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DOE OSTI2016

TRACING SLOW WINDS FROM T TAURI STARS VIA LOW-VELOCITY FORBIDDEN LINE EMISSION

Using Keck/HIRES spectra (Δ v ∼ 7 km s{sup -1}) we analyze forbidden lines of [O i] 6300 Å, [O i] 5577 Å and [S ii] 6731 Å from 33 T Tauri stars covering a range of disk evolutionary stages. After removing a high-velocity component (HVC) associated with microjets, we study the properties of the low-velocity component (LVC). The LVC can be attributed to slow disk winds that could be magnetically (magnetohydrodynamic) or thermally (photoevaporative) driven. Both of these winds play an important role in the evolution and dispersal of protoplanetary material. LVC emission is seen in all 30 stars with detected [O i] but only in two out of eight with detected [S ii], so our analysis is largely based on the properties of the [O i] LVC. The LVC itself is resolved into broad (BC) and narrow (NC) kinematic components. Both components are found over a wide range of accretion rates and their luminosity is correlated with the accretion luminosity, but the NC is proportionately stronger than the BC in transition disks. The full width at half maximum of both the BC and NC correlates with disk inclination, consistent with Keplerian broadening from radii of 0.05 to 0.5 au and 0.5 to 5 au, respectively. The velocity centroids of the BC suggest formation in an MHD disk wind, with the largest blueshifts found in sources with closer to face-on orientations. The velocity centroids of the NC, however, show no dependence on disk inclination. The origin of this component is less clear and the evidence for photoevaporation is not conclusive.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2017

Impacts of solar-absorbing aerosol layers on the transition of stratocumulus to trade cumulus clouds

Abstract. The effects of an initially overlying layer of solar-absorbing aerosol on the transition of stratocumulus to trade cumulus clouds are examined using large-eddy simulations. For lightly drizzling cloud the transition is generally hastened, resulting mainly from increased cloud droplet number concentration (Nc) induced by entrained aerosol. The increased Nc slows sedimentation of cloud droplets and shortens their relaxation time for diffusional growth, both of which accelerate entrainment of overlying air and thereby stratocumulus breakup. However, the decrease in albedo from cloud breakup is more than offset by redistributing cloud water over a greater number of droplets, such that the diurnal-average shortwave forcing at the top of the atmosphere is negative. The negative radiative forcing is enhanced by sizable longwave contributions, which result from the greater cloud breakup and a reduced boundary layer height associated with aerosol heating. A perturbation of moisture instead of aerosol aloft leads to a greater liquid water path and a more gradual transition. Adding absorbing aerosol to that atmosphere results in substantial reductions in liquid water path (LWP) and cloud cover that lead to positive shortwave and negative longwave forcings on average canceling each other. Only for heavily drizzling clouds is the breakup delayed, as inhibition of precipitation overcomes cloud water loss from enhanced entrainment. Considering these simulations as an imperfect proxy for biomass burning plumes influencing Namibian stratocumulus, we expect regional indirect plus semi-direct forcings to be substantially negative to negligible at the top of the atmosphere, with its magnitude sensitive to background and perturbation properties.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS2017

Impacts of Solar-Absorbing Aerosol Layers on the Transition of Stratocumulus to Trade Cumulus Clouds

The effects of an initially overlying layer of solar-absorbing aerosol on the transition of stratocumulus to trade cumulus clouds are examined using large-eddy simulations. For lightly drizzling cloud the transition is generally hastened, resulting mainly from increased cloud droplet number concentration (Nc) induced by entrained aerosol. The increased Nc slows sedimentation of cloud droplets and shortens their relaxation time for diffusional growth, both of which accelerate entrainment of overlying air and thereby stratocumulus breakup. However, the decrease in albedo from cloud breakup is more than offset by redistributing cloud water over a greater number of droplets, such that the diurnal-average shortwave forcing at the top of the atmosphere is negative. The negative radiative forcing is enhanced by sizable longwave contributions, which result from the greater cloud breakup and a reduced boundary layer height associated with aerosol heating. A perturbation of moisture instead of aerosol aloft leads to a greater liquid water path and a more gradual transition. Adding absorbing aerosol to that atmosphere results in substantial reductions in liquid water path (LWP) and cloud cover that lead to positive short-wave and negative longwave forcings on average canceling each other. Only for heavily drizzling clouds is the breakup delayed, as inhibition of precipitation overcomes cloud water loss from enhanced entrainment. Considering these simulations as an imperfect proxy for biomass burning plumes influencing Namibian stratocumulus, we expect regional indirect plus semi-direct forcings to be substantially negative to negligible at the top of the atmosphere, with its magnitude sensitive to background and perturbation properties.

