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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Indoor air quality in new and renovated low-income apartments with mechanical ventilation and natural gas cooking in California

This work presents pollutant concentrations and performance data for code-required mechanical ventilation equipment in 23 low-income apartments at 4 properties constructed or renovated 2013-2017. All apartments had natural gas cooking burners. Occupants pledged to not use windows for ventilation during the study but several did. Measured airflows of range hoods and bathroom exhaust fans were lower than product specifications. Only eight apartments operationally met all ventilation code requirements. Pollutants measured over one week in each apartment included time-resolved fine particulate matter (PM 2.5 ), nitrogen dioxide (NO 2 ), formaldehyde and carbon dioxide (CO 2 ) and time-integrated formaldehyde, NO 2 and nitrogen oxides (NO X ). Compared to a recent study of California houses with code-compliant ventilation, apartments were smaller, had fewer occupants, higher densities, and higher mechanical ventilation rates. Mean PM 2.5 , formaldehyde, NO 2 , and CO 2 were 7.7 µg/m 3 , 14.1 ppb, 18.8 ppb, and 741 ppm in apartments; these are 4% lower, 25% lower, 165% higher, and 18% higher compared to houses with similar cooking frequency. Four apartments had weekly PM 2.5 above the California annual outdoor standard of 12 µg/m 3 and also discrete days above the World Health Organization 24-h guideline of 25 µg/m 3 . Two apartments had weekly NO 2 above the California annual outdoor standard of 30 ppb.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2025

Detection limits for laser absorption spectroscopy of Li in laser ablation plumes

A high-sensitivity laser absorption spectroscopy (LAS) method is demonstrated for rapid and non-contact analysis of Li in solids. Glass samples with Li concentrations ranging from 1-500 ppm by mass are ablated in 5 Torr air, and time-resolved Li atomic absorption is measured using a tunable laser near 671 nm. Significant improvements in analytical performance over prior laser-induced breakdown techniques are demonstrated. Here, a single-shot limit of detection (LOD) of 180 ppb is shown for fixed wavelength operation, improving to 6 ppb with averaging over 1000 ablation shots (100 s acquisition time). Isotope-resolved Li absorption spectra are measured with a 17 ppb LOD in 40 s. Methods for optimizing LOD based on noise/averaging properties of LAS experiments in LA plumes are discussed.

(020.3260) Isotope shifts↗
DOE OSTI2023

Low ozone dry deposition rates to sea ice during the MOSAiC field campaign: Implications for the Arctic boundary layer ozone budget

Dry deposition to the surface is one of the main removal pathways of tropospheric ozone (O 3 ). We quantified for the first time the impact of O 3 deposition to the Arctic sea ice on the planetary boundary layer (PBL) O 3 concentration and budget using year-round flux and concentration observations from the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) campaign and simulations with a single-column atmospheric chemistry and meteorological model (SCM). Based on eddy-covariance O 3 surface flux observations, we find a median surface resistance on the order of 20,000 s m –1 , resulting in a dry deposition velocity of approximately 0.005 cm s –1 . This surface resistance is up to an order of magnitude larger than traditionally used values in many atmospheric chemistry and transport models. The SCM is able to accurately represent the yearly cycle, with maxima above 40 ppb in the winter and minima around 15 ppb at the end of summer. However, the observed springtime ozone depletion events are not captured by the SCM. In winter, the modelled PBL O 3 budget is governed by dry deposition at the surface mostly compensated by downward turbulent transport of O 3 towards the surface. Advection, which is accounted for implicitly by nudging to reanalysis data, poses a substantial, mostly negative, contribution to the simulated PBL O 3 budget in summer. During episodes with low wind speed (<5 m s –1 ) and shallow PBL (<50 m), the 7-day mean dry deposition removal rate can reach up to 1.0 ppb h –1 . Our study highlights the importance of an accurate description of dry deposition to Arctic sea ice in models to quantify the current and future O 3 sink in the Arctic, impacting the tropospheric O 3 budget, which has been modified in the last century largely due to anthropogenic activities.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Measurement of the Kicker transient magnetic field in the Muon g-2 Experiment at Fermilab

