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Observations of Particle Number Size Distributions and New Particle Formation in Six Indian Locations

Atmospheric new particle formation (NPF) is a crucial process driving aerosol number concentrations in the atmosphere; it can significantly impact the evolution of atmospheric aerosol and cloud processes. This study analyses at least 1 year of asynchronous particle number size distributions from six different locations in India. We also analyze the frequency of NPF and its contribution to cloud condensation nuclei (CCN) concentrations. We found that the NPF frequency has a considerable seasonal variability. At the measurement sites analyzed in this study, NPF frequently occurs in March–May (pre-monsoon, about 21 % of the days) and is the least common in October–November (post-monsoon, about 7 % of the days). Considering the NPF events in all locations, the particle formation rate (J_(SDS)) varied by more than 2 orders of magnitude (0.001–0.6 /cu.cm s) and the growth rate between the smallest detectable size and 25 nm (GR_(SDS-25 nm)) by about 3 orders of magnitude (0.2–17.2 nm/h). We found that JSDS was higher by nearly 1 order of magnitude during NPF events in urban areas than mountain sites. GRSDS did not show a systematic difference. Our results showed that NPF events could significantly modulate the shape of particle number size distributions and CCN concentrations in India. The contribution of a given NPF event to CCN concentrations was the highest in urban locations (4.3 × 10^(3) /cu.cm per event and 1.2 × 10^(3)/cu.cm per event for 50 and 100 nm, respectively) as compared to mountain background sites (2.7 × 10^(3)/cu.cm per event and 1.0 × 10^(3)/cu.cm per event, respectively). We emphasize that the physical and chemical pathways responsible for NPF and factors that control its contribution to CCN production require in situ field observations using recent advances in aerosol and its precursor gaseous measurement techniques.

particle number size distributions↗

Low-Flow-Rate Dry-Powder Feeder

Apparatus feeds small, precise flow of dry powder through laser beam of optical analyzer measuring patterns of light created by forward scattering (Fraunhofer diffraction) of laser beam from powder particles. From this optical measurement, statistical distribution of sizes of powder particles computed. Rates of flow optimized for measurement of particle-size distributions. Developed for analyzing particle-size distributions of solid-propellant powders. Also adapted to pharmaceutical industry, in manufacture of metal powder, and in other applications where particle-size distributions of materials used to control rates of chemical reactions and/or physical characteristics of processes.

Ramsey, Keith E.↗

The F and K components of the solar corona.

Numerical calculations of the F component are conducted for a large range of parameters, particle size distribution, minimum particle size, minimum approach to the sun, albedo, and spatial distribution. Various parametrized functional forms for the electron spatial distribution are assumed, and the parametrical elongation dependence of the K component is calculated. New and old data are analyzed by fitting the theoretical parametrized elongation dependence to observations of the total intensity of the solar corona. The orbital behavior of the dust is estimated together with the temperature and thermal emission.

Calbert, R.↗

Determination of Atmospheric Aerosol Characteristics from the Polarization of Scattered Radiation

Aerosols affect the polarization of radiation in scattering, hence measured polarization can be used to infer the nature of the particles. Size distribution, particle shape, real and absorption parts of the complex refractive index affect the scattering. From Lorenz-Mie calculations of the 4-Stokes parameters as a function of scattering angle for various wavelengths the following polarization parameters were plotted: total intensity, intensity of polarization in plane of observation, intensity perpendicular to the plane of observation, polarization ratio, polarization (using all 4-Stokes parameters), plane of the polarization ellipse and its ellipticity. A six-component log-Gaussian size distribution model was used to study the effects of the nature of the polarization due to variations in the size distribution and complex refractive index. Though a rigorous inversion from measurements of scattering to detailed specification of aerosol characteristics is not possible, considerable information about the nature of the aerosols can be obtained. Only single scattering from aerosols was used in this paper. Also, the background due to Rayleigh gas scattering, the reduction of effects as a result of multiple scattering and polarization effects of possible ground background (airborne platforms) were not included.

