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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Enhanced Tritium Retention in LiAlO2 Pellets via Engineered Glazes: Tritium Science Project

This project investigated the impact of adding a thin (10 – 50 µm) layer of amorphous glaze to the surface of a TPBAR pellet on its retention of helium, hydrogen (as a surrogate for tritium), and water (as a surrogate for tritiated water). The hypothesis was that the glaze would significantly reduce permeation of hydrogen species with a lesser impact on hindering helium permeation. A non-crystallizing soda-lime-silicate glass, known as SCN-1, was selected for this proof-of-concept study. It was found that continuous glaze layers of the desired thickness could be applied to the pellets with two or more dip coats, depending on the targeted thickness. At 330°C, the glaze was found to have a permeability that was lower than that of the pellet by a factor of ~10 6 , implying that a thin 10 – 50 µm layer can significantly increase pellet retention of hydrogen. Meanwhile, the permeation rate of helium through the glaze was found to be ~20 times higher than that of hydrogen or water. An unanticipated outcome of the study was that unglazed pellets were measured to have hydrogen diffusivities that are a factor of ~105 greater than the diffusivity value used in the TPBAR COMSOL model to achieve observed tritium retention rates. When the higher measured diffusivity was substituted into the model and the model was run with all tritium species in the pellet in the form of T 2 O at a partial pressure of 20 Pa in equilibrium with LiOT, the resulting retention was 50% after 500 days.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Portuguese Wood Pellets Market: Organization, Production and Consumption Analysis

Wood pellets are a form of energy that can be seen as an alternative to fossil fuels, thus contributing to the reduction of greenhouse gas emissions. In other words, wood pellets can be considered a solution contributing to the mitigation of climate change. The use of wood pellets has grown significantly in recent years, with different markets emerging, such as Portugal, both from production and consumption perspectives. The wood pellet industry in Portugal began its development about 15 years ago, with the companies installed in the country initially almost exclusively dedicated to the production of wood pellets for export to central and northern European markets. However, over the years, the domestic market, initially considered insignificant, began to develop; it recently reached a considerable consuming share of the national production. This study presents an analysis of the Portuguese wood pellet market using data collected on the sector, and specifically on producers and consumers. The information was gathered using surveys presented directly to consumers and producers and through interviews with other stakeholders in the sector. From the analysis of the information, it was possible to understand the market’s dynamics, its current evolution and its prospects for the upcoming years, since it can already be considered mature and consolidated.

Nunes, Leonel J. R. (ORCID:0000000154048163)↗
NASA NTRS1998

Drug marker absorption in relation to pellet size, gastric motility and viscous meals in humans

PURPOSE: The objective of this study was to evaluate drug marker absorption in relation to the gastric emptying (GE) of 0.7 mm and 3.6 mm enteric coated pellets as a function of viscosity and the underlying gastric motility. METHODS: Twelve subjects were evaluated in a 3-way crossover study. 0.7 mm caffeine and 3.6 mm acetaminophen enteric coated pellets were concurrently administered with a viscous caloric meal at the levels of 4000, 6000 and 8000 cP. Gastric motility was simultaneously measured with antral manometry and compared to time events in the plasma profiles of the drug markers. RESULTS: Caffeine, from the 0.7 mm pellets, was observed significantly earlier in the plasma than acetaminophen, from the 3.6 mm pellets, at all levels of viscosity. Motility related size differentiated GE was consistently observed at all viscosity levels, however, less variability was observed with the 4000 cP meal. Specifically, the onset of absorption from the of 3.6 mm pellets correlated with the onset of Phase II fasted state contractions (r = 0.929, p < 0.01). CONCLUSIONS: The timeframe of drug marker absorption and the onset of motility events were not altered within the range of viscosities evaluated. Rather, the differences in drug marker profiles from the non-digestible solids were most likely the result of the interaction between viscosity and motility influencing antral flow dynamics. The administration of the two sizes of pellets and a viscous caloric meal with subsequent monitoring of drug marker profiles is useful as a reference to assess the influence of motility patterns on the absorption profile of orally administered agents.

NASA Center JSC↗
NASA NTRS2006

Manufacture of Regularly Shaped Sol-Gel Pellets

An extrusion batch process for manufacturing regularly shaped sol-gel pellets has been devised as an improved alternative to a spray process that yields irregularly shaped pellets. The aspect ratio of regularly shaped pellets can be controlled more easily, while regularly shaped pellets pack more efficiently. In the extrusion process, a wet gel is pushed out of a mold and chopped repetitively into short, cylindrical pieces as it emerges from the mold. The pieces are collected and can be either (1) dried at ambient pressure to xerogel, (2) solvent exchanged and dried under ambient pressure to ambigels, or (3) supercritically dried to aerogel. Advantageously, the extruded pellets can be dropped directly in a cross-linking bath, where they develop a conformal polymer coating around the skeletal framework of the wet gel via reaction with the cross linker. These pellets can be dried to mechanically robust X-Aerogel.