The Muon g-2 experiment at Fermilab has the main goal to measure the muon anomalous magnetic moment $a_µ = \frac{g−2}{2}$ to a precision of 140 parts per billion (ppb), which means 4 times improvement in precision with respect to the final result from BNL: a µ (expt.B N L) = 11659208.0(6.3)×10 −10 (540 ppb) So far only RUN1 data have been analyzed showing the following improvement: a µ (expt.RU N1) = 116592061×10 −11 (465 ppb) In this report I summarize the work done at the g-2 experiment during my summer internship at Fermilab where I worked on the attempt to estimate the kicker transient field contribution in the Muon g-2 experiment.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2024

Muon g-2 experiment and future muon experiments

The Muon g-2 experiment at Fermilab aims to measure the muon anomalous magnetic moment, $a_{\mu}$, with a final precision of 140 part per billions (ppb). The first results from the Run-1 dataset were released on April 7, 2021, showing a very good agreement with the previous experimental result at Brookhaven National Laboratory (BNL) [1]. In light of the new theoretical calculation of the hadron vacuum polarization contribution of $a_{\mu}$ by the BMW group using the Lattice QCD, a strong tension arose within the theoretical side. Here we discuss this high precision measurement and the current work towards a new result, Run-2/3 analysis, on the muon anomaly that aims to reach a statistical uncertainty of 200 ppb and a systematic uncertainty of 70 ppb. Furthermore, a brief overview of other muon experiments will be given.

Bottalico, Elia↗
DOE OSTI2023

Reconstructing atmospheric H 2 over the past century from bi-polar firn air records

Abstract. Historical atmospheric H2 levels were reconstructed using firn air measurements from two sites in Greenland (NEEM and Summit) and two sites in Antarctica (South Pole and Megadunes). A joint reconstruction based on the two Antarctic sites yields H2 levels monotonically increasing from about 330 ppb in 1900 to 550 ppb in the late 1990s, leveling off thereafter. These results are similar to individual reconstructions published previously (Patterson et al., 2020, 2021). Interpretation of the Greenland firn air measurements is complicated by challenges in modeling enrichment induced by pore close-off at these sites. We used observations of neon enrichment at NEEM and Summit to tune the parameterization of enrichment induced by pore close-off in our firn air model. The joint reconstruction from the Greenland data shows H2 levels rising 30 % between 1950 and the late 1980s, reaching a maximum of 530 ppb. After 1990, reconstructed atmospheric H2 levels over Greenland are roughly constant, with a small decline of 3 % over the next 25 years. The reconstruction shows good agreement with the available flask measurements of H2 at high northern latitudes.

Geology↗
DOE OSTI2023

AMORE-Isoprene v1.0: a new reduced mechanism for gas-phase isoprene oxidation

Abstract. Gas-phase oxidation of isoprene by ozone (O3) and the hydroxyl (OH) and nitrate (NO3) radicals significantly impacts tropospheric oxidant levels and secondary organic aerosol formation. The most comprehensive and up-to-date chemical mechanism for isoprene oxidation consists of several hundred species and over 800 reactions. Therefore, the computational expense of including the entire mechanism in large-scale atmospheric chemical transport models is usually prohibitive, and most models employ reduced isoprene mechanisms ranging in size from ∼ 10 to ∼ 200 species. We have developed a new reduced isoprene oxidation mechanism using a directed-graph path-based automated model reduction approach, with minimal manual adjustment of the output mechanism. The approach takes as inputs a full isoprene oxidation mechanism, the environmental parameter space, and a list of priority species which are protected from elimination during the reduction process. Our reduced mechanism, AMORE-Isoprene (where AMORE stands for Automated Model Reduction), consists of 12 species which are unique to the isoprene mechanism as well as 22 reactions. We demonstrate its performance in a box model in comparison with experimental data from the literature and other current isoprene oxidation mechanisms. AMORE-Isoprene's performance with respect to predicting the time evolution of isoprene oxidation products, including isoprene epoxydiols (IEPOX) and formaldehyde, is favorable compared with other similarly sized mechanisms. When AMORE-Isoprene is included in the Community Regional Atmospheric Chemistry Multiphase Mechanism 1.0 (CRACMM1AMORE) in the Community Multiscale Air Quality Model (CMAQ, v5.3.3), O3 and formaldehyde agreement with Environmental Protection Agency (EPA) Air Quality System observations is improved. O3 bias is reduced by 3.4 ppb under daytime conditions for O3 concentrations over 50 ppb. Formaldehyde bias is reduced by 0.26 ppb on average for all formaldehyde measurements compared with the base CRACMM1. There was no significant change in computation time between CRACMM1AMORE and the base CRACMM. AMORE-Isoprene shows a 35 % improvement in agreement between simulated IEPOX concentrations and chamber data over the base CRACMM1 mechanism when compared in the Framework for 0-D Atmospheric Modeling (F0AM) box model framework. This work demonstrates a new highly reduced isoprene mechanism and shows the potential value of automated model reduction for complex reaction systems.

