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NASA NTRSDate not supplied

Dissociative Recombination (DR) and Associative Ionization (AI) Cross Section Calculations for the NO+ + e yields N + O (2D+3P, 2P+3P, and 2D+1D) Reaction for Atmospheric Entry Modeling

During entry of a space craft into Earth atmosphere, the flow surrounding the vehicle becomes partially ionized leading to significant cation and free-electron production. Subsequently, electron impact excitation and dissociation form radiating excited state species that contribute to the heat load on the vehicle. While experimental data on selected total cross sections are available, few experiments address the need for accurate AI cross sections for metastable atomic states at the high temperatures realized in atmospheric re-entry. In order to maintain desired safety margins during atmospheric entry of a space vehicle, chemical reaction models need to accurately account for this process. For the present study, we have computed vibrationally resolved cross sections for the DR of NO+ for electron energies between 0.01 to 10 eV and apply microscopic reversibility to obtain the AI cross sections and rate coefficients. For the DR cross section calculations, we use state-of-the-art MRCI potential energy curves. The resulting adiabatic potential curves are transformed to a diabatic representation, which is used in time-dependent wave packet calculations to describe the nuclear motion of the dissociating cation upon collision with an electron. Based on the wave function evolution in time, these calculations provide T-matrix and cross sections for the DR including recombination into the low energy metastable atomic states. The DR and AI rate coefficients are compared with the available experimental data.

Ewa Papajak↗
NASA NTRS1979

Cyclic tests of P-bulb end-seal designs for a shuttle-type wing-elevon cove membrane seal

Four P-bulb end seal designs were tested at room temperature in a cyclic seal test apparatus. Test results show that all the P-bulb end seals have the durability required for a 100 mission life (neglecting possible elevated-temperature effects) and three of the four P-bulbs provide an adequate seal against a 7.0-kPa air pressure differential. Antifriction material attached to the P-bulb rub surface reduced friction slightly but could degrade the sealing effectiveness. A flat rub surface molded into the P-bulb discouraged wrinkling and rolling and thereby reduced leakage. However, the P-bulbs lacked resilience, as indicated by increased leakage when P-bulb compression was reduced. The best P-bulb design tested included an antifriction interface bonded to a flat surface molded into the P-bulb.

Hunt, L. R.↗
NASA NTRS1992

Progress in p(+)n InP solar cells fabricated by thermal diffusion

In SPRAT XI, we proposed that p(sup +)n diffused junction InP solar cells should exhibit a higher conversion efficiency than their n(sup +)p counterparts. This was mainly due to the fact that our p(sup +)n (Cd,S) cell structures consistently showed higher V (sub OC) values than our n(sup +)p (S,Cd) structures. The highest V(sub OC) obtained with the p(sup +)n (Cd,S) cell configuration was 860 mV, as compared to the highest V(sub OC) 840 mV obtained with the n(sup +)p (S,Cd) configuration (AMO, 25 C). In this work, we present the performance results of our most recent thermally diffused cells using the p(sup +)n (Cd,S) structure. We have been able to fabricate cells with V(sub OC) values approaching 880 mV. Our best cell with an unoptimized front contact grid design (GS greater than or equal to 10%) showed a conversion efficiency of 13.4% (AMO, 25 C) without an AR coating layer. The emitter surface was passivated by a -50A P rich oxide. Achievement of such high V(sub OC) values was primarily due to the fabrication of emitter surfaces, having EPD densities as low as 2E2 cm(sup -2) and N(sub a)N(sub d) of about 3E18 cm (sup -3). In addition, our preliminary investigation of p(sup +)n structures seem to suggest that Cd-doped emitter cells are more radiation resistant than Zn-doped emitter cells against both high energy electron and proton irradiation.