Leventis, Nicholas↗
DOE OSTI2023

Reduction of Iron‐Ore Pellets Using Different Gas Mixtures and Temperatures

Direct reduction of iron ore (DRI) is gaining an increased attention due to the growing need to decarbonize industrial processes. The current industrial DRI processes are performed using reformed natural gas, which results in CO 2 emission, although it is less than carbothermic reduction in the blast furnace. Carbon‐free reduction may be realized through the utilization of green H 2 as a reducing agent, in place of natural gas. Herein, the effects of various gas mixtures and temperature on the reduction kinetics of the hematite iron‐ore pellets are focused on in this work. Pellets are reduced at 700, 800, 850, and 900 °C in hydrogen and using various gas mixes at 850 °C. Morphology of the pellets is investigated with the help of scanning electron microscopy and mercury intrusion porosimetry. The effects of temperature and gas composition on the reduction kinetics and porosity of the pellets are discussed. A notable effect of reduction rate on the internal structure of the pellets is detected, slower reduction rate yielded bigger pores offsetting the gas composition. Higher temperature results in coarser pores and higher porosity. Finally, increase of CO content in the gas mix also leads to bigger pore size.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Screening method for Enzyme-based liquefaction of corn stover pellets at high solids

Liquefaction of high solid loadings of unpretreated corn stover pellets has been demonstrated with rheology of the resulting slurries enabling mixing and movement within biorefinery bioreactors. However, some forms of pelleted stover do not readily liquefy, so it is important to screen out lots of unsuitable pellets before processing is initiated. This work reports a laboratory assay that rapidly assesses whether pellets have the potential for enzyme-based liquefaction at high solids loadings. Twenty-eight pelleted corn stover (harvested at the same time and location) were analyzed using 20 mL enzyme solutions (3 FPU cellulase/ g biomass) at 30 % w/v solids loading. Imaging together with measurement of reducing sugars were performed over 24-hours. Further, some samples formed concentrated slurries of 300 mg/mL (dry basis) in the small-scale assay, which was later confirmed in an agitated bioreactor. Also, the laboratory assay showed potential for optimizing enzyme formulations that could be employed for slurry formation.

Laboratory assay↗
DOE OSTI2020

European residential wood pellet trade and prices dataset

The European market for wood pellets used in small-scale heating systems has been expanding significantly over the past decade. For an analysis of market efficiency in the Journal Energy with the title “The European wood pellets for heating market - price developments, trade and market efficiency“ wood pellet prices have been collected as well as trade flows downloaded for the trade relations between Austria, Germany, Italy and France. Only since January 2012 monthly wood pellet trade data is published by Eurostat. This, now monthly expanding data-set provides new opportunities for analysing the development of this important renewable energy commodity. Furthermore, national wood pellet prices published by national authorities and interest groups are improving in quality in the recent years. The collection and combination of these data-sets are a chance for novel econometric analysis. This paper presents valuable tools and processes to acquire and prepare this data and connects to a data and code repository for downloading the resources described in this and the related Journal Energy publication.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2021

Effects of Production of Woody Pellets in the Southeastern United States on the Sustainable Development Goals

Wood-based pellets are produced in the southeastern United States (SE US) and shipped to Europe for the generation of heat and power. Effects of pellet production on selected Sustainability Development Goals (SDGs) are evaluated using industry information, available energy consumption data, and published research findings. Challenges associated with identifying relevant SDG goals and targets for this particular bioenergy supply chain and potential deleterious impacts are also discussed. We find that production of woody pellets in the SE US and shipments to displace coal for energy in Europe generate positive effects on affordable and clean energy (SDG 7), decent work and economic growth (SDG 8), industry innovation and infrastructure (SDG 9), responsible consumption and production (SDG 12), and life on land (SDG 15). Primary strengths of the pellet supply chain in the SE US are the provisioning of employment in depressed rural areas and the displacement of fossil fuels. Weaknesses are associated with potential impacts on air, water, and biodiversity that arise if the resource base and harvest activities are improperly managed. The SE US pellet supply chain provides an opportunity for transition to low-carbon industries and innovations while incentivizing better resource management.