Zhou, Xiaoli↗

DOE OSTI2026

Measuring the neutrino-oxygen neutral current quasielastic cross section using the accelerator neutrino neutron interaction experiment

The Accelerator Neutrino Neutron Interaction Experiment (ANNIE) is a 26-ton gadolinium-doped water Cherenkov detector located on-axis to Fermilab’s Booster Neutrino Beam (BNB). ANNIE is uniquely positioned to perform high-statistics measurements of neutrino-nucleus interactions in water, benefiting from a large neutrino flux due to a short (100-meter) baseline. A central focus of ANNIE’s physics program is the measurement of both charged current (CC) and neutral current (NC) cross sections on water, including neutral current quasielastic (NCQE) and CC-inclusive channels. The NCQE measurement is particularly critical for constraining uncertainties in rare-event searches such as the Diffuse Supernova Neutrino Background (DSNB), where atmospheric $\nu$NCQE interactions constitute a significant and poorly constrained background. This dissertation presents a measurement of the flux-averaged neutrino-oxygen neutral current quasielastic ($\nu$NCQE) cross section using $2.573 \times 10^{20}$~POT of BNB exposure from the 2022 and 2023 beam years. The $\nu$NCQE interaction is identified through the primary $\gamma$-rays produced by nuclear de-excitation of the residual $^{15}$N$^*$ or $^{15}$O$^*$ nucleus following nucleon knockout from $^{16}$O. A dedicated Monte Carlo (MC) re-tuning campaign was conducted using an americium-beryllium (AmBe) calibration source, Michel electrons from stopped muons, and throughgoing dirt muons originating upstream of the detector. This multi-sample approach provided a wide-ranging $\mathcal{O}(\text{MeV})$--$\mathcal{O}(\text{GeV})$ dataset for tuning the simulated detector response, which was subsequently validated against AmBe neutron and Michel electron data for use in the $\nu$NCQE analysis. A dedicated laser calibration campaign was carried out to reduce timing uncertainties across the PMT system, enabling reconstruction of the BNB bunch substructure with sufficient resolution to serve as a background rejection tool. By selecting events in-time with individual neutrino bunches, beam-correlated $\nu$NCQE events are separated from diffuse and accelerator-induced backgrounds, notably skyshine neutrons and externally-originating events, that would otherwise dominate traditional charge-based selections within a small-scale, surface-level, short-baseline detector. A data-driven estimation of the skyshine neutron and external background rates was performed and incorporated into the systematic uncertainty budget. The flux-averaged $\nu$NCQE cross section on oxygen is measured to be $1.57 \pm 0.06\,(\text{stat.})$ $^{+0.91}_{-0.67}\,(\text{syst.})$ $\times 10^{-38}\ \text{cm}^{2}$. A full systematic budget is constructed by propagating uncertainties in the secondary hadronic interaction modeling, background cross section normalizations, detector response, neutrino flux, and the primary $\gamma$-ray emission probabilities from oxygen nuclear de-excitation. An idealized de-excitation model, constructed from existing measurements in the literature is developed to benchmark the predictions of the \textsc{GENIE} event generator. A comparison reveals that \textsc{GENIE} systematically overpredicts the primary $\gamma$-ray emission probability from oxygen de-excitation by a factor of $1.49\times$ for $E_\gamma > 6$~MeV and $3.07\times$ in the $3$--$6$~MeV band. This comparison motivates the dominant systematic uncertainty in this analysis, where a conservative uncertainty of $^{+39.9\%}_{-0\%}$ on the primary $\gamma$-ray signal prediction is assigned. The ANNIE result is consistent with and complementary to existing flux-averaged $\nu$NCQE cross section measurements from T2K and Super-Kamiokande, providing an independent measurement with a different detector, neutrino beam, and analysis methodology. Looking ahead, an upgrade to the ANNIE DAQ infrastructure enabling continuous extended readout will allow a complementary $\nu$NCQE neutron multiplicity measurement, directly relevant to constraining the NCQE background in DSNB searches, competitive with the recent T2K measurement at SK-Gd. The planned Super-SANDI upgrade, deploying a large Water-based Liquid Scintillator (WbLS) volume, will further extend ANNIE's reach to hadronic final states and exclusive NC channels, and enable joint measurements with liquid argon detectors sharing the BNB beamline ahead of DUNE and Hyper-Kamiokande.

