Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Pu”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS1976

History and genesis of lunar troctolite 76535 or: How old is old

The history of lunar troctolite 76535 was investigated on the basis of information from the Sm-147-Nd-143 mineral isochron age, the Nd-143 evolution, extinct Pu-224, the Kr-81-Kr exposure age and the cosmic ray exposure record. It was found that the troctolite minerals last equilibrated 4.26 plus or minus 0.06 AE ago and that the Sm-Nd system became closed at this time. The rock remained at temperatures where the loss of radiogenic Ar-40 was small.

Lugmair, G. W.↗
NASA NTRS1977

Isotopic and chemical investigations on Angra dos Reis

Isotope ratios and chemical abundance measurements for a variety of elements are reported for total meteorite and mineral separates of the Angra dos Reis achondrite. U-Pb, Th-Pb, and Pb-Pb ages are concordant at 4.54 eons for the total meteorite and for high-purity whitlockite, which indicates that Angra dos Reis is an early planetary differentiate that has not been disturbed for these systems since 4.54 eons ago. The implications of different ratios of Sr-87 and Sr-86 found in different components are discussed. Xe isotopic measurements show that Pu-244 was enriched in the whitlockite relative to the pyroxene by a factor of about 18. Chemical enrichment factors between the whitlockite and the fassaitic pyroxene in Angra dos Reis are presented

Wasserburg, G. J.↗
NASA NTRS1978

Fission and activation of uranium by fusion-plasma neutrons

Fusion-fission hybrid reactors are discussed in terms of two main purposes: to breed fissile materials (Pu 233 and Th 233 from U 238 or Th 232) for use in low-reactivity breeders, and to produce tritium from lithium to refuel fusion plasma cores. Neutron flux generation is critical for both processes. Various methods for generating the flux are described, with attention to new geometries for multiple plasma focus arrays, e.g., hypocycloidal pinch and staged plasma focus devices. These methods are evaluated with reference to their applicability to D-D fusion reactors, which will ensure a virtually unlimited energy supply. Accurate observations of the neutron flux from such schemes are obtained by using different target materials in the plasma focus.

Lee, J. H.↗
NASA NTRS1975

Krypton and xenon in Apollo 14 samples - Fission and neutron capture effects in gas-rich samples

Gas-rich Apollo 14 breccias and trench soil are examined for fission xenon from the decay of the extinct isotopes Pu-244 and I-129, and some samples have been found to have an excess fission component which apparently was incorporated after decay elsewhere and was not produced by in situ decay. Two samples have excess Xe-129 resulting from the decay of I-129. The excess is correlated at low temperatures with excess Xe-128 resulting from neutron capture on I-127. This neutron capture effect is accompanied by related low-temperature excesses of Kr-80 and Kr-82 from neutron capture on the bromine isotopes. Surface correlated concentrations of iodine and bromine are calculated from the neutron capture excesses.

Drozd, R.↗
NASA NTRS1978

Isotopic anomalies from neutron reactions during explosive carbon burning

The possibility that the newly discovered correlated isotopic anomalies for heavy elements in the Allende meteorite were synthesized in the secondary neutron capture episode during the explosive carbon burning, the possible source of the O-16 and Al-26 anomalies, is examined. Explosive carbon burning calculations under typical conditions were first performed to generate time profiles of temperature, density, and free particle concentrations. These quantities were inputted into a general neutron capture code which calculates the resulting isotopic pattern from exposing the preexisting heavy seed nuclei to these free particles during the explosive carbon burning conditions. The interpretation avoids the problem of the Sr isotopic data and may resolve the conflict between the time scales inferred from 1-129, Pu-244, and Al-26.

Lee, T.↗
NASA NTRS1979

Xenon component organization in 14301

Xe in 14301 is a superposition of in situ spallation and presumably also fission Xe, of trapped solar wind, and of trapped fission Xe and Xe-129 redistributed after origin elsewhere on the moon. Some and probably most of the trapped fission originates from Pu-244. All of the components of various origins are released independently in stepwise heating, indicating that they were acquired by different means and remain in different sites within the sample. This applies to the excess fission and to the excess Xe-129, which fail to correlate quantitatively with each other; they must thus have been trapped by different mechanisms or at different times. In spite of their independent behavior in stepwise heating, the various trapped components contribute in constant proportion to the total Xe contents of the various size fractions. This quantitative correlation between excess Xe and solar wind Xe indicates that the same circumstances control the acquisition of both. The variation of the ratio of excess to solar wind Xe among different breccias thus can be ascribed more confidently to compositional variation in total Xe available for trapping rather than to the details of the trapping process.

