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At least 91 records · Page 5

Effect of Loading Rate on the Open Hole Compression Strength of Quasi-Isotropic Carbon/Epoxy Laminates

This study was undertaken to examine how well the 0.05 inch/min loading rate typically used to develop allowables for open hole compression strength of carbon/epoxy laminates represents structures that may experience a much lower loading rate (such as civil engineering structures) or a much higher loading rate (such as a rocket interstage at liftoff). The Composite Materials Handbook-17 (CMH-17) suggests developing strength allowables at the coupon level (lowest level of the “building block” approach) and using a rigorous statistical analysis to arrive at a strength allowable upon which the structure is to be further designed at higher levels of the building block pyramid. But do these coupon level tests truly represent meaningful stresses at which the composite in the final structure can withstand considering the effects of loading rate? Open hole compression (OHC) strength was chosen for this study since most structures are designed to some damage tolerance criteria and OHC strength testing is rather simple to perform. A quasi-isotropic lay-up was chosen since this is a very common lay-up sequence. The results show that for structures that experience a very small loading rate (0.0005 in/min) the allowables developed at the standard 0.05 in/min loading rate are higher than what the composite can withstand at this lower loading rate. Conversely, at a high loading rate of 10 in/min the strength values found at the standard test rate of 0.05 in/min are slightly lower and not “in family” using the statistics suggested in CMH-17. These results question if standardized test rates are reliable, at least to the fidelity of being “in family” per CMH-17. Some creep rupture tests were also performed to demonstrate that OHC strength values could be lower than the slowest test speed used in this study (0.0005 in/min).

open hole compression strength↗

The Effects of Off-Axis Loading on the Compression After Impact Strength of Quasi-Isotropic Face Sheet Honeycomb Core Sandwich Structure

This study presents experimental results of compression after impact (CAI) testing of aluminum honeycomb core sandwich structure with face sheets made of co-cured T1100/3960 quasi-isotropic carbon/epoxy when tested at +22.5⁰ and -22.5⁰ with respect to the 0⁰ fibers. In a previous study examining the CAI strengths of honeycomb sandwich structure, it was found that specimens had different CAI strengths, based on a [-45/90/+45/0]s layup, depending on whether they were tested in the 0⁰ direction (face sheet layup of [-45/90/+45/0]s) or 90⁰ direction (face sheet layup of [+45/0/-45/90]s). The CAI strength results showed that the specimens tested in the 90⁰ direction had a 19% drop in CAI strength compared to specimens tested in the 0⁰ direction. This was attributed to the 0⁰ load bearing plies in the 0⁰ direction specimens being “tucked in” at the center of the specimen thus providing more stability against microbuckling. This raised the question as to what CAI strength would specimens tested at +22.5⁰ (face sheet layup of [-22.5/- 67.5/+67.6/+22.5]s) and -22.5⁰ (face sheet layup of [-67.5/+67.5/+22.5/-22.5]s) have compared to specimens tested in the 0⁰ and 90⁰ direction. Results presented in this study show that the specimens loaded at +22.5⁰ and -22.5⁰ have a similar average CAI strength compared to the specimens loaded in the 0⁰ direction. The specimens loaded in the 90⁰ direction exhibit 16% lower average CAI strength. Additional specimens were tested in the +45⁰ direction to put the 0⁰ load bearing fibers on the outside of the specimen to see if this would decrease the strength as has been documented for undamaged strength. These specimens have average CAI strength values between the 0⁰ direction average CAI strength values and the 90⁰ direction average CAI strength values.

