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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS1998

Throughput of the Composite Infrared Spectrometer (CIRS) Mid Infrared (MIR) Channel for the Cassini Mission to Saturn

The Composite Infrared Spectrometer (CIRS) of the Cassini mission to Saturn has two interferometers covering the far infrared and mid infrared wavelength region. The instrument was aligned at ambient temperature, but operates at 170 Kelvin and has challenging interferometric alignment tolerances. Cryogenic alignment tests of the instrument indicate that it should suffer minimal degradation due to the cooldown from ambient to operational temperature. System level tests performed by the calibration team indicated a lower than expected signal level on the MIR channel, while providing ambiguous optical throughput data. Therefore it became imperative to develop a metric that could be used to determine the instrument performance at both the instrument and system levels, at ambient and cryogenic temperature. Modulation efficiency and throughput measurements were performed and new analytical models developed to evaluate the status of the instrument. Empirical and analytical data were eventually reconciled and deviations from the design values explained.

Hagopian, John G.↗
NASA NTRS1998

Acoustic Amplification in the Far Infrared Focal Plane Assembly of the Composite Infrared Spectrometer (CIRS) for the Cassini Mission to Saturn

The Composite Infrared Spectrometer (CIRS) of the Cassini mission to Saturn has two interferometers covering the far infrared FIR and mid infrared, MIR wavelength region. The FIR is a polarizing Michelson interferometer which presents a collimated output beam to the FIR focal plane. The focal plane consists of a parabolic focus mirror and an analyzer grid, which splits the output beams into transmitted and reflected components. The two polarizations are focussed onto two thermopile detectors; each consisting of a gold black foil welded to the top of two bismuth pyramids. The gold black is 30 microns thick, and the weld area is approximately 2 microns in diameter. The detectors are extremely fragile and the weld can be broken with a miniscule amount of airflow. The detectors consistently passed acoustic testing to qualification levels that simulated the launch environment of the Titan IV launch vehicle. However, they experienced a 50% failure rate when installed in the focal plane assembly during instrument level acoustic tests. A test focal plane was developed with small pressure transducers in the nominal detector locations. These tests indicated over 10 dB of acoustic amplification in the focal plane within the instrument during testing. New techniques were developed to allow testing of the focal plane without over testing the instrument, and modifications were made the focal plane assembly to successfully attenuate the amplification.

Hagopian, John G.↗
NASA NTRS2004

Rest-Frame Mid-Infrared Detection of an Extremely Luminous Lyman Break Galaxy with the Spitzer Infrared Spectrograph (IRS)

We present the first rest-frame of approximately 4 microns detection of a Lyman break galaxy. The data were obtained using the 16 microns imaging capability of the Spitzer Infrared Spectrograph. The target object, J134026.44+634433.2, is an extremely luminous Lyman break galaxy at z=2.79, first identified in Sloan Digital Sky Survey (SDSS) spectra (as reported by Bentz et al.). The source is strongly detected with a flux of 0.94 +/- 0.02 mJy. Combining Spitzer and SDSS photometry with supporting ground-based J- and K-band data, we show that the spectral energy distribution is consistent with an actively star-forming galaxy. We also detect other objects in the Spitzer field of view, including a very red mid-infrared source. We find no evidence of a strong lens among the mid-infrared sources.

cosmology↗
NASA NTRS2009

The Balloon Experimental Twin Telescope for Infrared Interferometry (BETTII): Spatially Resolved Spectroscopy in the Far-Infrared

Astronomical studies at infrared wavelengths have dramatically improved our understanding of the universe, and observations with Spitzer, the upcoming Herschel mission, and SOFIA will continue to provide exciting new discoveries. The relatively low angular resolution of these missions, however, is insufficient to resolve the physical scale on which mid-to far-infrared emission arises, resulting in source and structure ambiguities that limit our ability to answer key science questions. Interferometry enables high angular resolution at these wavelengths - a powerful tool for scientific discovery. We will build the Balloon Experimental Twin Telescope for Infrared Interferometry (BETTII), an eight-meter baseline Michelson stellar interferometer to fly on a high-altitude balloon. BETTII's spectral-spatial capability, provided by an instrument using double-Fourier techniques, will address key questions about the nature of disks in young star clusters and active galactic nuclei and the envelopes of evolved stars. BETTII will also lay the technological groundwork for future space interferometers and for suborbital programs optimized for studying extrasolar planets.

