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At least 91 records · Page 5

An interlaboratory comparison of mid-infrared spectra acquisition: Instruments and procedures matter

Diffuse reflectance spectroscopy has been extensively employed to deliver timely and cost-effective predictions of a number of soil properties. However, although several soil spectral laboratories have been established worldwide, the distinct characteristics of instruments and operations still hamper further integration and interoperability across mid-infrared (MIR) soil spectral libraries. In this study, we conducted a large-scale ring trial experiment to understand the lab-to-lab variability of multiple MIR instruments. By developing a systematic evaluation of different mathematical treatments with modeling algorithms, including regular preprocessing and spectral standardization, we quantified and evaluated instruments' dissimilarity and how this impacts internal and shared model performance. We found that all instruments delivered good predictions when calibrated internally using the same instruments' characteristics and standard operating procedures by solely relying on regular spectral preprocessing that accounts for light scattering and multiplicative/additive effects, e.g., using standard normal variate (SNV). When performing model transfer from a large public library (the USDA NSSCKSSL MIR library) to secondary instruments, good performance was also achieved by regular preprocessing (e. g., SNV) if both instruments shared the same manufacturer. However, significant differences between the KSSL MIR library and contrasting ring trial instruments responses were evident and confirmed by a semi-unsupervised spectral clustering. For heavily contrasting setups, spectral standardization was necessary before transferring prediction models. Non-linear model types like Cubist and memory-based learning delivered more precise estimates because they seemed to be less sensitive to spectral variations than global partial least square regression. In summary, the results from this study can assist new laboratories in building spectroscopy capacity utilizing existing MIR spectral libraries and support the recent global efforts to make soil spectroscopy universally accessible with centralized or shared operating procedures.

58 GEOSCIENCES↗

Laboratory and field assessment of mid-infrared absorption (MIRA) instrument performance for methane and ethane dry mole fractions

Concurrent measurements of methane (CH 4 ) and ethane (C 2 H 6 ) can be used to identify and separate methane sources, as ethane is present in thermogenic sources (e.g., oil and natural gas) but not in biogenic sources (e.g., agriculture). In this study, we evaluated the performance of multiple Aeris MIRA Ultra instruments (Versions 1 and 2) through controlled laboratory tests and tower-based deployments under field conditions. The systems were modified with an external pump, flow control, a Nafion dryer, and a custom-built auxiliary box to automate the system and transmit near real-time data. We determined the best calibration approach for our application, given practical limitations, to be a full calibration cycle (with ambient and high calibration cylinders) about once per day and an ambient calibration cylinder sampled hourly. Measurement uncertainty was assessed, including the uncertainty due to instrument noise as a function of calibration frequency, uncertainty in the water vapor correction, and cylinder assignment uncertainty. Instrument noise was the dominant source of uncertainty for C 2 H 6 , while the water vapor correction dominated the CH 4 uncertainty. For Version 2 systems with hourly calibrations and a Nafion dryer with counterflow, the mean total uncertainty, including both systematic errors and noise, of hourly averages was 0.8–3.0 ppb CH 4 and 0.35–0.37 ppb C 2 H 6 . Laboratory intercomparisons showed network compatibility within 1.2 ppb CH 4 and 0.23 ppb C 2 H6, and a collocated deployment with a NOAA Picarro system agreed within 1.8 ppb CH 4 . Instrument noise varied substantially amongst the instruments, with errors reaching up to 11 ppb CH 4 and 2 ppb C 2 H 6 for hourly means, with similar variability indicated in a 50 h cylinder test. With appropriate engineering and calibration, the Aeris MIRA Ultra has the potential to distinguish regional methane emission sources in many field settings.