Sandwich structure↗

Ultrafine-grained Fe-TiB 2 high-modulus nanocomposite steel with high strength and isotropic mechanical properties by laser powder bed fusion

Fe-TiB 2 metal matrix composite, also called high-modulus steels (HMSs), are of great interest for applications in fuel-efficient transportation infrastructure, aerospace, and wear industries due to their high specific stiffness and yield strength. However, conventional cast Fe-TiB 2 HMSs often contain coarse and sharp-edged TiB 2 particles which easily trigger premature cracking during loading. Here, we synthesized a Fe-TiB 2 nanocomposite HMS via laser powder bed fusion (LPBF) additive manufacturing of mixed micro-sized powders of Fe, Ti, and Fe 2 B. We investigated the microstructure formation and mechanical behavior of the Fe-TiB 2 HMS. We found that in situ chemical reaction of Ti and Fe 2 B enables the formation of TiB 2 particles at nanoscale during rapid solidification of LPBF. These nanoscale TiB 2 particles can serve as heterogeneous nucleation sites and promote the formation of ultrafine and equiaxed α-Fe grains with random crystallographic textures, which differ from many other additively manufactured (AM) metal alloys characteristic of strong crystallographic textures. As such, isotropic mechanical properties were achieved in the AM Fe-TiB 2 nanocomposite HMS with a high elastic modulus of ~ 240 GPa, an exceptional yield strength of ~ 1450 MPa, and a large plasticity of ~ 20% under compression. Quantitative analysis reveals that the high yield strength primarily originates from strengthening contributions of the ultrafine grains with an average grain size of ~450 nm, the nanoscale TiB 2 reinforcing particles of 20–180 nm, and a high density of printing-induced dislocations of the order of 10 15 m –2 . In situ synchrotron high-energy X-ray diffraction unveils the load partitioning from the softer α-Fe matrix to the stiffer and stronger TiB 2 nanoparticles, contributing to the sustained strain hardening during compression. Our work not only provides a general pathway for achieving high-performance metal matrix nanocomposites by in situ chemical reaction and precipitation of ceramic nanoparticles during additive manufacturing, but also offers mechanistic insights into the deformation mechanism of nanoparticle-reinforced HMS composites.

36 MATERIALS SCIENCE↗

Fate and transport of unruptured tri-structural isotropic (TRISO) fuel particles in the event of environmental release for advanced and micro reactor applications

Advanced nuclear reactor designs and advanced fuel types offer safety features that may reduce environmental consequences in an accident scenario when compared to conventional reactors and fuels. One advanced reactor fuel is tri-structural isotropic (TRISO) fuel particles which are approximately 0.9 mm in diameter. TRISO particle mobility, assuming the particle is unruptured and the encapsulated radionuclides are contained, was explored through a theoretical examination of mobility through atmospheric, soil and groundwater, surface water, and non-human biota transport pathways. TRISO particles are too large and dense to travel in the atmosphere except under extreme conditions. TRISO particles are too large to penetrate most soil profiles and so cannot be transported with groundwater. TRISO particles will settle out of the water column in surface waters but the transport will depend on the energy of the body of water and likelihood of extreme dispersion events. TRISO particles could be transported by non-human biota. The size of TRISO particles could allow them to be intentionally moved by non-human biota if they are ingested as a gastrolith or if they are mistaken for something in the organism’s diet. Generally, TRISO particles will have reduced environmental mobility compared to releases of radionuclides in the event of an accident in a conventional nuclear reactor. The extent of transport has implications in emergency planning zone designations and other considerations for licensing and deploying TRISO-fueled reactors. Finally, further research and experimental work exploring TRISO particle mobility is required to understand the full environmental mobility of TRISO particles.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Uranium nitride tristructural-isotropic fuel particle

A summary of activities around concept development, design, manufacturing, and early irradiation testing of a novel coated fuel particle, uranium nitride tristructural-isotropic fuel is provided. This fuel particle offers significantly higher uranium density over historic manifestations of coated fuel particles and may be more optimal for a range of advanced reactor applications. After reviewing the design process, steps involving production of this fuel form are discussed. Low burnup irradiation data on this fuel particle are now available, indicating that performance metrics have been met to date based on the original design expectations.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Understanding the effect of specimen size on the properties of fine-grain isotropic nuclear graphite for irradiation studies: Mechanical properties

