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Synthesis and characterisation of alites from reduced basic oxygen furnace slags

Basic oxygen furnace slags (BOFS) are by-products of the steelmaking process. Several researchers have studied the production of Portland cement clinker and metallic iron from BOFS via a reductive treatment. }In this study, we applied a carbothermal reduction of BOFS in a technical-scale electric arc furnace and characterised the clinker-like products. Those clinker-like non-metallic products (NMPs) had a chemical and mineralogical composition comparable to clinker for ordinary Portland cement (OPC) and contained large elongated alite crystals as major component. The pure NMPs reacted more slowly and achieved a lower degree of hydration compared with commercial OPC. }If the reactivity of the products can be further increased by employing specific adaptations, it can be used as a full clinker substitute for OPC. Nevertheless, it is also an option to use the material without further modifications as a cement component or concrete addition, which contributes to the strength development in both cases.

36 MATERIALS SCIENCE↗

Near-field infrared microscopy: A novel analytic mapping technique to nanocharacterize calcium silicate-based cement materials

Infrared imaging via scattering-type scanning near-field optical microscopy (s-SNOM) allows chemical mapping of organic and inorganic materials with nanoscale spatial resolution. However, its potential adaptation to the complex multiphase structure of Portland cement is yet to be explored. Here we demonstrate the successful implementation of s-SNOM to spatially resolve coexisting chemical phases in tricalcium silicate, Portland cement's main compound, with 20-nm resolution. We found that s-SNOM is sensitive to different anhydrous polymorphic phases, revealing nanoscale domains that are ‘invisible’ to other microscopic techniques. Furthermore, s-SNOM's ability to distinguish the unhydrated and hydrated phases signifies its great promise as an analytical tool to study the complex hydration process of cement. The key to s-SNOM's application was nano-modifying the surface roughness of the cement samples, allowing nanoscale infrared imaging without topographical artifacts. Our study opens a window for infrared spectral microscopy in cement and other porous inorganic materials.

36 MATERIALS SCIENCE↗

Efficiency of natural pozzolans, ground glasses and coal bottom ashes in mitigating sulfate attack and alkali-silica reaction

The use of pozzolans to partially replace Portland cement in concrete has generally demonstrated beneficial impacts on the durability characteristics of concrete for decades. In this paper a diverse range of pozzolans including natural pozzolans, ground glasses and industrial by-products such as coal ash (fly ash and bottom ash) and silica fume were investigated for their synergistic potential in binary or ternary blends with Portland cement in improving resistance to chemical sulfate attack and alkali-silica reaction (ASR). It is generally considered that pozzolans improve most of the durability issues encountered in concrete, including reducing the risk of sulfate attack or ASR. But this is not always the case. For example, it was found that ground glasses were very efficient in improving sulfate resistance, but their ability to mitigate expansion due to ASR was dictated by the equivalent alkalis content (Na{sub 2}O{sub e}) of the glass and high-alkali soda glass was generally not effective in this role. On the other hand, metakaolin, a highly reactive pozzolan, was highly effective in reducing ASR expansion, but may actually increase the damage due to sulfate attack when used at moderate replacement levels. Most pozzolans, such as low-CaO coal fly ash and ground coal bottom ash, silica fume, and pumice, were effective in controlling expansion due to both ASR and sulfate attack. The results demonstrated that the extent of the positive impact of using natural pozzolans on both properties was variable. The pozzolanic reactivity of materials alone was an unreliable indicator to assess the ability of the pozzolan to suppress expansion due to sulfate attack or ASR.

36 MATERIALS SCIENCE↗

Enabling phase quantification of anhydrous cements via Raman imaging

The phase composition of Portland cements is typically determined using conventional techniques like X-ray Diffraction (XRD) Rietveld analysis, optical microscopy point counting, and electron microscopy. However, these techniques have several limitations that may affect their accuracy in certain sample-specific scenarios. Here, we report a highly accurate phase quantification of 11 different types of commercial, anhydrous cements using a new and complementary technique: Raman imaging. Specifically, for the 4 principal phases, composition from our extensive data (250,000 Raman spectra per sample, error < 0.71%) and those obtained from XRD Rietveld and supplier data have high coefficients of determination (R{sup 2} > 0.98, mean deviation <2%). Additionally, we also quantify 8 secondary phases present in cement clinkers (gypsum, anhydrite, bassanite, syngenite, dolomite, calcite, quartz, and portlandite) with a high degree of confidence, thereby demonstrating that Raman imaging is a highly versatile tool for anhydrous phase quantification in a broad variety of cements.