Rinehart, Stephen↗
NASA NTRS2020

Radiometric Performance Characterization of the CubeSat Infrared Atmospheric Sounder (CIRAS) High Operating Temperature-Barrier Infrared Detectors (HOT-BIRD))

The CubeSat Infrared Atmospheric Sounder (CIRAS) is a remote sensing instrument under development for thedemonstration and technology maturation of hyperspectral infrared sounding in a 6U CubeSat. The CIRASinstrument utilizes a 2D Focal Plane Array (FPA) of High Operating Temperature-Barrier Infrared Detectors(HOT-BIRD). The HOT-BIRD material provides improved uniformity, higher allowable operating temperatures,and lower 1/f noise. The performance of the HOT-BIRD FPA was tested inside a Integrated Dewarand Cryocooler Assembly (IDCA), allowing the operating temperature of the FPA to reach low temperatures.Experimentation involved using an external Blackbody Calibrator Target (BCT) to generate numerous imagesof the BCT object at varying scene temperatures. The data acquired was compared to a radiometric model tocharacterize the responsivity of the detectors. In addition, a solid angle correction was developed to improve theaccuracy of the modeling. Real and synthetic images are presented in the comparative analysis to validate theexpected responsivity of the detectors through calculation of the quantum efficency.

Rafol, Sir B.↗
NASA NTRSDate not supplied

Implementing Atmospheric Infrared Sounder (AIRS) and Cross-Track Infrared Sounder (CrIS) Cloud-Clearing Algorithm into the NASA GEOS: Focus on the 2017 Atlantic Tropical Cyclone Season

Numerical Weather Prediction (NWP) centers assimilate cloud-free infrared (IR) radiances because the assimilation of all-sky IR radiances is not yet operationally achievable. The cloud-clearing procedure offers a simpler, but effective strategy that produces cloud-affected radiances suitable for assimilation in partially cloudy regions. Several studies conducted by this team have demonstrated that IR Cloud-Cleared Radiances (CCRs), if thinned more aggressively than clear-sky radiances, can improve analysis and forecasts, particularly in meteorologically active areas. However, CCRs are not used by operational centers due partly to the thought that the process of cloud-clearing may affect latency and introduce difficult-to-control external dependencies. This study presents the results of implementing an Atmospheric Infrared Sounder (AIRS) and Cross-Track Infrared Sounder (CrIS) cloud-clearing procedure into the NASA Goddard Earth Observing System (GEOS) to demonstrate the portability of the procedure. The AIRS and CrIS cloud-clearing algorithms have been deprived of external dependencies, made customizable to any specific model, and the computational efficiency has been improved via parallelization. The revised AIRS and CrIS cloud-clearing algorithms allow a customized choice of channel selection, the use of a user-specified model's fields as first guess, and can perform in real time. Data assimilation experiments with the hybrid 4DEnVar GEOS system were successfully performed for the 2017 tropical cyclones (TC) season with a focus on three major hurricanes (Harvey, Irma, and Maria). This study shows that assimilation of locally-generated CCRs have a positive impact on both global skill and TC representation, compared to the assimilation of AIRS and CrIS clear-sky radiances, and a comparable or slightly improved impact compared to assimilation of CCRs produced by external sources, such as NASA's Distributed Active Archive Centers and NOAA’s Comprehensive Large Array-data Stewardship System. The customization and computational efficiency of the revised procedure would enable its usability in a real-time forecast context.