Programs at Oak Ridge National Laboratory are investigating the effects of neutron irradiation in the High Flux Isotope Reactor (HFIR) on properties of fine-grain isotropic nuclear graphites. Specimens were irradiated in the HFIR flux trap, which requires using specimens that are smaller than the sizes recommended by ASTM standards. Here, this work has investigated whether subsized specimens can be used to reliably predict strength behavior. The results show that (1) tensile strength was loosely coupled to specimen volume, (2) the compression specimens had a slightly higher strength for larger volumes, (3) the uniaxial flexural strength was nearly independent of specimen effective area for one orientation whereas the other orientation showed a slight strength–size scaling Weibull behavior, and (4) equibiaxial flexural strength followed traditional strength–size scaling Weibull behavior. These results suggest that fine-grain graphite is more similar to ceramics than to medium- and large-grained graphite with respect to both the strength-limiting flaws (Griffith theory) and the effect of machining on the strength behavior. This work shows that using specimens that are smaller than ASTM recommendations are suitable for investigating the strength changes caused by neutron irradiation because the primary interest is the relative change in the strength distribution parameters rather than their absolute values.

36 MATERIALS SCIENCE↗

Understanding the effect of specimen size on the properties of fine-grain isotropic nuclear graphite for irradiation studies: Physical, electrical, thermal properties

Programs at Oak Ridge National Laboratory are investigating the effects of neutron irradiation in the High Flux Isotope Reactor (HFIR) on properties of fine-grain nuclear graphites. Specimens were irradiated in the HFIR flux trap, which required using specimens that are smaller than the sizes recommended by ASTM standards. Here, this work has investigated whether subsized specimens can be used to reliably determine the measured physical (density, elastic moduli, and electrical resistivity) and thermal properties (coefficient of thermal conductivity and thermal conductivity). The results show the specimen sizes in this investigation had a minimal influence on any of the measured properties. Even for the properties where size influenced the measured value (density and thermal conductivity), an explanation is provided, and the consequences can be accounted for in post-irradiation results. This work demonstrated that using subsized specimens for physical and thermal property measurements is suitable when necessary for fine-grain isotropic graphite.

36 MATERIALS SCIENCE↗

Microstructural analysis of tristructural isotropic particles in high-temperature steam mixed gas atmospheres

High-temperature gas-cooled reactors (HTGRs) use tristructural isotropic (TRISO) particles embedded in a graphitic matrix material to form the integral fuel element. Potential off-normal reactor conditions for HTGRs include steam ingress with temperatures above 1,000 °C. Fuel element exposure to steam can cause the graphitic matrix material to evolve, forming an atmosphere composed of oxidants and oxidation products and potentially exposing the TRISO particles to these conditions. Investigating the oxidation response of TRISO particles exposed to a mixed gas atmosphere will provide insight into the stability under off-normal conditions. In this study, surrogate TRISO particles were exposed to high temperatures (T = 1,200 °C) in flowing steam (3% < pH 2 O < 21%) and CO (pCO < 1%) to determine the oxidation behavior of the SiC layer when exposed to various mixed gas atmospheres. Scanning electron microscopy, x-ray diffraction, and focused ion beam milling was used to determine the impact of CO and steam on the oxidation behavior of the SiC layer. Therefore, the data presented demonstrates how the SiC layer showed strong oxidation resistance due to limited SiO 2 growth and maintained its structural integrity under these off-normal conditions.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Failure analysis of nuclear transient-tested UN tristructural isotropic fuel particles in a 3D printed SiC matrix