Faur, Mircea↗
NASA NTRS2021

Impact of Random and Periodic Surface Roughness on P- and L-band Radiometry

L-band passive microwave remote sensing is currently considered a robust technique for global monitoring of soil moisture. However, soil roughness complicates the relationship between brightness temperature and soil moisture, with current soil moisture retrieval algorithms typically assuming a constant roughness parameter globally, leading to a potential degradation in retrieval accuracy. This current investigation established a tower-based experiment site in Victoria, Australia. P-band (~40-cm wavelength/0.75 GHz) was compared with L-band (~21-cm wavelength/1.41 GHz) over random and periodic soil surfaces to determine if there is an improvement in brightness temperature simulation and soil moisture retrieval accuracy for bare soil conditions, due to reduced roughness impact when using a longer wavelength. The results showed that P-band was less impacted by random and periodic roughness than L-band, evidenced by more comparable statistics across different roughness conditions. The roughness effect from smooth surfaces (e.g., 0.8-cm root-mean-square height and 11.1-cm correlation length) could be potentially ignored at both P- and L-band with satisfactory simulation and retrieval performance. However, for rougher soil (e.g., 1.6-cm root-mean-square height and 6.8-cm correlation length), the roughness impact needed to be accounted for at both P- and L-band, with P-band observations showing less impact than L-band. Moreover, a sinusoidal soil surface with 10-cm amplitude and 80-cm period substantially impacted the brightness temperature simulation and soil moisture retrieval at both P- and L-band, which could not be fully accounted for using the SMOS and SMAP default roughness parameters. However, when retrieving roughness parameters along with soil moisture, the ubRMSE at P-band over periodic soil was improved to a similar level (0.01-0.02 m3/m3) as that of smooth flat soil (0.01 m3/m3), while L-band showed higher ubRMSE over the periodic soil (0.03-0.04 m3/m3) than over smooth flat soil (0.01 m3/m3). Accordingly, periodic roughness effects were reduced by using observations at P-band.

Soil roughness↗
NASA NTRS2000

p-n Junction Diodes Fabricated on Si-Si/Ge Heteroepitaxial Films

A set of photolithographic masks was designed for the fabrication of diodes in the Si-Si/Ge material system. Fabrication was performed on samples obtained from two different wafers: (1) a complete HBT structure with an n (Si emitter), p (Si/Ge base), and an n/n+ (Si collector/sub-collector) deposited epitaxially (MBE) on a high resistivity p-Si substrate, (2) an HBT structure where epitaxial growth was terminated after the p-type base (Si/Ge) layer deposition. Two different process runs were attempted for the fabrication of Si-Si/Ge (n-p) and Si/Ge-Si (p-n) junction diodes formed between the emitter-base and base-collector layers, respectively, of the Si-Si/Ge-Si HBT structure. One of the processes employed a plasma etching step to expose the p-layer in the structure (1) and to expose the e-layer in structure (2). The Contact metallization used for these diodes was a Cu-based metallization scheme that was developed during the first year of the grant. The plasma-etched base-collector diodes on structure (2) exhibited well-behaved diode-like characteristics. However, the plasma-etched emitter-base diodes demonstrated back-to-back diode characteristics. These back-to back characteristics were probably due to complete etching of the base-layer, yielding a p-n-p diode. The deep implantation process yielded rectifying diodes with asymmetric forward and reverse characteristics. The ideality factor of these diodes were between 1.6 -2.1, indicating that the quality of the MBE grown epitaxial films was not sufficiently high, and also incomplete annealing of the implantation damage. Further study will be conducted on CVD grown films, which are expected to have higher epitaxial quality.

