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Rate Constant for the Reaction CH3 + CH3 Yields C2H6 at T = 155 K and Model Calculation of the CH3 Abundance in the Atmospheres of Saturn and Neptune

The column abundances of CH3 observed by the Infrared Space Observatory (ISO) satellite on Saturn and Neptune were lower than predicted by atmospheric photochemical models, especially for Saturn. It has been suggested that the models underestimated the loss of CH3 due to poor knowledge of the rate constant k of the CH3 + CH3 self-reaction at the low temperatures and pressures of these atmospheres. Motivated by this suggestion, we undertook a combined experimental and photochemical modeling study of the CH3 + CH3 reaction and its role in determining planetary CH3 abundances. In a discharge flow-mass spectrometer system, k was measured at T = 155 K and three pressures of He. The results in units of cu cm/molecule/s are k(0.6 Torr) = 6.82 x 10(exp -11), k(1.0 Torr) = 6.98 x 10(exp -11), and k(1.5 Torr) = 6.91 x 10(exp -11). Analytical expressions for k were derived that (1) are consistent with the present laboratory data at T = 155 K, our previous data at T = 202 K and 298 K, and those of other studies in He at T = 296-298 K and (2) have some theoretical basis to provide justification for extrapolation. The derived analytical expressions were then used in atmospheric photochemical models for both Saturn and Neptune. These model results reduced the disparity with observations of Saturn, but not with observations of Neptune. However, the disparity for Neptune is much smaller. The solution to the remaining excess CH3 prediction in the models relative to the ISO observations lies, to a large extent, elsewhere in the CH3 photochemistry or transport, not in the CH3 + CH3 rate.

Cody, Regina J.

Benefits of Application of Advanced Technologies for a Neptune Orbiter, Atmospheric Probes and Triton Lander

Missions with planned launch dates several years from today pose significant design challenges in properly accounting for technology advances that may occur in the time leading up to actual spacecraft design, build, test and launch. Conceptual mission and spacecraft designs that rely solely on off the shelf technology will result in conservative estimates that may not be attractive or truly representative of the mission as it actually will be designed and built. This past summer, as part of one of NASA s Vision Mission Studies, a group of students at the Laboratory for Spacecraft and Mission Design (LSMD) have developed and analyzed different Neptune mission baselines, and determined the benefits of various assumed technology improvements. The baseline mission uses either a chemical propulsion system or a solar-electric system. Insertion into orbit around Neptune is achieved by means of aerocapture. Neptune s large moon Triton is used as a tour engine. With these technologies a comprehensive Cassini-class investigation of the Neptune system is possible. Technologies under investigation include the aerocapture heat shield and thermal protection system, both chemical and solar electric propulsion systems, spacecraft power, and energy storage systems.

Somers, Alan

Binaries in Transneptunian Resonances: Evidence for Slow Migration of Neptune?

A distinguishing feature of trans neptunian objects (TNO) is the high fraction that arc binary. This is particularly true for the Cold Classicals (CC), objects in lowe and low i orbits concentrated between the 3:2 and 2: 1 mean-motion resonances. CCs have other physical markers: red colors, high albedos, and equal-mass binaries. The CCs appear to be a coherent and physically distinct population of planetesimals that has survived to the present with their physical properties relatively unaltered. Their spatial concentration between 39.4 and 47.7 AU has made identification of the CCs as a physical group possible. However, objects that started out as CCs arc almost certainly 1101 limited to this one dynamical niche. We can, therefore, use the measurable physical properties of CCs as tracers of Neptune-driven dynamical mixing in the Kuiper Belt. As Neptune migrated, its mean-motion resonances preceded it into the planetesimal disk. The efficiency of capture into mean motion resonances depends on the smoothness of Neptune's migration and the local population available to be captured. The two strongest resonances, the 3:2 at 39.4 AU and 2: 1 at 47.7 AU, straddle the core repository of the physically distinct CCs, providing a unique opportunity to test the details of Neptune's migration. Smooth migration should result in a measurable difference between the 3:2 and 2:1 with low inclination 2:1s having a red, binary population mirroring that of the CC itself while the 3:2 will be less contaminated. Alternative models with rapid migration would generate a more homogeneous result.

