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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5

Power System Recovery Coordinated with (Non-)Black-Start Generators

Power restoration is an urgent task after a black-out, and recovery efficiency is critical when quantifying system resilience. Multiple elements should be considered to restore the power system quickly and safely. This paper proposes a recovery model to solve a direct-current optimal power flow (DCOPF) based on mixed-integer linear programming (MILP). Since most of the generators cannot start independently, the interaction between black-start (BS) and non-black-start (NBS) generators must be modeled appropriately. The energization status of the NBS is coordinated with the recovery status of transmission lines, and both of them are modeled as binary variables. Also, only after an NBS unit receives the cranking power through connected transmission lines, will it be allowed to participate in the following system dispatch. The amount of cranking power is estimated as a fixed proportion to the maximum generation capacity. The proposed model is validated on several test systems, as well as a 1393-bus representation system of the Puerto Rican electric power grid. Test results demonstrate how the recovery of NBS units and damaged transmission lines can be optimized, resulting in an efficient and well-coordinated recovery procedure.

Zhao, Meng↗

Spontaneous self-intercalation of copper atoms into transition metal dichalcogenides

Intercalated transition metal dichalcogenides (TMDs) have attracted substantial interest due to their exciting electronic properties. Here, we report a unique approach where copper (Cu) atoms from bulk Cu solid intercalate spontaneously into van der Waals (vdW) gaps of group IV and V layered TMDs at room temperature and atmospheric pressure. This distinctive phenomenon is used to develop a strategy to synthesize Cu species–intercalated layered TMD compounds. A series of Cu-intercalated 2H-NbS 2 compounds were obtained with homogeneous distribution of Cu intercalates in the form of monovalent Cu (I), occupying the tetrahedral sites coordinated by S atoms within the interlayer space of NbS 2 . The Fermi level of NbS 2 shifts up because of the intercalation of Cu, resulting in the improvement of electrical conductivity in the z-direction. On the other hand, intercalation of Cu into vdW gaps of NbS 2 systematically suppresses the superconducting transition temperature (T c ) and superconducting volume fraction.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Development of techniques and associated instrumentation for high temperature emissivity measurements

The calibrating and testing procedures for the radiometric emittance measurement apparatus are described. Test results are given for the NBS platinum-rhodium standard (SRM No. 1409), the NBS oxidized Kanthal standard, and the oxidized Rene 41 materials. Results indicate that with the platinum-rhodium standard the measurement system compared with the NBS data to within 0.02 for both total and spectral normal emitttance. Data from the Kanthal strip was consistently higher than NBS values. For oxidized Rene 41, no significant changes in as prepared emittance was observed. The emittance was stable for temperatures up to 1150 K.

Cunnington, G. R.↗

Numerical Modeling of Thermofluid Transients During Chilldown of Cryogenic Transfer Lines

The chilldown of fluid transfer lines is an important part of using cryogenic systems such as those found in both ground and space based applications. The chilldown process is a complex combination of both thermal and fluid transient phenomena. A cryogenic liquid flows through a transfer line that is initially at a much higher temperature than the cryogen. Transient heat transfer processes between the liquid and transfer line cause vaporization of the liquid, and this phase change can cause transient pressure and flow surges in the liquid. As the transfer line is cooled, these effects diminish until the liquid reaches a steady flow condition in the chilled transfer line. If these transient phenomena are not properly accounted for in the design process of a cryogenic system, it can lead to damage or failure of system components during operation. For such cases, analytical modeling is desirable for ensuring that a cryogenic system transfer line design is adequate for handling the effects of a chilldown process. The purpose of this paper is to present the results of a numerical model developed using Generalized Fluid System Simulation Program (GFSSP)'s new fluid transient capability in combination with its previously developed thermal transient capability to predict pressure and flow surge in cryogenic transfer lines during a chilldown process. An experiment performed by the National Bureau of Standards (NBS) in 1966 has been chosen as the baseline comparison case for this work. NBS s experimental set-up consisted of a 10.59 cubic foot supply dewar, an inlet valve, and a 200 foot long, in Outside Diameter (OD) vacuum jacketed copper transfer line that exhausted to atmosphere. Three different inlet valves, an in-port ball valve, a 1-in-port globe valve and a 1-in-port gate valve, were used in NBS's experiments. Experiments were performed using both liquid hydrogen and liquid nitrogen as the fluids. The proposed paper will include detailed comparisons of GFSSP's predictions with NBS's experimental results.