Das, K.↗
NASA NTRS2023

P-ACTIVE Project Report

The Phase change material-based actively-tunable filter (P-ACTIVE, Dr. Hyun Jung Kim, the Principal Investigator / PI) project is a NASA Langley Research Center (LaRC)-led research endeavor that began as a NASA CIF (Center Innovation Fund) project in 2019. The goal of P-ACTIVE is to develop all-solid-state tunable optical filters that can serve as low-Size, Weight, and Power (SWaP) replacements to the ubiquitous filter wheel technology current in use, and serve as a starting point for completely new optical component technologies. By using materials commonly used in electronic memory devices, namely chalcogenide phase-change materials (PCMs), in conjunction with nanostructured surfaces with exotic, tailored optical responses (“metasurfaces”), the P-ACTIVE filters are able to tune their optical transmission/reflection behavior in real-time. Because of this new functionality, P-ACTIVE filters are highlighted for NASA science and space programs such as next generation Lidar, landing system (SLS) thermal monitoring, thermal imaging, imaging spectroscopy, and disaster monitoring (e.g., volcanic eruption observations from SmallSats). This document intends to serve as a compendium of the P-ACTIVE project. We begin by describing the project from background science and assume no prior knowledge of the subject. We then address experimental and theoretical results of P-ACTIVE device performance, as well as recent results obtained from the MISSE-14 mission related to space qualification of P-ACTIVE devices and constituent materials. We conclude with a prospective view of the P-ACTIVE technology, and discuss the potential for these filters and other similar metasurface devices to serve NASA’s mission.

metamaterial↗
NASA NTRS2023

A Comparison of Passive Microwave Emission Models for Estimating Brightness Temperature at L- and P-band Under Bare and Vegetated Soil Conditions

P-band radiometry has been demonstrated to have a deeper sensing depth than at L-band, making the consideration of multi-layer microwave interactions necessary. Additionally, the scattering and phase interference effects are different at P-band, requiring a re-consideration of the need for coherent models. However, the impact remains to be clarified, and understanding the validity and limitations of these models at both L-band and P-band is crucial for their refinement and application. Therefore, two general categories of microwave emission models, including two stratified coherent models (Njoku and Wilhite) and four incoherent models (conventional tau-omega model and three multi-layer models being zero-order, first-order, and incoherent solution), were intercompared for the first time on the same dataset. This evaluation utilized observations of L-band and P-band radiometry under different land cover conditions from a tower-based experiment in Victoria, Australia. Model estimations of brightness temperature (TB) were consistent with measurements, with the lowest root mean square error (RMSE) at P-band V-polarization under corn (2 K) and the highest RMSE at L-band H-polarization under bare soil (13 K). Coherent models performed slightly better than incoherent models under bare soil (3 K less RMSE), while the opposite was true under vegetated soil conditions (1 K less RMSE). Coherent and incoherent models showed maximum differences (3 K at P-band, 2 K at L-band), correlating strongly with soil moisture variations at 0-10 cm. Findings suggest that coherent and incoherent models perform similarly; thus, incoherent models may be preferable for estimating TB at L- and P-band due to reduced computational complexity.

Soil moisture profile↗
NASA NTRS1991

High sensitivity of p-modes near the acoustic cutoff frequency to solar model parameters

The p-mode frequencies of low l have been calculated for solar models with initial helium mass fraction varying from Y = 0.2753-0.2875. The differences in frequency of the p-modes in the frequency range, 2500-4500 microHz, do not exceed 1-5 microHz among the models. But in the vicinity of the acoustic cutoff frequency, near 5000 microHz the p-mode frequency differences are enhanced by a factor of 4. The enhanced sensitivity of p-modes near the acoustic cutoff frequency was further tested by calculating and comparing p-mode frequencies of low l for two solar models one incorporating the Eddington T-tau relation and the other the Krishna Swamy T-tau relation. Again, it is found that p-modes with frequencies near the acoustic cutoff frequency show a significant increase in sensitivity to the different T-tau relations, compared to lower frequency p-modes. It is noted that frequencies above the acoustic cutoff frequency are complex, hence, cannot be modeled by the adiabatic pulsation code (assumes real eigenfrequencies) used in these calculations.