Doran, Steven [Iowa State U.]↗

DOE OSTI2016

Growth of boron doped hydrogenated nanocrystalline cubic silicon carbide (3C-SiC) films by Hot Wire-CVD

Highlights: • Boron doped nc-3C-SiC films prepared by HW-CVD using SiH{sub 4}/CH{sub 4}/B{sub 2}H{sub 6}. • 3C-Si-C films have preferred orientation in (1 1 1) direction. • Introduction of boron into SiC matrix retard the crystallanity in the film structure. • Film large number of SiC nanocrystallites embedded in the a-Si matrix. • Band gap values, E{sub Tauc} and E{sub 04} (E{sub 04} > E{sub Tauc}) decreases with increase in B{sub 2}H{sub 6} flow rate. - Abstract: Boron doped nanocrystalline cubic silicon carbide (3C-SiC) films have been prepared by HW-CVD using silane (SiH{sub 4})/methane (CH{sub 4})/diborane (B{sub 2}H{sub 6}) gas mixture. The influence of boron doping on structural, optical, morphological and electrical properties have been investigated. The formation of 3C-SiC films have been confirmed by low angle XRD, Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), Fourier transform infra-red (FTIR) spectroscopy and high resolution-transmission electron microscopy (HR-TEM) analysis whereas effective boron doping in nc-3C-SiC have been confirmed by conductivity, charge carrier activation energy, and Hall measurements. Raman spectroscopy and HR-TEM analysis revealed that introduction of boron into the SiC matrix retards the crystallanity in the film structure. The field emission scanning electron microscopy (FE-SEM) and non contact atomic force microscopy (NC-AFM) results signify that 3C-SiC film contain well resolved, large number of silicon carbide (SiC) nanocrystallites embedded in the a-Si matrix having rms surface roughness ∼1.64 nm. Hydrogen content in doped films are found smaller than that of un-doped films. Optical band gap values, E{sub Tauc} and E{sub 04} decreases with increase in B{sub 2}H{sub 6} flow rate.

36 MATERIALS SCIENCE↗

NASA NTRS2010

Comparison of Node-Centered and Cell-Centered Unstructured Finite-Volume Discretizations: Inviscid Fluxes

Cell-centered and node-centered approaches have been compared for unstructured finite-volume discretization of inviscid fluxes. The grids range from regular grids to irregular grids, including mixed-element grids and grids with random perturbations of nodes. Accuracy, complexity, and convergence rates of defect-correction iterations are studied for eight nominally second-order accurate schemes: two node-centered schemes with weighted and unweighted least-squares (LSQ) methods for gradient reconstruction and six cell-centered schemes two node-averaging with and without clipping and four schemes that employ different stencils for LSQ gradient reconstruction. The cell-centered nearest-neighbor (CC-NN) scheme has the lowest complexity; a version of the scheme that involves smart augmentation of the LSQ stencil (CC-SA) has only marginal complexity increase. All other schemes have larger complexity; complexity of node-centered (NC) schemes are somewhat lower than complexity of cell-centered node-averaging (CC-NA) and full-augmentation (CC-FA) schemes. On highly anisotropic grids typical of those encountered in grid adaptation, discretization errors of five of the six cell-centered schemes converge with second order on all tested grids; the CC-NA scheme with clipping degrades solution accuracy to first order. The NC schemes converge with second order on regular and/or triangular grids and with first order on perturbed quadrilaterals and mixed-element grids. All schemes may produce large relative errors in gradient reconstruction on grids with perturbed nodes. Defect-correction iterations for schemes employing weighted least-square gradient reconstruction diverge on perturbed stretched grids. Overall, the CC-NN and CC-SA schemes offer the best options of the lowest complexity and secondorder discretization errors. On anisotropic grids over a curved body typical of turbulent flow simulations, the discretization errors converge with second order and are small for the CC-NN, CC-SA, and CC-FA schemes on all grids and for NC schemes on triangular grids; the discretization errors of the CC-NA scheme without clipping do not converge on irregular grids. Accurate gradient reconstruction can be achieved by introducing a local approximate mapping; without approximate mapping, only the NC scheme with weighted LSQ method provides accurate gradients. Defect correction iterations for the CC-NA scheme without clipping diverge; for the NC scheme with weighted LSQ method, the iterations either diverge or converge very slowly. The best option in curved geometries is the CC-SA scheme that offers low complexity, second-order discretization errors, and fast convergence.