03 NATURAL GAS↗

The Origins Space Telescope

The Origins Space Telescope will trace the history of our origins from the time dust and heavy elements permanently altered the cosmic landscape to present-day life. How did galaxies evolve from the earliest galactic systems to those found in the universe today? How do habitable planets form? How common are life-bearing worlds? To answer these alluring questions, Origins will operate at mid- and far-infrared wavelengths and offer powerful spectroscopic instruments and sensitivity three orders of magnitude better than that of Herschel, the largest telescope flown in space to date. After a 3 ½ year study, the Origins Science and Technology Definition Team will recommend to the Decadal Survey a concept for Origins with a 5.9-m diameter telescope cryo cooled to 4.5 K and equipped with three scientific instruments. A mid-infrared instrument (MISC-T) will measure the spectra of transiting exoplanets in the 2.8 – 20 μm wavelength range and offer unprecedented sensitivity, enabling definitive biosignature detections. The Far-IR Imager Polarimeter (FIP) will be able to survey thousands of square degrees with broadband imaging at 50 and 250 μm. The Origins Survey Spectrometer (OSS) will cover wavelengths from 25 – 588 μm, make wide-area and deep spectroscopic surveys with spectral resolving power R ~ 300, and pointed observations at R ~ 40,000 and 300,000 with selectable instrument modes. Origins was designed to minimize complexity. The telescope has a Spitzer-like architecture and requires very few deployments after launch. The cryo-thermal system design leverages JWST technology and experience. A combination of current-state-of-the-art cryocoolers and next-generation detector technology will enable Origins’ natural background limited sensitivity.

Leisawitz, D.↗

Characterization of Si-Membrane TES Bolometer Arrays for the HIRMES Instrument

The High Resolution Mid-Infrared Spectrometer (HIRMES) instrument will fly onboard NASA's airborne Stratospheric Observatory for Infrared Astronomy (SOFIA) in 2019. HIRMES will provide astronomers with a unique observing window (25 122 µm) for exploring the evolution of protoplanetary disks into young solar systems, and the composition of our Solar System. There are two focal plane detector arrays for the instrument: a high-resolution (/ = 100,000) 8x16 detector array with a target noise-equivalent power, NEP 3x10-18 W/Hz; and a low-resolution (/ = 2,000 19,000) 16x64 detector array with a target NEP 2x10-17 W/Hz. The detectors for both of these arrays are superconducting Mo/Au bilayer transition edge sensor (TES) bolometers on thin suspended single-crystal silicon membranes. Here we present our characterization results for the detectors in both arrays, including measurements of thermal conductance with comparison to phonon transport models, saturation power, noise, and array uniformity.

Instrumentation and Photography↗

Development of mid-IR lasers for Laser Remote Sensing

There is an existing need in JPL and in NASA for development of mid-IR lasers, such as Quantum Cascade (QC) lasers, for in-situ and remote laser spectrometers. Mid-IR, compact, low power consumption laser spectrometers have a great potential for detection and measurements of planetary gases and biological important biomarker molecules such as H20, H202, CH4, and many additional chemical species on Mars and other Solar system planets. Another potential application of QC lasers for future NASA mission is in high power remote Laser Reflectance Spectrometers (LRS). In LSR instrument, mid-infrared lasers will act as the illumination source for conducting active mid-IR reflectance spectroscopy of solid-surfaced objects in the outer Solar System. These spectrometers have the potential to provide an incredible amount of information about the compositions of surfaces in the outer Solar System. In this work, we will discuss our current effort at JPL to advance QC lasers to a level that the laser performance, operational requirements and reliability be compatible with the instruments demands for space exploration applications.

Mid - IR lasers↗

VLTI-MATISSE Chromatic Aperture-Synthesis Imaging of η Carinae’s Stellar Wind Across the Brα Line: Periastron Passage Observations in February 2020