Majumdar, Alok↗

Layered Nano-Mosaic of Niobium Disulfide Heterostructures by Direct Sulfidation of Niobium Carbide MXenes for Hydrogen Evolution

MXene-transition metal dichalcogenide (TMD) heterostructures are synthesized through a one-step heat treatment of Nb 2 C and Nb 4 C 3 . These MXenes are used without delamination or any pre-treatment. Heat treatments accomplish the sacrificial transformation of these MXenes into TMD (NbS 2 ) at 700 and 900 °C under H 2 S. This work investigates, for the first time, the role of starting MXene phase in the derivative morphology. It is shown that while treatment of Nb 2 C at 700 °C leads to the formation of pillar-like structures on the parent MXene, Nb 4 C 3 produces nano-mosaic layered NbS 2 . At 900 °C, both MXene phases, of the same transition metal, fully convert into nanomosaic layered NbS 2 preserving the parent MXene’s layered morphology. When tested as electrodes for hydrogen evolution reaction, Nb 4 C 3 -derived hybrids show better performance than Nb 2 C derivatives. The Nb 4 C 3 -derived heterostructure exhibits a low overpotential of 198 mV at 10 mA cm -2 and a Tafel slope of 122 mV dec -1 , with good cycling stability in an acidic electrolyte

36 MATERIALS SCIENCE↗

Charge correlations and magnetoelastic coupling in intercalated transition metal dichalcogenides

The large van der Waals gap in transition metal dichalcogenides (TMDs) offers an avenue to tune the ground state of 2D materials through the intercalation of magnetic atoms. Here, we investigate the charge correlations in Fe 1/3 ⁢TaS 2 , Co 1/3 ⁢TaS 2 , and Fe 0.35 ⁢NbS 2 by combining angle-resolved photoemission spectroscopy (ARPES), x-ray scattering, magnetometry, and density functional theory (DFT). We find that, while short-range charge fluctuations develop in Ta-based compounds, Fe 0.35 ⁢NbS 2 exhibits long-range charge order which is strongly coupled with magnetic order and tunable by external magnetic field. Our electronic structure analysis reveals that intercalation reconstructs the Fermi surface via charge transfer and band renormalization, yet does not generate the nesting conditions compatible with the observed ordering vectors. Complementary phonon calculations further exclude a conventional electron-phonon origin of charge order. Together, these results establish magnetoelastic coupling as the dominant mechanism behind charge ordering in Fe 0.35 ⁢NbS 2 and highlight the contrasting role of Nb and Ta hosts in stabilizing correlated ground states in intercalated TMDs.

36 MATERIALS SCIENCE↗

The RNA-binding protein Modulo promotes neural stem cell maintenance in Drosophila

A small population of stem cells in the developing Drosophila central nervous system generates the large number of different cell types that make up the adult brain. To achieve this, these neural stem cells (neuroblasts, NBs) divide asymmetrically to produce non-identical daughter cells. The balance between stem cell self-renewal and neural differentiation is regulated by various cellular machinery, including transcription factors, chromatin remodelers, and RNA-binding proteins. The list of these components remains incomplete, and the mechanisms regulating their function are not fully understood, however. Here, we identify a role for the RNA-binding protein Modulo (Mod; nucleolin in humans) in NB maintenance. We employ transcriptomic analyses to identify RNA targets of Mod and assess changes in global gene expression following its knockdown, results of which suggest a link with notable proneural genes and those essential for neurogenesis. Mod is expressed in larval brains and its loss leads to a significant decrease in the number of central brain NBs. Stem cells that remain lack expression of key NB identity factors and exhibit cell proliferation defects. Mechanistically, our analysis suggests these deficiencies arise at least in part from altered cell cycle progression, with a proportion of NBs arresting prior to mitosis. Overall, our data show that Mod function is essential for neural stem cell maintenance during neurogenesis.