09 BIOMASS FUELS↗
DOE OSTI2020

Comparative analysis of temperature dependent properties of commercial nuclear fuel pellet and surrogates undergoing cracking: A review

A variety of normal and accident scenarios can generate thermal stresses enough to cause cracking in light water reactor (LWR) fuel. To better understand this behavior, cracking experiments have been carried out to induce thermal gradients in fuel pellets via induction heating and direct resistance heating. In this study, Ceria (CeO 2 ) and yttria stabilized zirconia (YSZ) pellets were chosen as a surrogate fuel material for uranium dioxide (UO 2 ). Induction heating was done using copper coils and molybdenum susceptors which heated the surrogates to a threshold temperature that is sufficiently high for the fuel material to conduct current. Thereafter, direct resistance heating was achieved by passing current through the specimen using a DC power supply to introduce volumetric heating to replicate reactor operating conditions. Simultaneous real-time dual imaging of the ceria pellet surface has been designed using optical and infra-red camera system to capture images of cracks and full-field temperature gradients on pellet. It was observed that YSZ pellets need a much higher voltage-current for volumetric heating and do not exhibit the cracking pattern as ceria and UO 2 , hence YSZ was ruled out for further consideration. Ceria was found to be an appropriate surrogate for UO 2 . Furthermore, the experimental set up and test conditions demand the need to primarily understand the thermo-physical, mechanical and optical properties of UO 2 and the surrogates. Thus, it is essential to have an in-depth knowledge about the various temperature dependent properties of UO 2 and CeO 2 for establishing a comparative analysis between the surrogate and UO 2 for conducting experiments.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Isotopic Heterogeneity Imaged in a Uranium Fuel Pellet with Extreme Ultraviolet Laser Ablation and Ionization Time-of-Flight Mass Spectrometry

We use extreme ultraviolet laser ablation and ionization time-of-flight mass spectrometry (EUV TOF) to map uranium isotopic heterogeneity at the nanoscale (=100 nm). Using low-enriched uranium fuel pellets that were made by blending two isotopically distinct feedstocks, we show that EUV TOF can map the 235U/238U content in 100 nm-sized pixels. The two-dimensional (2D) isotope maps reveal U ratio variations in sub-microscale to =1 µm areas of the pellet that had not been fully exposed by microscale or bulk mass spectrometry analyses. Compared to the ratio distribution measured in a homogeneous U reference material, the ratios in the enriched pellet follow a ~3× wider distribution. These results indicate U heterogeneity in the fuel pellet from incomplete blending of the different source materials. EUV TOF results agree well with those obtained on the same enriched pellets by nanoscale secondary ionization mass spectrometry (NanoSIMS), which reveals a comparable U isotope ratio distribution at the same spatial scale. EUV TOF’s ability to assess and map isotopic heterogeneity at the nanoscale makes it a promising tool in fields such as nuclear forensics, geochemistry, and biology that could benefit from uncovering sub-microscale sources of chemical modifications.

Rush, Lydia A.↗
DOE OSTI2021

Influence of Pelletization and Moisture Content of Oil Palm Empty Fruit Bunches (EFBs) on Dynamic Gasification Performance

Wet-ground empty fruit bunches (EFBs), dry-ground EFB, and pelletized EFB were gasified in a laboratory-scale updraft fixed-bed reactor at differing temperatures and equivalent ratios (ERs) between 0.19 and 0.78 to evaluate the performance and quality of the syngas under autothermal operating conditions. In addition, the theoretical estimation of the key performance indicator of the ashes on the performance of the gasification process was obtained. The results show that for ERs > 0.4 the autothermal operating condition was achieved for pretreatments with pelletized and dry-ground EFBs, with reactor operating temperatures T > 700 °C. With wet EFB, this condition is achieved at any ER value. The average composition of the syngas from pelletized EFB presented the best average concentrations of the combustible species CO, H2, and CH4 when the ER values were between 0.25 and 0.40. The highest hot and cold thermal efficiency values were obtained for the gasification of EFB pellets with ER values between 0.25 and 0.40. For ground EFB, increases in the ER value led to improvements in hot thermal efficiency. Finally, during the EFB pellet gasification tests, no agglomeration and sintering problems were evidenced in comparison with wet-ground and dry-ground EFBs that showed slag formation, especially at ER < 0.46.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2025

Quantifying Impacts of Biomass Pelletization on Fast Pyrolysis Using a Single-Particle Reactor, X-ray Computed Tomography, and Computational Modeling