Noll, Keith

Resonant Transneptunian Binaries: Evidence for Slow Migration of Neptune

As Neptune migrated, its mean-motion resonances preceded it into the planetesimal disk. The efficiency of capture into mean motion resonances depends on the smoothness of Neptune's migration and the local population available to be captured. The two strongest resonances, the 3:2 at 39.4 AU and 2:1 at 47.7 AU, straddle the core repository of the physically distinct and binary-rich Cold Classicals, providing a unique opportunity to test the details of Neptune's migration. Smooth migration should result in a measurable difference between the 3:2 and 2:1 resonant object properties, with low inclination 2:1s having a high fraction of red binaries, mirroring that of the Cold Classicals while the 3:2 will would have fewer binaries. Rapid migration would generate a more homogeneous result. Resonant objects observed with HST show a higher rate of binaries in the 2:1 relative to the 3:2, significant at the 2cr level. This suggests slow Neptune migration over a large enough distance that the 2:1 swept through the Cold Classical region. Colors are available for only a fraction of these targets but a prevalence of red objects in outer Resonances has been reported. We report here on ongoing observations with HST in cycle 19 targeting all unobserved Resonants with observations that will measure color and search for binary companions using the WFC3.

Noll, Keith S.

The JPL Neptune Radiation Model (NMOD)

The objective of this study is the development of a comprehensive radiation model of the Neptunian environment for JPL mission planning. The ultimate goal is to provide a description of the high-energy electron and proton environments and the magnetic field at Neptune that can be used for engineering design. The JPL Neptune Radiation Model (NMOD) models the high-energy electrons and protons between 0.025 MeV and 5 MeV based on the California Institute of Technology's Cosmic Ray Subsystem and the Applied Physics Laboratory's Low Energy Charged Particle Detector on Voyager 2. As in previous JPL radiation models, the form of the Neptunian model is based on magnetic field coordinates and requires a conversion from spacecraft coordinates to Neptunian-centered magnetic "B-L" coordinates. Two types of magnetic field models have been developed for Neptune: 1) simple "offset, tilted dipoles" (OTD), and 2) a complex, multi-pole expansion model ("O8"). A review of the existing data on Neptune and a search of the NASA Planetary Data System (PDS) were completed to obtain the most current descriptions of the Neptunian high-energy particle environment. These data were fit in terms of the O8 B-L coordinates to develop the electron and proton flux models. The flux predictions of the new model were used to estimate the total ionizing dose (TID) rate along the Neptunian equator, meridional flux contours for the electrons and protons, and for flux and dose comparisons with the other radiation belts in the Solar System.

Garrett, Henry

The JPL Neptune Radiation Model (NMOD)

The objective of this study is the development of a comprehensive radiation model of the Neptunian environment for JPL mission planning. The ultimate goal is to provide a description of the high-energy electron and proton environments and the magnetic field at Neptune that can be used for engineering design. The JPL Neptune Radiation Model (NMOD) models the high-energy electrons and protons between 0.025 MeV and 5 MeV based on the California Institute of Technology's Cosmic Ray Subsystem and the Applied Physics Laboratory's Low Energy Charged Particle Detector on Voyager 2. As in previous JPL radiation models, the form of the Neptunian model is based on magnetic field coordinates and requires a conversion from spacecraft coordinates to Neptunian-centered magnetic "B-L" coordinates. Two types of magnetic field models have been developed for Neptune: 1) simple "offset, tilted dipoles" (OTD), and 2) a complex, multi-pole expansion model ("O8"). A review of the existing data on Neptune and a search of the NASA Planetary Data System (PDS) were completed to obtain the most current descriptions of the Neptunian high-energy particle environment. These data were fit in terms of the O8 B-L coordinates to develop the electron and proton flux models. The flux predictions of the new model were used to estimate the total ionizing dose (TID) rate along the Neptunian equator, meridional flux contours for the electrons and protons, and for flux and dose comparisons with the other radiation belts in the Solar System.