Guenther, D. B.↗
NASA NTRS2004

[Analysis of Multiplatform CO (Carbon Monoxide) Measurements During Trace-P Mission]

Carbon monoxide is considered mission critical (TRACE-P NRA) because it is one of the gases involved in controlling the oxidizing power of the atmosphere and, as a tracer gas, is valuable in interpreting mission data sets. Carbon monoxide exhibits interannual differences, suggesting relatively short-term imbalances in sources and sinks. Sources of CO are dominated by fossil fuel combustion, biomass burning, and the photochemical oxidation of CH4 and nonmethane hydrocarbons while reaction with OH is believed to be the major sink for atmospheric CO, with additional losses due to soil uptake. Uncertainties in the magnitude and distribution of both sources and sinks remain fairly large however, and additional data are required to refine the global budget. Seasonal changes and a northern hemispheric latitudinal gradient have been described for a variety of Pacific basin sites through long-term monitoring of surface background levels. Latitudinal variations have also recently been described at upper tropospheric altitudes over a multi-year period by. TRACE-P will provide an aircraft survey of CO over the northern Pacific in the northern spring when CO concentrations are at their seasonal maximum in the northern hemisphere (NH) and at their seasonal minimum in the southern hemisphere (SH). Previous GTE missions, Le., PEM West-B and PEM Tropics-B, ground-based, and satellite observations (MAPS, April 1994) give us a general picture of the distribution of CO over the northern Pacific during this season. Based on these measurements, background CO levels over remote ocean areas are anticipated to be in the range of 110 - 180 ppbv, while those closer to the Asian continent may rise as high as 600 ppbv. These measurements also reveal high spatial variability (both horizontal and vertical) as well as temporal variations in CO over the area planned for the TRACE-P mission. This variability is a result of multiple CO sources, the meteorological complexity of transport processes, and the photochemical aging of air masses. The influence of biomass burning in the southern Pacific should be relatively small since the mission coincides with the southern tropical wet season when agricultural burning is at its seasonal low. The proposed CO measurements taken during TRACE-P should therefore largely be a function of the impact of various NH sources, primarily Asian and predominantly fossil fuel combustion and biomass burning. These processes are also major sources of many other atmospheric pollutants, consequently making accurate and precise CO measurements is one of the highest TRACE-P priorities [TRACE-P NRA]. The TRACE-P mission emphasizes the dual objectives of assessing the magnitude of the transport of chemically and radiatively important gases such as CO from Asia to the western Pacific, and determining how emissions change and are modified during this transport.

Pougatchev, Nikita S.↗
NASA NTRS1998

Venous levels of shear support neutrophil-platelet adhesion and neutrophil aggregation in blood via P-selectin and beta2-integrin

BACKGROUND: After activation, platelets adhere to neutrophils via P-selectin and beta2-integrin. The molecular mechanisms and adhesion events in whole blood exposed to venous levels of hydrodynamic shear in the absence of exogenous activation remain unknown. METHODS AND RESULTS: Whole blood was sheared at approximately 100 s(-1). The kinetics of neutrophil-platelet adhesion and neutrophil aggregation were measured in real time by flow cytometry. P-selectin was upregulated to the platelet surface in response to shear and was the primary factor mediating neutrophil-platelet adhesion. The extent of neutrophil aggregation increased linearly with platelet adhesion to neutrophils. Blocking either P-selectin, its glycoprotein ligand PSGL-1, or both simultaneously by preincubation with a monoclonal antibody resulted in equivalent inhibition of neutrophil-platelet adhesion (approximately 30%) and neutrophil aggregation (approximately 70%). The residual amount of neutrophil adhesion was blocked with anti-CD11b/CD18. Treatment of blood with prostacyclin analogue ZK36374, which raises cAMP levels in platelets, blocked P-selectin upregulation and neutrophil aggregation to baseline. Complete abrogation of platelet-neutrophil adhesion required both ZK36374 and anti-CD18. Electron microscopic observations of fixed blood specimens revealed that platelets augmented neutrophil aggregation both by forming bridges between neutrophils and through contact-mediated activation. CONCLUSIONS: The results are consistent with a model in which venous levels of shear support platelet adherence to neutrophils via P-selectin binding PSGL-1. This interaction alone is sufficient to mediate neutrophil aggregation. Abrogation of platelet adhesion and aggregation requires blocking Mac-1 in addition to PSGL-1 or P-selectin. The described mechanisms are likely of key importance in the pathogenesis and progression of thrombotic disorders that are exacerbated by leukocyte-platelet aggregation.

