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At least 91 records · Page 5

High Ice Water Content at Low Radar Reflectivity near Deep Convection: Part II. Evaluation of Microphysical Pathways in Updraft Parcel Simulations

The aeronautics industry has established that a threat to aircraft is posed by atmospheric conditions of substantial ice water content (IWC) where equivalent radar reflectivity (Ze) does not exceed 20-30 dBZ and supercooled water is not present; these conditions are encountered almost exclusively in the vicinity of deep convection. Part 1 (Fridlind et al., 2015) of this two-part study presents in situ measurements of such conditions sampled by Airbus in three tropical regions, commonly near 11 km and -43 C, and concludes that the measured ice particle size distributions are broadly consistent with past literature with profiling radar measurements of Z(sub e) and mean Doppler velocity obtained within monsoonal deep convection in one of the regions sampled. In all three regions, the Airbus measurements generally indicate variable IWC that often exceeds 2 gm (exp -3) with relatively uniform mass median area-equivalent diameter (MMD(sub eq) of 200-300 micrometers. Here we use a parcel model with size-resolved microphysics to investigate microphysical pathways that could lead to such conditions. Our simulations indicate that homogeneous freezing of water drops produces a much smaller ice MMD(sub eq) than observed, and occurs only in the absence of hydrometeor gravitational collection for the conditions considered. Development of a mass mode of ice aloft that overlaps with the measurements requires a substantial source of small ice particles at temperatures of about -10 C or warmer, which subsequently grow from water vapor. One conceivable source in our simulation framework is Hallett-Mossop ice production; another is abundant concentrations of heterogeneous ice freezing nuclei acting together with copious shattering of water drops upon freezing. Regardless of the production mechanism, the dominant mass modal diameter of vapor-grown ice is reduced as the ice-multiplication source strength increases and as competition for water vapor increases. Both mass and modal diameter are reduced by entrainment and by increasing aerosol concentrations. Weaker updrafts lead to greater mass and larger modal diameters of vapor-grown ice, the opposite of expectations regarding lofting of larger ice particles in stronger updrafts. While stronger updrafts do loft more dense ice particles produced primarily by raindrop freezing, we find that weaker updrafts allow the warm rain process to reduce competition for diffusional growth of the less dense ice expected to persist in convective outflow.

Reflectivity↗

Formation of Large (Approximately 100 micrometers) Ice Crystals Near the Tropical Tropopause

Recent high-altitude aircraft measurements with in situ imaging instruments indicated the presence of relatively large (approx.100 microns length), thin (aspect ratios of approx.6:1 or larger) hexagonal plate ice crystals near the tropical tropopause in very low concentrations (<0.01/L). These crystals were not produced by deep convection or aggregation. We use simple growth-sedimentation calculations as well as detailed cloud simulations to evaluate the conditions required to grow the large crystals. Uncertainties in crystal aspect ratio leave a range of possibilities, which could be constrained by knowledge of the water vapor concentration in the air where the crystal growth occurred. Unfortunately, water vapor measurements made in the cloud formation region near the tropopause with different instruments ranged from <2 ppmv to approx.3.5 ppmv. The higher water vapor concentrations correspond to very large ice supersaturations (relative humidities with respect to ice of about 200%). If the aspect ratios of the hexagonal plate crystals are as small as the image analysis suggests (6:1, see companion paper (Lawson et al., 2008)) then growth of the large crystals before they sediment out of the supersaturated layer would only be possible if the water vapor concentration were on the high end of the range indicated by the different measurements (>3 ppmv). On the other hand, if the crystal aspect ratios are quite a bit larger (approx.10:1), then H2O concentrations toward the low end of the measurement range (approx.2-2.5 ppmv) would suffice to grow the large crystals. Gravity-wave driven temperature and vertical wind perturbations only slightly modify the H2O concentrations needed to grow the crystals. We find that it would not be possible to grow the large crystals with water concentrations less than 2 ppmv, even with assumptions of a very high aspect ratio of 15 and steady upward motion of 2 cm/s to loft the crystals in the tropopause region. These calculations would seem to imply that the measurements indicating water vapor concentrations less than 2ppmv are implausible, but we cannot rule out the possibility that higher humidity prevailed upstream of the aircraft measurements and the air was dehydrated by the cloud formation. Simulations of the cloud formation with a detailed model indicate that homogeneous freezing should generate ice concentrations larger than the observed concentrations (20/L), and even concentrations as low as 20/L should have depleted the vapor in excess of saturation and prevented growth of large crystals. It seems likely that the large crystals resulted from ice nucleation on effective heterogeneous nuclei at low ice supersaturations. Improvements in our understanding of detailed cloud microphysical processes require resolution of the water vapor measurement discrepancies in these very cold, dry regions of the atmosphere.

