A novel machine learning based lumping approach for the reduction of large kinetic mechanisms for plasma-assisted combustion applications
Not Available
Rekkas-Ventiris, Georgios (ORCID:0000000226586586)↗
SEARCH · Engineering Papers
Results for “PACS”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Computational Investigation of the Catalytic Hydrodeoxygenation of Propanoic Acid over a Cu(111) Surface
Cu-based alloy catalysts have recently been investigated experimentally for the hydrodeoxygenation (HDO) of biomass-derived organic acids. Here, the HDO of propanoic acid (PAc) has been studied over Cu(111) by mean-field microkinetic modeling based on parameters obtained from first-principles calculations. Models were developed for the gas- and liquid-phase HDO in condensed water and 1,4-dioxane. In agreement with experimental observations, the gas-phase PAc conversion rate is low at 573 K and increases in liquid water by 1 order of magnitude. In all reaction environments, the decarboxylation mechanism is dominant at low hydrogen partial pressures less than 0.1 bar, and the C–COO bond dissociation is the rate-controlling elementary step. This observation contrasts with the rate-controlling step identified over most group VIII metal surfaces, which is the C–OH bond dissociation in the decarbonylation mechanism. At high hydrogen (H 2 ) partial pressures greater than 10 bar, the HDO of PAc produces propionaldehyde that can readsorb and further react through decarbonylation to produce C 2 alkane products, which is conceptually different from the low H 2 partial pressure scenario. At high H 2 partial pressures, the initial hydrogenation at the carbonyl carbon of PAc becomes the rate-controlling elementary step.
Catalysts↗
Photochemical Upconversion in Water Using Cu(I) MLCT Excited States: Role of Energy Shuttling at the Micellar/Water Interface
Photochemical upconversion (UC) through triplet–triplet annihilation (TTA), which employs a visible absorbing triplet photosensitizer and an annihilator, is a process that generates a high energy photon from two lower energy photons. TTA-UC has been largely developed in pure organic solvents and solid-state polymeric constructs while featuring near exclusive use of rare and expensive metals within the photosensitizer. In this current investigation, we demonstrate that TTA-UC from the long lifetime earth-abundant photosensitizer [Cu(dsbtmp) 2 ](PF) 6 (dsbtmp = 2,9-di(sec-butyl)-3,4,7,8-tetramethyl-1,10-phenanthroline), abbreviated as Cu-PS, functions in water through encapsulation within a cationic-based assembly. Cetyltrimethylammonium bromide was the surfactant of choice as it electrostatically binds the negatively charged water-soluble 10-phenylanthracene-9-carboxylate (PAC) acceptor/annihilator and ultimately facilitates energy transfer across the interface. Efficient triplet–triplet energy transfer (TTET) from Cu-PS to the PAC acceptor was achieved in this aqueous assembly. Unfortunately, the hindered mobility of the PAC moieties ultimately hampered the annihilation process, and this was reflected in attenuated TTA rates and efficiencies. The combined experimental data illustrated that the water-soluble PAC acceptor was able to vectorially deliver the excited-state energy stored in Cu-PS across the interface into the bulk aqueous solution by engaging in excited-state electron transfer with methyl viologen acceptors. Lastly, these results are important for remotely operating photoredox reactions in water while rendering a photosensitizer spatially isolated in the hydrophobic core of a micelle.
36 MATERIALS SCIENCE↗
Field Evaluation of Do-It-Yourself Air Filtration Solutions for Evaporative Coolers to Reduce Ambient Particle Infiltration in Homes in Wildfire-Affected Communities
Evaporative coolers (ECs) introduce outdoor air pollutants indoors when operating. This study evaluates the potential of do-it-yourself (DIY) air filtration solutions for ECs to cost-effectively reduce the infiltration of ambient fine particulate matter (PM2.5) in homes with ECs using measurements in 48 homes in wildfire-affected agricultural communities in California. All homes received one portable air cleaner (PAC); 25 homes also received DIY filters (mostly MERV 13) attached to their ECs. PurpleAir monitors measured indoor and outdoor PM2.5 concentrations. PAC operation was monitored in all of the homes. EC usage was monitored in some homes and predicted using relative humidity dynamics in all homes. Conditional analyses between EC likely on and off conditions were used to evaluate the impacts of DIY EC filters on ambient PM2.5 infiltration, including during several wildfire-affected days. Median levels of ambient PM2.5 infiltration increased ∼36-42% in homes with only PAC interventions when ECs were likely operating compared to only ∼10-11% in homes with both PACs and DIY EC filters. Pre/postintervention comparisons in a subset of homes confirmed PM2.5 infiltration reductions. EC filter performance declined after extended use. Results suggest that short-term EC filter deployments are likely a cost-effective way to mitigate wildfire smoke infiltration inside these homes.