Context: Eta Carinae is a highly eccentric, massive binary system (semimajor axis∼15.5 au) with powerful stellar winds and a phase-dependent wind-wind collision (WWC) zone. The primary star, ηCar A, is a luminous blue variable (LBV); the secondary, η Car B, is a Wolf-Rayet or O star with a faster but less dense wind. Aperture-synthesis imaging allows us to study the mass loss from the enigmatic LBV η Car. Understanding LBVs is a crucial step toward improving our knowledge about massive stars and their evolution. Aims: Our aim is to study the intensity distribution and kinematics of η Car’s WWC zone. Methods: Using the VLTI-MATISSE mid-infrared interferometry instrument, we perform Brα imaging of η Car’s distorted wind. Results: We present the first VLTI-MATISSE aperture-synthesis images of η Car A’s stellar wind in several spectral channels distributed across the Brα 4.052 μm line (spectral resolving power R∼960). Our observations were performed close to periastron passage in February 2020 (orbital phase∼14.0022). The reconstructed iso-velocity images show the dependence of the primary stellar wind on wavelength or line-of-sight (LOS) velocity with a spatial resolution of 6 mas (∼14 au). The radius of the faintest outer wind regions is∼26 mas (∼60 au). At several negative LOS velocities, the primary stellar wind is less extended to the northwest than in other directions. This asymmetry is most likely caused by the WWC. Therefore, we see both the velocity field of the undisturbed primary wind and the WWC cavity. In continuum spectral channels, the primary star wind is more compact than in line channels. A fit of the observed continuum visibilities with the visibilities of a stellar wind CMFGEN model (CMFGEN is an atmosphere code developed to model the spectra of a variety of objects) provides a full width at half maximum fit diameter of the primary stellar wind of 2.84±0.06 mas (6.54±0.14 au). We compare the derived intensity distributions with the CMFGEN stellar wind model and hydrodynamic WWC models.

G Weigelt↗

Mid-infrared detector development for the Origins Space Telescope

Mid-infrared detector arrays operating from 2.8 to 20 μm are baselined in the design of the Origins Space Telescope Mid-Infrared Spectrometer Instrument. This instrument is designed to detect and measure the spectral signatures of gases of biogenic origin in the atmospheres of exoplanets as they transit their host stars. In order to make these detections, the detector array’s pixels need to have high-signal stability when exposed to a constant flux in multiple time-series integration over a typical transit time of a few hours. With the use of a densified pupil spectrometer design, pointing effects can be mitigated because pointing variations do not displace spectra on the detector and each wavelength of light is averaged over a large number of pixels, giving good spectrophotometric stabilities. The current state-of-the-art detector arrays do not achieve these stabilities, although with a feasible development program this level of performance should be achievable. Three detector technologies are under consideration for this development, HgCdTe arrays, Si:As impurity band conduction arrays, and transition edge super-conductor bolometer arrays. We primarily treat the HgCdTe technology development, but also introduce the paths forward for the other two technologies. After a few years-long investigative programs, a down-select will be undertaken to select the flight technology.

Astronomy↗

VLTI-MATISSE L- and N-Band Aperture-Synthesis Imaging of the Unclassified B[e] star FS Canis Majoris

Context. FS Canis Majoris (FS CMa, HD 45677) is an unclassified B[e] star surrounded by an inclined dust disk. The evolutionary stage of FS CMa is still debated. Perpendicular to the circumstellar disk, a bipolar outflow was detected. Infrared aperture-synthesis imaging provides us with a unique opportunity to study the disk structure. Aims. Our aim is to study the intensity distribution of the disk of FS CMa in the mid-infrared L and N bands. Methods. We performed aperture-synthesis imaging of FS CMa with the MATISSE instrument (Multi AperTure mid-Infrared SpectroScopic Experiment) in the low spectral resolution mode to obtain images in the L and N bands. We computed radiative transfer models that reproduce the L- and N-band intensity distributions of the resolved disks. Results. We present L- and N-band aperture-synthesis images of FS CMa reconstructed in the wavelength bands of 3.4–3.8 and 8.6–9.0 μm. In the L-band image, the inner rim region of an inclined circumstellar disk and the central object can be seen with a spatial resolution of 2.7 milliarcsec (mas). An inner disk cavity with an angular diameter of ~6 × 12 mas is resolved. The L-band disk consists of a bright northwestern (NW) disk region and a much fainter southeastern (SE) region. The images suggest that we are looking at the bright inner wall of the NW disk rim, which is on the far side of the disk. In the N band, only the bright NW disk region is seen. In addition to deriving the inclination and the inner disk radius, fitting the reconstructed brightness distributions via radiative transfer modelling allows one to constrain the innermost disk structure, in particular the shape of the inner disk rim.