36 MATERIALS SCIENCE↗

Work In Progress: Using Internships as Means for Indirect Assessment of ABET Criteria 3 "1-7" Student Outcomes

PSU operates the Power Engineering Internship program with funding from two U.S. Department of Energy grants. The program is operated in partnership with the lead organizations of these grants, an investor-owned utility, Portland General Electric (PGE), and the Confederated Tribes of the Warm Springs (CTWS). One of the programmatic goals of the PEI is to create and sustain a clean energy engineering workforce pipeline on behalf of these lead organizations. Both grants support internships at PGE, which is also a partner on the CTWS grant. The PEI provides engineering students with year-long internships, spanning both the academic year and the summer. The interns work at PGE facilities located throughout the Portland metropolitan area. Interns are employed full-time during summers and part-time during the academic year. Proximity of the worksites to the PSU campus enables the interns to participate in the program while attending school full-time. During the academic year, students average fifteen hours per week, adjusting their work schedule according to their academic workload. The interns are allocated 930 hours per year, 480 in the summer and 450 during the academic year, which they can plan as they see fit. The internships provide meaningful financial support for the students, who can earn up to $21k if they use all of their allocated hours. Such funding is particularly important for the typical student who attends a minority serving institutions,

99 GENERAL AND MISCELLANEOUS↗

Experimental validation of multiphysics model simulations of the thermal response of a cement clinker rotary kiln at laboratory scale

Abstract An increasing demand for buildings, transportation systems and civil infrastructure development has driven expansion of cement consumption world‐wide, producing a significant increase in related global energy demand. With approximately 7% of the world‐wide industrial energy consumption (10.7 exajoules [EJ]), the cement industry is the third most energy intensive industrial processes and a key component for concrete, the most consumed composite material in the global construction industry. In cement manufacturing, the cement kiln accounts for most of the energy consumption in the production process. As the heart of a cement plant, the cement kiln is where the kiln feed primarily containing calcium oxide (CaO), silica (SiO 2 ), alumina (Al 2 O 3 ), and iron (Fe 2 O 3 ) are thermally and chemically transformed into clinker minerals. The presented work developed a multiphysics model, designed and built a laboratory‐scale rotary cement clinker kiln, and produced cement clinker at laboratory‐scale. The model was developed to study the interaction between the various thermal, fluid dynamic and chemical interactions involved in the sintering process used to form Portland cement clinker in an effort to reduce energy use. The analytical model was validated through experimental testing using a unique laboratory‐scale rotary cement kiln developed during the investigation. Also demonstrated was the feasibility of producing clinker at laboratory scale. This modeling and lab scale tests were designed to better understand the clinker sintering process so that operational and quality decisions can be made to optimize energy consumption without compromising cement clinker quality. The computational fluid dynamics modeling was developed in COMSOL Multiphysics 6.0. The characteristics of the combustion fluid flow, concentration of species, temperature and heat transfer were studied for a turbulent flow of methane (CH 4 ) gas and oxygen (O 2 ). Theory suggests that heat transfer impacts the cement production process but the multiphysics model more accurately describes the convection, conduction, and radiant heat transfer in the kilning process and thus allows for a better understanding of the energy exchange driving the chemical reactions that produce Portland cement. Clinker minerals were formed because of appropriate burning conditions implemented during experimental model validation.