magnetic field

The Sub-Neptune Desert and Its Dependence on Stellar Type: Controlled by Lifetime X-Ray Irradiation

Short-period sub-Neptunes with substantial volatile envelopes are among the most common type of known exoplanets. However, recent studies of the Kepler population have suggested a dearth of sub-Neptunes on highly irradiated orbits, where they are vulnerable to atmospheric photoevaporation. Physically, we expect this "photoevaporation desert" to depend on the total lifetime X-ray and extreme ultraviolet flux, the main drivers of atmospheric escape. In this work, we study the demographics of sub-Neptunes as a function of lifetime exposure to high-energy radiation and host-star mass. We find that for a given present-day insolation, planets orbiting a 0.3 solar mass star experience approximately 100 times more X-ray flux over their lifetimes versus a 1.2 solar mass star. Defining the photoevaporation desert as a region consistent with zero occurrence at 2 sigma, the onset of the desert happens for integrated X-ray fluxes greater than 1.43 times 10 (sup 22) to 8.23 times 10 (sup 20) as a function of planetary radii for 1.8 to 4 Earth radius. We also compare the location of the photoevaporation desert for different stellar types. We find much greater variability in the desert onset in the bolometric flux space compared to the integrated X-ray flux space, suggestive of photoevaporation driven by steady-state stellar X-ray emissions as the dominant control on desert location. Finally, we report tentative evidence for the sub-Neptune valley, first seen around Sun-like stars, for M&K dwarfs. The discovery of additional planets around low-mass stars from surveys such as the Transiting Exoplanet Survey Satellite (TESS) mission will enable detailed exploration of these trends.

Planets and Satellites: Gaseous Planets

Neptune Long-Lived Atmospheric Features in 2013 - 2015 from Small (28-cm) to Large (10-m) Telescopes

Since 2013, observations of Neptune with small telescopes (28-50 cm) have resulted in several detections of long-lived bright atmospheric features that have also been observed by large telescopes such as Keck II or Hubble. The combination of both types of images allows the study of the long-term evolution of major cloud systems in the planet. In 2013 and 2014 two bright features were present on the planet at southern mid-latitudes. These may have merged in late 2014, possibly leading to the formation of a single bright feature observed during 2015 at the same latitude. This cloud system was first observed in January 2015 and nearly continuously from July to December 2015 in observations with telescopes in the 2-10-m class and in images from amateur astronomers. These images show the bright spot as a compact feature at −40.1 +/- 1.6 deg planetographic latitude well resolved from a nearby bright zonal band that extended from −42 deg to −20 deg. The size of this system depends on wavelength and varies from a longitudinal extension of 8000 +/- 900 km and latitudinal extension of 6500 +/- 900 km in Keck II images in H and Ks bands to 5100 +/- 1400 km in longitude and 4500 +/- 1400 km in latitude in HST images in 657 nm. Over July to September 2015 the structure drifted westward in longitude at a rate of 24.48 +/- 0.03 deg/day or −94 +/- 3 m/s. This is about 30 m/s slower than the zonal winds measured at the time of the Voyager 2 flyby. Tracking its motion from July to November 2015 suggests a longitudinal oscillation of 16 deg in amplitude with a 90-day period, typical of dark spots on Neptune and similar to the Great Red Spot oscillation in Jupiter. The limited time covered by high-resolution observations only covers one full oscillation and other interpretations of the changing motions could be possible. HST images in September 2015 show the presence of a dark spot at short wavelengths located in the southern flank (planetographic latitude −47.0 deg) of the bright compact cloud observed throughout 2015. The drift rate of the bright cloud and dark spot translates to a zonal speed of −87.0 +/- 2.0 m/s, which matches the Voyager 2 zonal speeds at the latitude of the dark spot. Identification of a few other features in 2015 enabled the extraction of some limited wind information over this period. This work demonstrates the need of frequently monitoring Neptune to understand its atmospheric dynamics and shows excellent opportunities for professional and amateur collaborations.