NASA Discipline Cell Biology↗
NASA NTRS2022

Evaluation of the Tau-Omega Model Over Bare and Wheat-Covered Flat and Periodic Soil Surfaces at P- and L-band

It has been over ten years since the successful launch of the first-ever dedicated satellite for global soil moisture monitoring; Soil Moisture and Ocean Salinity (SMOS). Looking towards the future, P-band (0.3-1 GHz) is a promising technique to replace or enhance the L-band (1.4 GHz) SMOS and SMAP (Soil Moisture Active Passive) missions because of an expected reduction in roughness and vegetation impact, leading to an improved soil moisture accuracy over rougher soil surfaces and more densely vegetated areas. Accordingly, this investigation evaluated the tau-omega model at P-band (0.75 GHz) using a tower-based experiment in Victoria, Australia, where brightness temperature observations were collected concurrently at P- and L-band over bare and wheat-covered flat and periodic soil surfaces. The potential to retrieve soil moisture without discriminating periodic and flat surfaces was investigated by applying the roughness and vegetation parameters calibrated for flat soil to retrieve the moisture of periodic soil. Results showed that P-band had a comparable RMSE across different roughness configurations (variations less than 0.016 m3/m3) for both bare and wheat-covered soil, while the L-band RMSE was only comparable for wheat-covered soil, indicating that periodic surfaces did not need to be discriminated in such scenarios. Conversely, a difference of 0.022 m3/m3 was observed for L-band with bare soil. A reduced vegetation impact was also demonstrated at P-band, with an RMSE of 0.029 m3/m3 achieved when completely ignoring the wheat existence with under 4-kg/m2 vegetation water content, whereas at L-band the RMSE increased to 0.063 m3/m3. This study therefore paves the way for a successful P-band radiometer mission for obtaining more accurate global soil moisture information.

P-band↗
NASA NTRS2023

Evaluation of the Tau-Omega Model over a Dense Corn Canopy at P- and L-band

As an emerging technique, P-band (0.3-1GHz) may improve soil moisture remote sensing compared to L-band (1.4 GHz) SMOS (Soil Moisture and Ocean Salinity) and SMAP (Soil Moisture Active Passive) missions, because of its greater moisture retrieval depth resulting from its longer wavelength. Consequently, a number of tower-based experiments were undertaken in Victoria, Australia, to understand and quantify potential improvements. The study reported here has extended the evaluation of the tau-omega model to a scenario with a dense corn canopy whose vegetation water content reached ~20 kg/m 2 , and compared the soil moisture retrieval performance at P- and L-band. Based on the locally calibrated parameters, the results from both the SCA (Single Channel Algorithm) and DCA (Dual Channel Algorithm) approaches presented a clear reduction in vegetation impact at P-band compared to L-band. While the root-mean-square error (RMSE) for P-band did not achieve the 0.04-m 3 /m 3 target accuracy of SMOS and SMAP, i.e., 0.054 m 3 /m 3 for the SCA and 0.074 m 3 /m 3 for the DCA, this performance can be regarded as acceptable considering the extremely high vegetation water content. In comparison, the RMSEs at L-band were larger than 0.1 m 3 /m 3 for both the SCA and the DCA approaches. Additionally, DCA performed better in correlation coefficient and unbiased RMSE, while SCA performed better in RMSE at P-band due to the larger bias when using DCA. Moreover, the calibrated vegetation parameters at P-band were found to apply to broader conditions than those at L-band, likely due to the reduced vegetation impact.