Tabares, Juan David↗

Towards ternary binders involving limestone additions — A review

The review summarises literature to examine the transition from portland limestone cement system to composite ternary binder systems involving limestone. Interest in limestone addition as an ideal component in multicomponent binder systems has surged as evident from the large volume of literature published in the recent past. A ternary blended system, with co-substitution of limestone, has the potential to complement the reaction of the supplementary cementitious materials (SCMs). The direct addition of limestone powder helps to attain higher substitution levels of portland cement clinker, improve early age properties, and supplement SCM's reactivity. However, the dilution of hydrates could hamper the long-term benefits. In this review, the interaction of fine limestone is classified and elaborated under two broad umbrellas: physical and chemical interactions. The physical interactions can manifest in three ways, namely, filler action, shearing action and improved packing, which alters reaction rate and extent at early ages. The chemical interactions also modify the reaction kinetics and phase assemblage due to nucleation of C-S-H on calcite surfaces, preservation of the ettringite phase and formation of carboaluminates. Two different forms of carboaluminate hydrates — hemicarboaluminate and mono-carboaluminate can be present in the hydrate matrix depending on the balance between carbonate ions and aluminates in the pore solution. Several factors such as replacement level, particle size, choice of SCM, its reactivity and reactive aluminates content, sulphate levels, curing temperature, and duration of curing can control the carboaluminate formation, reaction degree of SCMs and chemical interaction from limestone additions. A combination of physical and chemical effects makes fine limestone a potential material for co-substitution with aluminosilicate based SCMs, mainly fly ash, slag, and calcined clay. In this review, the factors affecting limestone-SCM composites are summarised based on a detailed literature survey. The effects of SCM-limestone cement composites on hydration kinetics, reaction chemistry, the reactivity of SCMs, the stability of hydrated phases, and contribution to the physical structure development and macroscopic properties by evaluating hydration and mechanical properties are discussed. The importance of AFm (Al{sub 2}O{sub 3}–Fe{sub 2}O{sub 3}-mono) phases in various deterioration mechanisms in concrete and their influence on performance characteristics in different exposure environment is critically appraised.

36 MATERIALS SCIENCE↗

On the use of limestone calcined clay cement (LC3) in high-strength strain-hardening cement-based composites (HS-SHCC)

Highlights: • Use of LC{sup 3} slightly reduces flowability and shortens the setting time of fresh matrices. • Highly polymerized C-A-S-H gel and abundant ettringite benefit flexural strength of LC{sup 3}-matrices. • Use of LC{sup 3} enhances the bond strength between fiber and high-strength matrix. • LC{sup 3}-based HS-SHCC yields similar flexural performance as the composite with Portland cement. High-strength strain-hardening cement-based composites (HS-SHCC) demonstrate excellent mechanical and durability properties. However, high cement content typical to HS-SHCC results not only in high carbon footprint, but also in excessive hydration heat and severe autogenous shrinkage. In this investigation, Limestone Calcined Clay Cement (LC{sup 3}) was used to produce sustainable HS-SHCC. The LC{sup 3} substitution resulted in higher energy consumption during mixing and in shorter setting times of the fresh, plain matrices. Although the LC{sup 3} substitution slightly reduced the compressive strength, the formation of highly polymerized C-A-S-H gel and abundant ettringite benefited the flexural strength of the plain matrices. Additionally, single-fiber pullout experiments showed that the use of LC{sup 3} led to increased fiber-matrix bond strength and pullout energy. Finally, the replacement of Portland cement by LC{sup 3} resulted in HS-SHCC with similar mechanical performance to the reference composite, indicating a high potential for using LC{sup 3} in high-performance cement-based composites.

36 MATERIALS SCIENCE↗

Geo-Responsive Chemomechanics in Aluminum Oxyhydroxide via Alkali-Driven Dehydroxylation for Supercritical Geothermal Systems

Widespread use of enhanced geothermal systems can revolutionize global renewable electrical power access, yet its advancement is hindered by the inherent instability of Portland cement-based chemistries for geothermal well construction under high-temperature corrosive conditions. Here, in this work, we demonstrate the tunable mechanical performance of aluminum oxyhydroxides as cementitious materials through an alkali-controlled dehydroxylation reaction pathway for long-term applications under supercritical geothermal environments. Notably, the synthesized aluminum oxyhydroxides demonstrate remarkable stability, maintaining superior mechanical performance under supercritical conditions for over 30 days. Synchrotron X-ray diffraction, spectroscopy measurements and geochemical thermodynamic modeling uncover that the gibbsite dehydroxylation pathway functions as a key dial for tuning the chemomechanics, rendering the aluminum oxyhydroxide a strong cementitious material. By uncovering the mechanistic role of alkali-driven dehydroxylation, this work proposes a cementitious chemistry distinct from conventional Portland cement and geopolymer-dominated alkali-activated systems, laying the groundwork for developing next-generation cementitious materials for supercritical geothermal energy exploitation.