Harris, F. S., Jr.↗

High-Resolution Simulation of Hurricane Bonnie (1998): Microphysics Validation using TRMM Data

A simulation of Hurricane Bonnie (1998) has been performed using multiple grid nesting to 2 km grid spacing. The simulation is initialized with large-scale analysis fields from the European Center for Medium Range Forecasts and with a bogus vortex inserted via four-dimensional variational data assimilation. The simulation reproduces well the storm intensity, the wavenumber 1 asymmetry of the precipitation field, the occurrence of deep convective towers within the eyewall, and the presence of broad stratiform precipitation regions. Radar and microwave observations from TRMM are used to validate the simulation. Result show excessive graupel production and, to some extent, excessive precipitation production in general by the model. Additional simulations are conducted (and validated by TRMM data) to test parameters and assumptions within the microphysics parameterizations including particle size distributions, particle densities, and assumptions that impact the partitioning of precipitation mass between graupel and snow.

Starr, David OC.↗

Aeronomy of Ice in the Mesosphere (AIM)

The overall goal of the Aeronomy of Ice in the Mesosphere (AIM) experiment is to resolve why Polar Mesospheric Clouds form and why they vary. By measuring PMCs and the thermal, chemical and dynamical environment in which they form, we will quanti@ the connection between these clouds and the meteorology of the polar mesosphere. In the end, this will provide the basis for study of long-term variability in the mesospheric climate and its relationship to global change. The results of AIM will be a rigorous validation of predictive models that can reliably use past PMC changes and present trends as indicators of global change. The AIM goal will be achieved by measuring PMC extinction, brightness, spatial distribution, particle size distributions, gravity wave activity, dust influx to the atmosphere and precise, vertical profile measurements of temperature, H20, C&, 0 3 , C02, NO. and aerosols. These data can only be obtained by a complement of instruments on an orbiting spacecraft (S/C).

Source record↗

Analysis of Lunar Highland Regolith Samples From Apollo 16 Drive Core 64001/2 and Lunar Regolith Simulants - an Expanding Comparative Database

This slide presentation reviews the work to analyze the lunar highland regolith samples that came from the Apollo 16 core sample 64001/2 and simulants of lunar regolith, and build a comparative database. The work is part of a larger effort to compile an internally consistent database on lunar regolith (Apollo Samples) and lunar regolith simulants. This is in support of a future lunar outpost. The work is to characterize existing lunar regolith and simulants in terms of particle type, particle size distribution, particle shape distribution, bulk density, and other compositional characteristics, and to evaluate the regolith simulants by the same properties in comparison to the Apollo sample lunar regolith.

Schrader, Christian M.↗

Figure of Merit Characteristics Compared to Engineering Parameters

A workshop held in 2005 defined a large number of parameters of interest for users of lunar simulants. The need for formal requirements and standards in the manufacture and use of simulants necessitates certain features of measurements. They must be definable, measureable, useful, and primary rather than derived. There are also certain features that must be avoided. Analysis of the total parameter list led to the realization that almost all of the parameters could be tightly constrained, though not predicted, if only four properties were measured: Particle composition, particle size distribution, particle shape distribution, and bulk density. These four are collectively referred to as figures of merit (FoMs). An evaluation of how each of the parameters identified in 2005 is controlled by the four FoMs is given.

Rickman, D.L.↗

Lunar Regolith Simulant User's Guide

Based on primary characteristics, currently or recently available lunar regolith simulants are discussed from the perspective of potential experimental uses. The characteristics used are inherent properties of the material rather than their responses to behavioral (geomechanical, physiochemical, etc.) tests. We define these inherent or primary properties to be particle composition, particle size distribution, particle shape distribution, and bulk density. Comparable information about lunar materials is also provided. It is strongly emphasized that anyone considering either choosing or using a simulant should contact one of the members of the simulant program listed at the end of this document.

Schrader, C. M.↗

Figures of Merit Software: Description, User's Guide, Installation Notes, Versions Description, and License Agreement

Figures of Merit (FoMs) and the FoM software provide a method for quantitatively evaluating the quality of a regolith simulant by comparing the simulant to a reference material. FoMs may be used for comparing a simulant to actual regolith material, specification by stating the value a simulant s FoMs must attain to be suitable for a given application and comparing simulants from different vendors or production runs. FoMs may even be used to compare different simulants to each other. A single FoM is conceptually an algorithm that computes a single number for quantifying the similarity or difference of a single characteristic of a simulant material and a reference material and provides a clear measure of how well a simulant and reference material match or compare. FoMs have been constructed to lie between zero and 1, with zero indicating a poor or no match and 1 indicating a perfect match. FoMs are defined for modal composition, particle size distribution, particle shape distribution, (aspect ratio and angularity), and density. This TM covers the mathematics, use, installation, and licensing for the existing FoM code in detail.

