to obscure desired interference fringes. With the refractive optical element in close proximity to the focal plane of the system, the undesired reflected light reflects at an angle 180 degrees opposite from the desired transmitted beam. The device exploits the 180-degree offset, or rotational shear, of the undesired reflected light by providing an optical stop for blocking one-half of the cross-section of the test beam. By blocking one-half of the test beam, the undesired offset beam is blocked, while the returning transmitted beam passes into the optical system unaffected. An image is thereby produced from only the desired transmitted beam. In one configuration, the blocking device includes a semicircular aperture which is caused to rotate about the axis of the test beam. By rotating, all portions of the test beam are cyclically projected into the optical system to thereby produce a complete test image. The rotating optical stop is preferably caused to rotate rapidly to eliminate flicker in the resulting image.

Steimle, Lawrence J.

Relationships between pigment composition variation and reflectance for plant species from a coastal savannah in California

Advances in imaging spectroscopy have indicated that remotely sensed reflectance measurements of the plant canopy may be used to identify and qualify some classes of canopy biochemicals; however, the manner in which differences in biochemical compositions translate into differences is not well understood. Most frequently, multiple linear regression routines have been used to correlate narrow band reflectance values with measured biochemical concentrations. Although some success has been achieved with such methods for given data sets, the bands selected by multiple regression are not consistent between data sets, nor is it always clear what physical or biological basis underlies the correlation. To examine the relationship between biochemical concentration and leaf reflectance signal we chose to focus on the visible spectrum where the primary biochemical absorbances are due to photosynthetic pigments. Pigments provide a range of absorbance features, occur over a range of concentrations in natural samples, and are ecophysiologically important. Concentrations of chlorophyll, for example, have been strongly correlated to foliar nitrogen levels within a species and to photosynthetic capacity across many species. In addition pigments effectively absorb most of the photosynthetically active radiation between 400-700 nm, a spectral region for which silicon detectors have good signal/noise characteristics. Our strategy has been to sample a variety of naturally occurring species to measure leaf reflectance and pigment compositions. We hope to extend our understanding of pigment reflectance effects to interpret small overlapping absorbances of other biochemicals in the infrared region. For this reason, selected samples were also tested to determine total nitrogen, crude protein, cellulose, and lignin levels. Leaf reflectance spectra measured with AVIRIS bandwidths and wavelengths were compared between species and within species and for differences between seasons, for changes in the the shape of the spectra. We attempt to statistically correlate these shape changes with differences in pigment compositions. In parallel with our comparisons of pigment composition and leaf reflectance, we have modified the PROSPECT leaf reflectance model to test the contributions of pigments or pigment group concentrations. PROSPECT considers a leaf as a multi-layer dielectric plane with an uneven surface. Jacquemoud adapted the basic analysis of Allen for surface effects, a leaf thickness factor, and the absorption of water and chlorophyll (actually all pigments) and the plant matrix. Our modifications to PROSPECT in the forward direction include breaking out the pigment concentration parameter into separate components for chlorophyll a and b and a number of xanthophylls and carotenes, and introducing a shift and convolution function to model the spread and shift from their in vitro measurements to their in vivo state. Further, we have considered how the matrix elements (i.e., all biochemicals and structural effects not modeled explicity) vary with species.

Ustin, Susan L.

The vertical profile of radar reflectivity of convective cells: A strong indicator of storm intensity and lightning probability?

Reflectivity data from Doppler radars are used to construct vertical profiles of radar reflectivity (VPRR) of convective cells in mesoscale convective systems (MCSs) in three different environmental regimes. The National Center for Atmospheric Research CP-3 and CP-4 radars are used to calculate median VPRR for MCSs in the Oklahoma-Kansas Preliminary Regional Experiment for STORM-Central in 1985. The National Oceanic and Atmospheric Administration-Tropical Ocean Global Atmosphere radar in Darwin, Australia, is used to calculate VPRR for MCSs observed both in oceanic, monsoon regimes and in continental, break period regimes during the wet seasons of 1987/88 and 1988/89. The midlatitude and tropical continental VPRRs both exhibit maximum reflectivity somewhat above the surface and have a gradual decrease in reflectivity with height above the freezing level. In sharp contrast, the tropical oceanic profile has a maximum reflectivity at the lowest level and a very rapid decrease in reflectivity with height beginning just above the freezing level. The tropical oceanic profile in the Darwin area is almost the same shape as that for two other tropical oceanic regimes, leading to the conclustion that it is characteristic. The absolute values of reflectivity in the 0 to 20 C range are compared with values in the literature thought to represent a threshold for rapid storm electrification leading to lightning, about 40 dBZ at -10 C. The large negative vertical gradient of reflectivity in this temperature range for oceanic storms is hypothesized to be a direct result of the characteristically weaker vertical velocities observed in MCSs over tropical oceans. It is proposed, as a necessary condition for rapid electrification, that a convective cell must have its updraft speed exceed some threshold value. Based upon field program data, a tentative estimate for the magnitude of this threshold is 6-7 m/s for mean speed and 10-12 m/s for peak speed.

