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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS2011

High precision electric gate for time-of-flight ion mass spectrometers

A time-of-flight mass spectrometer having a chamber with electrodes to generate an electric field in the chamber and electric gating for allowing ions with a predetermined mass and velocity into the electric field. The design uses a row of very thin parallel aligned wires that are pulsed in sequence so the ion can pass through the gap of two parallel plates, which are biased to prevent passage of the ion. This design by itself can provide a high mass resolution capability and a very precise start pulse for an ion mass spectrometer. Furthermore, the ion will only pass through the chamber if it is within a wire diameter of the first wire when it is pulsed and has the right speed so it is near all other wires when they are pulsed.

Sittler, Edward C.↗
NASA NTRS1986

High-resolution mapping of mass loss from highly evolved carbon stars

The molecular component of the mass outflow at high resolution was mapped with the Owens Valley Millimeter-Wave Interferometer in two well-known objects, CRL 2688 and CIT 6. Interferometric observations of a pair of carbon stars which are evolving toward the planetary nebula stage have revealed evidence of episodic, nonspherically symmetric mass loss, and may lead to a fuller understanding of shielding properties of the dust grains involved in these flows.

Ball, R.↗
NASA NTRS1980

Pioneer Venus Sounder Probe Neutral Gas Mass Spectrometer

A neutral gas mass spectrometer was flown to Venus as part of the Pioneer Venus Multiprobe to measure the composition of its lower atmosphere. The instrument, mounted in the Sounder Probe, was activated after the probe entered the top of the atmosphere, and it obtained data during the descent from 62 km to the surface. Atmospheric gases were sampled through a pair of microleaks, the effluent from which was pumped by a combination of ion and getter pumping. A pneumatically operated valve, controlled by the ambient atmospheric pressure, maintained the ion source pressure at a nearly constant value during descent while the atmospheric pressure varied by three orders of magnitude. A single focusing magnetic sector field mass spectrometer with mass resolution sufficient to reasonably separate argon from C3H4 at 40 amu provided the mass analysis and relative abundance measurements. A microprocessor controlled the operation of the mass spectrometer through a highly efficient peak-tip stepping routine and data compression algorithm that effected a scan of the mass spectrum from 1 to 208 amu in 64 sec while requiring an information rate of only 40 bits/sec to return the data to earth. A subscale height altitude resolution was thus obtained. Weight, size, and power requirements were minimized to be consistent with interplanetary flight contraints.

Hoffman, J. H.↗
NASA NTRS1974

Analytical techniques for identification and study of organic matter in returned lunar samples

The results of geochemical research are reviewed. Emphasis is placed on the contribution of mass spectrometric data to the solution of specific structural problems. Information on the mass spectrometric behavior of compounds of geochemical interest is reviewed and currently available techniques of particular importance to geochemistry, such as gas chromatograph-mass spectrometer coupling, modern sample introduction methods, and computer application in high resolution mass spectrometry, receive particular attention.

Burlingame, A. L.↗
NASA NTRS1987

The heavy ion analyser PICCA for the comet Halley fly-by with Giotto

The heavy ion analyzer RPA2-PICCA is designed to identify the composition and distribution of thermal positive ions in the coma of the comet Halley. The instrument is an electrostatic analyzer which takes advantage of the large relative flyby velocity and the fact that the ions in the inner coma should have low temperatures and be predominantly singly charged. Thus, the energy/charged measurements can be directly related to the mass distribution of the ions. Mass identification will be provided in the range from 10 to 203 amu (atomic mass units) with a mass resolution of either 0.4 amu or 1 amu, dependent on the ion mass.

Korth, A.↗
NASA NTRS1981

Isotopes of cosmic ray elements from neon to nickel

Results obtained from a balloon exposure of a cosmic ray detector flown in 1977 are reported. The charge resolution ranged from 0.19 to 0.21 charge units between neon and nickel and the mass resolution for nuclei stopped in the emulsions ranged from 0.40 to 0.70 amu for A between 20 and 60 amu. This was enough to correctly identify almost all nuclei, but not to uniquely resolve neighboring mass peaks. Both Ne and Mg show evidence for neutron enrichment relative to the solar system abundance. Si and S are consistent with solar abundances, while Ar has no significant source abundances. P, Cl and K have essentially no primary component and the isotopic distribution observed is quite consistent with that expected from propagation. An excess of Ca-44 at the source is shown, indicating high metallicity in the source. The abundance of Fe-58 is nine percent or less, and Ni shows a one-to-one ratio for Ni-58 to 60, implying intermediate metallicity.