techniques↗

Maintaining Flatness of a Large Aperture Potassium Bromide Beamsplitter through Mounting and Vibration

The Composite Infrared Spectrometer (CIRS) instrument on the Cassini Mission launched in October of 1997. The CIRS instrument contains a mid-infrared and a far-infrared interferometer and operates at 170 Kelvin. The mid-infrared interferometer is a Michelson- type Fourier transform spectrometer utilizing a 3 inch diameter potassium bromide beamsplitter/compensator pair. The potassium bromide elements were tested to verify effects of cooldown and vibration prior to integration into the instrument. The instrument was then aligned at ambient temperatures, tested cryogenically and re-verified after vibration. The stringent design optical figure requirements for the beamsplitter and compensator included fabrication errors, mounting stresses and vibration load effects. This paper describes the challenges encountered in mounting the elements to minimize distortion and to survive vibration.

Losch, Patricia↗

Maintaining Flatness of a Large Aperture Potassium Bromide Beamsplitter Through Mounting and Vibration

The Composite Infrared Spectrometer (CIRS) instrument on the Cassini Mission launched in October of 1997. The CIRS instrument contains a mid-infrared (MIR) and a far-infrared interferometer (FIR) and operates at 170 Kelvin. The MIR is a Michelson Fourier transform spectrometer utilizing a 76 mm (3 inch) diameter potassium bromide beamsplitter and compensator pair. The potassium bromide elements were tested to verify effects of cooldown and vibration prior to integration into the instrument. The instrument was then aligned at ambient temperatures, tested cryogenically and re-verified after vibration. 'Me stringent design optical figure requirements for the beamsplitter and compensator included fabrication errors, mounting stresses and vibration load effects. This paper describes the challenges encountered in mounting the elements to minimize distortion and to survive vibration.

Losch, Patricia↗

Mobile Instruments Measure Atmospheric Pollutants

As a part of NASA's active research of the Earth s atmosphere, which has included missions such as the Atmospheric Laboratory of Applications and Science (ATLAS, launched in 1992) and the Total Ozone Mapping Spectrometer (TOMS, launched on the Earth Probe satellite in 1996), the Agency also performs ground-based air pollution research. The ability to measure trace amounts of airborne pollutants precisely and quickly is important for determining natural patterns and human effects on global warming and air pollution, but until recent advances in field-grade spectroscopic instrumentation, this rapid, accurate data collection was limited and extremely difficult. In order to understand causes of climate change and airborne pollution, NASA has supported the development of compact, low power, rapid response instruments operating in the mid-infrared "molecular fingerprint" portion of the electromagnetic spectrum. These instruments, which measure atmospheric trace gases and airborne particles, can be deployed in mobile laboratories - customized ground vehicles, typically - to map distributions of pollutants in real time. The instruments must be rugged enough to operate rapidly and accurately, despite frequent jostling that can misalign, damage, or disconnect sensitive components. By measuring quickly while moving through an environment, a mobile laboratory can correlate data and geographic points, revealing patterns in the environment s pollutants. Rapid pollutant measurements also enable direct determination of pollutant sources and sinks (mechanisms that remove greenhouse gases and pollutants), providing information critical to understanding and managing atmospheric greenhouse gas and air pollutant concentrations.

Source record↗

Mid-Infrared Astronomy with the NGST

We present an overview of the science capabilities enabled by a mid-infrared camera/spectrometer on board the NGST. Even without full mid-IR optimization, a mid-infrared (5-30 microns) instrument on the NGST will be orders of magnitude more sensitive than any equivalent ground-based instrument/telescope combination. In the extragalactic arena, the mid-IR region is critical for a complete understanding of the or high-redshift universe, dusty star-formation regions at low and high redshifts, and starburst vs. AGN discrimination. In the local universe, great strides forward can be made using mid-IR imaging, spectroscopy, and coronagraphy of dusty and rocky disks of all ages, from protostellar to remnant debris disks. Near-neighbor detection and characterization can also be greatly advanced by mid-infrared observations.