Zipser, Edward J.

Coronagraphic imaging of pre-main-sequence stars: Remnant evvelopes of star formation seen in reflection

We have obtained R- and I-band coronagraphic images of the vicinities of 11 pre-main sequence (PMS) stars to search for faint, small-scale reflection nebulae. The inner radius of the search and the field of view are 1.9 arcsec and 1x1 arcmin, respectively. Reflection nebulae were imaged around RY Tau, T Tau,DG Tau, SU Aur, AB Aur, FU Ori, and Z CMa. No nebulae were detected around HBC 347, GG Tau, V773 Tau, and V830 Tau. Categorically speaking, most of the classical T Tauri program stars and all the FU Orionis-type program stars are associated with the reflection nebulae, while none of the weak-line T Tauri program stars are associated with nebulae. The detected nebulae range in size from 250 to 37 000 AU. From the brightness ratios of the stars and nebulae, we obtain a lower limit to the visual extinction of PMS star light through the nebulae of (A(sub V))(sub neb) = 0.1. The lower limits of masses and volume densities of the nebulae associated with the classical T Tauri stars are 10(exp-6) Solar mass and N(sub H) = 10(exp 5)/cu cm, respectively. Lower limits for the nebulae around FU Orionis stars are 10(exp -5) Solar mass and n(sub H) = 10 (exp 5)/cu cm, respectively. Some reflection nebulae may trace the illuminated surfaces of the optically thick dust nebulae, so these mass estimates are not stringent. All the PMS stars with associated nebulae are strong far-infrared emitters. Both the far-infrared emission and the reflection nebulae appear to originate from the remnant envelopes of star formation. The 100 micrometers emitting regions of SU Aur and FU Ori are likely to be cospatial with the reflection nebulae. A spatial discontinuity between FU Ori and its reflection nebula may explain the dip in the far-infrared spectral energy distribution at 60 micrometers. The warped, disk-like nebulae around T Tau and Z CMa are aligned with and embrace the inner star/circumstellar disk systems. The arc-shaped nebula around DG Tau may be in contact with the coaligned inner star/disk system. These three-reflection nebulae may trace the surfaces of pseudodisks from which matter accretes onto the stars or the inner circumstellar disks. 19 stellar objects brighter than I = 19 were detected around 9 program stars. Using a color-magnitude diagram, we have identified three new PMS candidates aroun Z CMa and one previously known PMS candidate, GG Tau/c.

Nakajima, Tadashi

Evidence of Boundary Reflection of Kelvin and First-Mode Rossby Waves from Topex/Poseidon Sea Level Data

The TOPEX/POSEIDON sea level data lead to new opportunities to investigate some theoretical mechanisms suggested to be involved in the El Nino-Southern Oscillation phenomenon in the tropical Pacific ocean. In particular, we are interested in studying the western boundary reflection, a process crucial for the delayed action oscillator theory, by using the TOPEX/POSEIDON data from November 1992 to May 1995. We first projected the sea level data onto Kelvin and first-mode Ross waves. Then we estimated the contribution of wind forcing to these waves by using a single baroclinic mode simple wave model forced by the ERS-1 wind data. Wave propagation was clearly observed with amplitudes well explained by the wind forcing in the ocean interior. Evidence of wave reflection was detected at both the western and eastern boundaries of the tropical Pacific ocean. At the eastern boundary, Kelvin waves were seen to reflect as first-mode Rossby waves during the entire period. The reflection efficiency (in terms of wave amplitude) of the South American coasts was estimated to be 80% of that of an infinite meridional wall. At the western boundary, reflection was observed in April-August 1993, in January-June 1994, and, later, in December 1994 to February 1995. Although the general roles of these reflection events in the variability observed in the equatorial Pacific ocean are not clear, the data suggest that the reflections in January-June 1994 have played a role in the onset of the warm conditions observed in late 1994 to early 1995. Indeed, during the January-June 1994 period, as strong downwelling first-mode Rossby waves reflected into downwelling Kelvin waves, easterly wind and cold sea surface temperature anomalies located near the date line weakened and eventually reversed in June-July 1994. The presence of the warm anomalies near the date line then favored convection and westerly wind anomalies that triggered strong downwelling Kelvin waves propagating throughout the basin simultaneously with the beginning of the 1994-1995 warm conditions.

