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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Roadmap for Assessing Fuel Reprocessing in Fluoride-Based Salts

This joint report assesses the pyroprocessing of used nuclear fuel from molten fluoride salts being conducted between Idaho National Laboratory and Argonne National Laboratory. The goal of this report is to identify the research and development gaps needed to reduce the technical risks of extending pyroprocessing technologies and unit operations to molten fluoride salts used in molten salt reactors (MSRs). Assessing and performing the tasks outlined in this report will help mitigate the technical risks and design appropriate flowsheets for reprocessing fuel and coolant salts. These suggested tasks will provide necessary data to implement the development of unit operations. Sections are highlighted to identify processes that need to be assessed and unit operations that may be used in fluoride-based chemistries. Research and development needs are listed and discussed including re-fluorination methods, electrowinning for separations, reference electrode development, materials compatibility, salt purification/re-fluorination, and waste disposition. This report will examine the technical challenges associated with pyroprocessing in molten fluoride-based salt and outline approaches to increase the technical readiness level of pyroprocessing in molten fluoride salts.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
NASA NTRS1988

Gamma-ray burst reprocessing

A review of three theoretical models for the generation of transient optical emission thought to accompany the gamma-ray bursts is presented. The physics of reprocessing by Compton-heated electrons in the magnetosphere of a highly magnetized neutron star, the surface layers of a companion star, and an accretion disk are discussed. The spectral shapes, time scales, and arrival time delays between low and high energy photons predicted by the models are compared. These predictions are so different that broad band monitoring could be used to indicate which of the three scenarios (if any) is correct.

Melia, Fulvio↗
NASA NTRS1999

Iodine-Xenon Dating: Sensitive Chronometer for Reprocessing in the Primitive Solar System

The I-Xe chronometer is based upon decay of I-129 to Xe-129 in the early Solar System. Recent comparison of I-Xe system in individual mineral separates from twelve different meteorites with independent Pb-Pb data has demonstrated that I-Xe clock is a reliable sensitive chronometer when applied to a single mineral system. Since most iodine hosts are secondary minerals, the I-Xe clock generally records post-formational processing, providing the information on early meteorite evolution. Absolute I-Xe ages can be found by normalization using the measured I-Xe and Pb-Pb ages of Acapulco phosphate (4.557 plus or minus 0.002 Ga). Absolute ages for the I-Xe internal standards Shallow water and Bjurbole, 4.566 plus or minus 0.002 Ga and 4.565 plus or minus 0.003 Ga, respectively, provide absolute I-Xe ages for all other samples. The I-Xe age of bulk meteorite is meaningful and interpretable only when the carrier of primordial iodine is a major mineral phase (e. g., enstatite chondrites). Using the "monomineral" approach, separated phases from the Richardton H5 chondrite provide a case history of post-formational alteration in this object. This work applies the I-Xe chronometer to determine the times of reprocessing of selected minerals in single meteorite types. A preliminary account of this work was recently reported. Additional information is contained in the original extended abstract.

Pravdivtseva, O. V.↗
NASA NTRS2002

An X-Ray Reprocessing Model of Disk Thermal Emission in Type 1 Seyfert Galaxies

Using a geometry consisting of a hot central Comptonizing plasma surrounded by a thin accretion disk, we model the optical through hard X-ray spectral energy distributions of the type 1 Seyfert. galaxies NGC 3516 and NGC 7469. As in the model proposed by Poutanen, Krolik, and Ryde for the X-ray binary Cygnus X-1 and later applied to Seyfert galaxies by Zdziarski, Lubifiski, and Smith, feedback between the radiation reprocessed by the disk and the thermal Comptonization emission from the hot central plasma plays a pivotal role in determining the X-ray spectrum, and as we show, the optical and ultraviolet spectra as well. Seemingly uncorrelated optical/UV and X-ray light curves, similar to those which have been observed from these objects can, in principle, be explained by variations in the size, shape, and temperature of the Comptonizing plasma. Furthermore, by positing a disk mass accretion rate which satisfies a condition for global energy balance between the thermal Comptonization luminosity and the power available from accretion, one can predict the spectral properties of the heretofore poorly measured hard X-ray continuum above approximately 50 keV in type 1 Seyfert galaxies. Conversely, forthcoming measurements of the hard X-ray continuum by more sensitive hard X-ray and soft gamma-ray telescopes, such as those aboard the International Gamma-Ray Astrophysics Laboratory (INTEGRAL) in conjunction with simultaneous optical, UV, and soft X-ray monitoring, will allow the mass accretion rates to be directly constrained for these sources in the context of this model.