Bernatowicz, T. J.↗
NASA NTRS1979

Review of the metallographic cooling rates of meteorites and a new model for the planetesimals in which they formed

The cooling rates of meteorites through approximately 900 -650 K, as read from their metal alloy compositions, are reviewed. Metallographic cooling rates are compared with the cooling rates that appear to be required by the K/Ar and Ar-40/Ar-39 ages of five meteorite classes, and discrepancies are found in all cases. Either (1) the metallographic cooling rates (and also Pu-244 fission cooling rates) are systematically in error, being too slow by a factor of approximately 6; or (2) the traditional thermal model for parent meteorite planets (having constant dimension and uniform physical properties) is oversimplified and the Ar closure temperatures for chondrites derived by Turner et al. (1978) are too low. An alternative parent planet model is proposed and numerically modeled, in which accretion of thermally insulating particulate matter, heat generation by Al-26 decay, melting or sintering of the particulate matter into conductive rock, and establishment of the properties of the meteorites occurred concurrently. Meteorite chronologies are somewhat easier to understand in this context, since the initially small, hot (thus sintered and conductive) bodies would have cooled rapidly to isotopic closure, but later cooling might have been much slower as a result of the continued accretion of insulating particulate matter.

Wood, J. A.↗
NASA NTRS1980

Search for Xe-129 in mineral grains from Allende inclusions - An exercise in miniaturized rare gas analysis

The paper considers the use of a static mass spectrometer modified by installation of a Baur-Signer ion source and an ion-counting system to detect xenon from single grains from inclusions in the C3 meteorite Allende. The inferred iodine concentrations increased from pentlandite to melilite, but vary widely from one grain to another, indicating that the iodine resides in a minor phase which is included 'spottily' in the bulk phases. It is likely that the detectability for excess Xe achieved here could be improved; about 23,000 of fissiogenic Xe-132 was detected in the largest melelite sample analyzed, but it cannot be determined from this study whether the PU-244 is 'spotty' like I-129 or is uniformly distributed in the melilite.

Reynolds, J. H.↗
NASA NTRS1979

Isotopic anomalies from neutron reactions during explosive carbon burning

The heavy isotopic anomalies observed recently in the fractionation and unknown nuclear inclusions from the Allende meteorite are explained by neutron reactions during the explosive carbon burning (ECB). This model produces heavy anomalies in the same zone where Al-26 and O-16 are produced, thus reducing the number of source zones required for the isotopic anomalies. Unlike the classical r-process, the ECB n-process avoids the problem with the Sr anomaly and may resolve the problem of conflicting time scales between Al-26 and the r-process isotopes I-129 and Pu-244. Experimental studies of Zr and Ce isotopic composition are proposed to test this model.

Lee, T.↗
NASA NTRS1980

Evidence for live Cm-247 in the early solar system

Variations of the U-238/U-235 ratio in the Allende meteorite, ranging from -35% to +19% are interpreted as evidence of live Cm-247 in the early solar system. The amounts of these and other r-products in the solar system indicate values of (9000 + or - 3000) million years for the age of the Galaxy and approximately 8 million years for the time between the end of nucleosynthesis and the formation of meteoritic grains. Three possible explanations are presented for the different values of the latter time period which are indicated by the decay of products of Cm-247, Al-27, Pu-244, and I-129.

Tatsumoto, M.↗
NASA NTRS1980

Fission xenon in troctolite 76535

Xenon released in stepwise heating of troctolite 76535 shows remarkable similarity to that from the gas-rich breccias. The low temperature fractions are highly enriched in fissiogenic xenon from Pu-244. Although the quantity of fission xenon is not inconsistent with reported age data, release patterns demonstrate that this component is not due to in situ decay. However, in contrast with the gas-rich breccias, the parentless radionuclear component in 76535 is not accompanied by solar wind xenon. Mechanisms for the emplacement of this component in 76535 cannot, therefore, involve exposure on the lunar surface but most likely involve adsorption along intergranular boundaries or thermally driven redistribution. The fact that xenon released from a gas-poor igneous cumulate can mimic that from gas-rich breccias, except for the presence of solar wind xenon in the latter, suggests that direct exposure to space is not required for the incorporation of these weakly bound, surface-correlated, parentless radionuclear components in lunar samples.

Hohenberg, C. M.↗
NASA NTRS1980

Noble gas component organization in 14301

A study is conducted of the organization of noble gases in the Apollo 14 breccia 14301, giving particular attention to xenon from the extinct radionuclides I-129 and Pu-244. An essential ingredient of this work is the intercomparison between noble gases released in single-stage melts of grain size fractions and those released in stepwise extractions. This approach resolves 'functional' noble gas components, which are organized by siting, into the specific genetic contributions on the basis of the 'activation energies' for diffusive loss. The procedure makes it possible to resolve various genetic components on the basis of the chemical and structural differences in their specific locations. Consequently, distinctions can be made among components acquired by different processes and among components which have undergone different regolith histories.

Bernatowicz, T. J.↗
NASA NTRS1982

Troctolite 76535 - A study in the preservation of early isotopic records

The lunar rock considered in the present investigation is a coarse-grained troctolite granulite containing about 58(vol)% plagioclase, 37% olivine, 4% pyroxene, and less than 1% accessory phases with a texture which indicates formation as a cumulate at depths between 10 and 30 km followed by an extended period of slow cooling. A description is presented of noble gas studies of separated minerals from 76535. The quantity of fission xenon from the in situ decay of Pu-244 provides further evidence for different, mineral-specific, isotopic closure times. The presented data shows that 76535 loses its surface-correlated xenon component upon disaggregation. No other xenon component is lost. The presence of solar gases in 76535 would seem to argue in favor of the external acquisition of the parentless extinct isotope effects and consequently favor 'thermal diffusion' and 'adsorption' over local redistribution models.