Boulanger, Jean-Philippe

TRMM Precipitation Radar Reflectivity Profiles Compared to High-Resolution Airborne and Ground-Based Radar Measurements

In this paper, TRMM (Tropical Rainfall Measuring Mission Satellite) Precipitation Radar (PR) products are evaluated by means of simultaneous comparisons with data from the high-altitude ER-2 Doppler Radar (EDOP), as well as ground-based radars. The comparison is aimed primarily at the vertical reflectivity structure, which is of key importance in TRMM rain type classification and latent heating estimation. The radars used in this study have considerably different viewing geometries and resolutions, demanding non-trivial mapping procedures in common earth-relative coordinates. Mapped vertical cross sections and mean profiles of reflectivity from the PR, EDOP, and ground-based radars are compared for six cases. These cases cover a stratiform frontal rainband, convective cells of various sizes and stages, and a hurricane. For precipitating systems that are large relative to the PR footprint size, PR reflectivity profiles compare very well to high-resolution measurements thresholded to the PR minimum reflectivity, and derived variables such as bright band height and rain types are accurate, even at high PR incidence angles. It was found that for, the PR reflectivity of convective cells small relative to the PR footprint is weaker than in reality. Some of these differences can be explained by non-uniform beam filling. For other cases where strong reflectivity gradients occur within a PR footprint, the reflectivity distribution is spread out due to filtering by the PR antenna illumination pattern. In these cases, rain type classification may err and be biased towards the stratiform type, and the average reflectivity tends to be underestimated. The limited sensitivity of the PR implies that the upper regions of precipitation systems remain undetected and that the PR storm top height estimate is unreliable, usually underestimating the actual storm top height. This applies to all cases but the discrepancy is larger for smaller cells where limited sensitivity is compounded by incomplete beam filling. Users of level three TRMM PR products should be aware of this scale dependency.

Heymsfield, G. M.

Changes in the Earth's UV Reflectivity (1979 to 1992)

Measurements of the Earth,s 380 nm UV reflectivity combine the effects of surface reflectivity, aerosols, haze, cloud optical thickness, and the fraction of the scene covered by clouds. Since the 380 nm surface reflectivity is low (2 to 8%) over most surfaces, water and land, the observed reflectivity changes are mostly caused by changes in the amount of snow/ice, cloudiness and aerosols. Time-series analysis of TOMS reflectivity over the period from 1979 to 1992 shows that there were no significant changes in annually-averaged zonal-average reflectivity at latitudes within 60 degrees S to 60 degrees N, even though there were changes at higher latitudes (e.g., 3% per decade, in reflectivity units, between 60 degrees N and 70 degrees N). When the effects of the 11-year solar cycle and ENSO (El Nino Southern Oscillation) are removed from the data, statistically significant reflectivity changes are observed poleward of both 40 degrees S and 40 degrees N. The solar-cycle results suggest a possible Sun-weather relationship.

Hermana, J. R.

Characteristics of Vertical Profiles of Reflectivity and Doppler Derived From TRMM Field Campaigns