Fully ceramic microencapsulated fuel elements containing UN tristructural isotropic (TRISO) fuel particles within a 3D printed SiC matrix were subjected to transient testing with varying energy depositions. Detailed post-irradiation examinations were performed, including leaching in hot HNO3 and post-leaching X-ray computed tomography, to quantify the percentage of failed TRISO particles and crack propagation within the particles and surrounding fuel matrix. In parallel, detailed finite element analyses were performed for comparison with experimental findings and to better evaluate transient failure modes. The lowest transient energy deposition—which still exceeded bounding values for high-temperature gas-cooled reactor applications—resulted in no detectable TRISO particle failures or matrix cracking, which was consistent with the simulations. Simulations of the higher-energy transients for which significant TRISO particle failure was expected were generally able to reproduce the transient temperatures and matrix cracking. Thus, the TRISO particle failures were explained based on the effects of local SiC matrix thickness and porosity. Results generally confirmed the high strength of the additively manufactured SiC matrix but also affirmed the need for a modified UN TRISO architecture to prevent SiC matrix cracks from propagating through TRISO layers. This unique failure mode has not historically been considered for TRISO fuels contained in weaker graphite matrices.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Bayesian uncertainty quantification of tristructural isotropic particle fuel silver release: Decomposing model inadequacy plus experimental noise and parametric uncertainties

Tristructural isotropic (TRISO) particle fuel is one of the most promising fuel concepts enabling high temperature and high burnup reactor operation. One dominant source of radioactivity released from the TRISO particles is silver (Ag), which is subject to a high release fraction and long decay life compared to other fission products. Previous modeling efforts using the fuel performance code BISON indicated nonnegligible uncertainties in modeling the diffusion process of fission products in TRISO compared to the Advanced Gas Reactor experiments. The overall uncertainties observed when modeling the fission product diffusion can result from uncertainties in model parameters, noisy experimental measurements, and deficiencies in the developed models. The three types of underlying uncertainties have not yet been properly quantified in open literature. Here, this paper presents the Bayesian uncertainty quantification (UQ) using massively parallelizable Markov chain Monte Carlo samplers. The uncertainties due to model parameters, model inadequacy, and experimental measurement noise are quantified, with the σ term used to represent the sum of the model inadequacy and measurement noise uncertainties. It is worth noting that this is the first time the σ term is inferred for nuclear fuel experiments, as compared to using prescribed values for uncertainty quantification in previous work. The parallelizable Markov chain Monte Carlo samplers efficiently infer the model parameters and the σ term, giving insight into physical parameters like diffusion coefficients and the combined model discrepancy and measurement noise. A subsequent forward uncertainty quantification (UQ) is also performed based on the calibration results to generate more accurate predictions of the Ag release. The model inadequacy plus experimental noise is the most dominant source of uncertainty compared to the parametric uncertainty. All the UQ analyses presented in this work are based on the second series of the irradiation experiments in the Advanced Gas Reactor program.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Effect of isotropic and anisotropic porous microstructure on electrochemical performance of Li ion battery cathodes: An experimental and computational study

Liquid electrolyte mass transport is a major limitation affecting high-power Li ion batteries. Fast discharging causes Li salt depletion in the current collector region of the cathode which produces overpotential in the electrolyte and consequently a drop of cell voltage to below the cut-off voltage, especially at higher electrode thickness and discharge rate. In this study, through experiment and simulation, we have investigated the effect of electrode thickness, mass loading, discharge rate and tortuosity on electrolyte mass transport and final derived areal capacity and specific energy for electrodes having isotropic (normal tape casting) and anisotropic (freeze tape casting) porous microstructure. Furthermore, the macroporous channels in freeze tape cast electrodes facilitate Li salt transport and reduce the Li salt mass transport limitations even at high electrode thickness and discharge rates, and high electrode tortuosity. In our results, computer simulations show that freeze tape cast electrodes may be fully discharged up to 750 μm thickness at 1 C rate compared to 300 μm for normal tape cast electrodes with the same mass loading. Freeze tape cast electrodes also show stable maximum areal capacity for C rates about double the maximum C rates of their normal tape cast electrode counterparts with the same mass loading.