Niama Boukachaba↗
DOE OSTI2024

Nonadiabatic Derivative Couplings through Multiple Franck–Condon Modes Dictate the Energy Gap Law for Near and Short-Wave Infrared Dye Molecules

Near infrared (NIR, 700–1000 nm) and short-wave infrared (SWIR, 1000–2000 nm) dye molecules exhibit significant nonradiative decay rates from the first singlet excited state to the ground state. While these trends can be empirically explained by a simple energy gap law, detailed mechanisms of nearly universal behavior have remained unsettled for many cases. Theoretical and experimental results for two representative NIR/SWIR dye molecules reported here clarify the key mechanism for the observed energy gap law behavior. It is shown that the first derivative nonadiabatic coupling terms serve as major coupling pathways for nonadiabatic decay processes from the first excited singlet state to the ground state for these NIR and SWIR dye molecules and that vibrational modes other than the highest frequency modes also make significant contributions to the rate. Finally, this assessment is corroborated by further theoretical comparison with possible alternative mechanisms of intersystem crossing to triplet states and also by comparison with experimental data for deuterated molecules.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Simulations of the infrared, Raman, and 2D-IR photon echo spectra of water in nanoscale silica pores

Vibrational spectroscopy is frequently used to characterize nanoconfined liquids and probe the effect of the confining framework on the liquid structure and dynamics relative to the corresponding bulk fluid. However, it is still unclear what molecular-level information can be obtained from such measurements. In this paper, we address this question by using molecular dynamics (MD) simulations to reproduce the linear infrared (IR), Raman, and two-dimensional IR (2D-IR) photon echo spectra for water confined within hydrophilic (hydroxyl-terminated) silica mesopores. To simplify the spectra the OH stretching region of isotopically dilute HOD in D{sub 2}O is considered. An empirical mapping approach is used to obtain the OH vibrational frequencies, transition dipoles, and transition polarizabilities from the MD simulations. The simulated linear IR and Raman spectra are in good general agreement with measured spectra of water in mesoporous silica reported in the literature. The key effect of confinement on the water spectrum is a vibrational blueshift for OH groups that are closest to the pore interface. The blueshift can be attributed to the weaker hydrogen bonds (H-bonds) formed between the OH groups and silica oxygen acceptors. Non-Condon effects greatly diminish the contribution of these OH moieties to the linear IR spectrum, but these weaker H-bonds are readily apparent in the Raman spectrum. The 2D-IR spectra have not yet been measured and thus the present results represent a prediction. The simulated spectra indicates that it should be possible to probe the slower spectral diffusion of confined water compared to the bulk liquid by analysis of the 2D-IR spectra.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Detection of Foreign Materials on Broiler Breast Meat Using a Fusion of Visible Near-Infrared and Short-Wave Infrared Hyperspectral Imaging

Foreign material (FM) found on a poultry product lowers the quality and safety of the product. We developed a fusion method combining two hyperspectral imaging (HSI) modalities in the visible-near infrared (VNIR) range of 400–1000 nm and the short-wave infrared (SWIR) range of 1000–2500 nm for the detection of FMs on the surface of fresh raw broiler breast fillets. Thirty different types of FMs that could be commonly found in poultry processing plants were used as samples and prepared in two different sizes (5 × 5 mm 2 and 2 × 2 mm 2 ). The accuracies of the developed Fusion model for detecting 2 × 2 mm 2 pieces of polymer, wood, and metal were 95%, 95%, and 81%, respectively, while the detection accuracies of the Fusion model for detecting 5 × 5 mm 2 pieces of polymer, wood, and metal were all 100%. The performance of the Fusion model was higher than the VNIR- and SWIR-based detection models by 18% and 5%, respectively, when F1 scores were compared, and by 38% and 5%, when average detection rates were compared. The study results suggested that the fusion of two HSI modalities could detect FMs more effectively than a single HSI modality.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Cyclotrimerization of Acetylene in Gas Phase V + (C 2 H 2 ) n Complexes: Detection of Intermediates and Products with Infrared Spectroscopy