Diskin, Boris↗

DOE OSTI2026

Near Detector Selection for Neutral Current Disappearance Search at the Short-Baseline Neutrino Program

Various short baseline neutrino experiments observe anomalies that challenge the three-flavor neutrino oscillation model, consistent with a hypothetical “sterile” neutrino that does not interact via the weak force. This poster presents a near detector event selection at the Short-Baseline Near Detector (SBND), developed for the first search for neutral current (NC) disappearance at short-baseline experiments. NC disappearance provides ``smoking gun” insight into the sterile neutrino question because NC interactions are equally sensitive to all three active neutrinos, meaning any change in the NC interaction rate between near and far detectors cannot be explained by oscillations among known flavor states. This analysis focuses on the NC1p topology, the most common NC interaction type at the Short-Baseline Neutrino (SBN) Program. NC topologies are inherently challenging due to their low light yield and the absence of an outgoing charged lepton, which complicates identification and leads to poor energy reconstruction as the outgoing neutrino carries away a large portion of the neutrino’s initial energy. This work presents an NC1p event selection at the near detector, highlighting SBND’s impressive detector capabilities, including trigger efficiency studies. Combined with a novel kinematic energy reconstruction technique leveraging the detector’s outstanding hadronic detail, this analysis establishes a robust near detector foundation to target an NC disappearance measurement consistent with the 3$+$1 sterile neutrino model. This SBND selection will soon be combined with the far detector to conduct an NC disappearance search, providing unique insight and complementary information to traditional charged current searches and advancing the SBN Program’s goal to resolve the sterile neutrino question, including 3$+$1 searches and beyond.

Nicole Pallat, Nicole Pallat [Minnesota U.] (ORCID↗

NASA NTRSDate not supplied

The ZBOT-NC Experiment - Effects of Non-Condensable Gases on Propellant Tank Pressurization and Pressure Control

Introduction Integral to all phases of NASA’s projected planetary expeditions is affordable and reliable cryogenic fluid storage for use in propellant or life support systems. It is greatly advantageous to develop innovative vent-less pressure control designs based on cooling/mixing of the bulk tank fluid to allow storage of the cryogenic fluid with zero or reduced boil-off. The presence of noncondensable gases, can interfere with the condensation at the interface impacting tank pressure control during subcooled jet mixing especially in microgravity. The Zero-Boil-Off Tank (ZBOT) Experiments are a series of small-scale experiments aboard the International Space Station (ISS) that use a transparent volatile simulant fluid in a transparent sealed tank to delineate various fundamental fluid flow, heat and mass transport, and phase change phenomena associated with storage tank pressurization and pressure control in microgravity. The ZBOT-1 experiment was performed on the ISS 2017-2018 timeframe and collected data to validate a state-of-the-art CFD model for tank pressurization and pressure control for a pure system. The ZBOT-NC Experiment is the second experiment in the series to be performed on the International Space Station (ISS) in 2025. Its goal is to investigate the effects of noncondensable gases on interfacial evaporation and condensation during self -pressurization and jet-mixing pressure control in microgravity for a two-component system. Materials & Methods In this work, we will describe the detailed features of the ZBOT-NC experimental hardware and Diagnostics that includes nonintrusive Quantum Dot Thermometry (QDT) for whole field temperature measurement. All microgravity pressurization and pressure control tests will be performed for both the pure and the two-components systems with Xenon and Neon as the two noncondensable gases spanning small and large molecular weights and sizes. The two-phase CFD model that is developed as part of the project will be also presented and discussed. Results Ground-based pressurization and jet mixing experiments and CFD simulation results are compared to each other to validate both the fidelity of the CFD model predictions and the accuracy of the QDT measurement. Model simulations for noncondensable gas effects will also be compared against large Cryogenic LH2-GHe experiments to indicate the noncondensable gas effects on tank pressure control during jet mixing in 1G. Finally, CFD results will be presented to predict the effects of the noncondensable gas during subcooled jet mixing during the ZBOT-NC in advance of the microgravity experiment in 2015.