dynamics

Ultraviolet photometry from the Orbiting Astronomical Observatory. XIII - The albedos of Jupiter, Uranus, and Neptune

Presentation of OAO-2 broad-band ultraviolet photometry data for Jupiter, Uranus, and Neptune. These data have been combined with observations of 23 late-type stars to derive planetary albedos over the region 2000-4300 A. The new broad-band albedo for Jupiter agrees well with a previous measurement based on OAO-2 spectrometer data. The albedos for Uranus and Neptune are in good agreement with ground measurements in the region of overlap. The results for Uranus and Neptune have been compared with theoretical calculations for semiinfinite and finite pure H2 Rayleigh-Raman scattering atmospheres. Except for the shortest wavelengths, the measurements lie below the semiinfinite theoretical calculations. The calculations for the finite atmospheres suggest that an additional absorbing constituent will be needed to explain the observed albedos.

Savage, B. D.

Possibility of detecting magnetospheric radio bursts from Uranus and Neptune

The intensity of magnetospheric radio bursts (MRBs) is scaled to solar-wind input into planetary magnetospheres and the frequency of emission is scaled to polar surface magnetic-field strength in order to estimate the possibility of detecting MRBs from Uranus and Neptune. A scaling law is derived which relates the ratio of power radiated in MRBs to the solar-wind input for earth, Jupiter, and Saturn. Power-flux spectra of MRBs from these three planets are plotted, and it is shown that Jupiter and Saturn may radiate 1% to 5% of the solar-wind energy input into their magnetospheres. The properties of MRBs from Uranus and Neptune are estimated by assuming a conversion efficiency of 1% to 5%, a bandwidth of half the peak frequency, and conformity of Uranus' and Neptune's dipole moments with the magnetic Bode's law. Based on the results, it is suggested that detection of MRBs from these two planets may be a reasonable cruise-mode radio-astronomy objective on future missions to the outer solar system.

Kennel, C. F.

Comparative thermal evolution of Uranus and Neptune

We extend a Jovian convective-cooling model to Uranus and Neptune. The model assumes that efficient interior convection prevails, so that escape of interior heat is governed by the radiative properties of the atmosphere. A comparison of the thermal evolution of Uranus and Neptune indicates that the large amount of solar radiation absorbed in Uranus' atmosphere tends to differentially suppress the escape of interior heat. The model is shown to be consistent with recent infrared observations of the thermal balance of Uranus and Neptune, and with the presumed age of these planets.

Hubbard, W. B.

Far-infrared observations of Uranus, Neptune, and Ceres

During a single flight of our 102 cm balloon-borne telescope and 40-250 micron photometer we observed Uranus, Neptune, Ceres, Venus, Mars, and Saturn. Effective temperatures for Uranus (58.5 plus or minus 2 K) and Neptune (59.7 plus or minus 4 K) were determined, thus confirming the absence of a substantial internal heat source for Uranus and the presence of one for Neptune. Ceres has a brightness temperature of 195 plus or minus 12 K at an effective wavelength of 60 microns.

Stier, M. T.

The rotation period of Neptune

Photometric observations of Neptune with a highly accurate doubly differential photometer, two filters centered in the 6190-A band of methane, and two immediately adjacent continuum filters centered at 5993 and 6332 A are reported which were performed in the interval from March 29 to August 8, 1977. The principal rotation period of at least a major methane albedo feature of Neptune's deeper atmosphere is found to be 18.44 + or - 0.01 (est. error) hr, assuming that such features are stable in longitude over weeks or months. The result obtained is compared with previous determinations, and reasons for a discrepancy between the present and a previous photometric period are considered. It is suggested that the period of 18.44 hr is likely to be quite close to that of the main body of Neptune.

