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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Transient GaAs plasmonic metasurfaces at terahertz frequencies

Here we demonstrate the ultrafast formation of terahertz (THz) metasurfaces through all-optical creation of spatially modulated carrier density profiles in a deep-subwavelength GaAs film. The switch-on of the transient plasmon mode, governed by the GaAs effective electron mass and electron–phonon interactions, is revealed by structured-optical pump THz probe spectroscopy, on a time scale of 500 fs. By modulating the carrier density using different pump fluences, we observe a wide tuning of the electric dipole resonance of the transient GaAs metasurface from 0.5 THz to 1.7 THz. Furthermore, we numerically demonstrate that the metasurface presented here can be generalized to more complex architectures for realizing functionalities such as perfect absorption, leading to a 30 dB modulation depth. In conclusion, the platform also provides a pathway to achieve ultrafast manipulation of infrared beams in the linear and, potentially, nonlinear regime.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Surface plasmon transmission through discontinuous conducting surfaces: Plasmon amplitude modulation by grazing scattered fields

We have studied numerically the diffraction of a surface plasmon polariton (SPP) when it encounters a wide multi-wavelength slit in conducting films. As a jump process a SPP is excited beyond the slit by wave scattering at the second slit edge. The exciting radiation is produced when the incident SPP collapses at the first slit edge. We have found that the transmitted SPP supports inherent and unavoidable interference with grazing scattered radiation; the spatial modulation extends to the fields in the diffraction region where a series of low intensity spots arises. We demonstrate that the SPP generated on the second slab depends on the frequency but not on the wave vector of the collapsed SPP; a SPP is transmitted even when the two metals forming the slit are different. The numerical results were obtained using the Finite Difference Time Domain (FDTD) method with a grid size λ/100.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2016

Atmospheric-pressure glow plasma synthesis of plasmonic and photoluminescent zinc oxide nanocrystals

In this paper, we present a large-volume (non-micro) atmospheric pressure glow plasma capable of rapid, large-scale zinc oxide nanocrystal synthesis and deposition (up to 400 μg/min), whereas in the majority of the literature, nanoparticles are synthesized using micro-scale or filamentary plasmas. The reactor is an RF dielectric barrier discharge with a non-uniform gap spacing. This design encourages pre-ionization during the plasma breakdown, making the discharge uniform over a large volume. The produced zinc oxide nanocrystals typically have diameters ranging from 4 to 15 nm and exhibit photoluminescence at ≈550 nm and localized surface plasmon resonance at ≈1900 cm{sup −1} due to oxygen vacancies. The particle size can be tuned to a degree by varying the gas temperature and the precursor mixing ratio.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2021

Heterogeneity and Hysteresis in the Polymer Collapse of Single Core–Shell Stimuli-Responsive Plasmonic Nanohybrids

Broad application of polymeric stimuli-responsive smart nanohybrids requires understanding the mechanisms governing active control. Ensemble techniques have identified inhomogeneous polymer collapse in microgels that potentially arise from heterogeneous interchain interactions and differences in core size. A single-particle examination would establish the influence of core size and internal polymer network heterogeneity on local interactions that contribute to the observed inhomogeneous polymer collapse dynamics of nanohybrids. Using single-particle dark-field spectroscopy, we investigated the complex polymer collapse profiles of core–shell plasmonic nanohybrids comprising thermoresponsive poly(N-isopropylacrylamide) (pNIPAM)-encapsulated gold nanorods (AuNRs). We report that the polymer collapse behavior was independent of the core size. For thinner polymer shells, we observed hysteresis in the collapse of AuNR@pNIPAMs, likely related to local pNIPAM aggregation due to interchain hydrogen bonding. For thicker polymer shells, we observed a broad polymer collapse distribution that we attributed to a two-step phase transition that arises from a polymer network density gradient. Furthermore, our single-particle approach relates the internal heterogeneity of the polymer network of nanohybrids to the mechanisms underlying heterogeneous phase transitions that traditional, ensemble-averaged approaches are unable to discern.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

Direct observation of the two-plasmon-decay common plasma wave using ultraviolet Thomson scattering

A 263-nm Thomson-scattering beam was used to directly probe two-plasmon-decay (TPD) excited electron plasma waves (EPWs) driven by between two and five 351-nm beams on the OMEGA Laser System. The amplitude of these waves was nearly independent of the number of drive beams at constant overlapped intensity, showing that the observed EPWs are common to the multiple beams. In an experimental configuration where the Thomson-scattering diagnostic was not wave matched to the common TPD EPWs, a broad spectrum of TPD-driven EPWs was observed, indicative of nonlinear effects associated with TPD saturation. Electron plasma waves corresponding to Langmuir decay of TPD EPWs were observed in both Thomson-scattering spectra, suggesting the Langmuir decay instability as a TPD saturation mechanism. Simulated Thomson-scattering spectra from three-dimensional numerical solutions of the extended Zakharov equations of TPD are in excellent agreement with the experimental spectra and verify the presence of the Langmuir decay instability.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1984

Plasmon device design: Conversion from surface to junction plasmons with grating-couplers

Scaling calculations and numerical studies are used to show that grating couplers provide effective energy transfer between surface plasmons and slower modes localized in the tunnel diodes. Within first order perturbation theory in grating amplitude, 90% efficiency energy transfer occurs within micrometers for realistic structures and materials parameters. Scaling laws are derived. Seventy to 90% of the electromagnetic field energy is concentrated in the oxide layer of an MOM diode after the energy is distributed by longer range modes that have less than 0.1% overlap with the tunneling region. The mode conversion allows the requirements separation for energy transport and power production by inelastic tunneling.

Anderson, L. M.↗
DOE OSTI2016

Ultrasmall Mode Volumes in Plasmonic Cavities of Nanoparticle‐On‐Mirror Structures

The mode volume and Purcell factor are two important parameters to assess the performance of optical nanocavities. Achieving small mode volumes and high Purcell factors for nanocavity structures while simplifying their fabrication has been a major task to realize high‐performance and large‐scale photonic devices and systems. Different optical resonators based on nanoparticle‐on‐mirror (NPoM) structures are systematically analyzed, which are easy to fabricate and flexible to use. Direct comparison of these optical resonators is made through finite‐difference time‐domain (FDTD) simulations. The achievement of ultrasmall mode volumes below 10 −7 based on the NPoM structure through FDTD simulations is demonstrated by rationally selecting the structural parameters. Such NPoM structures provide a decent Purcell factor on the order of 10 7 , which can effectively enhance spontaneous emission and facilitate a number of photonic applications. The simulation results are confirmed by dark field scattering and second‐harmonic generation measurements. This work is scientifically important and offers practical guidelines for the design of optical resonators for state‐of‐the‐art optical and photonic devices.

Huang, Shengxi↗