The TRMM Precipitation Radar (PR) measures the vertical profile of reflectivity from which the surface rain rate is estimated after attenuation corrections in the 2A21 algorithm. Characteristics of the vertical reflectivity profile is important for various reasons ranging from scientific to instrument algorithms. It is well known that different types of precipitation such as stratiform or convection, have different heating profiles. The vertical profile of reflectivity can provide information on precipitation classification. The vertical reflectivity structure also provides information on precipitation processes such as growth and aggregation. In terms of TRMM algorithms, an independent estimate of the vertical profiles are also extremely important since the PR returns can be attenuated in the rain layer near the surface. Corrections for attenuation are required in the lowest few kilometers, necessitating some assumptions about the rain size distributions and the reflectivity profile below the lowest measurement unaffected by the surface return. Furthermore, some assumptions about the vertical reflectivity profile are required for Ground Validation (GV) radars, since their lowest scan may be 1 or more kilometers above the surface. Statistics on the vertical reflectivity and Doppler structure are presented from the ER-2 Doppler Radar (EDOP) which participated in several TRMM field campaigns (TEFLUN-A, TEFLUN-B, and LBA) and CAMEX-3. The ER-2 aircraft overflew diverse precipitation types during these campaigns. EDOP is an X-band (9.6 GHz) radar for which returns are less attenuated than at the TRMM PR frequency. The EDOP profiles are first corrected for attenuation using the SRT method. The data from all the ER-2 campaigns are then classified by type (convection, stratiform, and other) and then statistics were performed on the vertical reflectivity and Doppler profiles in the form of CFAD's. These CFADs are compared and discussed. The computed CFAD's indicate significant differences as a function of precipitation type and location (hurricane versus non-hurricane, Brazil versus Florida). The implications of these profiles will be discussed.

Starr, David OC.

jasonSWIR Calibration of Spectralon Reflectance Factor

Satellite instruments operating in the reflective solar wavelength region require accurate and precise determination of the Bidirectional Reflectance Factor (BRF) of laboratory-based diffusers used in their pre-flight and on-orbit radiometric calibrations. BRF measurements are required throughout the reflected-solar spectrum from the ultraviolet through the shortwave infrared. Spectralon diffusers are commonly used as a reflectance standard for bidirectional and hemispherical geometries. The Diffuser Calibration Laboratory (DCaL) at NASA's Goddard Space Flight Center is a secondary calibration facility with reflectance measurements traceable to those made by the Spectral Tri-function Automated Reference Reflectometer (STARR) facility at the National Institute of Standards and Technology (NIST). For more than two decades, the DCaL has provided numerous NASA projects with BRF data in the ultraviolet (UV), visible (VIS) and the Near infraRed (NIR) spectral regions. Presented in this paper are measurements of BRF from 1475nm to 1625nm obtained using an indium gallium arsenide detector and a tunable coherent light source. The sample was a 2 inch diameter, 99% white Spectralon target. The BRF results are discussed and compared to empirically generated data from a model based on NIST certified values of 6deg directional/hemispherical spectral reflectance factors from 900nm to 2500nm. Employing a new NIST capability for measuring bidirectional reflectance using a cooled, extended InGaAs detector, BRF calibration measurements of the same sample were also made using NIST's STARR from 1475nm to 1625nm at an incident angle of 0deg and at viewing angles of 40deg, 45deg, and 50deg. The total combined uncertainty for BRF in this ShortWave Infrared (SWIR) range is less than 1%. This measurement capability will evolve into a BRF calibration service in SWIR region in support of NASA remote sensing missions. Keywords: BRF, BRDF, Calibration, Spectralon, Reflectance, Remote Sensing.

Georgiev, Georgi T.

Preliminary Error Budget for the Reflected Solar Instrument for the Climate Absolute Radiance and Refractivity Observatory