Serabyn, E.↗

Mid-infrared spectroscopic investigation

Mid-infrared spectroscopic research efforts are discussed. The development of a new instrumentation to permit advanced measurements in the mid-infrared region of the spectrum, the development of a special library of well-characterized mineral and rock specimens for interpretation of remote sensing data, and cooperative measurements of the spectral signatures of analogues of materials that may be present on the surfaces of asteroids, planets or their Moons are discussed.

Salisbury, John W.↗

Radiation Hard Bandpass Filters for Mid- to Far-IR Planetary Instruments

We present a novel method to fabricate compact metal mesh bandpass filters for use in mid- to far-infrared planetary instruments operating in the 20-600 micron wavelength spectral regime. Our target applications include thermal mapping instruments on ESA's JUICE as well as on a de-scoped JEO. These filters are novel because they are compact, customizable, free-standing copper mesh resonant bandpass filters with micromachined silicon support frames. The filters are well suited for thermal mapping mission to the outer planets and their moons because the filter material is radiation hard. Furthermore, the silicon support frame allows for effective hybridization with sensors made on silicon substrates. Using a Fourier Transform Spectrometer, we have demonstrated high transmittance within the passband as well as good out-of-band rejection [1]. In addition, we have developed a unique method of filter stacking in order to increase the bandwidth and sharpen the roll-off of the filters. This method allows one to reliably control the spacing between filters to within 2 microns. Furthermore, our method allows for reliable control over the relative position and orienta-tion between the shared faces of the filters.

Brown, Ari D.↗

Throughput of the Composite Infrared Spectrometer (CIRS) Mid Infrared (MIR) Channel for the Cassini Mission to Saturn

The Composite Infrared Spectrometer (CIRS) of the Cassini mission to Saturn has two interferometers covering the far infrared and mid infrared wavelength region. The instrument was aligned at ambient temperature, but operates at 170 Kelvin and has challenging interferometric alignment tolerances. Cryogenic alignment tests of the instrument indicate that it should suffer minimal degradation due to the cooldown from ambient to operational temperature. System level tests performed by the calibration team indicated a lower than expected signal level on the MIR channel, while providing ambiguous optical throughput data. Therefore it became imperative to develop a metric that could be used to determine the instrument performance at both the instrument and system levels, at ambient and cryogenic temperature. Modulation efficiency and throughput measurements were performed and new analytical models developed to evaluate the status of the instrument. Empirical and analytical data were eventually reconciled and deviations from the design values explained.

Hagopian, John G.↗

Multi-Color QWIP FPAs for Hyperspectral Thermal Emission Instruments

Infrared focal plane arrays (FPAs) covering broad mid- and long-IR spectral ranges are the central parts of the spectroscopic and imaging instruments in several Earth and planetary science missions. To be implemented in the space instrument these FPAs need to be large-format, uniform, reproducible, low-cost, low 1/f noise, and radiation hard. Quantum Well Infrared Photodetectors (QWIPs), which possess all needed characteristics, have a great potential for implementation in the space instruments. However a standard QWIP has only a relatively narrow spectral coverage. A multi-color QWIP, which is compromised of two or more detector stacks, can to be used to cover the broad spectral range of interest. We will discuss our recent work on development of multi-color QWIP for Hyperspectral Thermal Emission Spectrometer instruments. We developed QWIP compromising of two stacks centered at 9 and 10.5 ?m, and featuring 9 grating regions optimized to maximize the responsivity in the individual subbands across the 7.5-12 ?m spectral range. The demonstrated 1024x1024 QWIP FPA exhibited excellent performance with operability exceeding 99% and noise equivalent differential temperature of less than 15 mK across the entire 7.5-12 ?m spectral range.

Infrared focal plane arrays (FPAs)↗