Parra, Amalia S.↗

Materials Data on Nb11S12 by Materials Project

(Nb)3(NbS3)2(NbS)6 crystallizes in the triclinic P1 space group. The structure is two-dimensional and consists of six niobium molecules; four NbS sheets oriented in the (0, 0, 1) direction; and two NbS3 sheets oriented in the (0, 0, 1) direction. In each NbS sheet, there are three inequivalent Nb+2.18+ sites. In the first Nb+2.18+ site, Nb+2.18+ is bonded in a distorted T-shaped geometry to three S2- atoms. There are one shorter (2.44 Å) and two longer (2.45 Å) Nb–S bond lengths. In the second Nb+2.18+ site, Nb+2.18+ is bonded in a distorted T-shaped geometry to three S2- atoms. There are two shorter (2.45 Å) and one longer (2.46 Å) Nb–S bond lengths. In the third Nb+2.18+ site, Nb+2.18+ is bonded in a distorted T-shaped geometry to three S2- atoms. There are two shorter (2.44 Å) and one longer (2.45 Å) Nb–S bond lengths. There are three inequivalent S2- sites. In the first S2- site, S2- is bonded in a distorted T-shaped geometry to three Nb+2.18+ atoms. In the second S2- site, S2- is bonded in a distorted T-shaped geometry to three Nb+2.18+ atoms. In the third S2- site, S2- is bonded in a distorted T-shaped geometry to three Nb+2.18+ atoms. In each NbS3 sheet, there are two inequivalent Nb+2.18+ sites. In the first Nb+2.18+ site, Nb+2.18+ is bonded to six S2- atoms to form edge-sharing NbS6 octahedra. There are a spread of Nb–S bond distances ranging from 2.42–2.46 Å. In the second Nb+2.18+ site, Nb+2.18+ is bonded to six S2- atoms to form edge-sharing NbS6 octahedra. There are a spread of Nb–S bond distances ranging from 2.42–2.46 Å. There are six inequivalent S2- sites. In the first S2- site, S2- is bonded in an L-shaped geometry to two Nb+2.18+ atoms. In the second S2- site, S2- is bonded in a distorted L-shaped geometry to two Nb+2.18+ atoms. In the third S2- site, S2- is bonded in an L-shaped geometry to two Nb+2.18+ atoms. In the fourth S2- site, S2- is bonded in an L-shaped geometry to two Nb+2.18+ atoms. In the fifth S2- site, S2- is bonded in a distorted L-shaped geometry to two Nb+2.18+ atoms. In the sixth S2- site, S2- is bonded in an L-shaped geometry to two Nb+2.18+ atoms.

36 MATERIALS SCIENCE↗

Evaluation of powder metallurgy manufactured nanostructured bainitic steel for wind turbine gearbox applications

This project evaluated the feasibility of nanostructured bainitic steel (NBS) for wind turbine gearbox applications. NBS alloys show superior rolling-contact fatigue and wear performance and require only minimal heat-treatment steps to form the desirable microstructure. However, despite the single-step heat treatment, NBS takes longer to form the target microstructure, and the high carbon content of the alloy requires careful processing to avoid cracking.

17 WIND ENERGY↗

Optimizing Optical Searches for Supermassive Black Hole Binaries in Active Galactic Nuclei Light Curves: Fourier versus Bayesian Periodicity Detection

