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Bandgap closure and reopening in CsAuI[subscript 3] at high pressure
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Anomalous density and elastic properties of basalt at high pressure: Reevaluating of the effect of melt fraction on seismic velocity in the Earth's crust and upper mantle
Independent measurements of the volumetric and elastic properties of Columbia River basalt glass were made up to 5.5 GPa by high-pressure X-ray microtomography and GHz-ultrasonic interferometry, respectively. The Columbia River basalt displays P and S wave velocity minima at 4.5 and 5 GPa, respectively, violating Birch’s law. These data constrain the pressure dependence of the density and elastic moduli at high pressure, which cannot be modeled through usual equations of state nor determined by stepwise integrating the bulk sound velocity as is common practice. We propose a systematic variation in compression behavior of silicate glasses that is dependent on the degree of polymerization and arises from the flexibility of the aluminosilicate network. Likewise, this behavior likely persists into the liquid state for basaltic melts resulting in weak pressure dependence for P wave velocities perhaps to depths of the transition zone. By modeling the effect of partial melt on P wave velocity reductions it is suggested that melt fraction determined by seismic velocity variations may be significantly overestimated in the crust and upper mantle.
Measurements of CO 2 ‐brine relative permeability in Berea sandstone using pressure taps and a long core
Abstract We measured CO 2 ‐brine relative permeability by performing five steady‐state primary drainage experiments in a 116 mD Berea sandstone core at 20°C and 10.34 MPa. We used a long (60.8 cm) core and four pressure taps to study and minimize end effects that can plague CO 2 ‐brine relative permeability measurements, and we obtained in situ saturation profiles using a medical X‐ray Computed Tomography (CT) scanner. We found that entrance and exit effects propagated ∼5 cm into the core, but the center sections of the core had uniform saturation. From the saturations and pressure drops, we obtained both CO 2 and brine relative permeability in the center sections. We also obtained CO 2 relative permeability at the entrance section where the brine saturation was lower and not uniform. The 15‐cm long exit section of the core had non‐uniform saturation and a measured pressure drop that was on the order of the capillary pressure and hence was unreliable for calculating relative permeability. We found that the CO 2 and brine relative permeabilities determined in five experiments were consistent with each other and followed two simple Corey‐type models that are similar to those seen in oil‐brine relative permeability measurements. We discuss why end effects are much greater in the CO 2 ‐brine system than in oil‐brine systems, and how this is a possible explanation of the low CO 2 relative permeabilities recently reported for the CO 2 ‐brine systems. © 2016 Society of Chemical Industry and John Wiley & Sons, Ltd.
Pressure induced metallization with absence of structural transition in layered molybdenum diselenide
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Pressure-induced polymerization in substituted acetylenes
A fundamental understanding of shock-induced chemical reactions in organics is still lacking and there are limited studies devoted to determining reaction mechanisms, evolution of bonding, and effect of functional group substitutions. The fast timescale of reactions occurring during shock compression create significant experimental challenges (diagnostics) to fully quantify the mechanisms involved. Static compression combined with temperature provides a complementary route to investigate the equilibrium phase space and metastable intermediates under extreme P-T conditions. In this study, we present our results from our ongoing high pressure in situ synchrotron x-ray diffraction experiments on substituted acetylenes: tert-butyl acetylene [TBA: (CH{sub 3}){sub 3}-C=CH] and ethynyl trimethylsilane [ETMS: (CH{sub 3}){sub 3}-SiC=CH]. We observed that the onset pressure of chemical reactions (at room temperature) in these compounds is higher under static compression (TBA: 12 GPa and ETMS: 17.6 GPa) when compared to shock input pressures (TBA: 6.1 GPa and ETMS: 6.6 GPa). At elevated temperatures, reactivity was observed to occur at pressures comparable to shock conditions. The products were polymeric in nature, recovered to ambient conditions with little degradation.
The stress state in bismuth to 298 GPa and its use as a pressure transmitting medium and pressure marker at multi-megabar pressures
We have conducted diffraction studies of bismuth (Bi) to 298 GPa using both conventional and toroidal diamond anvil cells (DACs) to investigate its suitability as a pressure-transmitting medium (PTM) to such pressures. Using microfocused x-ray beams, we have determined the pressure dependence of the uniaxial stress component (t) in cubic Bi-V from 7 to 298 GPa and find that at 298 GPa, t < 0.5 GPa. Bi-V, therefore, cannot support significant shear stresses, making it an excellent PTM. We have also measured the compressibility of Bi-V against that of copper (Cu) and gold (Au), allowing it to be used as a pressure marker as well as a PTM.
High-pressure EXAFS measurements of crystalline Ge using nanocrystalline diamond anvils
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Direct probe of Fermi surface evolution across a pressure-induced quantum phase transition
Not Available
The Structural Transition Behavior of CdSe/ZnS Core/shell Quantum Dots under High Pressure
The structural phase transition of CdSe/ZnS core/shell quantum dots (QDs) has been studied by in situ angle-dispersive X-ray diffraction under high pressure up to 53.6?GPa. The CdSe core transforms from wurtzite to rock-salt structure near 6.3?GPa and then to Cmcm or distorted Cmcm structure probably occurs at 45.1?GPa which has not been observed in CdSe nanomaterials before. The critical pressure from wurtzite to rock-salt and the bulk modulus of rock-salt phase are much higher than those for bulky and uncapped nanoparticle CdSe. The released sample can be kept in rock-salt phase for a certain time, verified by photoluminescence (PL) spectra, quite different from the reversible transition for pure CdSe. A reasonable interpretation of the experimental phenomena is given by comparing the bulk modulus of the core and shell and studying the stress sate of the core after decompression. Our study suggests that capping a hard shell is an effective approach to quench the high pressure phase of nanomaterial with a reversible phase transition.
Structure Stability of Methane Hydrate at High Pressures
The structural stability of methane hydrate under pressure at room temperature was examined by both in-situ single-crystal and powder X-ray diffraction techniques on samples with structure types I, II, and H in diamond-anvil cells. The diffraction data for types II (sII) and H (sH) were refined to the known structures with space groups Fd3m and P6{sub 3}/mmc, respectively. Upon compression, sI methanehydrate transforms to the sII phase at 120 MPa, and then to the sH phase at 600 MPa. The sII methanehydrate was found to coexist locally with sI phase up to 500 MPa and with sH phase up to 600 MPa. The pure sH structure was found to be stable between 600 and 900 MPa. Methanehydrate decomposes at pressures above 3 GPa to form methane with the orientationally disordered Fm3mstructure and ice VII (Pn3m). The results highlight the role of guest (CH{sub 4})-host (H{sub 2}O) interactions in the stabilization of the hydratestructures under pressure.
Shear-driven instability in zirconium at high pressure and temperature and its relationship to phase-boundary behaviors
Not Available
High-Pressure Raman and Infrared Spectroscopic Study of Prehnite
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