15 GEOTHERMAL ENERGY↗

Scalable electrified cementitious materials production and recycling

The production of Portland cement, the industry-standard cement, contributes ~8% of global CO 2 emissions through fossil-fuel heating and decomposition of limestone (the primary cement raw material). Decarbonization, e.g., via direct electrification, of this 200-year-old liming routine is extremely challenging at the industry scale. We propose a scalable electrochemical decarbonization approach to circumvent the limestone use by switching to carbon-free calcium silicates from abundant minerals and recycled concrete. Water electrolysis produces protons and hydroxides to drive a pH gradient that accelerates Ca 2+ ion leaching from calcium silicates and captures atmospheric CO 2 to form carbon-negative CaCO 3 , which serves as the feedstock for cement manufacturing or as the carbon-mineralized product for cement substitution with permanent carbon storage. Value-added co-products amorphous silica and green H 2 further enhance cement performance and supplant fossil fuels for net-zero transition, respectively. The products readily meet present-day regulatory standards and demands, and the approach readily synergizes with business-as-usual cement manufacturing and concrete construction, which are important for upscaling and structural safety, promising ready reception by the public and industries. Blended Portland cement produced through our approach with carbon-negative CaCO 3 and silica demonstrates enhanced resilience and achieves carbon neutrality or negativity when incorporating storage or circulation of CO 2 from cement plant flue gas, respectively. This low-cost, electrochemical cement production approach using abundant ubiquitous raw materials enables electrification, transition to clean fuel, and decarbonization at a gigaton scale.

36 MATERIALS SCIENCE↗

Engineered Barrier System R&D and International Collaborations – LANL (FY20): Spent Fuel and Waste Disposition