Simulations predict that supermassive black hole binaries (SMBHBs) will exhibit periodic brightness variations that may exceed the stochastic variability intrinsic to active galactic nuclei (AGN). In this paper, we simulate SMBHBs with damped random walk (DRW) AGN variability and an added sinusoidal signal from the orbital motion, and test three methods—a generalized Lomb–Scargle periodogram (GLSP), a nested Bayesian sampler (NBS), and a weighted wavelet z-transform (or WWZ)—to determine which is best at recovering the periodicity. Our simulated light curves follow the properties of the Catalina Real-Time Transient Survey (or CRTS), Legacy Survey of Space and Time (LSST), and Zwicky Transient Facility (ZTF) to best inform current and future SMBHB searches. We map a broad range of parameter space and identify which DRW-only light curves best mimic periodicity and pass each method’s model selection. The NBS performs best at detecting periodicity and filtering out DRW-only light curves. Combined candidate selection with both the NBS and GLSP significantly reduces false-positive rates (FPRs) with marginal impact on true-positive rates (TPRs). With this joint model selection pipeline, we find the lowest FPRs in ZTF-like simulations and the highest detection rates in LSST-like simulations. Using a modified computation of the false-alarm probability with GLSP, we efficiently triage LSST AGN light curves (∼10 7 light curves in ∼10–30 hr) and achieve TPRs and FPRs of ∼40% and ∼0.5%, respectively.

Banaszak, Sebastian M. [Vanderbilt Univ., Nashvill↗

Apparatus description and data analysis of a radiometric technique for measurements of spectral and total normal emittance

The development of a radiometric technique for determining the spectral and total normal emittance of materials heated to temperatures of 800, 1100, and 1300 K by direct comparison with National Bureau of Standards (NBS) reference specimens is discussed. Emittances are measured over the spectral range of 1 to 15 microns and are statistically compared with NBS reference specimens. Results are included for NBS reference specimens, Rene 41, alundum, zirconia, AISI type 321 stainless steel, nickel 201, and a space-shuttle reusable surface insulation.

Edwards, S. F.↗

Spectral radiance calibrations between 165-300 nm - An interlaboratory comparison

The spectral radiance of deuterium lamps calibrated by the Max-Planck-Institut fuer Astronomie (MPI), by the U.S. National Bureau of Standards (NBS), and by the Physikalisch-Technische Bundesanstalt (PTB) are compared to check the agreement of UV radiometric scales. The NBS group used the optically thin continuum radiation from a wall-stabilized hydrogen arc as its fundamental radiometric standard, while the MPI and PTB groups used the synchrotron radiation facility in DESY. It is found that the spectral radiance scales based upon the DESY synchrotron and the NBS hydrogen arc are consistent, at least for one wavelength relative to another.

Bridges, J. M.↗

Studies with the Arapahoe smoke chamber

Samples of polymethyl methacrylate, polyvinyl chloride, polyester, and polystyrene were evaluated using the Arapahoe smoke chamber. These same materials had been previously evaluated using the National Bureau of Standards (NBS) smoke chamber. The percent smoke based on initial weight as determined using the Arapahoe smoke chamber appeared to correlate with the maximum specific optical density under flaming conditions as determined using the NBS smoke chamber. In addition, the percent smoke based on weight loss as determined using the Arapahoe smoke chamber appeared to correlate with the maximum specific optical density under nonflaming conditions as determined using the NBS smoke chamber. The Arapahoe smoke chamber also offers the advantage of high sample throughput and the possibility of related studies of smoke particulates.

Hilado, C. J.↗

Test methodology for evaluation of fireworthy aircraft seat cushions

Aircraft seat materials were evaluated in terms of their thermal performance. The materials were evaluated using (a) thermogravimetric analysis, (b) differential scanning calorimetry, (c) a modified NBS smoke chamber to determine the rate of mass loss and (d) the NASA T-3 apparatus to determine the thermal efficiency. In this paper, the modified NBS smoke chamber will be described in detail since it provided the most conclusive results. The NBS smoke chamber was modified to measure the weight loss of materials when exposed to a radiant heat source over the range of 2.5 to 7.5 W/cm sq. This chamber has been utilized to evaluate the thermal performance of various heat blocking layers utilized to protect the polyurethane cushioning foam used in aircraft seats. Various kinds of heat blocking layers were evaluated by monitoring the weight loss of miniature seat cushions when exposed to the radiant heat. The effectiveness of aluminized heat blocking systems was demonstrated when compared to conventional heat blocking layers such as neoprene. All heat blocking systems showed good fire protection capabilities when compared to the state-of-the-art, i.e., wool-nylon over polyurethane foam.