Waddington, C. J.↗
NASA NTRS1972

Three bit mass spectral search program

Computer program is developed to interpret spectral data in order to assist chemist in identifying low resolution mass spectra. Two versions of program, using approximately same amount of core are available. In both programs, core requirements are roughly proportional to maximum number of unknowns to be handled on each pass through tape.

Grotch, S. L.↗
NASA NTRS1972

The electron-impact promoted fragmentation of aurone epoxides.

The mass spectra of six aurone epoxides have been rationalized with the aid of high resolution mass spectrometry and metastable ion evidence. These compounds fragment in a well defined manner and mechanisms are proposed for the formation of their characteristic ions. Some similarity was observed between the mass spectra of 6-methoxyaurone epoxide (II), 4-hydroxy-7-methoxy-3-phenylcoumarin (VII) and 7-methoxyflavonol (IX). The possibility that VII and IX are intermediates in the fragmentation of epoxide II is discussed. Thermal rearrangement of aurone epoxide II was shown to yield the corresponding flavonol IX and coumarin VII.

Brady, B. A.↗
NASA NTRS2012

Comparing the Performance of Hyperbolic and Circular Rod Quadrupole Mass Spectrometers with Applied Higher Order Auxiliary Excitation

This work applies higher order auxiliary excitation techniques to two types of quadrupole mass spectrometers (QMSs): commercial systems and spaceborne instruments. The operational settings of a circular rod geometry commercial system and an engineering test-bed for a hyperbolic rod geometry spaceborne instrument were matched, with the relative performance of each sensor characterized with and without applied excitation using isotopic measurements of Kr+. Each instrument was operated at the limit of the test electronics to determine the effect of auxiliary excitation on extending instrument capabilities. For the circular rod sensor, with applied excitation, a doubling of the mass resolution at 1% of peak transmission resulted from the elimination of the low-mass side peak tail typical of such rod geometries. The mass peak stability and ion rejection efficiency were also increased by factors of 2 and 10, respectively, with voltage scan lines passing through the center of stability islands formed from auxiliary excitation. Auxiliary excitation also resulted in factors of 6 and 2 in peak stability and ion rejection efficiency, respectively, for the hyperbolic rod sensor. These results not only have significant implications for the use of circular rod quadrupoles with applied excitation as a suitable replacement for traditional hyperbolic rod sensors, but also for extending the capabilities of existing hyperbolic rod QMSs for the next generation of spaceborne instruments and low-mass commercial systems.

Gershman, D. J.↗
NASA NTRS2012

Comparing the Performance of Hyperbolic and Circular Rod Quadrupole Mass Spectrometers with Applied Higher Order Auxiliary Excitation

This work applies higher order auxiliary excitation techniques to two types of quadrupole mass spectrometers (QMSs): commercial systems and spaceborne instruments. The operational settings of a circular rod geometry commercial system and an engineering test-bed for a hyperbolic rod geometry spaceborne instrument were matched, with the relative performance of each sensor characterized with and without applied excitation using isotopic measurements of Kr+. Each instrument was operated at the limit of the test electronics to determine the effect of auxiliary excitation on extending instrument capabilities. For the circular rod sensor, with applied excitation, a doubling of the mass resolution at 1% of peak transmission resulted from the elimination of the low-mass side peak tail typical of such rod geometries. The mass peak stability and ion rejection efficiency were also increased by factors of 2 and 10, respectively, with voltage scan lines passing through the center of stability islands formed from auxiliary excitation. Auxiliary excitation also resulted in factors of 6 and 2 in peak stability and ion rejection efficiency, respectively, for the hyperbolic rod sensor. These results not only have significant implications for the use of circular rod quadrupoles with applied excitation as a suitable replacement for traditional hyperbolic rod sensors, but also for extending the capabilities of existing hyperbolic rod QMSs for the next generation of spaceborne instruments and low-mass commercial systems.