The United States Department of Energy’s Spent Fuel and Waste Disposition (SFWD) program is investigating the design and safety function of generic nuclear geologic repositories in a variety of geologic settings (salt, argillite, and crystalline rock). Different configurations and loadings of spent nuclear fuel and waste within disposal canisters are also being investigated, some of which have the potential to generate repository temperatures higher than previously considered (i.e., temperatures >100ºC) by foreign and domestic concepts. This report expands on engineered barrier material stability in a high temperature crystalline rock repository through high temperature hydrothermal experiments. Experiments were designed to develop engineered barrier system (EBS) concepts in a hightemperature crystalline environment in 1) bentonite-Grimsel Granodiorite interactions, 2) bentonite-cement reactions, and 3) interaction between waste canister materials and bentonite. Experiment results are applied to understanding long-term repository performance in terms of radionuclide isolation. One hydrothermal experiment was completed in the rocking autoclaves at LANL in FY-20: IEBS-6 (Grimsel Granodiorite + Wyoming bentonite + cured ordinary Portland cement + Grimsel Granodiorite synthetic groundwater, 250ºC/150 bar, 8 weeks). Several other experiments were planned but were delayed due to the COVID-19 pause in laboratory work. In addition, some characterization of the reaction products of experiments conducted in FY-20 was prevented by COVID-19. Mineral phase chemistry was not measured via electron microprobe analyses for IEBS-6. Quantitative X-ray diffraction results from IEBS-6 and HBT-1 were not completed. The missing analyses and discussion of the results will be included in next year’s report. New characterization that was completed includes scanning electron microscopy of reaction products from IEBS-6, quantitative X-ray diffraction results are presented from IEBS-1 through IBES-5, preliminary scanning electron microscope images and chemical analyses for IEBS-6, X-ray diffraction of the clay fraction from all experiments, measurement/imaging of mineral growth on the surface of steel coupons. Major observations pertaining to bentonite stability in a Grimsel Granodiorite environment include the stability of Na-montmorillonite at 250°C, the formation of trace CSH phases, and the formation of bentonite colloids on experiment cooling. The addition of a cured chip of Portland cement to the bentonite-Grimsel system results in slightly higher pH values and the formation of diverse secondary mineral phases that were not observed in the previous experiments (e.g., analcime, garronite, CSH phases). The new characterization efforts related to the interaction of stainless-steel coupons and bentonite clay focused on thickness and mineralogy of phases that formed at the steel surface. In Wyoming bentonite + Grimsel Granodiorite systems, newly formed minerals at the bentonitesteel coupon interface included alteration of the outermost steel edge to Fe,Cr-oxide phases, followed by Fe-rich phyllosilicates (Fe-saponite, chlorite) and interbedded Fe,Cr,Ni-sulfide phases (pentlandite). Hydrothermal experiments were completed to assess uranium-carbonate complexation at conditions relevant to high-temperature disposal. Autoclave solubility experiments were conducted at 150 to 250ºC with a range of carbonate and uranium concentrations. The experiment results were characterized via situ UV-Visible spectroscopy and synchrotron-based in situ XAS techniques. Results show a significant decrease in the stability of uranyl-carbonate complexes at temperatures above 100ºC along with the precipitation of uranium oxides. Further, at T > 200ºC, results show that uranyl-hydroxyl complexes control solubility of uranium instead of the previously predicted uranyl-carbonate species. These results are significant for understanding the mobility of uranium in the EBS, which will likely contain carbonate-rich fluids. International research efforts focused on three main areas: 1) participation in international conferences, 2) building collaborations with foreign repository programs, and 3) the initiation of an experimental program to complement the full-scale HotBENT test at the Grimsel test site. This experiment included Wyoming bentonite + low carbon steel + Grimsel Granodiorite synthetic groundwater and was run at the planned maximum temperature of the HotBENT test (200°C). Complete characterization of reaction products was hindered by disruptions to laboratory work but will be reported in the next FY. The experimental results obtained in FY-20 continue to document the wide-ranging effects of bulk composition and pressure-temperature conditions in the mineralogical and geochemical evolution of a high-temperature repository environment. Concepts developed will be used to inform models of long-term material stability in a generic crystalline rock-hosted repository.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Development and Characterization of 3D-Printed Cementitious Sytems for Innovative Nuclear Systems

The Transformational Challenge Reactor (TCR) is being developed to demonstrate a revolutionary approach to deploying new nuclear power systems by building and operating an additively manufactured microreactor. This initiative provides a unique opportunity to investigate the possibility of taking advantage of the recent development of the 3D-printed concrete system using the Sky Big Area Additive Manufacturing (SkyBAAM) printer at the Manufacturing Demonstration Facility (MDF) at Oak Ridge National Laboratory. Two pathways have been pursued in parallel since the end of the second quarter of FY19: 1. Development of methods to characterize the performance of additive manufacturing concrete using traditional Portland-cement based solution, and 2. Investigation of the opportunity to develop innovation of printable materials with higher irradiation-resistance performance using nontraditional concrete solutions in favor of carbonated cementitious materials (CCMs). This report describes the results achieved to date for both pathways. The main results are listed below: 1. A test protocol has been established to characterize the fracture properties of 3D-printed concrete; this protocol will be used to assess the performance of printed traditional and nontraditional cementitious materials, with a focus on performance of the interfaces inherent to the additive manufacturing process. 2. A state-of-the-art review of the mechanisms, fabrication method, and performance of CCMs was conducted. CCMs appear to be a viable, highly innovative, more performant alternative to Portland-based cementitious solution for the erection of biological shield pending some materials development.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Characterization of Saltstone Grout Line Samples