Chiang, James↗
NASA NTRS2002

Thermal Comptonization and Disk Thermal Reprocessing in NGC3516

We present an application of the thermal Comptonization/disk reprocessing model recently proposed by Zdziarski, Lubiniski, and Smith. We show that the absence of strong optical variations in the presence of strong concurrent X-ray variations, similar to those found by Hubble Space Telescope (HST)/Rossi X-Ray Timing Explorer (RXTE) monitoring observations of NGC 3516, can be explained by changing the geometry of the Comptonizing plasma rather than the accretion disk itself. The total X-ray luminosity of the Comptonizing plasma must decrease as its spatial extent increases. In contrast, the disk inner radius must be roughly fixed in order not to produce optical/ultraviolet color variations stronger than observed. By including emission due to internal viscous dissipation in the disk, we can roughly match the optical and X-ray flux levels and variability amplitudes seen from NGC 3516 during the HST/RXTE campaign.

Chiang, James↗
NASA NTRS2004

X-Ray Reprocessing in Active Galactic Nuclei

This is the final report for research entitled "X-ray reprocessing in active galactic nuclei," into X-ray absorption and emission in various classes of active galaxy via X-ray spectral signatures. The fundamental goal of the research was to use these signatures as probes of the central engine structure and circumnuclear environment of active galactic nuclei. The most important accomplishment supported by this grant involved the detailed analysis and interpretation of the XMM data for the bright Seyfert 1 galaxy MCG-6-30-15. This work was performed by Drs. Christopher Reynolds and Mitchell Begelman in collaboration with Dr. Jorn Wilms (University of Tubingen, Germany; PI of the XMM observation) and other European scientists. With XMM we obtained medium resolution X-ray spectra of unprecedented quality for this Seyfert galaxy. Modeling the X-ray spectrum within the framework of accretion disk reflection models produced the first evidence for energy extraction from the spin of a black hole. Specifically, we found that the extreme gravitational redshifts required to explain the X-ray spectrum suggests that the bulk of the energy dissipation is concentrated very close to the black hole, in contrast with the expectations of any pure accretion disk model. In a second paper we addressed the low- energy spectral complexity and used RXTE specta to pin down the high-energy spectral index, thus firming up our initial interpretation. Additionally, we carried out detailed spectral and variability analyses of a number of Seyfert and radio galaxies (e.g., NGC 5548 and 3C 111) and developed general techniques that will be useful in performing X-ray reverberation mapping of accretion disks in AGN, once adequate data becomes available. A list of papers supported by this research is included.

Begelman, Mitchell C.↗
NASA NTRS2004

Parameter Trending, Geolocation Quality Control and the Procedures to Support Preparation of Next Versions of the TRMM Reprocessing Algorithm

TRMM has been an imminently successful mission from an engineering standpoint but even more from a science standpoint. An important part of this science success has been the careful quality control of the TRMM standard products. This paper will present the quality monitoring efforts that the TRMM Science Data and Information System (TSDIS) conducts on a routine basis. The paper will detail parameter trending, geolocation quality control and the procedures to support the preparation of next versions of the algorithm used for reprocessing.

Stocker, Erich Franz↗
NASA NTRS2011

Adjustments to the MODIS Terra Radiometric Calibration and Polarization Sensitivity in the 2010 Reprocessing

The Moderate-Resolution Imaging Spectroradiometer (MODIS) on NASA s Earth Observing System (EOS) satellite Terra provides global coverage of top-of-atmosphere (TOA) radiances that have been successfully used for terrestrial and atmospheric research. The MODIS Terra ocean color products, however, have been compromised by an inadequate radiometric calibration at the short wavelengths. The Ocean Biology Processing Group (OBPG) at NASA has derived radiometric corrections using ocean color products from the SeaWiFS sensor as truth fields. In the R2010.0 reprocessing, these corrections have been applied to the whole mission life span of 10 years. This paper presents the corrections to the radiometric gains and to the instrument polarization sensitivity, demonstrates the improvement to the Terra ocean color products, and discusses issues that need further investigation. Although the global averages of MODIS Terra ocean color products are now in excellent agreement with those of SeaWiFS and MODIS Aqua, and image quality has been significantly improved, the large corrections applied to the radiometric calibration and polarization sensitivity require additional caution when using the data.