auxiliary excitation↗
NASA NTRSDate not supplied

Application of High-Spatial Resolution LA-MC-ICP-MS in Planetary Materials

High-precision stable and radiogenic isotopic measurements of planetary materials can help elucidate processes taking place during early Solar System formation, as well as during subsequent planetary differentiation. Laser Ablation Multi Collector Inductively Coupled Plasma Mass Spectrometry (LA-MC-ICP-MS) adds the valuable ability of preserving the spatial context of these isotopic measurements, by sampling small sample volumes (~10 – 60 um diameter) using a pulsed laser system. In the Center for Isotope Cosmochemistry and Geochronology (CICG) at NASA Johnson Space Center, these in-situ isotopic measurements are primarily made using the Applied SpectraTM iX-fs-Tandem LA-LIBS Instrument coupled to the Nu InstrumentsTM SP1700 MC-ICP-MS. The instrumental set-up also provides simultaneous Laser Induced Breakdown Spectroscopy (LIBS) measurements and the potential use of a low energy path with a collision/reaction cell for additional interference removal, though we focus here on the typical high-energy LA-MC-ICP-MS operation. We will provide examples of stable (e.g., Mg) and radiogenic (e.g., Lu-Hf) isotopic systems measured in planetary materials and their terrestrial analogs. The measurement of mass dependent Mg isotopic variations is an important tool for reconstructing processes such as evaporation and condensation of solids in the solar nebula. For early Solar System samples, Mg isotope measurements are also important for the short-lived (t1/2 = 0.7 Ma) Al-Mg chronometer. During laser ablation analyses, the measurement of the Al-Mg isotopic system is made in medium mass resolution (RP ~9500 at ~20% transmission) to limit interferences from 48Ti2+ and 48Ca2+ on 24Mg+, in addition to 52Cr2+ and 12C14N+ on 26Mg+. Measured in the mineral zircon, the 176Lu-176Hf decay system is often used for understanding the growth of continents on Earth, and is also a vital aid in deciphering early large-scale planetary differentiation processes, such as the crystallization of the lunar magma ocean, which is thought to be responsible for much of the Moon’s crust. Lu-Hf measurements are made in low resolution mode (RP <2000), with 10 ion masses (from 171Yb to 180Hf) measured simultaneously to facilitate corrections for isobaric interferences from 176Yb and 176Lu on 176Hf.

Jacob B Setera↗
NASA NTRS1989

Gravitational instability with high resolution

A series of very high resolution simulations have been performed for gravitational clustering in two dimensions. It is shown that mass resolution, achieved by having large numbers of particles, is as important as spatial resolution. New objects arising inside pancakes are found, which are coherent with structure on much larger scales. The evolution of structure in hierarchical clustering models with a sufficiently flat power spectrum includes pancake-like structures, confirming the presence of filaments in cold dark matter universes.

Melott, Adrian L.↗
NASA NTRS1971

Measurement of Particulate Pollutants in the Atmosphere

Representative measurements of the mass concentration of particulate matter in the atmosphere are presented, to demonstrate the application of a new type of instrument evolved from aerospace research to various types of particulate pollution and their dynamics. The instrument employs aerodynamic impaction of particles onto an adhesive-coated piezo-electric crystal whose resonant frequency decreases with mass accretion on its surface, with a resulting particulate mass resolution of 10(exp -11) gram. Applications include air basin with aerial measurement of particulate mass concentration, jet aircraft wake, stationary industrial sources, direct on-line measurement of automobile exhaust, and techniques for source detection.