Jensen, E. J.↗

Conference on Cloud Physics, Tucson, Ariz., October 21-24, 1974, Proceedings

Condensation and ice nucleation processes are considered, taking into account measurements of cloud nuclei and aerosol size spectra in the semiarid Southwest, the formation of sulfates and the enhancement of cloud condensation nuclei in clouds, biogenic sources of atmospheric ice nuclei, and the experimental determination of the deposition coefficient of water vapor onto ice. Other topics discussed are related to precipitation growth processes, the role of ice in cloud systems, cloud modeling, measurements in Colorado hailstorms during the national hail research experiment, cloud measurements, and measurement techniques. Attention is also given to cloud electrification, zero-gravity experiments, and the control of cloud development by larger scale motions. Individual items are announced in this issue.

Source record↗

Ice Nucleation and Dehydration in the Tropical Tropopause Layer

Optically thin cirrus near the tropical tropopause regulate the humidity of air entering the stratosphere, which in turn has a strong influence on the Earth's radiation budget and climate. Recent highaltitude, unmanned aircraft measurements provide evidence for two distinct classes of cirrus formed in the tropical tropopause region: (i) vertically extensive cirrus with low ice number concentrations, low extinctions, and large supersaturations (up to approx. 70%) with respect to ice; and (ii) vertically thin cirrus layers with much higher ice concentrations that effectively deplete the vapor in excess of saturation. The persistent supersaturation in the former class of cirrus is consistent with the long time-scales (several hours or longer) for quenching of vapor in excess of saturation given the low ice concentrations and cold tropical tropopause temperatures. The low-concentration clouds are likely formed on a background population of insoluble particles with concentrations less than 100 L−1 (often less than 20 L−1), whereas the high ice concentration layers (with concentrations up to 10,000 L−1) can only be produced by homogeneous freezing of an abundant population of aqueous aerosols. These measurements, along with past high-altitude aircraft measurements, indicate that the low-concentration cirrus occur frequently in the tropical tropopause region, whereas the high-concentration cirrus occur infrequently. The predominance of the low-concentration clouds means cirrus near the tropical tropopause may typically allow entry of air into the stratosphere with as much as approx. 1.7 times the ice saturation mixing ratio.

dehydration↗

Amorphous ice and the behavior of cometary nuclei

The gradual heating of the nucleus of a comet approaching the sun may produce solid-state phase changes that are of particular importance for new comets, which may never have been heated before. The water-ice component of new comets is expected to be amorphous rather than crystalline, and its subsequent crystallization should produce gaseous tails and flareups at heliocentric distances about 70% greater than those expected for crystalline nuclei. These distances and the size of the flareups depend strongly on the inclination of the rotation axis and on the porosity of the ice. The effect should be weaker for older comets, but it may be related to the behavior of P/Schwassmann-Wachmann 1 if the layers of the crystallized ice peel off.