The pore structure and density of lignocellulosic feedstocks dictate intraparticle transport phenomena and thereby play an important role in thermochemical conversion processes such as fast pyrolysis for biofuel and biochemical production. Variations in microstructure are inherent from different biomass species and can be introduced by preprocessing techniques such as cutting and pelletization. Morphological changes also occur during conversion and lead to vastly different pore structures and behavior during pyrolysis, which impact required conversion times and product distributions. The current work presents a comprehensive comparison of fast pyrolysis of neat and pelletized pine feedstocks, which includes single-particle experiments, modeling, and 3D imaging by X-ray computed tomography (XCT). The particle-scale model included anisotropic heat and mass transport in a shrinking particle with pyrolysis reactions based on the CRECK mechanism with boundary conditions informed by reactor-scale simulations of the single-particle reactor. The models were validated by measurements of the temperature and mass loss from single-particle pyrolysis experiments of neat and pelletized pine. Quantitative analysis of XCT geometries revealed that pyrolytic conversion yielded chars with increased porosity and permeability compared to the unpyrolyzed materials, along with decreased tortuosity and anisotropy. Pelletization of the pine feedstock resulted in a much denser, less permeable material, which converted slower and produced more residual char after pyrolysis compared to neat pine. The results from particle modeling revealed that accounting for the dynamic and anisotropic heat and mass transport caused by differences in pore structure is critical to achieving agreement with experimental results. Overall, this study highlights the dramatic differences in conversion behavior imparted by pelletization and the importance of capturing microstructural attributes in computational models to guide the design and optimization of pyrolysis processes for specific biomass feedstocks.

09 BIOMASS FUELS↗
DOE OSTI2020

A reduced model for edge localized mode control by supersonic molecular beam injection and pellet injection

We develop a diffusive, bistable, tri-unstable cellular automata (CA) model to study the dynamics of H-mode pedestal with edge localized modes (ELMs) and their control by supersonic molecular beam injection (SMBI) and pellet injection (PI). It is shown that the new CA model can reproduce the key features of H-mode pedestals with various types of ELM, including Type-I ELM. SMBI and PI are modeled as additional grain injections into pedestal with varying degrees of injected materials and profiles. It is found that H-mode pedestal responds to SMBI differently depending on the baseline fueling. If the baseline fueling is large enough to allow Type-I ELM, SMBI enhances large transport avalanches caused by ballooning instabilities. These avalanches prevent the total pedestal current from reaching the boundary for peeling instability. On the other hand, if the baseline fueling is low to avoid Type-I ELM, SMBI enhances small scale avalanches, which prevent the pedestal from growing to profiles globally vulnerable to ballooning instabilities. These imply that SMBI can mitigate different types of ELM by converting them to more benign types. From CA modeling of pellet injection, it is shown that Type-I ELM can be triggered by pellet injection with sufficient strength and depth. Scanning the frequency of pellet injection, it is found that a maximum efficiency of pellet pacing is achieved when the injection frequency is approximately ten times the natural frequency of Type-I ELM.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Measurement and simulation of small cryogenic neon pellet Ne-I 640 nm photon efficiency during ablation in DIII-D plasma

Small (~1 mm) neon pellet fragments are fired into DIII-D H-mode plasmas, and resulting trajectory-averaged photon efficiencies (neutral neon ionization events for every photon emitted) of S/XB ≈ 85 are estimated for Ne-I 640 nm by dividing the estimated initial pellet fragment mass by the measured number of emitted Ne-I photons. The experiments are modeled by running the Lagrangian particle (LP) fluid/magneto-hydrodynamic pellet code to estimate axial ablation plume neon density profiles and temperature profiles at each pellet position. These solutions are then fed into the PrismSPECT collisional-radiative code, which calculates resulting neon charge states and photon emission rates, giving a profile-average of S/XB ≈ 109. The burnthrough plasma minor radius predicted by LP (ρ ≈ 0.63) is reasonably close to the experimental observation ρ ≈ 0.6. Furthermore, the modeling indicates that local S/XB is not constant along the pellet trajectory but tends to increase with increasing ablation rate. Non-equilibrium kinetics are predicted to be very important, while line trapping is predicted to be relatively unimportant (for Ne-I 640 nm S/XB).

