Correlation effects of pi electrons. III - Oscillator strength distribution.
Response of pi electrons in large organic molecule to scalar field for coronene, showing oscillator strength enhancement near single particle excitation band
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Response of pi electrons in large organic molecule to scalar field for coronene, showing oscillator strength enhancement near single particle excitation band
Measurements of neutral silicon oscillator strengths (f-values) obtained by absorption and emission techniques have been combined using the numerical procedure of Cardon et al. (1979) to produce 108 f-values for the Si I lines between 163 and 410 nm. Beam-foil-lifetime measurements were employed to determine the absolute scale. The present measurements have uncertainties of about 0.07 dex (+ or - 16 percent) at the 1-sigma level of confidence. Good agreement is obtained between the results and previous data. The data also provide upper limits for the f-values of 22 other lines and information on the lifetimes for 36 levels in Si I.
Analyses on the abundance of interstellar chlorine rely on accurate oscillator strengths for ultraviolet transitions. Beam-foil spectroscopy was used to obtain f-values for the astrophysically important lines of Cl I at 1088, 1097, and 1347 A. In addition, the line at 1363 A was studied. Our f-values for 1088, 1097 A represent the first laboratory measurements for these lines; the values are f(1088)=0.081 +/- 0.007 (1 sigma) and f(1097) = 0.0088 +/- 0.0013 (1 sigma). These results resolve the issue regarding the relative strengths for 1088, 1097 A in favor of those suggested by astronomical measurements. For the other lines, our results of f(1347) = 0.153 +/- 0.011 (1 sigma) and f(1363) = 0.055 +/- 0.004 (1 sigma) are the most precisely measured values available. The f-values are somewhat greater than previous experimental and theoretical determinations.
Quantum mechanical study of transition probabilities, Einstein A coefficients, and oscillator strengths of band systems of diatomic molecules
Oscillator strengths and wavelengths of X ray and EUV transitions in highly ionized iron line spectra
Hydrogen and deuterium oscillator strengths and transition probabilities for Lyman and Werner system individual bands by electronic dipole moment functions
Measurements of the oscillator strengths of the ultraviolet lines of neutral nickel obtained by the use of the combined hook and absorption technique are reported. A total of 221 transitions in the range 1964-4094 A was measured for nickel atoms from a high-temperature graphite furnace (2000-2500 K) using a continuum background source, a Mach-Zehnder interferometer and a 3-m Czerny-Turner spectrograph. Hook and absorption measurements are presented, and radiative lifetimes are derived from log gf values. Comparison of the present values with previous results indicates only those of Bell et al. (1966) and Lennard et al. (1975) to consistently agree with the data presented, although the reliability laser-excitation technique of lifetime measurement is supported over that of Hanle methods.
Born approximation used in calculating wave functions of helium atom for determining generalized oscillator strengths in first ionized continuum of helium
Electronic oscillator strengths for nitrogen second positive and nitrogen first negative systems from observations of shock layers about hypersonic projectiles
Shock tube measurement of autoionization lifetime and oscillator strengths of states above first ionization potential for aluminum
Flash photolysis produced methyl and methylene radical transitions maximum extinction coefficients and oscillator strength in vacuum UV
The stopping of a charged particle by isolated atoms is investigated theoretically using an 'atomic plasma' model in which atomic oscillator strengths are replaced by the plasma frequency spectrum. The plasma-frequency correction factor for individual electron motion proposed by Pines (1953) is incorporated, and atomic mean excitation energies are calculated for atoms through Sr. The results are compared in a graph with those obtained theoretically by Inokuti et al. (1978, 1981) and Dehmer et al. (1975) and with the experimental values compiled by Seltzer and Berger (1982): good agreement is shown.
Oscillator strengths and autoionization lifetime of aluminum I doublet measured in shock tube
Atomic O 1302 A and 1152 A lines oscillator strengths determined from radiative lifetimes measured by phase shift
He isoelectronic sequence 3d-nf transitions, determining UV wavelengths and oscillator strengths
Theoretical calculations of selected excitation energies and oscillator strengths for Ba are presented that overcome the difficulties of previous theoretical treatments. A relativistic effective-core potential treatment is used to account for the relativistic core contraction, but the outermost ten electrons are treated explicitly. Core-valence correlation can be included in this procedure in a rigorous and systematic way through a configuration-interaction calculation. Insight is gained into the importance of relativistic effects by repeating many of the calculations using an all-electron nonrelativistic treatment employing an extended Slater basis set. It is found that the intensity of the intercombination line 3P1-1S0 is accurately determined by accounting for the deviation from LS coupling through spin-orbit mixing with the 1P1 state, and that deviations from the Lande interval rule provide an accurate measure of the degree of mixing.
Absolute absorption values of four strongest bands in molecular N dipole, determining oscillator strengths
Oscillator strengths for 134 lines from the ground term of neutral titanium have been measured by the hook method. The data, which are normalized to those of Bell, Kalman and Tubbs, agree well with most previously measured data but indicate that there is a line strength dependent error in the National Bureau of Standards compilation of TiIf-values by Wiese and Fuhr.