Wang, Mingyu↗
The magnetic behavior of the intermetallic compound NdMn{sub 2}Ge{sub 2} studied by magnetization and hyperfine interactions measurements
The magnetic behavior of the intermetallic compound NdMn{sub 2}Ge{sub 2} was investigated by bulk magnetization measurements and measurements of hyperfine interactions using perturbed γ–γ angular correlation (PAC) spectroscopy. Magnetization measurements indicate the presence of four magnetic transitions associated with the Mn and Nd magnetic sublattices. At high temperatures, magnetic measurements show a change in the slope of the magnetization due to an antiferromagnetic transition around T{sub N} ∼ 425 K and a well defined ferromagnetic transition at T{sub C} ∼ 320 K. Moreover, at ∼210 K a peak is observed in the magnetization curve, which is assigned to the reorientation of the Mn spin, and at ∼25 K an increase in the magnetic moment is also observed, which is ascribed to the ordering of Nd ions. PAC measurements using {sup 140}La({sup 140}Ce) and {sup 111}In({sup 111}Cd) probe nuclei allowed the determination of the temperature dependence of the magnetic hyperfine field (B{sub hf}) at Nd and Mn sites, respectively. PAC results with {sup 111}Cd probe nuclei at Mn sites show that the dependence of B{sub hf} with temperature follows the expected behavior for the host magnetization associated with the magnetic ordering of Mn ions. From these results, the antiferromagnetic transition followed by a ferromagnetic ordering is clearly observed. PAC results with {sup 140}Ce probe nuclei at Nd sites, however, showed a strong deviation from the Brillouin function, which is attributed to the Ce 4f-electron contribution to B{sub hf}.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
L1448-MM OBSERVATIONS BY THE HERSCHEL KEY PROGRAM, ''DUST, ICE, AND GAS IN TIME'' (DIGIT)
We present Herschel/Photodetector Array Camera and Spectrometer (PACS) observations of L1448-MM, a Class 0 protostar with a prominent outflow. Numerous emission lines are detected at 55 <λ < 210 μm including CO, OH, H{sub 2}O, and [O I]. We investigate the spatial distribution of each transition to find that lines from low energy levels tend to distribute along the outflow direction while lines from high energy levels peak at the central spatial pixel. Spatial maps reveal that OH emission lines are formed in a relatively small area, while [O I] emission is extended. According to the rotational diagram analysis, the CO emission can be fitted by two (warm and hot) temperature components. For H{sub 2}O, the ortho-to-para ratio is close to 3. The non-LTE large velocity gradient (LVG) calculations suggest that CO and H{sub 2}O lines could instead be formed in a high kinetic temperature (T > 1000 K) environment, indicative of a shock origin. For OH, IR-pumping processes play an important role in the level population. The molecular emission in L1448-MM is better explained with a C-shock model, but the atomic emission of PACS [O I] and Spitzer/Infrared Spectrograph [Si II] emission is not consistent with C-shocks, suggesting multiple shocks in this region. Water is the major line coolant of L1448-MM in the PACS wavelength range, and the best-fit LVG models predict that H{sub 2}O and CO emit (50%-80%) of their line luminosity in the PACS wavelength range.