Ckuan, Raymond L.↗
NASA NTRS2000

Outgassing of Flown and Unflown MIR Solar Cells

A solar panel array with more than ten years space exposure was removed from the Mir core module in November 1997, and an eight panel section was returned to Earth in January 1998. Several solar cells were removed from panel eight of the returned array and placed in a high vacuum system with a residual gas analyzer (200 amu mass spectrometer) and a cold finger. Similar unflown solar cells of the same vintage were later obtained from Energia. Several of the unflown cells were also placed in the vacuum system and outgassed residues were collected on the LN2 cold finger. Almost 3 mg of outgassed residue was collected -from a string of three unflown solar cells over a period of 94 hours under vacuum. The collected residue was weighed with a microbalance, and then the residue was analyzed by FTIR spectroscopy, and by gas chromatograph-mass spectroscopy. About 25 outgassed constituents were separated by the gas chromatograph, and a high-resolution mass spectrum was obtained of each constituent. Molecular identifications have been made for the constituents. The constituents are primarily cyclic siloxanes, and several of the constituents are isomers of the same molecule. Most of the outgassed constituents have a molecular mass of about 500 amu. Almost one mg of residue was extracted from one sq cm of coverglass/adhesive from a flown solar cell by soaking in isopropyl alcohol for 30 minutes. The gas chromatograph separated about 20 constituents. The constituents are mostly cyclic siloxanes with linear branches, hydrocarbons, and phthalates. The typical molecular mass is about 600 amu. These identifications of specific outgassing molecules have resulted in a more complete understanding of the SiO(x) contamination on the Mir solar cell coverglasses, and on the MEEP experiment trays and optical specimens during the Shuttle-Mir Phase One flight experiment program. Adjusted outgassing rates based on the data reported here, and/or measured outgassing rates and specific molecular identifications of ISS hardware samples are needed to input into model predictions of induced environment effects of the ISS.

Harvey, Gale A.↗
NASA NTRS1981

The isotopic composition of Fe and fragmentation nuclei with Z equals 17-25

Using the combined data from 1976 and 1977 balloon flights the isotopic composition of cosmic ray Fe and fragmentation nuclei with Z equals 17-25 have been determined. The telescope used in these studies contains two Cerenkov counters and four total energy counters with an overall mass resolution sigma equals 0.35-0.40 amu. For Fe, approximately 320 nuclei with C/C(max) less than 0.5 are mass analyzed with the result extrapolated to the cosmic ray source, Fe-56 equals 0.952, Fe-54 equals 0.048 plus or minus 0.030 and Fe-58 less than 0.030 of all Fe. Two other isotopes are found to have a significant source abundance, A-36 with an abundance of 0.048 plus or minus 0.013 x Fe and Ca-40 equals 0.088 plus or minus 0.016 x Fe at the source. The source abundance of all other isotopes is less than 0.015 x Fe at the 1 sigma level. Of these fragmentation isotopes there is evidence that most of the Cl-36 has decayed as well as possibly some Mn-54.

Webber, W. R.↗
NASA NTRS2012

Lunar Pickup Ions Observed by ARTEMIS: Spatial and Temporal Distribution and Constraints on Species and Source Locations

ARTEMIS observes pickup ions around the Moon, at distances of up to 20,000 km from the surface. The observed ions form a plume with a narrow spatial and angular extent, generally seen in a single energy/angle bin of the ESA instrument. Though ARTEMIS has no mass resolution capability, we can utilize the analytically describable characteristics of pickup ion trajectories to constrain the possible ion masses that can reach the spacecraft at the observation location in the correct energy/angle bin. We find that most of the observations are consistent with a mass range of approx. 20-45 amu, with a smaller fraction consistent with higher masses, and very few consistent with masses below 15 amu. With the assumption that the highest fluxes of pickup ions come from near the surface, the observations favor mass ranges of approx. 20-24 and approx. 36-40 amu. Although many of the observations have properties consistent with a surface or near-surface release of ions, some do not, suggesting that at least some of the observed ions have an exospheric source. Of all the proposed sources for ions and neutrals about the Moon, the pickup ion flux measured by ARTEMIS correlates best with the solar wind proton flux, indicating that sputtering plays a key role in either directly producing ions from the surface, or producing neutrals that subsequently become ionized.

Artemis↗
NASA NTRS1971

Electron-impact promoted fragmentation of alkyl-n-/1-phenylethyl/-carbamates of primary, secondary and tertiary alcohols.

The mass spectra of twenty alkyl carbamates derived from primary, secondary, and tertiary alcohols are investigated, using deuterium labeling and high-resolution mass spectrometry. Several of the primary and secondary alcohol derivatives are found to yield an ion formally equivalent to the product ion of a McLafferty rearrangement. Deuterium labeling, however, revealed a lack, in these carbamate derivatives, of the usual site specificity associated with the McLafferty rearrangement. A double hydrogen rearrangement process was observed in the mass spectra of several carbamates derived from tertiary alcohols.

Pereira, W. E.↗