hoelzer, H. D.↗

Martian and Asteroid Dusts as Toxicological Risks for Human Exploration Missions

As the lunar dust toxicity project winds down, our attention is drawn to the potential toxicity of dust present at the surface of more distant celestial objects. Lunar dust has proven to be surprisingly toxic to the respiratory systems of test animals, so one might expect dust from other celestial bodies to hold toxicological surprises for us. At this point all one can do is consider what should be known about these dusts to characterize their toxicity, and then ask to what extent that information is known. In an ideal world it might be possible to suggest an exposure standard based on the known properties of a celestial dust without direct testing of the dust in laboratory animals. Factors known to affect the toxicity of mineral dusts under some conditions include the following: particle size distribution, particle shape/porosity, mineralogical properties (crystalline vs. amorphous), chemical properties and composition, and surface reactivity. Data from a recent Japanese mission to the S-type asteroid Itokawa revealed some surprises about the dust found there, given that there is only a very week gravitational field to hold the dust on the surface. On Mars the reddish-brown dust is widely distributed by global dust storms and by local clusters of dust devils. Past surface probes have revealed some of the properties of dust found there. Contemporary data from Curiosity and other surface probes will be weighed against the data needed to set a defensible safe exposure limit. Gaps will emerge.

James, John T.↗

An Engineering Guide to Lunar Geotechnical Properties

The renewed interest in returning human and robotic explorers to the lunar surface has identified a need for a renewed understanding of lunar geotechnical properties related to landing, exploration, excavation, and construction activities on the lunar surface. This paper summarizes measurements conducted during US and Russian/Soviet landed missions as well as experiments performed on returned samples to establish fundamental geotechnical properties such as particle size distribution, particle shape, bulk density, shear strength, cohesion and bearing strength. While many of these properties are well known, how they vary with increased lunar soil depth is less understood, and those properties that vary significantly as a function of depth are explored in additional detail. Selected examples discuss mechanical excavation forces, rocket exhaust erosion forces, and the preparation of launch/landing pad surfaces, with the goal of a better understanding of lunar soil geotechnical properties that apply to large-scale exploration of the lunar surface and dictate the design of future exploration systems.

Lunar Soil↗

Quantitative Characterization of Lunar Regolith Simulants for Direct Comparison to Apollo Soil Samples

Introduction: Sustained characterization efforts of lunar regolith simulant properties are not only integral for verification of commercially-produced material designed for a wide array of testing applications but are also necessary in establishing a comprehensive comparison to a lunar reference source. As a resource for the lunar science and engineering communities, the Simulant Development Lab (SDL) within the Astromaterials Research & Exploration Science (ARES) division at the Johnson Space Center (JSC) is actively pursuing closure of existing knowledge gaps in fundamental simulant attributes, including chemistry, mineralogy, particle size distribution, particle geometry, bulk and relative density, magnetic susceptibility, and shear strength (i.e., cohesion and angle of internal friction), as well as producing Figures of Merit for comparison of lunar simulants to Apollo regolith samples.

R. Kovtun↗

3d Particle Geometry Characterization of Apollo Regolith Samples Via Laser Diffraction and Dynamic Image Analysis

Establishing a fundamental understanding of regolith mechanics hinges on the characterization of the foundational physical parameters that dictate granular particle interactions both on micro- and macro-scales. Specifically, particle size distribution, particle geometry and grain density govern the geotechnical properties, including compressibility, shear strength, hydraulic conductivity (i.e., permeability), void ratio (i.e., porosity), and thermal conductivity of the lunar regolith. The absence of terrestrial geologic processes on the lunar surface, a lack of water, clay minerals, and organic material in lunar soils, and the narrow compositional range in terms of mineral diversity of the regolith produces a unique problem when attempting to project terrestrial soil mechanics concepts to the lunar surface. Additionally, the occurrence of agglutinates, exclusive to the lunar surface, further disassociates the physical behavior (e.g., particle crushability, flowability, etc.) of regolith from that observed in terrestrial soils.