79 ASTRONOMY AND ASTROPHYSICS↗
THE CARMA PAIRED ANTENNA CALIBRATION SYSTEM: ATMOSPHERIC PHASE CORRECTION FOR MILLIMETER WAVE INTERFEROMETRY AND ITS APPLICATION TO MAPPING THE ULTRALUMINOUS GALAXY ARP 193
Phase fluctuations introduced by the atmosphere are the main limiting factor in attaining diffraction limited performance in extended interferometric arrays at millimeter and submillimeter wavelengths. We report the results of C-PACS, the Combined Array for Research in Millimeter-Wave Astronomy Paired Antenna Calibration System. We present a systematic study of several hundred test observations taken during the 2009–2010 winter observing season where we utilize CARMA's eight 3.5 m antennas to monitor an atmospheric calibrator while simultaneously acquiring science observations with 6.1 and 10.4 m antennas on baselines ranging from a few hundred meters to ∼2 km. We find that C-PACS is systematically successful at improving coherence on long baselines under a variety of atmospheric conditions. We find that the angular separation between the atmospheric calibrator and target source is the most important consideration, with consistently successful phase correction at CARMA requiring a suitable calibrator located ≲6° away from the science target. We show that cloud cover does not affect the success of C-PACS. We demonstrate C-PACS in typical use by applying it to the observations of the nearby very luminous infrared galaxy Arp 193 in {sup 12}CO(2-1) at a linear resolution of ≈70 pc (0.″12 × 0.″18), 3 times better than previously published molecular maps of this galaxy. We resolve the molecular disk rotation kinematics and the molecular gas distribution and measure the gas surface densities and masses on 90 pc scales. We find that molecular gas constitutes ∼30% of the dynamical mass in the inner 700 pc of this object with a surface density ∼10{sup 4} M{sub ⊙} pc{sup −2}; we compare these properties to those of the starburst region of NGC 253.
79 ASTRONOMY AND ASTROPHYSICS↗
The cold dust content of the oxygen-rich supernova remnant G292.0+1.8
We present far-infrared images of the Galactic oxygen-rich supernova remnant (SNR) G292.0+1.8, acquired with the PACS and SPIRE instruments of the Herschel Space Observatory. We find that the SNR shell is detected in the PACS blue (100 μm) band, but not in the red (160 μm) band, broadly consistent with results from AKARI observations. There is no discernible emission from G292.0+1.8 in SPIRE imagery at 250, 350 and 500 μm. Comparing the 100 μm emission to that observed with Spitzer at 24 and 70 μm, we find a very similar appearance for G292.0+1.8 at all three wavelengths. The infrared emission is dominated by dust from non-radiative circumstellar shocks. In addition, the radiatively shocked O-rich clump known as the “Spur” on the eastern side of G292.0+1.8 is clearly detected in the PACS blue images, with marginal detection in the red. Fitting the existing 14–40 μm IRS spectra of the Spur together with photometric measurements from 70 μm MIPS and 100 μm PACS photometry, we place an upper limit of ≲0.04 M {sub ⊙} of ejecta dust mass in the Spur, under the most conservative assumption that the ejecta dust has a temperature of 15 K. Modeling the dust continuum in the IRS spectra at four positions around the rim, we estimate post-shock densities ranging from n{sub p}=3.5 cm{sup −3} to 11 cm{sup −3}. The integrated spectrum of the entire SNR, dominated by swept-up circumstellar dust, can be fitted with a two-component dust model with a silicate component at 62 K and graphite component at 40 K for a total dust mass of 0.023 M {sub ⊙}.
79 ASTRONOMY AND ASTROPHYSICS↗
Vertical Stratification of Peat Pore Water Dissolved Organic Matter Composition in a Peat Bog in Northern Minnesota: Pore Water DOM composition in a peat bog
We characterized dissolved organic matter (DOM) composition throughout the peat column at the Marcell S1 forested bog in northern Minnesota and tested the hypothesis that redox oscillations associated with cycles of wetting and drying at the surface of the fluctuating water table correlate with increased carbon, sulfur and nitrogen turn over. We found significant vertical stratification of DOM molecular composition and EEM-PARAFAC components within the peat column. In particular the intermediate depth zone (~ 50 cm) was identified as a zone where maximum decomposition and turnover is taking place. Surface DOM was dominated by inputs from surface vegetation. The intermediate-depth zone was an area of high organic matter reactivity and increased microbial activity with diagenetic formation of many unique compounds, among them polycyclic aromatic compounds (PAC) that contain both nitrogen and sulfur heteroatoms. These compounds have been previously observed in coal-derived compounds and were assumed to be responsible for coal's biological activity. Biological processes triggered by redox oscillations taking place at the intermediate depth zone of the peat profile at the S1 bog are assumed to be responsible for the formation of these heteroatomic PACs in this system. Alternatively these compounds could stem from black carbon and nitrogen derived from fires that have occurred at the site in the past. Surface and deep DOM exhibited more similar characteristics, compared to the intermediate-depth zone, with the deep layer exhibiting greater input of microbially degraded organic matter than the surface suggesting that the entire peat profile consists of similar parent material at different degrees of decomposition and that lateral and vertical advection of pore water from the surface to the deeper horizons is responsible for such similarities. Our findings suggest that molecular composition of DOM in peatland pore water is dynamic and is a function of ecosystem activity, water table and redox oscillation and porewater advection.