58 GEOSCIENCES↗
DOE OSTI2024

EPCAPE-PT-LANL Measurements: NO/NOx Analyzer

Coastal cities offer a unique environment for studying aerosol-cloud interactions and the effects of urban emissions on cloud properties. As part of the Eastern Pacific Cloud Aerosol Precipitation Experiment (EPCAPE), the Partitioning Thrust by Los Alamos National Laboratory (EPCAPE-PT-LANL) was conducted. Our campaign focused on measuring the optical and chemical properties of aerosols and their interactions within marine stratocumulus clouds in La Jolla, California. EPCAPE-PT-LANL enhances the primary goals of EPCAPE through innovative observations of vapor-phase transitions between aerosols and cloud droplets, the impact of black carbon on aerosol-cloud dynamics, and the effects of cloud processing on aerosol optical properties. Instrument: NO2/NO/NOx Monitor (2B-Technology) Header: - NO2_2B[ppb]: Concentration of nitrogen dioxide (NO2) measured at the time of the sampling, expressed in parts per billion. - NO_2B[ppb]: Concentration of nitric oxide (NO) measured at the time of the sampling, expressed in parts per billion. - NOx_2B[ppb]: Total concentration of nitrogen oxides (NOx, which includes NO and NO2) measured at the time of the sampling, expressed in parts per billion.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1972

Rare-gas analyses on neutron irradiated Apollo 12 samples.

Argon, krypton, and xenon from stepwise heating of five Apollo 12 rocks that had been irradiated to a neutron fluence of about 10 to the 19th neutrons/sq cm were analyzed mass-spectrometrically. The Ar40-Ar39 ages were determined and range from 3.18 plus or minus 0.06 x 10 to the 9th years to 3.32 plus or minus 0.06 x 10 to the 9th years. Trace elements Ba, Br, I, and U were measured via the neutron-induced reactions that produce isotopes of krypton and xenon. The following concentration ranges were observed: Ba, 46 to 70 ppm; Br, 48 to 146 ppb; I, 16 to 73 ppb; and U, 170 to 247 ppb.

Alexander, E. C., Jr.↗
NASA NTRS1976

Remote sensing of atmospheric SO2 using the differential absorption LIDAR technique

The paper reports an investigation of the capabilities of a UV differential absorption lidar (DIAL) system for remote measurements of sulfur dioxide emissions. Two features of the present DIAL system are an absorption cell permitting the determination of the difference in SO2 absorption coefficients for the two transmitted wavelengths and a calibration cell permitting the linearity and performance of the system to be evaluated. The DIAL technique is described along with the transmitter, receiver, data-adquisition, and data-processing components of the investigated system. Quantitative measurements of the average SO2 concentration in a region surrounding the exhaust stack of a steam-generating plant are discussed which show that the present system has measurement sensitivities of 10 ppb at a range of 0.8 km and 20 ppb at 1.9 km. Based on performance characteristics obtained during a calibration of this system, it is predicted that a measurement sensitivity of less than 4 ppb over a 1-km path will be attained.