Infrared laser spectroscopy and mass spectrometry were used to determine the structures of intermediates and products in the single-atom-catalyzed trimerization of acetylene to form benzene. Complexes of the form V + (C 2 H 2 ) n were produced in the gas phase via laser ablation in a pulsed-nozzle source, size-selected with a mass spectrometer, and studied with infrared laser photodissociation spectroscopy. Density Functional Theory (DFT) calculations were performed in support of the experiments. Single- and doub le-acetylene complexes form V + (C 2 H 2 ) n metallacycle structures. Three-acetylene complexes exhibit a surprising dependence on the acetylene concentration, forming V + (C 2 H 2 ) 3 and (C 2 H 2 )V + (C 4 H 4 ) tri- and dimetallacycle ion structures at low concentration, and eventually V + (benzene) at higher concentrations. Finally, these observations reveal intermediates along the reaction path of acetylene cyclotrimerization to benzene.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2014

Near-infrared induced optical quenching effects on mid-infrared quantum cascade lasers

In space communications, atmospheric absorption and Rayleigh scattering are the dominant channel impairments. Transmission using mid-infrared (MIR) wavelengths offers the benefits of lower loss and less scintillation effects. In this work, we report the telecom wavelengths (1.55 μm and 1.3 μm) induced optical quenching effects on MIR quantum cascade lasers (QCLs), when QCLs are operated well above their thresholds. The QCL output power can be near 100% quenched using 20 mW of near-infrared (NIR) power, and the quenching effect depends on the input NIR intensity as well as wavelength. Time resolved measurement was conducted to explore the quenching mechanism. The measured recovery time is around 14 ns, which indicates that NIR generated electron-hole pairs may play a key role in the quenching process. The photocarrier created local field and band bending can effectively deteriorate the dipole transition matrix element and quench the QCL. As a result, MIR QCLs can be used as an optical modulator and switch controlled by NIR lasers. They can also be used as “converters” to convert telecom optical signals into MIR optical signals.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

Development of nanosecond time-resolved infrared detection at the LEAF pulse radiolysis facility

When coupled with transient absorption spectroscopy, pulse radiolysis, which utilizes high-energy electron pulses from an accelerator, is a powerful tool for investigating the kinetics and thermodynamics of a wide range of radiation-induced redox and electron transfer processes. The majority of these investigations detect transient species in the UV, visible, or near-IR spectral regions. Unfortunately, the often-broad and featureless absorption bands in these regions can make the definitive identification of intermediates difficult. Time-resolved vibrational spectroscopy would offer much improved structural characterization, but has received only limited application in pulse radiolysis. In this paper, we describe in detail the development of a unique nanosecond time-resolved infrared (TRIR) detection capability for condensed-phase pulse radiolysis on a new beam line at the LEAF facility of Brookhaven National Laboratory. The system makes use of a suite of high-power, continuous wave external-cavity quantum cascade lasers as the IR probe source, with coverage from 2330-1051 cm⁻¹. The response time of the TRIR detection setup is ~40 ns, with a typical sensitivity of ~100 µOD after 4-8 signal averages using a dual-beam probe/reference normalization detection scheme. As a result, this new detection method has enabled mechanistic investigations of a range of radiation-induced chemical processes, some of which are highlighted here.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

Mid-infrared photodetection in an AlGaAs/GaAs quantum-well infrared photodetector using photoinduced noise

We propose a new way to assess the output signal of a quantum-well infrared photodetector (QWIP). Instead of measuring the photocurrent produced by the device, as usually done, we show that the noise induced by the absorption process can be used to generate a useful detection signal. We built a simple electronic circuit able to quantify the noise of an AlGaAs/GaAs QWIP that was intentionally designed to produce no photocurrent at all, and we demonstrated that such a circuit was able to generate a strong output signal whenever an infrared radiation of a specific wavelength was shed on the detector. This concept opens new possibilities for the design of novel types of photodetection systems.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2016