Meister, Gerhard↗
NASA NTRS2016

NASA/GEWEX Surface Radiation Budget: Integrated Data Product With Reprocessed Radiance, Cloud, and Meteorology Inputs, and New Surface Albedo Treatment

The NASA/GEWEX Surface Radiation Budget (SRB) project produces shortwave and longwave surface and top of atmosphere radiative fluxes for the 1983-near present time period. Spatial resolution is 1 degree. The current release 3.0 (available at gewex-srb.larc.nasa.gov) uses the International Satellite Cloud Climatology Project (ISCCP) DX product for pixel level radiance and cloud information. This product is subsampled to 30 km. ISCCP is currently recalibrating and recomputing their entire data series, to be released as the H product, at 10km resolution. The ninefold increase in pixel number will allow SRB a higher resolution gridded product (e.g. 0.5 degree), as well as the production of pixel-level fluxes. In addition to the input data improvements, several important algorithm improvements have been made. Most notable has been the adaptation of Angular Distribution Models (ADMs) from CERES to improve the initial calculation of shortwave TOA fluxes, from which the surface flux calculations follow. Other key input improvements include a detailed aerosol history using the Max Planck Institut Aerosol Climatology (MAC), temperature and moisture profiles from HIRS, and new topography, surface type, and snow/ice. Here we present results for the improved GEWEX Shortwave and Longwave algorithm (GSW and GLW) with new ISCCP data, the various other improved input data sets and the incorporation of many additional internal SRB model improvements. As of the time of abstract submission, results from 2007 have been produced with ISCCP H availability the limiting factor. More SRB data will be produced as ISCCP reprocessing continues. The SRB data produced will be released as part of the Release 4.0 Integrated Product, recognizing the interdependence of the radiative fluxes with other GEWEX products providing estimates of the Earth's global water and energy cycle (I.e., ISCCP, SeaFlux, LandFlux, NVAP, etc.).

Cox, Stephen J.↗
DOE OSTI2020

Machine Learning Approaches for Nuclear Material Accounting Data from Irradiation and Reprocessing

We are currently exploring data analysis methods for their ability to strengthen the synthesis and evaluation of information generated within domestic and international safeguard regimes. Safeguard data typically includes rich heterogenous datasets amenable to advanced data analytics methods, such as machine learning. We have converted transactional data containing both numerical and categorical attributes from a domestic nuclear material control and accountability (NMC&A) system into a low-dimensional numerical structure via linear principal component analysis. This data representation allows for global structure discovery via cluster analysis, which can characterize the typical behavior of each of the primary types of transaction events. Furthermore, the structure of the top principal components captures the “typical behavior” of the data and is thus amenable to anomaly detection through statistical hypothesis testing. We explored this capability by generating erroneous permutations of the data and computing the Q-residual quantity increase associated with the information loss when these data are projected into the low-dimensional principal component analysis space representative of typical transactions.Future work will focus on identifying data transformations (e.g., graph networks) that more closely align with the inherent structure of these transactions to explain more salient information and disambiguate the underlying nuclear process—in this case, irradiation and reprocessing—from artifacts of NMC&A system transactional record keeping data.

Drescher, Adam↗
DOE OSTI2019

Modification of an Agitated Tube Reactor for use in the Reprocessing of Spent Nuclear Fuel

Aims: Convert an Agitated Tube Reactor (ATR) into a counter-current solvent extraction device. Assess effect of liquid fill level on liquid dispersion. The agitated tube reactor (ATR) is an array of connected tubes. The ATR laterally shakes in a sinusoidal path, moving the agitator bar to create mixing. Originally designed by AM Technology as a cocurrent reactor, the ATR has many features that are potentially useful in the nuclear industry: Tubes are connected by non-moving seals; Reduction in seal damage and reduced risk of expensive repairs in radioactive environments; Minimal axial dispersion within a tube; Plug flow; Narrower residence time distributions that traditional technology; Multiple tubes allow for multiple reactions in series; Converting to a counter-current design allows the ATR to be used for solvent extraction; Reprocessing or decommissioning. A 180 ml PERSPEX ATR tube with no liquid flow through was constructed and filled with a 1:1 solvent:aqueous ratio of kerosene and water. The tube was filled such that the total liquid filled 25 %, 50 %, 75 % or 100 % of the tube. A Photron Fastcam SA5, positioned at the side and the end of the tube was set to a frame rate of 5400 fps with a resolution of 1024 x 1024 and 6000 fps with a resolution of 1024 x 896 respectively. Droplets were recorded after 2 minutes of shaking to ensure good mixing. Droplet sizes are used to determine optimum fill level in the ATR. The shaking frequency follows a sinusoidal path and was set to 5 Hz. The images shown in the results section were taken at the peak of the sinusoidal motion. To convert to a counter-current design the two liquids need to be separated at the end of each tube. Liquids have been allowed to separate under gravity separation. Inclusion of baffles to reduce remixing by sloshing. Wall with height corresponding to 25 % fill volume allows kerosene to overflow into separate outlet. Increase in liquid fill level decreases the dispersion of the two liquid phases. Higher dispersion of droplets decreases surface area and therefore increases mass transfer in solvent extraction. 25 % should provide the greatest mass transfer though more work needs to completed to confirm this.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2026