Smoluchowski, R.↗

Ice Cloud Formation and Dehydration in the Tropical Tropopause Layer

Stratospheric water vapor is important not only for its greenhouse forcing, but also because it plays a significant role in stratospheric chemistry. several recent studies have focused on the potential for dehydration due to ice cloud formation in air rising slowly through the tropical tropopause layer. Holton and Gettelman showed that temperature variations associated with horizontal transport of air in the tropopause layer can drive ice cloud formation and dehydration, and Gettelman et al. recently examined the cloud formation and dehydration along kinematic trajectories using simple assumptions about the cloud properties. In this study, we use a Lagrangian, one-dimensional cloud model to further investigate cloud formation and dehydration as air is transported horizontally and vertically through the tropical tropopause layer. Time-height curtains of temperature are extracted from meteorological analyses. The model tracks the growth and sedimentation of individual cloud particles. The regional distribution of clouds simulated in the model is comparable to the subvisible cirrus distribution indicated by SAGE II. The simulated cloud properties depend strongly on the assumed ice supersaturation threshold for ice nucleation. with effective nuclei present (low supersaturation threshold), ice number densities are high (0.1--10 cm(circumflex)-3), and ice crystals do not grow large enough to fall very far, resulting in limited dehydration. With higher supersaturation thresholds, ice number densities are much lower (less than 0.01 cm(circumflex)-3), and ice crystals grow large enough to fall substantially; however, supersaturated air often crosses the tropopause without cloud formation. The clouds typically do not dehydrate the air along trajectories down to the temperature minimum saturation mixing ratio. Rather the water vapor mixing ratio crossing the tropopause along trajectories is typically 10-50% larger than the saturation mixing ratio.

Jensen, Eric↗

Microphysics and Radiative Properties of Cirrus: Instrumentation and Analysis

Work under this grant has involved further development of a new aircraft instrument (the cloudscope) for real time characterization of atmospheric particulates together with field observations of such particulates, both in the form of ice and also as nuclei responsible for nucleation of both ice and water cloud particles. Part of the work involving assessment of the frequency of ice crystal shapes has been carried out in collaboration with the Meteorological Service of Canada; part of the work in a field program with the NCAR C-130. Part of the work has been interpreted in terms of laboratory simulation of ice crystal growth under a wide variety of conditions carried out under a grant from Physical Meteorology Program, National Science Foundation.

Hallett, John↗

The influence of CO ice on the activity and the near-surface differentiation of comet nuclei

A comet nucleus model whose composition is a homogeneous mixture of water ice, CO ice, and dust, in a Halley-type orbit, is presently used to investigate the role of unclathrated CO ice in the activity and near-surface differentiation of comet nuclei. Temperatures of water and CO ice surfaces, CO gas and water steam fluxes, and depths of CO ice, are presented as functions of orbital position. It is determined that CO ice should always exist within 3 m of the surface; CO gas production exceeds water steam production beyond 2.5 AU, with consequences for the planned in situ elemental analysis of nuclei.

Fanale, Fraser P.↗

Radar Reflectivity Simulated by a 2-D Spectra Bin Model: Sensitivity of Cloud-aerosol Interaction

The Goddard Cumulus Ensemble (GCE) model with bin spectra microphysics is used to simulate mesoscale convective systems.The model uses explicit bins to represent size spectra of cloud nuclei, water drops, ice crystals, snow and graupel. Each hydrometeorite category is described by 33 mass bins. The simulations provide a unique data set of simulated raindrop size distribution in a realistic dynamic frame. Calculations of radar parameters using simulated drop size distribution serve as an evaluation of numerical model performance. In addition, the GCE bin spectra modes is a very useful tool to study uncertainties related to radar observations; all the environmental parameters are precisely known. In this presentation, we concentrate on the discussion of Z-R (ZDR-R) relation in the simulated systems. Due to computational limitations, the spectra bin model has been run in two dimensions with 31 stretched vertical layers and 1026 horizontal grid points (1 km resolution). Two different cases, one in midlatitude continent, the other in tropical ocean, have been simulated. The continental case is a strong convection which lasted for two hours. The oceanic case is a persistent system with more than 10 hours' life span. It is shown that the simulated Z-R (ZDR-R) relations generally agree with observations using radar and rain gauge data. The spatial and temporal variations of Z-R relation in different locations are also analyzed. Impact of aerosols on cloud formation and raindrop size distribution was studied. Both clean (low CCN) and dirty (high CCN) cases are simulated. The Z-R relation is shown to vary considerable in the initial CCN concentrations.