During a prestart recirculation operation in the Saltstone Processing Facility (SPF), operations staff noticed hardened scaling falling into the hopper. As a result, SPF operators and Saltstone Engineering decided to postpone operation and conduct a process room hopper cleanout. During the cleanout effort personnel noted greater than normal buildup of damp solid material in the transfer line. A borescope investigation was conducted and confirmed buildup was present throughout the transfer line to the downstream valves. Savannah River National Laboratory personnel were asked to characterize the scale material and samples collected from the saltstone grout line and provide recommendations and/or further guidance as to whether additional corrosion testing is needed for useful equipment operating life information. Based on the samples characterized results, the plug material contained only the 60:40 slag:fly ash saltstone. Portland cement in the original 10:45:45 Portland cement:slag:fly ash mix may result in a less abrasive slurry compared to the 60:40 slag:fly ash mix because the slag is > 95 % crushed angular, sharp edged glass. Saltstone grout erosion and corrosion testing of A36 carbon steel is needed to determine if the 60:40 mix is more abrasive and corrosive for A36 carbon steel than the 10:45:45 mix.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

ASSESSMENT OF HIGH-VOLUME HARVESTED FLY ASH BLENDS FOR USE IN PRECAST CONSTRUCTION

Declining supplies of fresh fly ashes in some regions have further driven the importance of using harvested fly ash as a supplementary cementitious material and thus replacement for more energy-intensive ordinary Portland cement (OPC). Higher replacement rates of OPC with fly ash in general has traditionally been limited in precast operations due to stringent early-age strength requirements necessitated by initial prestress and lifting/handling of hardened components – often well within 24 hours after fresh concrete placement. Therefore, a series of mix designs were developed, as part of a larger framework for reassessing high-volume fly ash (HVFA) use in the context of precast construction, to demonstrate the feasibility of using larger fractions of harvested fly ash in concrete formulations suitable for precast fabrication demands. More specifically, a target minimum 24-hour compressive strength of 24.1 MPa (3500 psi) was set, in accordance with conventional precast structural design checks, while increasing the fly ash content to 40% replacement of OPC – at least a 15% increase above the traditional limit of 25%. The effect of using more sustainable Type IL cement in contrast to conventional Type III Portland cement (the traditional standard for precast use) – both in conjunction with HVFA use – was also examined. Early-age mechanical properties including compressive strength, modulus of rupture, and modulus of elasticity were evaluated within the aforementioned early-age window. Lastly, corresponding design equations were then reassessed for their applicability with respect to the high-early strength HVFA mixes examined herein.

Gombeda, Matthew J.↗

LANDSAT 7: Early on-Orbit Results

As this article was being submitted in mid-March, 1999, Landsat 7 had been cleared for an official launch date of April, 15, 1999, approximately 4 - 5 weeks prior to the Portland ASPRS conference. Although it is hoped that the presentation in Portland will be the first public status report on the in-orbit performance of the Landsat 7 spacecraft and the ETM+ instrument, it is impossible to discuss "early on-orbit performance" prior to launch. Therefore, we have chosen to summarize the overarching salient features of the Landsat 7 program, and we will point to some web sites where additional information about the program can be found (e.g., http://geo.arc.nasa.gov/sge/landsat/landsat. html). At this time, the Landsat Project Science Office is pleased to report that the performance of the ETM+ instrument appears to be very good. In addition to excellent instrument performance, a robust data acquisition plan has been developed with the goal of acquiring a seasonally-refreshed archive of global land observations at the EROS Data Center annually. A ground processing system is being implemented at EROS that will be capable of capturing, processing and archiving 250 Landsat scenes per day, and delivering 100 scene products to users each day. The cost of a systematically-processed Level 1 product will be less than $600, and there will be no copyright protection on the data. The net result is that the use of remote sensing data in our daily lives is expected to grow dramatically. This growth is expected to benefit all facets of the land remote sensing community.

Williams, D. L.↗

Application of Interparticle Spacing Model to Maximize Filler Content in Cementitious Pastes

One of the most impactful ways to reduce embodied carbon of concrete in the near term is by partially replacing Portland cement with supplementary cementitious materials and/or fillers. This article describes an approach to reduce cement content in concrete through the development of high filler, low water (HFLW) cementitious pastes. Pastes with cement content as low as 50% (% weight of fines) were designed by applying models that maximize the packing density of the granular system and that consider the characteristics of the materials to calculate interparticle spacing (IPS), thereby allowing to obtain pastes with higher solids concentration and lower water demand. Strong correlations were found between IPS, the consistency index of the Herschel-Bulkley rheological model, and cement hydration kinetic parameters of binary and ternary pastes containing a Portland limestone cement and up to two different types of ground limestone. The approach showed to be feasible for the design of HFLW concrete paste fraction.