Environmental Molecular Sciences Laboratory↗
A Strategy for Constructing Pore‐Space‐Partitioned MOFs with High Uptake Capacity for C 2 Hydrocarbons and CO 2
Abstract Introduction of pore partition agents into hexagonal channels of MIL‐88 type (acs topology) endows materials with high tunability in gas sorption. Here, we report a strategy to partition acs framework into pacs (partitioned acs) crystalline porous materials (CPM). This strategy is based on insertion of in situ synthesized 4,4′‐dipyridylsulfide (dps) ligands. One third of open metal sites in the acs net are retained in pacs MOFs; two thirds are used for pore‐space partition. The Co 2 V‐pacs MOFs exhibit near or at record high uptake capacities for C 2 H 2 , C 2 H 4 , C 2 H 6 , and CO 2 among MOFs. The storage capacity of C 2 H 2 is 234 cm 3 g −1 (298 K) and 330 cm 3 g −1 (273 K) at 1 atm for CPM‐733‐dps (the Co 2 V‐BDC form, BDC=1,4‐benzenedicarboxylate). These high uptake capacities are accomplished with low heat of adsorption, a feature desirable for low‐energy‐cost adsorbent regeneration. CPM‐733‐dps is stable and shows no loss of C 2 H 2 adsorption capacity following multiple adsorption–desorption cycles.
Wang, Yong↗
Isoreticular Tolerance and Phase Selection in the Synthesis of Multi‐Module Metal–Organic Frameworks for Gas Separation and Electrocatalytic OER
Abstract Although metal–organic frameworks are coordination‐driven assemblies, the structural prediction and design using metal‐ligand interactions can be unreliable due to other competing interactions. Leveraging non‐coordination interactions to develop porous assemblies could enable new materials and applications. Here, we use a multi‐module MOF system to explore important and pervasive impact of ligand‐ligand interactions on metal‐ligand as well as ligand‐ligand co‐assembly process. It is found that ligand‐ligand interactions play critical roles on the scope or breakdown of isoreticular chemistry. With cooperative di‐ and tri‐topic ligands, a family of Ni‐MOFs has been synthesized in various structure types including partitioned MIL‐88‐acs ( pacs ), interrupted pacs (i‐ pacs ), and UMCM‐1‐muo. A new type of isoreticular chemistry on the muo platform is established between two drastically different chemical systems. The gas sorption and electrocatalytic studies were performed that reveal excellent performance such as high C 2 H 2 /CO 2 selectivity of 21.8 and high C 2 H 2 uptake capacity of 114.5 cm 3 /g at 298 K and 1 bar.
Xiao, Yuchen [Department of Chemistry University o↗
Isoreticular Tolerance and Phase Selection in the Synthesis of Multi‐Module Metal–Organic Frameworks for Gas Separation and Electrocatalytic OER
Abstract Although metal–organic frameworks are coordination‐driven assemblies, the structural prediction and design using metal‐ligand interactions can be unreliable due to other competing interactions. Leveraging non‐coordination interactions to develop porous assemblies could enable new materials and applications. Here, we use a multi‐module MOF system to explore important and pervasive impact of ligand‐ligand interactions on metal‐ligand as well as ligand‐ligand co‐assembly process. It is found that ligand‐ligand interactions play critical roles on the scope or breakdown of isoreticular chemistry. With cooperative di‐ and tri‐topic ligands, a family of Ni‐MOFs has been synthesized in various structure types including partitioned MIL‐88‐acs ( pacs ), interrupted pacs (i‐ pacs ), and UMCM‐1‐muo. A new type of isoreticular chemistry on the muo platform is established between two drastically different chemical systems. The gas sorption and electrocatalytic studies were performed that reveal excellent performance such as high C 2 H 2 /CO 2 selectivity of 21.8 and high C 2 H 2 uptake capacity of 114.5 cm 3 /g at 298 K and 1 bar.