Evaporation Condensation↗

NASA NTRSDate not supplied

The Zero-Boil-Off Tank Experiment: the Effects of Non-Condensable Gases on Pressurization and Pressure Control of Propellant Tanks in Microgravity

Evaporation Condensation↗

DOE OSTI2019

High power conditioning and benchmarking of planar nitrogen-incorporated ultrananocrystalline diamond field emission electron source

Planar nitrogen-incorporated ultrananocrystalline diamond [(N)UNCD] has emerged as a unique field emission source attractive for accelerator applications because of its capability to generate a high charge beam and handle moderate vacuum conditions. Most importantly, (N)UNCD sources are simple to produce: Conventional high aspect ratio isolated emitters are not required to be formed on the surface, and the actual emitter surface roughness is on the order of only 10–100 nm. A careful reliability assessment of (N)UNCD is required before it may find routine application in accelerator systems. In the present study using an L-band normal conducting single-cell rf gun, a (N)UNCD cathode has been conditioned to ~ 42 MV / m in a well-controlled manner. It reached a maximum output charge of 15 nC corresponding to an average current of 6 mA during an emission period of 2.5 $μ$s . Imaging of the emission current revealed a large number of isolated emitters (density over 100/cm 2 ) distributed on the cathode, which is consistent with previous tests in dc environments. The performance metrics, the emission imaging, and the systematic study of emission properties during rf conditioning in a wide gradient range assert (N)UNCD as an enabling electron source for rf injector designs serving industrial and scientific applications. These studies also improve the fundamental knowledge of the practical conditioning procedure via a better understanding of the emission mechanisms.

43 PARTICLE ACCELERATORS↗

DOE OSTI2024

Impurity induced confinement effects in size-separated Mn-doped CsPbCl 3 nanocrystals

Beyond quantum confinement, impurity doping of semiconductor nanocrystals (NCs) offers a degree of control over their optical and electronic properties, which are of interest for potential applications. Manganese (Mn)-doped CsPbCl 3 NCs, for example, show synergistic effects in the visible, with large enhancements in both blue (exciton) and red (dopant) emission over a narrow range of dopant concentration. Although Mn concentration is the primary parameter, NC size offers an additional degree of control over the number of dopants per NC. Size-resolved CsPbCl 3 NCs prepared in the limit of strong Mn doping highlight the emergence of defective NCs with deviations from anticipated confinement trends. In conclusion, the transition correlates with a redshift and increase in the amplitude of dopant emission, and we discuss these observations in the context of atomistic simulations of Ruddlesden-Popper defects in CsPbCl 3 .

36 MATERIALS SCIENCE↗

DOE OSTI2022

Rapidly changing high-latitude seasonality: Implications for the 21st century carbon cycle in Alaska: Modeling Archive

This Modeling Archive is in support of an NGEE Arctic publication "Rapidly changing high-latitude seasonality: Implications for the 21st century carbon cycle in Alaska" DOI: 10.1088/1748-9326/ac4362.The dataset contains "ecosys" model outputs reported in Shirley et al. (2022) that explored how climate warming will shift carbon cycle seasonality in Alaska. The study used analysis of seasonal dynamics to support the prediction that high-latitude ecosystems are carbon sinks and will continue to accumulate carbon throughout the century. The study predicts surprisingly large increases in spring net carbon uptake that result in larger net carbon uptake in spring than in summer by year 2100. Included as *.nc files are modeled daily net ecosystem exchange (NEE), net primary productivity (NPP), heterotrophic respiration (Rh), autotrophic respiration (Ra), gross primary productivity (GPP), and plant nitrogen uptake. The output is provided (1) at 25 km resolution across Alaska; (2) for years 2010 through 2100. Scripts to generate publication figures included as text files (*.m) from MATLAB. A user guide included as *.pdf.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2021