Caffee, M.↗
NASA NTRS1983

Photovoltaic stand-alone modular systems, phase 2

The final hardware and system qualification phase of a two part stand-alone photovoltaic (PV) system development is covered. The final design incorporated modular, power blocks capable of expanding incrementally from 320 watts to twenty kilowatts (PK). The basic power unit (PU) was nominally rated 1.28 kWp. The controls units, power collection buses and main lugs, electrical protection subsystems, power switching, and load management circuits are housed in a common control enclosure. Photo-voltaic modules are electrically connected in a horizontal daisy-chain method via Amp Solarlok plugs mating with compatible connectors installed on the back side of each photovoltaic module. A pair of channel rails accommodate the mounting of the modules into a frameless panel support structure. Foundations are of a unique planter (tub-like) configuration to allow for world-wide deployment without restriction as to types of soil. One battery string capable of supplying approximately 240 ampere hours nominal of carryover power is specified for each basic power unit. Load prioritization and shedding circuits are included to protect critical loads and selectively shed and defer lower priority or noncritical power demands. The baseline system, operating at approximately 2 1/2 PUs (3.2 kW pk.) was installed and deployed. Qualification was successfully complete in March 1983; since that time, the demonstration system has logged approximately 3000 hours of continuous operation under load without major incident.

Naff, G. J.↗
NASA NTRS1982

Fission track studies of xenolithic chondrites - Implications regarding brecciation and metamorphism

Fission tracks in phosphates from one gas-poor chondrite and three gas-rich ones are studied to determine their thermal history and brecciation time scales. Model fission track ages are calculated for given track densities due to Pu-244 and U-238; track densities and uranium measurements for whitlockite are shown, and possible sources of the tracks are mentioned. Details of track density and uranium measurements are discussed for each meteorite separately. Whitlockites from all the meteorites give model fission track ages of 4.4 Gyr assuming a Pu/U ratio at 4.55 Gyr of 0.045. The final brecciation event definitely did not reset the track clock in phosphates of one meteor and probably not in another two. It is concluded that the observed fission track ages date the end of metamorphic cooling in the meteorite parent bodies and support the planetesimal model for the formation of xenolithic chondrites.

Kothari, B. K.↗
NASA NTRS1983

Extinct radioactivities - A three-phase mixing model

A new class of models is advanced for interpreting the relationship of radioactive abundances in the early solar system to their average concentration in the interstellar medium. The model assumes that fresh radioactivities are ejected from supernovae into the hot interstellar medium, and that the time scales for changes of phase into molecular clouds determine how much survives for formation therein of the solar system. A more realistic and physically motivated understanding of the low observed concentrations of I-129, Pu-244, and Pd-107 may result.

Clayton, D. D.↗
NASA NTRS1983

In situ trace element microanalysis

The use of particle-track-radiography and X-ray- fluorescence techniques in the in situ measurement of trace (less than 1000 ppm) elements in single mineral phases of polished sections is surveyed, and examples of their application to ordinary, carbonaceous and enstatite chondrites are provided. Radiographic methods surveyed include fission-track radiography (for U, Th, and Pu-244), alpha radiography using nuclear reactions (for Li and B), alpha autoradiography (for Bi and Pb), and beta autoradiography (for several elements in synthetic or biological samples). Two X-ray-fluorescence methods are compared: (1) photon-induced X-ray emission (PIXE), and (2) the potential use of synchrotron radiation. The latter is shown to allow much greater sensitivity than current PIXE technology and a much broader range of elements than particle-track radiography: the ppm analysis of 10-micron grains for all elements heavier than Na. These advantages are seen as balancing the high cost of accelerator use.

Burnett, D. S.↗
NASA NTRS1983

Hf chronometer for the early solar system

It is now widely believed that Al-26 (half-life, 7.2 x 10 to the 5th yr) and Pd-107 (half-life, 6.5 x 10 to the 6th yr) were present in the early solar system. The nucleosynthetic event responsible for the production of these nuclei must therefore have occurred no more than a few million years before the formation of solid bodies. It is possible that this event also gave a rise to the I-129 believed to be present in the early solar system. The last event to contribute Pu-244 to the solar system, however, occurred approximately 10 to the 8th yr before the time of solidification. It is noted that this latter time scale is also consistent with the lack of evidence for a Cm-247 chronometer. It is proposed that Hf-182 (half-life, 9 x 10 to the 6th yr) can resolve the question whether heavy-element nonactinide nucleosynthesis occurred during the (Al-26)-producing event. It is believed that an answer to this question will help to clarify the chronology of the formation of the solar system and will help to determine the astrophysical sites of heavy-element nucleosynthesis.

Norman, E. B.↗