R. Kovtun↗

Particle Size Effects on Flow Properties of PS304 Plasma Spray Feedstock Powder Blend

The effects of BaF2-CaF2 particle size and size distribution on PS304 feedstock powder flowability have been investigated. Angular BaF2-CaF2 eutectic powders were produced by comminution and classified by screening to obtain 38 to 45 microns 45 to 106 microns, 63 to 106 microns, 45 to 53 microns, 63 to 75 microns, and 90 to 106 microns particle size distributions. The fluorides were added incrementally from 0 to 10 wt% to the other powder constituents of the PS304 feedstock: nichrome, chromia, and silver powders. The flow rate of the powder blends decreased linearly with increasing concentration of the fluorides. Flow was degraded with decreasing BaF2-CaF2 particle size and with increasing BaF2-CaF2 particle size distribution. A semiempirical relationship is offered to describe the PS304 powder blend flow behavior. The Hausner Ratio confirmed the funnel flow test results, but was slightly less sensitive to differences in BaF2-CaF2 particle size and size distribution. These findings may have applicability to other powders that do not flow easily, such as ceramic powders.

Stanford, Malcolm K.↗

Cirrus microphysics and infrared radiative transfer: A case study

Coincident measurements of cirrus cloud microphysical properties such as particle size distribution and particle shape and morphology, and measurements of infrared intensity and flux were made. Data was acquired nearly simultaneously in space and time by a KingAir in cloud and by an ER-2 at an altitude of 19 km. Upwelling infrared intensities and fluxes measured from the ER-2 and observations of cloud particle size distributions and particle phase and morphology made from the KingAir are discussed. Broad-band flux measurements were available both in and below the cirrus layer from the KingAir.

Ackerman, Thomas P.↗

Cloud Uniformity Measurement from NASA's 2nd Fundamental Ice Crystal Icing Test Part 1 (Water Content & PSD)

This paper presents water content and particle measurements from the second Fundamental Ice Crystal Icing Physics test conducted in the NASA Propulsion Systems Laboratory. The water content measurements came from the Science Engineering Associates Multi-Element Probe and the Isokinetic Probe whereas the Artium Technologies, Inc. Phase Doppler Interferometer and High Speed Imaging instruments measured the particle size distribution. Ice particle accretion due to the ingestion of ice-crystals is attributed to numerous jet engine powerloss events. The NASA PSL is an altitude jet-engine test facility which has recently added a capability to inject ice particles into the flow. This work focuses on characterizing the icing cloud by traversing the instruments across the test section at four different conditions where velocity and water content were varied. For this test, the nozzle patterns were selected to make a uniform cloud in the center 6-inch diameter of the test section. Radial trends for the ice and water content measurements are presented and the melt ratio is calculated at the measurement locations. Particle size distributions are also presented. The measured water content, melt ratio, and particle size decreased moving out radially. Measured water content trends show uniformity to within 19.2% for the center 6 inches of the cloud, as intended. In addition, the total water content increased at centerline with velocity, whereas the melt ratio decreased.

Ice-Crystal Icing↗

Cloud Uniformity Measurements from NASA's 2nd Fundamental Ice Crystal Icing Test Part 1 (Water Content & PSD)

This paper presents water content and particle measurements from the second Fundamental Ice Crystal Icing Physics test conducted in the NASA Propulsion Systems Laboratory. The water content measurements came from the Science Engineering Associates Multi-Element Probe and the Isokinetic Probe whereas the Artium Technologies, Inc. Phase Doppler Interferometer and High Speed Imaging instruments measured the particle size distribution. Ice particle accretion due to the ingestion of ice-crystals is attributed to numerous jet engine powerloss events. The NASA PSL is an altitude jet-engine test facility which has recently added a capability to inject ice particles into the flow. This work focuses on characterizing the icing cloud by traversing the instruments across the test section at four different conditions where velocity and water content were varied. For this test, the nozzle patterns were selected to make a uniform cloud in the center 6-inch diameter of the test section. Radial trends for the ice and water content measurements are presented and the melt ratio is calculated at the measurement locations. Particle size distributions are also presented. The measured water content, melt ratio, and particle size decreased moving out radially. Measured water content trends show uniformity to within 19.2% for the center 6 inches of the cloud, as intended. In addition, the total water content increased at centerline with velocity, whereas the melt ratio decreased.

Ice-Crystal Icing↗