Xiao, Yuchen [Department of Chemistry University o↗
Broadband Calibration of Acoustic Emission and Ultrasonic Sensors from Generalized Ray Theory and Finite Element Models
This paper describes a calibration method for acoustic emission and ultrasonic sensors that is effective from 1 kHz to 1 MHz. The method combines generalized ray theory and finite element analysis to model wave propagation at higher and lower frequencies, respectively. A ball impact is used as a calibration source, a thick aluminum plate is used as the test block, and hot glue is used as the couplant. We demonstrate this method on five commercial piezoelectric sensors: Physical Acoustics (PAC) R15a, PAC WSa, Panametrics V101, Panametrics V103, and Valpey-Fisher Pinducer. Our calibration results show that reflections and other wave phases can be more clearly identified with the less-resonant Panametrics sensors. The PAC sensors have the greatest sensitivity and are able to detect surface normal displacements at least down to 1 pm amplitude in the 100s of kHz frequency band. Aperture effect is minimized by the small size of the Pinducer. Our method focuses on the amplitude response of the sensors (phase is ignored) and extends the calibration to a frequency band that is lower than typical analyses. Low frequency information is useful for determining the seismic moment of a seismic source (analogous to the magnitude of an earthquake) and can increase the amount of information acquired in a single recording.
42 ENGINEERING↗
Comparative study on the growth mechanisms of PAHs
The efficiencies of recently proposed, phenyl addition/cyclization (PAC), methyl addition/cyclization (MAC) and a popular hydrogen abstraction/acetylene addition (HACA) mechanisms have been examined experimentally by detecting the gas phase reaction products of pyrolysis of toluene with/without addition of benzene + acetylene by using vacuum ultraviolet (VUV) single photon ionization (SPI) time of flight mass spectrometry (TOFMS). Besides the observation of verities of large polycyclic aromatic hydrocarbons (PAHs), intense mass peaks of indene, phenylacetylene and propyne confirmed a remarkable quenching of the major active species, benzyl, phenyl and methyl radicals by acetylene. In spite of quenching, only benzyl contributed products were diminished while phenyl and methyl contributed products were enhanced. Uniquely observed symmetrical PAHs; corrannulene/coronene; formed by the active involvement of PAC, HACA and/or MAC mechanisms, reflects the interdependencies of these mechanisms. Individually, PAC was found highly efficient for endless growth, HACA for filling triple fusing site and MAC for expanding cyclotetra/pentafused into benzenoid structure, respectively. (author)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Application of Cell Painting for chemical hazard evaluation in support of screening-level chemical assessments
‘Cell Painting’ is an imaging-based high-throughput phenotypic profiling (HTPP) method in which cultured cells are fluorescently labeled to visualize subcellular structures (i.e., nucleus, nucleoli, endoplasmic reticulum, cytoskeleton, Golgi apparatus / plasma membrane and mitochondria) and to quantify morphological changes in response to chemicals or other perturbagens. HTPP is a high-throughput and cost-effective bioactivity screening method that detects effects associated with many different molecular mechanisms in an untargeted manner, enabling rapid in vitro hazard assessment for thousands of chemicals. Here, 1201 chemicals from the ToxCast library were screened in concentration-response up to ~100 μM in human U-2 OS cells using HTPP. A phenotype altering concentration (PAC) was estimated for chemicals active in the tested range. PACs tended to be higher than lower bound potency values estimated from a broad collection of targeted high-throughput assays, but lower than the threshold for cytotoxicity. In vitro to in vivo extrapolation (IVIVE) was used to estimate administered equivalent doses (AEDs) based on PACs for comparison to human exposure predictions. AEDs for 18/412 chemicals overlapped with predicted human exposures. Phenotypic profile information was also leveraged to identify putative mechanisms of action and group chemicals. Of 58 known nuclear receptor modulators, only glucocorticoids and retinoids produced characteristic profiles; and both receptor types are expressed in U-2 OS cells. Thirteen chemicals with profile similarity to glucocorticoids were tested in a secondary screen and one chemical, pyrene, was confirmed by an orthogonal gene expression assay as a novel putative GR modulating chemical. Most active chemicals demonstrated profiles not associated with a known mechanism-of-action. However, many structurally related chemicals produced similar profiles, with exceptions such as diniconazole, whose profile differed from other active conazoles. Overall, the present study demonstrates how HTPP can be applied in screening-level chemical assessments through a series of examples and brief case studies.