The Climate Absolute Radiance and Refractivity Observatory (CLARREO) plans to observe climate change trends over decadal time scales to determine the accuracy of climate projections. The project relies on spaceborne earth observations of SI-traceable variables sensitive to key decadal change parameters. The mission includes a reflected solar instrument retrieving at-sensor reflectance over the 320 to 2300 nm spectral range with 500-m spatial resolution and 100-km swath. Reflectance is obtained from the ratio of measurements of the earth s surface to those while viewing the sun relying on a calibration approach that retrieves reflectance with uncertainties less than 0.3%. The calibration is predicated on heritage hardware, reduction of sensor complexity, adherence to detector-based calibration standards, and an ability to simulate in the laboratory on-orbit sources in both size and brightness to provide the basis of a transfer to orbit of the laboratory calibration including a link to absolute solar irradiance measurements. The Climate Absolute Radiance and Refractivity Observatory (CLARREO) mission addresses the need to observe high-accuracy, long-term climate change trends and to use decadal change observations as the most critical method to determine the accuracy of climate change projections such as those in the IPCC Report. A rigorously known accuracy of both decadal change observations as well as climate projections is critical in order to enable sound policy decisions. The CLARREO Project will implement a spaceborne earth observation mission designed to provide rigorous SI traceable observations (i.e., radiance, reflectance, and refractivity) that are sensitive to a wide range of key decadal change variables, including: 1) Surface temperature and atmospheric temperature profile 2) Atmospheric water vapor profile 3) Far infrared water vapor greenhouse 4) Aerosol properties and anthropogenic aerosol direct radiative forcing 5) Total and spectral solar irradiance 6) Broadband reflected and emitted radiative fluxes 7) Cloud properties 8) Surface albedo There are two methods the CLARREO mission will rely on to achieve these critical decadal change benchmarks: direct and reference inter-calibration. A quantitative analysis of the strengths and weaknesses of the two methods has led to the recommended CLARREO mission approach. The project consists of two satellites launched into 90-degree, precessing orbits separated by 90 degrees. The instrument suite receiver on each spacecraft includes one emitted infrared spectrometer, two reflected solar spectrometers: dividing the spectrum from ultraviolet through near infrared, and one global navigation receiver for radio occultation. The measurements will be acquired for a period of three years minimum, with a five-year lifetime goal, enabling follow-on missions to extend the climate record over the decades needed to understand climate change. The current work concentrates on the reflected solar instrument giving an overview of its design and calibration approach. The calibration description includes the approach to achieving an SI-traceable system on orbit. The calibration overview is followed by a preliminary error budget based on techniques currently in place at the National Institute of Standards and Technology (NIST).

Thome, Kurtis

Estimating Major Ion and Nutrient Concentrations in Mangrove Estuaries in Everglades National Park Using Leaf and Satellite Reflectance

Coastal mangrove ecosystems are under duress worldwide because of urban development, sea-level rise, and climate change, processes that are capable of changing the salinity and nutrient concentration of the water utilized by the mangroves. This study correlates long-term water chemistry in mangrove environments, located in Everglades National Park,with mangrove spectral reflectance measurements made at both the leaf and canopy scales. Spectral reflectance measurements were collected using a handheld spectrometer for leaf-level measurements and Landsat 5TMdata for regional coverage. Leaf-level reflectance data were collected from three mangrove species (i.e., red, black and white mangroves) across two regions; a tall mangrove (approximately 18m) and dwarf mangrove (1- 2 m) region. The reflectance data were then used to calculate a wide variety of biophysical reflectance indices (e.g., NDVI, EVI, SAVI) to determine signs of stress. Discrete, quarterly water samples from the surface water, groundwater, and pore water (20 and 85 cm depths) and daily autonomous surface water samples were collected at each site and analyzed for major anions (Cl(−) and SO(2(-)/4)), cations (Na(+), K(+), Mg(sup 2(+)), and Ca(sup 2(+)), total nitrogen (TN) and total phosphorus (TP).Mangrove sites that exhibited the highest salinity and ionic concentrations in the surface and subsurface water also had the lowest near-infrared reflectance at both the leaf and satellite levels. Seasonal reflectance responses were measured in the near-infrared (NIR) wavelengths at both the leaf and canopy scales and were strongly correlated with nutrient and ionic concentrations in the surface and subsurface water, even though there was no significant separability between the three mangrove species. Study sites that experienced the greatest variability in surface and subsurface water ionic concentrations also exhibited the greatest fluctuations in NIR spectral reflectance. Landsat 5TM images were able to detect tall and dwarf mangroves by the differences in spectral indices (e.g., NDVI, NDWI, and EVI) because of the variability in the background conditions amongst the environments. In addition, Landsat 5TM images spanning 16 years (1993- 2009) were successfully used to estimate the seasonal variability in ionic concentrations in the surface water across the Florida Coastal mangrove ecotone. This study has shown that water chemistry can be estimated indirectly by measuring the change in spectral response at the leaf- or satellite-scale. Furthermore, the results of this research may be extrapolated to similar coastal mangrove systems throughout the Caribbean and world-wide wherever red, black, and white mangroves occur.