P-band↗
NASA NTRS2023

Towards Soil Moisture Profile Estimation in the Root Zone Using L- and P-Band Radiometer Observations: A Coherent Modelling Approach

Precision irrigation management and crop water stress assessment rely on accurate estimation of root zone soil moisture. However, only the top 5cm soil moisture can be estimated using the two current passive microwave satellite missions, Soil Moisture and Ocean Salinity (SMOS) and Soil Moisture Active Passive (SMAP), which operate at L-band (wavelength of ~21cm). Since the contributing depth of the soil to brightness temperature increases with observation wavelength, it is expected that a P-band (wavelength of ~40cm) radiometer could potentially provide soil moisture information from deeper layers of the soil profile. Moreover, by combining both L- and P- bands, it is hypothesized that the soil moisture profile can be estimated even beyond their individual observation depths. The aim of this study was to demonstrate the potential of combined L-band and P-band radiometer observations to estimate the soil moisture profile under flat bare soil using a stratified coherent forward model. Brightness temperature observations at L-band and P-band from a tower based experimental site across a dry (April 2019) and a wet (March 2020) period, covering different soil moisture profile shapes, were used in this study. Results from an initial synthetic study showed that the performance of a combined L-band and P-band approach was better than the performance of using either band individually, with an average depth over which reliable soil moisture profile information could be estimated (i.e. with a target root mean square error (RMSE) of less than 0.04 m3/m3) being 20cm for linear and 15cm for second-order polynomial functions. Other functions were also tested but found to have a poorer performance. Applying the method to the tower-based brightness temperature achieved an average estimation depth of 28cm (20cm) and 5cm (5cm) during the dry and wet periods respectively when using a second-order polynomial (linear) function. These findings highlight the opportunity of a satellite mission with L-band and P-band observations to accurately estimate the soil moisture profile to as deep as 30cm globally.

Foad Brakhasi↗
NASA NTRS1990

Small gain robustness issues in the p-integrator repetitive controller

The basic theory of the digital p-integrator controller is utilized to modify the command to a stable analog feedback control system in order to produce zero tracking error of a repetitive command. Mapping of continuous time poles and zeros to the images in the discrete time domain is performed. It is shown that for a pole excess of one, with p odd, the p-integrator learning controller will often produce a stable learning process, even for relatively large sample times. For a pole excess of two, a stable learning process can often be achieved for any p as long as the sample time is kept sufficiently short. Therefore, when the pole excess is zero and one utilizes the proper p-integrator controller with p odd, stable performance is often produced, even for relatively large sample times.

Longman, Richard W.↗
NASA NTRS1994

Effect of nonlinear interactions on p-mode frequencies and line widths

We calculate the effect of nonlinear interactions among solar acoustic modes upon the modal frequencies and energy loss rates (or line widths). The frequency shift for a radial p-mode of frequency 3 mHz is found to be about -0.5 microHz. The magnitude of nonlinear frequency shift increases more rapidly with frequency than the inverse mode mass (mode mass is defined as the ratio of energy in the mode to its surface velocity amplitude squared). This frequency shift is primarily due to nonresonant three-mode interactions and is dominated by high l surface gravity waves (f-modes) and p-modes. The line width of a radial p-mode of frequency 3 mHz, due to resonant nonlinear interactions, is about 0.3 microHz. This result is consistent with that of Kumar and Goldreich (1989). We also find, in agreement with these authors, that the most important nonlinear interactions of trapped p-modes involve f-modes and high-frequency p-modes (frequency greater than about 5 mHz) which propagate in the solar photosphere. Thus, using the arguments advanced by Kumar & Goldreich (1989), we conclude that nonlinear couplings cannot saturate the overstable solar p-modes at their small observed amplitudes. Both the nonlinear frequency shifts and line widths, at a fixed frequency, are proportional to the inverse of mode mass which for modes of degree greater than about 100 is approximately l(exp 0.8). Therefore, the frequency of an f-mode of l = 1000, due to nonlinear interactions, is decreased by approximately 0.4%.

Kumar, Pawan↗