Kourtides, D. A.↗

Results of using the global positioning system to maintain the time and frequency synchronization in the Deep Space Network

There are two hydrogen maser clocks located at each signal processing center (SPC) in the DSN. Close coordination of the time and frequency of the SPC clocks is needed to navigate spacecraft to the outer planets. A recent example was the Voyager spacecraft's encounter with Uranus in January 1986. The clocks were adjusted with the goal of minimizing time and frequency offsets between the SPCs at encounter. How time and frequency at each SPC is estimated using data acquired from the Global Positioning System Timing Receivers operating on the NBS-BIH (National Bureau of Standards-Bureau International de l'Heure) tracking schedule is described. These data are combined with other available timing receiver data to calculate the time offset estimates. The adjustment of the clocks is described. It was determined that long range hydrogen maser drift is quite predictable and adjustable within limits. This enables one to minimize time and frequency differences between the three SPCs for many months by matching the drift rates of the three standards. Data acquisition and processing techniques using a Kalman filter to make estimates of time and frequency offsets between the clocks at the SPCs and UTC(NBS) (Coordinated Universal Time realized at NBS) are described.

Clements, P. A.↗

The design and development of the Hubble space telescope neutral buoyancy trainer

The design and fabrication of Hubble Space Telescope (HST) Extra Vehicular Activity (EVA) training hardware for zero-gravity simulations in the Marshall Space Flight Center Neutral Buoyancy Simulator (NBS) are discussed. The HST NBS hardware was also used to support flight hardware development and development of EVA crew servicing procedures. The design and fabrication of simulator training and development hardware, the associated test support from utility divers, test conductors, and test subjects have all been with the common goal of enabling HST program management to use NBS EVA data to make design and program decisions.

Source record↗

Computer program for thermal and transport properties of parahydrogen from 20 to 10,000 K

A computer program was recently developed to provide thermal and transport properties for parahydrogen across a wide temperature and pressure range. The program, NBS+/-pH2, matches the most recent parahydrogen property data from the National Bureau of Standards up to 3000 K and property data from the NASA Lewis Research Center's Chemical Equilibrium Computer Program up to 10,000 K. The pressure range of NBS+/-pH2 is from 1 x 10(exp 4) to 1.6 x 10(exp 7) Pa. The program was developed to meet the need for accurate parahydrogen properties from liquid to dissociated conditions as required by propulsion simulation programs being developed under the Space Exploration Initiative. NBS+/-pH2 is a machine-independent, standard Fortran 77 program which provides density, thermal conductivity, viscosity, Prandtl number, entropy, specific heats, and speed of sound given pressure and either temperature or enthalpy. This program is described and a comparison to programs previously available is provided.

Walton, James T.↗

Thermal Performance of Aircraft Polyurethane Seat Cushions

Aircraft seat materials were evaluated in terms of their thermal performance. The materials were evaluated using (a) thermogravimetric analysis, (b) differential scanning calorimetry, (c) a modified NBS smoke chamber to determine the rate of mass loss and (d) the NASA T-3 apparatus to determine the thermal efficiency. In this paper, the modified NBS smoke chamber will be described in detail since it provided the most conclusive results. The NBS smoke chamber was modified to measure the weight loss of material when exposed to a radiant heat source over the range of 2.5 to 7.5 W/sq cm. This chamber has been utilized to evaluate the thermal performance of various heat blocking layers utilized to protect the polyurethane cushioning foam used in aircraft seats. Various kinds of heat blocking layers were evaluated by monitoring the weight loss of miniature seat cushions when exposed to the radiant heat. The effectiveness of aluminized heat blocking systems was demonstrated when compared to conventional heat blocking layers such as neoprene. All heat blocking systems showed good fire protection capabilities when compared to the state-of-the-art, i.e., wool-nylon over polyurethane foam.

Kourtides, D. A.↗