Impact of Molten Gallium on the Microstructure and Corrosion Behavior of Aluminum and Uranium-Aluminum Alloys for Used Nuclear Fuel Reprocessing

Test reactors around the world utilize highly enriched uranium fuel to achieve high neutron fluxes for materials testing. Once spent, the remaining uranium is a valuable resource for subsequent fuel fabrication. However, some of these test reactor cores consist of curved plate-type fuel elements, fabricated using aluminum alloy 6061 (AA6061) cladding to encapsulate a uranium-aluminum alloy (UAlx) fuel matrix. These assemblies require non-standard reprocessing approaches for uranium recovery, as aluminum dissolves readily in acidic solutions, generating large volumes of waste and complicating downstream chemical separations. In this work, we investigate a novel chemical decladding strategy based on the interaction between AA6061/UAlx and molten gallium (Ga). Ga is known to induce severe degradation of aluminum metal through liquid metal embrittlement (LME), even at relatively low Ga concentrations. By penetrating the aluminum crystal lattice, Ga disrupts grain cohesion and facilitates fracture or dissolution of the aluminum matrix. Thermodynamic analysis of the Al–Ga binary phase diagram suggests that Ga may offer a viable pathway to selectively weaken or dissolve the AA6061 cladding, and potentially the aluminum component of the UAlx fuel matrix within. To this end, parametric experiments were performed at 50 °C and 100 °C across a range of Al–Ga atomic fractions. At lower Al fractions, the AA6061 was completely molten after 2 hours of exposure to the Ga metal. In contrast, samples with higher Al fractions (0.9 Al, 0.1 Ga) contained residual solids after 2 hours, which were characterized by microstructural examination using electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM). These Al-Ga compositions were also evaluated using FactSage thermodynamic modeling to further elucidate the relationship between phase diagram behavior and LME.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2026

Radiation Effects in Used Next Generation Nuclear Fuel Reprocessing Strategies

Given global commitments to significantly increase nuclear energy capacity, it is now more important than ever to develop efficient used nuclear fuel (UNF) management strategies to encourage widespread adoption of closed fuel cycles. To achieve this ambitious goal, a comprehensive understanding of radiation effects is essential for these next generation technologies, as radiolysis often limits longevity and performance. Here, we present new findings on: (i) the radiation robustness and performance of advanced sulfur chloride-based chlorination processes in the presence of nuclear materials (Fig. 1A); and (ii) the impacts of voloxidized uranium and rhenium complexation on monoamide-based UNF direct dissolution strategies (Fig 1B). These studies employed a combination of time-resolved electron pulse and dose accumulation gamma and electron beam irradiation techniques.

38 - RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCL↗
DOE OSTI2020

Glass waste form options for rare-earth fission products from electrochemical reprocessing

Herein, we describe a first-of-a-kind study where lead tellurite (Pb-Te-O), iron phosphate (Fe-P-O), and lanthanide aluminoborosilicate (LABS) waste forms are evaluated for treating and/or immobilizing waste streams containing high rare-earth (RE) content, e.g., RECl 3 , REOCl, and/or REO x . Results from this study show that NdOCl can be immobilized in 78TeO 2 -22PbO glass at up to 10 mass%. Higher loadings of up to 15 mass% were demonstrated, but with a small fraction of crystallization. Two Fe-P-O glasses produced from either RECl 3 (RE = Nd,Ce) or NdOCl revealed products with very similar properties, demonstrating that the phosphate process can be used to chlorinate a variety of RE-containing waste streams. Two LABS glasses produced from Nd 2 O 3 or NdOCl showed similar properties, but the LABS-NdOCl glass did have some residual Cl present. Characterization is provided for all waste forms including chemical analysis, X-ray diffraction, and bulk density.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