Summer mean and extreme precipitation over the Mid-Atlantic region: climatological characteristics and contributions from different precipitation types

Based on a long-term observational dataset from the tracking of mesoscale convective systems (MCSs), isolated deep convection (IDC), and tropical cyclones (TCs), we examine the climatological characteristics of summer mean and extreme precipitation during 2004 – 2017 and their respective contributions from MCS, IDC, TC, and non-convective (NC) systems and the local vs. remote influence of MCS and IDC over the MAR. On average, MCS, IDC, TC, and NC contribute 22%, 29%, 4%, and 45% to the total summer mean precipitation in the region. While MCS and TC precipitation primarily occurs in the coastal areas east of the Appalachian Mountains, IDC precipitation is more concentrated in the southern MAR and near the mountain windward slopes. Each summer, ~41 MCSs with an average lifetime of 19.6 hours influence the MAR, with 80% initiated outside and traveling on average 10 hours to the region. Around 13 MCSs initiated in the Great Plains and Midwest propagate across the Appalachian Mountains and contribute 20-40% to summer MCS precipitation in the central Mid-Atlantic coastal areas. In contrast, more than 2000 IDCs with an average lifetime of 2.0 hours influence the MAR each summer, and 77% are initiated locally. MCS, IDC, TC, and NC contribute 31% (30%), 26% (31%), 18% (7%), and 26% (32%) to the top 1% (5%) extreme daily precipitation, respectively. Considering extreme hourly precipitation, however, the IDC contributions increase to 41% (top 1%) and 38% (top 5%) due to the shorter duration of IDC events than the other precipitation types.

Li, Jianfeng↗

DOE OSTI2016

Electrical and optical characterization of green synthesized Gd{sub 2}S{sub 3}

Gadolinium sulphide (Gd{sub 2}S{sub 3}) is a magnetic semiconductor with large band gap. Gd{sub 2}S{sub 3} was synthesized following chemical and green techniques. Later process provides good stability of the nano clusters (NC) due to in-situ capping of Gd{sub 2}S{sub 3} NC. It has been found that the optical band gap in Gd{sub 2}S{sub 3} developed by green synthesis is lowered considerably over that in chemically synthesized Gd{sub 2}S{sub 3}. The green agencies used in this work are Jatropha Latex and dilute Garlic extract; both are enriched in sulphur and other organic polymer molecules. Simple observation shows that Gd{sub 2}S{sub 3} NC retains residual magnetization. In this work optical and electrical characterization of the developed Gd{sub 2}S{sub 3} specimens are carried out. The overall results obtained are good.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2018

Electronic Structure and Dynamics of Copper-Doped Indium Phosphide Nanocrystals Studied with Time-Resolved X-ray Absorption and Large-Scale DFT Calculations

Here, the recent development of time-resolved X-ray absorption spectroscopy (TR-XAS) has opened avenues for fundamental research on doped semiconductors. Reported herein are results on the successful doping of indium phosphide nanocrystals (NCs) with copper and subsequent charactenzation with time-resolved X-ray studies and largescale density functional theory (DFT) calculations. The synthetic protocol that was based on the cluster seed method afforded control of both the doping level and the quantity of NCs produced in a batch. The stability of the colloidal dispersion allowed us to monitor the photophysical properties of copper guest ions with static and TR-XAS at the copper K-edge. These data reveal that copper captures a hole from the photoexcited InP NC, and relaxation to the ground state occurs via multiple timescales likely due to the presence of interior and surface-bound dopant ions as well as recombination with surfaceand defect-trapped electrons. Large-scale DFT calculations reveal a striking dependence of the electronic structure on the ligand coating and other effects such as self-compensation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2014