Hoell, J. M., Jr.↗
NASA NTRS1977

Atomic and molecular fluorescence as a stratospheric species monitor

The results of an investigation are presented evaluating the potential of atomic and molecular fluorescence as a stratospheric monitor of the concentrations of any one of 18 minor species: Cl, Cl2, ClO, ClO2, CO, H2, HCHO, HCl, HNO2, HNO3, H2S, NH3, NO, NO2, N2O, O, OH, and SO2. All spectral regions from the vacuum ultraviolet through the infrared were included. It was found that suitable systems can be constructed for the stratospheric monitoring of CO (5 ppb), NO2 (less than 1 ppb), OH (0.2 ppt), and O (50-200 ppt). The fluorescence sensitivities for Cl (0.5-1.0 ppt), H2 (0.2 ppm at 10 torr) and SO2 (1-10 ppb) are marginally insufficient with current technology.

Schofield, K.↗
NASA NTRS1981

Krypton and xenon in the atmosphere of Venus

The paper reports a determination by the Pioneer Venus large probe neutral mass spectrometer of upper limits to the concentration of krypton and xenon along with most of their isotopes in the atmosphere of Venus. The upper limit to the krypton mixing ratio is estimated at 47 ppb, with a very conservative estimate at 69 ppb. The probable upper limit to the sum of the mixing ratios of the isotopes Xe-128, Xe-129, Xe-130, Xe-131, and Xe-132 is 40 ppb by volume, with a very conservative upper limit three times this large.

Donahue, T. M.↗
NASA NTRS1984

Measurements of free tropospheric ozone - An aircraft survey from 44 degrees north to 46 south latitude

Ozone data were obtained in the free troposphere at altitudes of 5 to 7.5 km and at latitudes from 44 degrees N to 46 degrees S during a 3-week period from October 19 to November 4, 1982. Flight trajectories included the continental U.S., Central America, and the western coast of South America. Maximum observed ozone was 110 ppb at about 41 degrees S latitude and at an altitude of 7.3 km (msl). Analysis of the data as a function of latitude showed a region of elevated ozone in the southern latitudes extending from about 2 degrees to 30 degrees in which latitudinal ozone averages (2 degree bands) peaked at about 80 ppb. Ozone concentrations, measured at northern latitudes, were lower, averaging about 35 ppb. A discussion of the data, including comparison with other ozone data sets, is presented.

Gregory, G. L.↗
NASA NTRS1985

Laser remote sensing of atmospheric ammonia using a CO2 lidar system

A CO2 differential-absorption lidar system has been used for the remote sensing of ammonia in the atmosphere. For CO2 lidar returns backscattered from topographic targets at ranges up to 2.7 km, the path-averaged sensitivity of the DIAL system was 5 ppb of NH3. Concentrations of atmospheric ammonia were found to vary during the day from undetectable levels (less than 5 ppb) to as high as 20 ppb, depending on temperature and humidity conditions.

Force, A. P.↗
NASA NTRS1988

Mineralogy and phase-chemistry of the Cretaceous/Tertiary section in the Lattengebirge, Bavarian Alps

The Lattengebirge K/T section reveals three distinct Ir spikes. Two of them are contained in the K/T transition zone sensu-strictu termed clayey interval, with 4.4 ppb Ir at the actual K/T boundary, and 2.8 ppb Ir 10 cm above the boundary. The highest Ir enrichment of 9 ppb, however, was detected in semi-cleaned organic material from a thin sandstone layer of Upper Maastrichtian age at 16 cm below the boundary. In this layer various discernible phases are preserved, contrasting with the worldwide observed K/T transition zones which are generally entirely composed of diagenetically altered materials. Given that, important clues to understanding the Cretaceous terminal events may be provided. The phases of the Cretaceous Ir bearing layer at Lattengebirge consist of: sandstone fragmental minerals in a carbonate matrix, coal which is partly burnt, melt glasses presumably of combustion-metamorphic origin, and sulfides, mainly chalcopyrite, contained in the coal. Like many known K/T sections and the Lattengebirge boundary sensu-strictu, the Cretaceous horizon is enriched in Ir and chalcophile elements as well. Although the Lattengebirge section offers the freshest materials, including melt glasses, of all K/T localities investigated, no unequivocal evidence of formation by impact has been found there.