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Lagrangian particle simulation of hydrogen pellets and SPI into runaway electron beam in ITER

Numerical studies of the ablation of pellets and shattered pellet injection (SPI) fragments into a runaway electron beam in ITER have been performed using a time-dependent pellet ablation code [Samulyak et al., Nucl. Fusion, 61(4), 046007 (2021)]. The code resolves detailed ablation physics near pellet fragments and large-scale expansion of ablated clouds. The study of a single-fragment ablation quantifies the influence of various factors, in particular, the impact ionization by runaway electrons and cross-field transport models, on the dynamics of ablated plasma and its penetration into the runaway beam. Simulations of SPI performed using different numbers of pellet fragments study the formation and evolution of the ablation clouds and their large-scale dynamics in ITER. In conclusion, the penetration depth of the ablation clouds is found to be of the order of 50 cm.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Radial electric field and density fluctuations measured by Doppler reflectometry during the post-pellet enhanced confinement phase in W7-X

Radial profiles of density fluctuations and the radial electric field, Er, have been measured using Doppler reflectometry during the post-pellet enhanced confinement phase achieved, under different heating power levels and magnetic configurations, during the 2018 W7-X experimental campaign. A pronounced Er-well is measured with local values as high as -40 kV m -1 in the radial range ρ ~ 0.7–0.8 during the post-pellet enhanced confinement phase. The maximum Er intensity scales with both the plasma density and electron cyclotron heating power level, following a similar trend to the plasma energy content. A good agreement is found when the experimental Er profiles are compared to simulations carried out using the neoclassical codes, the drift kinetic equation solver (DKES) and kinetic orbit-averaging solver for stellarators (KNOSOS). The density fluctuation level decreases from the plasma edge toward the plasma core and the drop is more pronounced in the post-pellet enhanced confinement phase than in reference gas-fuelled plasmas. Besides, in the post-pellet phase, the density fluctuation level is lower in the high iota magnetic configuration than in the standard one. Therefore, to determine whether this difference is related to the differences in the plasma profiles or to the stability properties of the two configurations, gyrokinetic simulations have been carried out using the codes stella and EUTERPE. The simulation results point to the plasma profile evolution after the pellet injection and the stabilization effect of the radial electric field profile as the dominant players in the stabilization of the plasma turbulence.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Estimation of China Fusion Engineering Test Reactor performance and burning fraction in different pellet fueling scenarios by a multi-species radial transport model

Tritium self-sufficiency in future deuterium–tritium fusion reactors is a crucial challenge. As an engineering test reactor, the China Fusion Engineering Test Reactor requires a burning fraction of 3% for the goal to test the accessibility to the future fusion plant. To self-consistently simulate burning plasmas with profile changes in pellet injection scenarios and to estimate the corresponding burning fraction, a one-dimensional multi-species radial transport model is developed in the BOUT++ framework. Here several pellet-fueling scenarios are then tested in the model. The results show that the increased fueling depth improves the burning fraction by particle confinement improvement and fusion power increase. Nevertheless, by increasing the depth, the pellet cooling-down may significantly lower the temperature in the core region. Taking the density perturbation into consideration, the reasonable parameters of the fueling scenario in these simulations are estimated as pellet radius ${r}_{{\rm{p}}}=3\,{\rm{mm}},$ injection rate $=\,4\,\mathrm{Hz},$ and pellet injection velocity $=\,1000\mbox{-}2000\,{\rm{m}}\,{{\rm{s}}}^{-1}$ without drift or $450\,{\rm{m}}\,{{\rm{s}}}^{-1}$ with high-field-side drift.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Investigating Hydrogen Isotope Exchange Reactions on Lithium Aluminate Pellets in TPBAR (FY22 Report)

We developed a novel operando Raman spectroscopy method for investigation of hydrogen (H) isotope exchange reactions in the lithium aluminate (γ-LiAlO 2 ) that allows modeling of tritium behaviors in high temperature and in an irradiated environment. The lithium aluminate pellet is a main component in the Tritium-Producing Burnable Absorber Rod (TPBAR). We used deuterium ( 2 H or D) as a surrogate to simulate tritium ( 3 H or T). We used a surface analysis tools in situ/operando Raman spectroscopy to observe the transformation OH and OD compositional changes. We also used ToF-SIMS to analyze the lithium aluminate pellet control sample to build the base line for future in situ/operando analysis. To conduct operando Raman spectroscopy, we developed a custom reaction cell with a detachable micro heater using microelectromechanical systems (MEMS) and 3D printing techniques. Multiple versions were developed and tested. Using the new reaction cell, we demonstrated operando Raman spectroscopy of water (H 2 O) and deuterated water (D 2 O) with nitrogen (N 2 ) exposure onto the lithium aluminate (LiAlO2) pellet specimen, respectively, using a wet gas injection setup. We also successfully developed a detachable microheater that can heat up to ~250°C for ~90 mins. The Raman spectra did not show clear H 2 O and D 2 O characteristic peaks, which indicates that introducing H 2 O and D 2 O onto the surface of the pellet is challenging due to its dense structure nature. Our efforts suggest that various improvements are needed, such as increasing reaction cell operating gas pressure and thinning pellet sample thickness, to obtain meaningful measurements.

07 ISOTOPE AND RADIATION SOURCES↗