60 APPLIED LIFE SCIENCES↗
Tailoring Interface Energies via Phosphonic Acids to Grow and Stabilize Cubic FAPbI 3 Deposited by Thermal Evaporation
Coevaporation of formamidinium lead iodide (FAPbI 3 ) is a promising route for the fabrication of highly efficient and scalable optoelectronic devices, such as perovskite solar cells. However, it poses experimental challenges in achieving stoichiometric FAPbI 3 films with a cubic structure (α-FAPbI 3 ). In this work, we show that undesired hexagonal phases of both PbI 2 and FAPbI 3 form during thermal evaporation, including the well-known 2H-FAPbI 3 , which are detrimental for optoelectronic performance. We demonstrate the growth of α-FAPbI 3 at room temperature via thermal evaporation by depositing phosphonic acids (PAc) on substrates and subsequently coevaporating PbI 2 and formamidinium iodide. We use density-functional theory to develop a theoretical model to understand the relative growth energetics of the α and 2H phases of FAPbI 3 for different molecular interactions. Experiments and theory show that the presence of PAc molecules stabilizes the formation of α-FAPbI 3 in thin films when excess molecules are available to migrate during growth. This migration of molecules facilitates the continued presence of adsorbed organic precursors at the free surface throughout the evaporation, which lowers the growth energy of the α-FAPbI 3 phase. Our theoretical analyses of PAc molecule–molecule interactions show that ligands can form hydrogen bonding to reduce the migration rate of the molecules through the deposited film, limiting the effects on the crystal structure stabilization. Our results also show that the phase stabilization with molecules that migrate is long-lasting and resistant to moist air. These findings enable reliable formation and processing of α-FAPbI 3 films via vapor deposition.
36 MATERIALS SCIENCE↗
A Jacobian-free pseudo-arclength continuation method for phase transitions in inhomogeneous thermodynamic systems
Developing phase diagrams for inhomogeneous systems in thermodynamics is difficult, in part, due to the large phase space and the possibility of unstable and metastable solutions arising from first-order phase transitions. Pseudo-arclength continuation (PAC) is a method that allows one to trace out stable and unstable solutions of nonlinear systems. Typically, PAC utilizes the Jacobian in order to implement Newton (or quasi-Newton) steps. In this work, we present a Jacobian-free PAC method that is amenable to the usual workflows in inhomogeneous thermodynamics. We demonstrate our method in systems that have first-order phase transitions, including a novel example of polyelectrolyte complex coacervation in confinement, where multiple surface phase transitions occur and can overlap with one another.
Chemistry↗
STAR FORMATION IN LINER HOST GALAXIES AT z {approx} 0.3
We present the results of a Herschel-PACS study of a sample of 97 low-ionization nuclear emission-line regions (LINERs) at redshift z {approx} 0.3 selected from the zCOSMOS survey. Of these sources, 34 are detected in at least one PACS band, enabling reliable estimates of the far-infrared L{sub FIR} luminosities, and a comparison to the FIR luminosities of local LINERs. Many of our PACS-detected LINERs are also UV sources detected by GALEX. Assuming that the FIR is produced in young dusty star-forming regions, the typical star formation rates (SFRs) for the host galaxies in our sample are {approx}10 M{sub Sun} yr{sup -1}, 1-2 orders of magnitude larger than in many local LINERs. Given stellar masses inferred from optical/NIR photometry of the (unobscured) evolved stellar populations, we find that the entire sample lies close to the star-forming 'main sequence' for galaxies at redshift 0.3. For young star-forming regions, the H{alpha}- and UV-based estimates of the SFRs are much smaller than the FIR-based estimates, by factors {approx}30, even assuming that all of the H{alpha} emission is produced by O-star ionization rather than by the active galactic nuclei (AGNs). These discrepancies may be due to large (and uncertain) extinctions toward the young stellar systems. Alternatively, the H{alpha} and UV emissions could be tracing residual star formation in an older, less obscured population with decaying star formation. We also compare L{sub SF} and L(AGN) in local LINERs and in our sample. Finally, we comment on the problematic use of several line diagnostic diagrams in cases with an estimated obscuration similar to that in the sample under study.
79 ASTRONOMY AND ASTROPHYSICS↗