Graup, G.↗
NASA NTRS1990

International Ultraviolet Explorer observations of Venus SO2 and SO

Results of recent International Ultraviolet Explorer observations of Venus made on January 20, 1987 and April 2 and 3, 1988 are presented along with a reanalysis of the 1979 observations (Conway et al., 1979). The observations indicate that the amount of sulfur dioxide at the cloud tops of Venus declined by a factor of 8 + or - 4 from 380 + or - 70 ppb in 1979 to 50 + or - 20 ppb in 1987 and 1988. These values are consistent with the Pioneer Venus results. Absorption features of sulfur monoxide are identified for the first time, and the SO mixing ratio above the cloud level is estimated to be 20 + or - 10 ppb for 1979. This is consistent with photochemical models by Winick and Stewart (1980) and Yung and DeMore (1982) and with the upper limit from Wilson et al. (1981).

Na, Chan Y.↗
NASA NTRS1995

VRA Modeling, phase 1

The destruction of organic contaminants in waste water for closed systems, such as that of Space Station, is crucial due to the need for recycling the waste water. A co-current upflow bubble column using oxygen as the gas phase oxidant and packed with catalyst particles consisting of a noble metal on an alumina substrate is being developed for this process. The objective of this study is to develop a plug-flow model that will predict the performance of this three phase reactor system in destroying a multicomponent mixture of organic contaminants in water. Mass balances on a series of contaminants and oxygen in both the liquid and gas phases are used to develop this model. These mass balances incorporate the gas-to-liquid and liquid-to-particle mass transfer coefficients, the catalyst effectiveness factor, and intrinsic reaction rate. To validate this model, a bench scale reactor has been tested at Michigan Technological University at elevated pressures (50-83 psig,) and a temperature range of 200 to 290 F. Feeds consisting of five dilute solutions of ethanol (approx. 10 ppm), chlorobenzene (approx. 20 ppb), formaldehyde (approx. 100 ppb), dimethyl sulfoxide (DMSO approx. 300 ppb), and urea (approx. 20 ppm) in water were tested individually with an oxygen mass flow rate of 0.009 lb/h. The results from these individual tests were used to develop the kinetic parameter inputs necessary for the computer model. The computer simulated results are compared to the experimental data obtained for all 5 components run in a mixture on the differential test column for a range of reactor contact times.

Kindt, Louis M.↗
NASA NTRS1997

A Summary of Ambient Air at John F. Kennedy Space Center with a Comparison to Data from the Florida Statewide Monitoring Network (1983-1992)

The EPA criteria air pollutants were monitored at Kennedy Space Center (KSC) since 1983 to comply the prevention of significant deterioration requirements under the Clean Air Act amendments passed by Congress in 1977 and 1990. Monitoring results show that monthly maximum 24-hour total suspended particulates decreased from 144.6 micograms/cu m in 1988 to 73.0 micrograms/cu m in 1991 and increased to 149.3 micrograms/cu m in 1992. Inhalable particulates increased from 56.1 gg/M3 in 1983 to 131.4 micrograms/cu m in 1988, and then decreased to 38.5 micrograms/cu m in 1992. Sulfur dioxide monthly maximum 24-hour average concentrations decreased each year from 135.2 micrograms/cu m in 1983 to 33.8 micrograms/cu m in 1992. Nitrogen dioxide concentrations increased from 5.1 micrograms/cu m in 1983 to 5.9 micrograms/cu m in 1988, then decreased to 4.5 micrograms/cu m in 1992. Carbon monoxide annual average concentrations decreased from 6.2 micrograms/cu m in 1983 to 1.1 micrograms/cu m in 1988, and increased to 1.2 micrograms/cu m in 1992. Ozone maximum 1-hour concentrations increased from 98 parts per billion (ppb) in 1983 to 134 ppb in 1989, and then decreased to 80 ppb in 1992. Total annual rainfall ranged from 37.47 inches to 57.47 inches and shows a 6.6 percent increase over this same ten year period.

Drese, John H.↗