Li, Kiaowen↗

Solid organic residues produced by irradiation of hydrocarbon-containing H2O and H2O/NH3 ices - Infrared spectroscopy and astronomical implications

Plasma-discharge irradiations were conducted for the methane clathrate expected in outer solar system satellites and cometary nuclei; also irradiated were ices prepared from other combinations of H2O with CH4, C2H6, or C2H2. Upon evaporation of the yellowish-to-tan irradiated ices, it is found that a colored solid film adheres to the walls of the reaction vessel at room temperature. These organic films are found to exhibit IR band identifiable with alkane, aldehide, alcohol, and perhaps alkene, as well as substituted aromatic functional groups. These spectra are compared with previous studies of UV- or photon-irradiated nonclathrated hydrocarbon-containing ices.

Khare, B. N.↗

Present status of the icy conglomerate model

A brief history of the ice comglomerate model (ICM) of the nuclei of comets is presented. Emphasis is given to the usefulness if the ICM in describing cometary behavior despite its vagueness with respect to the chemical composition and physical structure of cometry nuclei. Alternative theories concerning the relationship between the chemical composition of cometary ices and comet behavior are briefly discussed.

Whipple, F. L.↗

Physical interpretations from the motions of comets Halley and Giacobini-Zinner

For comets Halley and Giacobini-Zinner (GZ), the model of the rocket-like, outgassing forces affecting the comet motion is shown to be consistent with the vaporization of water ice from the comet nuclei. For comet GZ, the dramatic time dependence of the outgassing forces suggests that this comet's spin axis passed through the orbit plane in the mid 1960's. Modeling of Halley's motion over two millennia indicates that the comet is rotating in a direct sense, with no obvious long-term time dependence in the average outgassing forces. The precession of the spin pole axis is not apparent. Secular changes in the comet's angular elements show no evidence for a ring of comet-like material beyond the orbit of Neptune. An obvious 1986 postperihelion bias in comet Halley's observation residuals is modeled by assuming a radial center-of-light/center-of-mass offset.

Yeomans, D. K.↗

In-Situ Measurements of Cosmogenic Radionuclides on the Surface of Mars

Cosmogenic nuclides are produced by cosmic-ray nuclear interactions with target nuclei in rocks, soils, ice, and the atmosphere. Cosmogenic nuclides have been widely used for investigation of solar system matter for several decades. Stable nuclides, such as He-1, Ne-21, and Ar-38, are built up over time as the surface is exposed to cosmic rays. The concentrations of cosmogenic radionuclides, such as Be-10 (halflife = 1.5 Myr), Al-26 (0.705 Myr), and C-14 (5,730 yr) also build up with exposure time but reach saturation values after several half-lives. Especially after development of accelerator mass spectrometry (AMS), cosmogenic nuclides in terrestrial samples are routinely used for geomorphic studies such as glaciation, surface erosion, and tectonics, and studies of atmospheric and ocean circulation. Cosmogenic nuclides on Mars will be able to answer questions of exposure ages, erosion rates, tectonic events, and deposition rates of sediments and/or volatiles. The concentrations of cosmogenic stable nuclides gives the integrated exposure time of the rock/mineral, and the activities of radionuclides give recent records for times back as long as a few half-lives.