The in-medium effects on the neutrino reaction in dense matter

The nucleon form factors in free space are usually thought to be modified when a nucleon is bound in a nucleus or immersed in a nuclear medium. We investigated effects of the density-dependent axial and weak-vector form factors on the electro-neutrino (ν{sub e}) and anti-electro-neutrino (¯ν{sub e}) reactions with incident energy E{sub v} ≤ 80 MeV via neutral current (NC) and charged current (CC) for a nucleon in a nuclear medium or ¹²C. For the density-dependent form factors, we exploited the quark-meson-coupling (QMC) model, and apply them to the ν{sub e} and ¯ν{sub e} induced reactions by NC and CC. In CC reaction, about 5 % decrease of the electro neutrino (ν{sub e}) reaction cross section on the nucleon is shown to be occurred in normal density, ρ=ρ{sub 0}~0.15fm⁻³, and also about 5 % reduction of total ν{sub e} cross section on ¹²C is obtained by the modification of the weak form factors for bound nucleons. Density effects for both cases are relatively small, but they are as large as the effect by the Coulomb distortion of outgoing leptons in the ν-reaction. However, density effects in the anti-electro neutrino (¯ν{sub e}) reaction reduced significantly about 30 % the cross sections for both the nucleon and ¹²C cases. For NC, about 12 % decrease of the total cross section by the ν{sub e} reaction on the nucleon is obtained at normal density, ρ=ρ₀~0.15fm⁻³, as well as about 18 % reduction of the total ν{sub e} cross section on ¹²C, by the modification of the weak form factors of the bound nucleon. However, similarly to the CC reaction, effects of the nucleon property change in the ¯ν{sub e} reaction reduce significantly the cross sections about 30 % for the nucleon in matter and ¹²C cases. In this talk, we address that such a large asymmetry in the ¯ν{sub e} cross sections in both reactions is originated from the different helicities of ¯ν{sub e} and ν{sub e}.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

DOE OSTI2014

Carrier Transport in Films of Alkyl-Ligand-Terminated Silicon Nanocrystals

Silicon nanocrystals (Si NCs) have shown great promise for electroluminescent and photoluminescent applications. In order to optimize the properties of Si NC devices, however, electronic transport in Si NC films needs to be thoroughly understood. Here we present a systematic study of the temperature and electric field dependence of conductivity in films of alkyl-ligand-terminated Si NCs, which to date have shown the highest potential for device applications. Our measurements suggest that the conductivity is limited by the ionization of rare NCs containing donor impurities. At low bias, this ionization is thermally activated, with an ionization energy equal to twice the NC charging energy. As the bias is increased, the ionization energy is reduced by the electric field, as determined by the Poole-Frenkel effect. At large bias and sufficiently low temperature, we observe cold ionization of electrons from donor-containing NCs, with a characteristic tunneling length of about 1 nm. The temperature- and electric-field-dependent conductance measurements presented here provide a systematic and comprehensive picture for electron transport in lightly doped nanocrystal films.

Chen, Ting↗

DOE OSTI2025

Temporal persistence of postfire flood hazards under present and future climate conditions in southern Arizona, USA

Changes to soil hydraulic properties that reduce infiltration capacity following fire can increase flash flood risks. These risks are exacerbated by rainfall intensification associated with a warming climate. However, the potential effects of climate-change-driven rainfall intensification on postfire floods remain largely unexplored. Using rainfall and runoff observations from a 49.4 km 2 watershed in southern Arizona, USA, and a hydrologic model (KINEROS2), we examined the temporal evolution following a historic fire of three crucial hydrologic parameters: soil saturated hydraulic conductivity (K sp ), net capillary drive (G p ), and hydraulic roughness (n c ). We explored how the effect of fire on these parameters may influence peak flow under future climate scenarios derived from CMIP6, specifically the medium emissions scenario (SSP2-4.5) and high emissions scenario (SSP5-8.5). Results demonstrate an increase in K sp from 11 mm h −1 in the first postfire year to 60 mm h −1 in postfire year 3. G p similarly increased from 19 mm in the first postfire year to 30 mm in the third, while nc was relatively constant. The highest simulated Q p occurred in the first postfire year. Under the SSP2-4.5 scenario, the likelihood of a 100-year flood is projected to be twice as large by the middle of the century relative to its historical magnitude. Simulations further indicate that the maximum expected discharge associated with a postfire flood, as derived from historical data, could be triggered by a 10-year rainstorm under the SSP5-8.5 scenario by the late century. Simulations also demonstrate that rainfall intensification will lead to greater persistence of elevated flood hazards following fire by the late century under both the SSP2-4.5 and the SSP5-8.5 scenarios.

54 ENVIRONMENTAL SCIENCES↗