Antunes da Silva, Denise↗

GEOPHIRES Simulations for Deep Direct Use (DDU) Projects

This folder contains the GEOPHIRES codes and input files for running the base case scenarios for the six deep direct-use (DDU) projects. The six DDU projects took place during 2017-2020 and were funded by the U.S. Department of Energy Geothermal Technologies Office. They investigated the potential of geothermal deep direct-use at six locations across the country. The projects were conducted by Cornell University, West Virginia University (WVU), University of Illinois (U of IL), Sandia National Laboratory (SNL), Portland State University (PSU), and National Renewable Energy Laboratory (NREL). Four projects (Cornell, WVU, U of IL, SNL) investigated geothermal for direct heating of a local campus or community, the project by PSU considered seasonal subsurface storage of solar heating, and the NREL project investigated geothermal heating for turbine inlet cooling using absorption chillers. To allow comparison of techno-economic results across the six DDU projects, GEOPHIRES simulations were set up and conducted for each project. The GEOPHIRES code was modified for each project to simulate the local application and incorporate project-specific assumptions and results such as reservoir production temperature or financing conditions. The base case input file is included which simulates the base case conditions assumed by each project team. The levelized cost of heat (LCOH) is calculated and matches the base case LCOH reported by the project teams.

15 GEOTHERMAL ENERGY↗

Quantitative Risk Assessment for Fuel Cell Electric Bus Hydrogen Storage and Refueling Facility

It is necessary to understand the safety implications and risk mitigation options for fuel cell electric bus fleet deployment, especially for related facilities responsible for operations such as production, storage, compression, and dispensing of hydrogen for use by the buses. In this report, we present a quantitative risk assessment for a potential fuel cell electric bus fleet that was motivated by efforts to improve resilience at the Portland International Airport but can be applicable to a range of hydrogen case studies and use cases. We estimated risk for a facility that produces, stores, compresses, and dispenses hydrogen for the fleet of buses, with a focus on individual risk to people in terms of annual frequency of fatality. We considered the frequency of hydrogen leaks that could result in harmful physical outcomes like jet fires or explosions, and the consequences of those outcomes for people. We created customized fault trees to calculate the frequencies of different sizes of leaks and event sequence diagrams to calculate ignition probabilities for the various leak sizes. We also leveraged the HyRAM+ toolkit to use these inputs to calculate overall risk for the facility, which we separated into one section responsible for producing, storing, and compressing hydrogen, and one section responsible for dispensing the hydrogen to the buses. We found that the dispensing area seemed to have a higher risk than the production/storage/compression area of the facility, largely because of the inclusion of a component with a high leak frequency (the heat exchanger used to cool the hydrogen before entering the vehicle, to prevent overheating and expansion of hydrogen in the onboard tank). For the example production and refueling facility we evaluated and the data we used for the analysis, the leak frequency had a larger impact on the risk differences between the two sections on the facility, compared to the physical outcome consequence, which was slightly different due to the varying fuel conditions, but not substantially different. Actions can be taken to prevent these hazards (e.g., lowering leak frequencies in system components) or to mitigate the consequences if they do occur (e.g., installing barriers to protect people if ignition events occur). The choice of which actions to take depends not only on safety considerations but also on space, time, staffing, feasibility, and financial constraints. Therefore, the quantitative risk assessment approach can help understand relative risk contributions from different components, leak sizes, consequences, and human actions, to prioritize risk reduction strategies and balance these parameters. The outcomes of this report may be useful for a variety of stakeholders working in the hydrogen, transportation, vehicle, and aviation sector, including those responsible for aspects like facility design, operations, and regulations. There is not a single value of risk that determines whether a hypothetical system is “safe” or not. The insights about risk mitigations may be leveraged, and the quantitative risk assessment approach can be applied to other case studies to understand risk priorities and contributions specific to different FCEB and hydrogen facility uses.

08 HYDROGEN↗