Nishiizumi, K.↗

Surficial Studies of Mars Using Cosmogenic Nuclides

Cosmogenic nuclides (CNs) are produced by cosmic-ray nuclear interactions with target nuclei in rocks, soils, ice, and the atmosphere. Cosmogenic nuclides have been widely used for investigation of solar system matter for several decades. Stable nuclides, such as He-3, Ne-21, and Ar-38, are built up over time as the surface is exposed to cosmic rays. The concentrations of cosmogenic radionuclides, such as Be-10, Al-26, and C-14 also build up with exposure time but reach saturation values after several half-lives. Especially since the development of accelerator mass spectrometry (AMS), CNs in terrestrial samples have been routinely used for geomorphic studies such as glaciation, surface erosion, and tectonics, and studies of atmospheric and ocean circulation. Cosmogenic nuclides on Mars will be able to answer questions of exposure ages, erosion rates, tectonic events, and deposition rates of sediments and/or volatiles. The concentrations of cosmogenic stable nuclides give the integrated exposure time of the rock/mineral, and the activities of radionuclides give recent records for times back as long as a few half-lives.

Nishiizumi, K.↗

Microbial Extremophiles in Evolutionary Aspect

The microflora of the cryosphere of planet Earth provides the best analogs for life forms that might be found in the permafrost or polar ice caps of Mars, near the surface of the cometary nuclei, or in the liquid water beneath the ice crusts of icy moons of Jupiter and Saturn. For astrobiology the focus on the study alkaliphilic microorganisms was enhanced by the findings of abundant carbonates and carbonate globules rimmed with possibly biogenic magnetites in association with the putative microfossils in the ALH84001 meteorite. Although the ALH84001 "nanofossils" were to small and simple to be unambiguously recognized as biogenic, they stimulated Astrobiology research and studies of microbial extremophiles and biomarkers in ancient rocks and meteorites. Recent studies of CI and CM carbonaceous meteorites have resulted in the detection of the well-preserved mineralized remains of coccoidal and" filamentous microorganisms in cyanobacterial mats. Energy Dispersive X-ray Analysis has shown anomalous biogenic element ratios clearly indicating they are not recent biological contaminants. This paper reviews microbial extremophiles in context of their significance to Astrobiology and the evolution of life. Extremophilic microorganisms on Earth are models for life that might endure high radiation environments in the ice near the surface of comets or on the icy moons of Jupiter and Saturn and in the seafloor deep beneath the icy crusts of Europa and Enceladus.

Pikuta, Elena V.↗

Analyses of Cometary Silicate Crystals: DDA Spectral Modeling of Forsterite

Comets are the Solar System's deep freezers of gases, ices, and particulates that were present in the outer protoplanetary disk. Where comet nuclei accreted was so cold that CO ice (approximately 50K) and other supervolatile ices like ethane (C2H2) were preserved. However, comets also accreted high temperature minerals: silicate crystals that either condensed (greater than or equal to 1400 K) or that were annealed from amorphous (glassy) silicates (greater than 850-1000 K). By their rarity in the interstellar medium, cometary crystalline silicates are thought to be grains that formed in the inner disk and were then radially transported out to the cold and ice-rich regimes near Neptune. The questions that comets can potentially address are: How fast, how far, and over what duration were crystals that formed in the inner disk transported out to the comet-forming region(s)? In comets, the mass fractions of silicates that are crystalline, f_cryst, translate to benchmarks for protoplanetary disk radial transport models. The infamous comet Hale-Bopp has crystalline fractions of over 55%. The values for cometary crystalline mass fractions, however, are derived assuming that the mineralogy assessed for the submicron to micron-sized portion of the size distribution represents the compositional makeup of all larger grains in the coma. Models for fitting cometary SEDs make this assumption because models can only fit the observed features with submicron to micron-sized discrete crystals. On the other hand, larger (0.1-100 micrometer radii) porous grains composed of amorphous silicates and amorphous carbon can be easily computed with mixed medium theory wherein vacuum mixed into a spherical particle mimics a porous aggregate. If crystalline silicates are mixed in, the models completely fail to match the observations. Moreover, models for a size distribution of discrete crystalline forsterite grains commonly employs the CDE computational method for ellipsoidal platelets (c:a:b=8.14x8.14xl in shape with geometrical factors of x:y:z=1:1:10, Fabian et al. 2001; Harker et al. 2007). Alternatively, models for forsterite employ statistical methods like the Distribution of Hollow Spheres (Min et al. 2008; Oliveira et al. 2011) or Gaussian Random Spheres (GRS) or RGF (Gielen et al. 200S). Pancakes, hollow spheres, or GRS shapes similar to wheat sheaf crystal habit (e.g., Volten et al. 2001; Veihelmann et al. 2006), however, do not have the sharp edges, flat faces, and vertices seen in images of cometary crystals in interplanetary dust particles (IDPs) or in Stardust samples. Cometary forsterite crystals often have equant or tabular crystal habit (J. Bradley). To simulate cometary crystals, we have computed absorption efficiencies of forsterite using the Discrete Dipole Approximation (DDA) DDSCAT code on NAS supercomputers. We compute thermal models that employ a size distribution of discrete irregularly shaped forsterite crystals (nonspherical shapes with faces and vertices) to explore how crystal shape affects the shape and wavelength positions of the forsterite spectral features and to explore whether cometary crystal shapes support either condensation or annealing scenarios (Lindsay et al. 2012a, b). We find forsterite crystal shapes that best-fit comet Hale-Bopp are tetrahedron, bricks or brick platelets, essentially equant or tabular (Lindsay et al. 2012a,b), commensurate with high temperature condensation experiments (Kobatake et al. 2008). We also have computed porous aggregates with crystal monomers and find that the crystal resonances are amplified. i.e., the crystalline fraction is lower in the aggregate than is derived by fitting a linear mix of spectral features from discrete subcomponents, and the crystal resonances 'appear' to be from larger crystals (Wooden et al. 2012). These results may indicate that the crystalline mass fraction in comets with comae dominated by aggregates may be lower than deduced by popular methods that only emoy ensembles of discrete crystals.