Mangroves

Laser Pulse Bidirectional Reflectance from CALIPSO Mission

In this Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) study, we present a simple way of determining laser pulse bidirectional reflectance over snow/ice surface using the Cloud-Aerosol LIdar with Orthogonal Polarization (CALIOP) 532 nanometer polarization channels' measurements. The saturated laser pulse returns from snow and ice surfaces are recovered based on surface tail information. The method overview and initial assessment of the method performance will be presented. The retrieved snow surface bidirectional reflectance is compared with reflectance from both CALIOP cloud cover regions and Moderate Resolution Imaging Spectroradiometer (Earth Observing System (EOS)) (MODIS) Bi-directional Reflectance Distribution Function (BRDF) / Albedo model parameters. The comparisons show that the snow surface bidirectional reflectance over Antarctica for saturation region are generally reliable with a mean value of about 0.90 plus or minus 0.10, while the mean surface reflectance from cloud cover region is about 0.84 plus or minus 0.13 and the calculated MODIS reflectance at 555 nanometers from the BRDF / Albedo model with near nadir illumination and viewing angles is about 0.96 plus or minus 0.04. The comparisons here demonstrate that the snow surface reflectance underneath the cloud with cloud optical depth of about 1 is significantly lower than that for a clear sky condition.

Lu, Xiaomei

Near-infrared Reflectance of Rocks at high Temperature: Preliminary Results and Implications for Near-infrared Emissivity of Venus's Surface

Light emitted from Venus’s surface can be viewed through spectral “windows” in its atmosphere, in the nearinfrared (NIR) around 1000 nanometer (nm) wavelengths. The NIR emissivity of Venus’s surface can constrain rock types and their weathering state; emissivities can be measured directly or calculated from reflectances. We measured the reflectances of igneous and sedimentary rocks at Venus’s surface temperature, 400 °C–500 °C at 850 and 950 nm; samples were heated in a box furnace in air, illuminated by light-emitting diodes (LEDs), and imaged with a modified charge-coupled device (CCD) camera. Reflectances were also measured at 25 °C from 350 to 1400 nm. Rock reflectances at 850 and 950 nm and 400 °C–500 °C are nearly identical to those at 25 °C, except for the effects of nanophase hematite forming on some surfaces. Fresh basalts have reflectances (high and low temperatures) near 7.5%; a leucogranite similarly has reflectances near 50%. Pigmentary hematite has nearly identical reflectances at high- and low-temperature at these wavelengths. Pigmentary hematite appears dark brown 400 °C–500 °C because its absorption edge has shifted to beyond the limit of human vision. These rock reflectances imply that basalts should have emissivities near 0.9, and granite (and similar felsic rocks) should have lower emissivities ∼0.5. Thus, basalt and felsic rock should be easily distinguished in NIR emissivity measurements of Venus’s surface, such as are baselined in recent Venus mission proposals. Other sedimentary rocks should have even lower emissivities: quartz sand at around ∼0.3, and anhydrite as low as 0.1.

Allan H Treiman

Aerosol Models from the AERONET Database: Application to Surface Reflectance Validation Satellite Data

Aerosols play a critical role in radiative transfer within the atmosphere, and they have a significant impact on climate change. In this paper, we propose and implement a framework for developing an aerosol model using their microphysical properties. Such microphysical properties as the size distribution, the complex refractive index, and the percentage of sphericity are derived from the global AERosol RObotic NETwork (AERONET). These measurements, however, are typically retrieved when almucantar measurement procedures are performed (i.e., early mornings and late afternoons with clear sky) and might not have a temporal correspondence to a satellite overpass time, so a valid validation of satellite-derived products cannot be carried out. To address this problem of temporal inconsistency of satellite and ground-based measurements, we developed an approach to retrieve these microphysical properties (and the corresponding aerosol model) using the optical thickness at 440 nm, τ440, and the Ångström coefficient between 440 and 870 nm, α440–870. Such aerosol models were developed for 851 AERONET sites within the last 28 years. Obtained results suggest that empirically microphysical properties can be retrieved with uncertainties of up to 23 %. An exception is the imaginary part of the refractive index ni, for which the derived uncertainties reach up to 38 %. These specific parametric models of aerosol can be used for the studies when retrieval of microphysical properties is required as well as validation of satellite-derived products over land. Specifically, we demonstrate the usefulness of the aerosol models to validate surface reflectance records over land derived from optical remote sensing sensors. We then quantify the propagation of uncertainties in the surface reflectance due to uncertainties with the aerosol model retrieval that is used as a reference from radiative transfer simulations. Results indicate that individual aerosol microphysical properties can impact uncertainties in surface reflectance retrievals between 3.5 × 10(exp -5) to 1 × 10(exp -3) (in reflectance units). The overall impact of microphysical properties combined yields an overall uncertainty in surface reflectance <0.004 (in reflectance units). That corresponds, for example, to 1 to 3 % of the retrieved surface reflectance in the red spectral band (620–670 nm) by the Moderate Resolution Imaging Spectroradiometer (MODIS) instrument. These uncertainty values are well below the specification (0.005 + 0.05ρ; ρ is the retrieved surface reflectance) used for the MODIS atmospheric correction.