Slavsky, D.

Galileo's observations of Neptune

Galileo's recorded observations of Neptune are examined, including an assessment of the accuracies of the positions of Neptune and those of the Jovian satellites. It is shown that one observation may be of astrometric value. The possible error in the ephemeris of Neptune is also discussed.

Kowal, C. T.

Observations of Uranus, Neptune, and Titan by the International Ultraviolet Explorer

The ultraviolet spectra of Uranus, Neptune, and Titan do not reveal absorption features at 7-A resolution from 2100 to 3200 A. Upper limits of from 1 to 3 A are set for the equivalent widths of narrow absorptions, which corresponds to a CO/H2 mixing ratio less than 2 x 10 to the -4th in the case of Uranus. The slopes of the continuum reflectivities of Uranus and Neptune are consistent with the semi-infinite Rayleigh-Raman scattering model of Cochran, while the absolute levels are matched only if solar photometry is modified within acceptable limits. An alternative, but less satisfactory explanation of the new data is that the UV reflectivities of both Uranus and Neptune are depressed uniformly by a continuum absorber. The suggestion by Savage et al (1980) that the albedo of Uranus decreases by approximately 20% from 2200 to 1800 A is not confirmed. For Titan, the albedo decreases monotonically toward shorter wavelengths down to 2300 A. New limits are set for the pressure level in the atmosphere of Titan up to which the real, but presently unidentified, UV absorber there must extend, and for the fraction of Titan that must be covered by this absorber

Caldwell, J.

The rotation period of Neptune's upper atmosphere

The variations in the near-infrared brightness of Neptune observed during July and August 1980 show a well-defined, large-amplitude variation in Neptune's J-K color, with a period of 17.73 + or - 0.1 hour. These results are interpreted as diurnal variations resulting from the 17.73-hour rotation period of the Neptune upper atmosphere in the presence of inhomogeneous weather, and are found to qualitatively corroborate those of Cruikshank (1978). It is also noted that Smith and Slavsky (1980) report a 17.7-hour component as a secondary periodicity in their data. Variations were observed in the 5-0-micron spectral region which are in phase with the variations seen at shorter wavelengths.

Brown, R. H.

New observational constraints on the temperature inversions of Uranus and Neptune

The presence of a temperature inversion in the lower stratospheres of both Uranus and Neptune is confirmed by the 20-micron photometric data presented. It is found that the brightness temperature difference between 17.8 and 19.6 microns is 0.8 + or - 0.5 K for Uranus and 1.8 + or - 0.6 K for Neptune, implying that the temperature inversions of both planets are weaker than previously thought. Comparisons with model atmospheres suggested by Appleby (1980) imply that these temperature inversions may be understood as a consequence of heating through CH4 and aerosol absorption of sunlight. The stratospheric CH4 mixing ratio of Neptune must, however, be higher than that at the temperature minimum.

Tokunaga, A. T.

The structure of Neptune's upper atmosphere - The stellar occultation of 24 May 1981

Observations of the 24 May 1981 occulation of an uncatalogued star by Neptune made at the Cerro Tololo Inter-American Observatory have been analyzed to yield temperature profiles of Neptune's upper atmosphere for number densities near 5 x 10 to the 13th per cu cm. The mean temperatures at immersion (latitude - 56 deg) and emersion (latitude - 16 deg) obtained by numerical inversion were 140 + or - 10 K and 154 + or - 10 K, respectively. The immersion and emersion profiles are remarkably similar in overall shape, suggestive of global atmospheric layering. From the astrometry of the event, precise relative positions of Neptune and the occulted star were obtained.

French, R. G.