Wooden, Diane↗

Properties of Cometary Nuclei

Active long- and short-period comets contribute about 20 to 30 % of the major impactors on the Earth. Cometary nuclei are irregular bodies, typically a few to ten kilometers in diameter, with masses in the range 10(sup 15) to 10(sup 18) g. The nuclei are composed of an intimate mixture of volatile ices, mostly water ice and hydrocarbon and silicate grains. The composition is the closest to solar composition of any known bodies in the solar system. The nuclei appear to be weakly bonded agglomerations of smaller icy planetesimals, and material strengths estimated from observed tidal disruption events are fairly low, typically 10(sup 2) to 10(sup 4) N m(sup -2). Density estimates range between 0.2 and 1.2 g cm(sup -3) but are very poorly determined, if at all. As comets age they develop nonvolitile crusts on their surfaces which eventually render them inactive, similar in appearance to carbonaceous asteroids. However, dormant comets may continue to show sporadic activity and outbursts for some time before they become truly extinct. The source of the long-period comets is the Oort cloud, a vast spherical cloud of perhaps 10(sup 12) to 10(sup 13) comets surrounding the solar system and extending to interstellar distances. The likely source for short-period comets is the Kuiper belt. a ring of perhaps 10(sup 8) to 10(sup 10) remnant icy planetesimals beyond the orbit of Neptune, though some short-period comets may also be long-period comets from the Oort cloud which have been perturbed into short-period orbits.

comets nuclei volitile ices Oort cloud Kuiper belt↗

Denitrification in the Antarctic stratosphere

Rapid loss of ozone over Antarctica in spring requires that the abundance of gaseous nitric acid be very low. Precipitation of particulate nitric acid has been assumed to occur in association with large ice crystals, requiring significant removal of H2O and temperatures well below the frost point. However, stratospheric clouds exhibit a bimodal size distribution in the Antarctic atmosphere, with most of the nitrate concentrated in particles with radii of 1 micron or greater. It is argued here that the bimodal size distribution sets the stage for efficient denitrification, with nitrate particles either falling on their own or serving as nuclei for the condensation of ice. Denitrification can therefore occur without significant dehydration, and it is unnecessary for temperatures to drop significantly below the frost point.

Salawitch, R. J.↗