The near-infrared spectrum of ethynyl radical

Transient diode laser absorption spectroscopy has been used to measure three strong vibronic bands in the near infrared spectrum of the C{sub 2}H, ethynyl, radical not previously observed in the gas phase. The radical was produced by ultraviolet excimer laser photolysis of either acetylene or (1,1,1)-trifluoropropyne in a slowly flowing sample of the precursor diluted in inert gas, and the spectral resolution was Doppler-limited. The character of the upper states was determined from the rotational and fine structure in the observed spectra and assigned by measurement of ground state rotational combination differences. The upper states include a {sup 2}Σ{sup +} state at 6696 cm{sup −1}, a second {sup 2}Σ{sup +} state at 7088 cm{sup −1}, and a {sup 2}Π state at 7110 cm{sup −1}. By comparison with published calculations [R. Tarroni and S. Carter, J. Chem. Phys 119, 12878 (2003); Mol. Phys. 102, 2167 (2004)], the vibronic character of these levels was also assigned. The observed states contain both X{sup 2}Σ{sup +} and A{sup 2}Π electronic characters. Several local rotational level perturbations were observed in the excited states. Kinetic measurements of the time-evolution of the ground state populations following collisional relaxation and reactive loss of the radicals formed in a hot, non-thermal, population distribution were made using some of the strong rotational lines observed. The case of C{sub 2}H may be a good place to investigate the behavior at intermediate pressures of inert colliders, where the competition between relaxation and reaction can be tuned and observed to compare with master equation models, rather than deliberately suppressed to measure thermal rate constants.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Anharmonic exciton dynamics and energy dissipation in liquid water from two-dimensional infrared spectroscopy

Water’s extended hydrogen-bond network results in rich and complex dynamics on the sub-picosecond time scale. In this paper, we present a comprehensive analysis of the two-dimensional infrared (2D IR) spectrum of O–H stretching vibrations in liquid H{sub 2}O and their interactions with bending and intermolecular vibrations. By exploring the dependence of the spectrum on waiting time, temperature, and laser polarization, we refine our molecular picture of water’s complex ultrafast dynamics. The spectral evolution following excitation of the O–H stretching resonance reveals vibrational dynamics on the 50–300 fs time scale that are dominated by intermolecular delocalization. These O–H stretch excitons are a result of the anharmonicity of the nuclear potential energy surface that arises from the hydrogen-bonding interaction. The extent of O–H stretching excitons is characterized through 2D depolarization measurements that show spectrally dependent delocalization in agreement with theoretical predictions. Furthermore, we show that these dynamics are insensitive to temperature, indicating that the exciton dynamics alone set the important time scales in the system. Finally, we study the evolution of the O–H stretching mode, which shows highly non-adiabatic dynamics suggestive of vibrational conical intersections. We argue that the so-called heating, commonly observed within ∼1 ps in nonlinear IR spectroscopy of water, is a nonequilibrium state better described by a kinetic temperature rather than a Boltzmann distribution. Our conclusions imply that the collective nature of water vibrations should be considered in describing aqueous solvation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Developing a robust sensor for infrared imaging bolometers

A new type of large area sensor for infrared imaging bolometers has been developed. It replaces the thin and fragile free-standing metal foils, which typically have been used, with a multi-layer coated sapphire (or diamond) substrate. Sapphire is transparent to mid-infrared wavelengths, is robust against transients, and can be thick enough to even be the vacuum window. The primary radiation absorber is still a thin deposited metal layer, but now it is partially insulated from the supporting sapphire substrate by a black (carbon-based) layer, which also acts as a blackbody remitter. Test results indicate 6× more noise equivalent power density (estimated NEPD = 23 W/m 2 at 5 ms camera exposure time, foil temperature decay time 60 ms) for a 2 μm gold-coated sapphire disk compared to estimated NEP = 4 W/m 2 at 1.8 ms exposure time, with foil decay time 420 ms, for a nominal 2.5 μm thick platinum-free-standing foil.

47 OTHER INSTRUMENTATION↗