Characterization of Low Level and Intermediate Nuclear Waste: improvements in calorimetric measurement combined radiological modelling - 16144
Since 40 years, calorimetry allows to determine precisely amounts of nuclear material within a container. Combined with gamma spectrometry, calorimetric measurements give plutonium contents with a low level of uncertainty for each isotope. Calorimetry is used in a lot of nuclear facilities all around the world for plutonium or tritium inventories. It is one of the best solutions to estimate the overall quantity of nuclear material on a wide range of mass, from a few milligrams up to kilograms of radionuclides. In the case of drums containing nuclear waste, characterization was very challenging due to complex matrix, volume and low level activities. The measurement time was a real problem with large volume container and organic matrix with high air content. New designs of SETARAM calorimeters allow to measure nuclear material contents in very large container (up to 385 liters) and/or with a very low detection limit (10 μWatt). These new concepts are based on single measurement cell and vacuum chamber for low level uncertainties. The acquisition system and electronic temperature regulation are highly improved to increase the detection limit, accuracy and precision of the measurement. These modern technological developments within the calorimetry field give the promise of faster measurement times and precise measurements. These devices can be used in waste management of nuclear facilities with a better accuracy and lower uncertainties than others techniques. It is a non-destructive and non-intrusive method. There is no matrix effect which can bias the results. Waste can also be in solid, liquid or gas phase. The new calorimeters are able to give amounts of plutonium, tritium or others alpha or beta emitter radionuclides and allow determining the classification of waste (low level or intermediate). A measurement approach combining very large volume calorimeter, gamma spectrometry and radiological modelling will be presented as an integrated automatic waste characterization system. This system with a calculation step is taking into account the gamma emitters contribution on the total thermal power measured within the calorimeter. The aim of the system is to give a precise quantification of the radionuclides in the waste container with a precise value of the total uncertainties. (authors)