Jean-Claude Roger

Accounting for the Effects of Surface BRDF on Satellite Cloud and Trace-Gas Retrievals: A New Approach Based on Geometry-Dependent Lambertian-Equivalent Reflectivity Applied to OMI Algorithms

Most satellite nadir ultraviolet and visible cloud, aerosol, and trace-gas algorithms make use of climatological surface reflectivity databases. For example, cloud and NO2 retrievals for the Ozone Monitoring Instrument (OMI) use monthly gridded surface reflectivity climatologies that do not depend upon the observation geometry. In reality, reflection of incoming direct and diffuse solar light from land or ocean surfaces is sensitive to the sun-sensor geometry. This dependence is described by the bidirectional reflectance distribution function (BRDF). To account for the BRDF, we propose to use a new concept of geometry-dependent Lambertian equivalent reflectivity (LER). Implementation within the existing OMI cloud and NO2 retrieval infrastructure requires changes only to the input surface reflectivity database. The geometry-dependent LER is calculated using a vector radiative transfer model with high spatial resolution BRDF information from the Moderate Resolution Imaging Spectroradiometer (MODIS) over land and the Cox-Munk slope distribution over ocean with a contribution from water-leaving radiance. We compare the geometry-dependent and climatological LERs for two wavelengths, 354 and 466 nm, that are used in OMI cloud algorithms to derive cloud fractions. A detailed comparison of the cloud fractions and pressures derived with climatological and geometry-dependent LERs is carried out. Geometry-dependent LER and corresponding retrieved cloud products are then used as inputs to our OMI NO2 algorithm. We find that replacing the climatological OMI-based LERs with geometry-dependent LERs can increase NO2 vertical columns by up to 50% in highly polluted areas; the differences include both BRDF effects and biases between the MODIS and OMI-based surface reflectance data sets. Only minor changes to NO2 columns (within 5 %) are found over unpolluted and overcast areas.

Lambert-equivalent reflectivity

Quality Assessment of Landsat Surface Reflectance Products Using MODIS Data

Surface reflectance adjusted for atmospheric effects is a primary input for land cover change detection and for developing many higher level surface geophysical parameters. With the development of automated atmospheric correction algorithms, it is now feasible to produce large quantities of surface reflectance products using Landsat images. Validation of these products requires in situ measurements, which either do not exist or are difficult to obtain for most Landsat images. The surface reflectance products derived using data acquired by the Moderate Resolution Imaging Spectroradiometer (MODIS), however, have been validated more comprehensively. Because the MODIS on the Terra platform and the Landsat 7 are only half an hour apart following the same orbit, and each of the 6 Landsat spectral bands overlaps with a MODIS band, good agreements between MODIS and Landsat surface reflectance values can be considered indicators of the reliability of the Landsat products, while disagreements may suggest potential quality problems that need to be further investigated. Here we develop a system called Landsat-MODIS Consistency Checking System (LMCCS). This system automatically matches Landsat data with MODIS observations acquired on the same date over the same locations and uses them to calculate a set of agreement metrics. To maximize its portability, Java and open-source libraries were used in developing this system, and object-oriented programming (OOP) principles were followed to make it more flexible for future expansion. As a highly automated system designed to run as a stand-alone package or as a component of other Landsat data processing systems, this system can be used to assess the quality of essentially every Landsat surface reflectance image where spatially and temporally matching MODIS data are available. The effectiveness of this system was demonstrated using it to assess preliminary surface reflectance products derived using the Global Land Survey (GLS) Landsat images for the 2000 epoch. As surface reflectance likely will be a standard product for future Landsat missions, the approach developed in this study can be adapted as an operational quality assessment system for those missions.

Landsat