25 ENERGY STORAGE↗

The estimation of Poisson’s ratio by time-averaging and Cornu’s method for isotropic beams

Prior research suggests that direct static (e.g., uniaxial testing) and dynamic (e.g., ultrasonic wave propagation analysis) measurements differ in the estimation of Poisson’s ratio because anisotropies and heterogeneities in the sample material affect the two types of tests differently. Even assuming isotropic and homogeneous material properties, prior research further suggests that discrepancies between static/dynamic test results will exist because the error of the diagnostic techniques for the measurand are inherently different. Finally, thermodynamic effects are not present in static tests but can significantly affect dynamic test results. Given the potential for all these variables to produce discrepancies, it would be helpful to have the measurement of Poisson’s ratio obtainable from the same theory and experimental measurements by either static or dynamic testing methods. Our finite element calculations show that by combining time-averaged scanning digital holography with Cornu’s method, it is theoretically possible to estimate the effective Poisson’s ratio from the anticlastic contours at the antinode of the first out-of-plane bending mode shape. This is true regardless of frequency and therefore applicable for both static and dynamic measurements. Our results show that the estimate of Poisson’s ratio by Cornu’s method using data from simulations of mode shapes approaches the true value of Poisson’s ratio. Additionally, our research suggests that beam geometry and boundary conditions are fundamental factors limiting the convergence of the estimate of Poisson’s ratio to the true value of Poisson’s ratio regardless of performing a static or dynamic test.

42 ENGINEERING↗

Thermal fluctuations in the dissipation range of homogeneous isotropic turbulence

In this work, using fluctuating hydrodynamics we investigate the effect of thermal fluctuations in the dissipation range of homogeneous isotropic turbulence. Simulations confirm theoretical predictions that the energy spectrum is dominated by these fluctuations at length scales comparable to the Kolmogorov length. We also find that the extreme intermittency in the far-dissipation range predicted by Kraichnan is replaced by Gaussian thermal equipartition.

42 ENGINEERING↗

The Effects of Field Line Curvature (FLC) Scattering on Ring Current Dynamics and Isotropic Boundary

Abstract In the ring current dynamics, various loss mechanisms contribute to the ring current decay, including losses to the upper atmosphere through particle precipitation. This study implements the field line curvature (FLC) scattering mechanism in a kinetic ring current model and investigates its role in precipitating ions into the ionosphere during the 17 March 2013 storm. Simulation results indicate that (1) the FLC scattering process exerts on energetic ions on the nightside where the magnetospheric configuration is more stretching. It is more effective on heavy ions (e.g., O + ). These ion losses thereafter lead to a faster recovery of the ring current. (2) The FLC‐associated ion precipitation mainly occurs in the outer region (L > 5 for protons and L > 4.5 for oxygen ions) on the nightside. The O + precipitation takes places in a wider region than protons although its intensity is much lower. Comparisons with POES observations suggest that more proton precipitation is needed in the inner region. This is probably caused by the less stretched configuration in the simulation that prevents more precipitation. It may also imply that other loss process is required in the model such as wave‐particle interactions. (3) The storm time precipitating proton flux of tens of keV due to the FLC scattering sometimes becomes comparable to that of electrons on the nightside, although electrons usually dominate the ionospheric energy deposition from the midnight eastward toward the dayside. (4) The FLC scattering process seems to be capable of explaining the formation of isotropic boundary in the ionosphere during the investigated event.

79 ASTRONOMY AND ASTROPHYSICS↗

Quadrupolar magnetic excitations in an isotropic spin-1 antiferromagnet

The microscopic origins of emergent behaviours in condensed matter systems are encoded in their excitations. In ordinary magnetic materials, single spin-flips give rise to collective dipolar magnetic excitations called magnons. Likewise, multiple spin-flips can give rise to multipolar magnetic excitations in magnetic materials with spin S ≥ 1. Unfortunately, since most experimental probes are governed by dipolar selection rules, collective multipolar excitations have generally remained elusive. For instance, only dipolar magnetic excitations have been observed in isotropic S = 1 Haldane spin systems. Here, we unveil a hidden quadrupolar constituent of the spin dynamics in antiferromagnetic S = 1 Haldane chain material Y 2 BaNiO 5 using Ni L 3 -edge resonant inelastic x-ray scattering. Our results demonstrate that pure quadrupolar magnetic excitations can be probed without direct interactions with dipolar excitations or anisotropic perturbations. Originating from on-site double spin-flip processes, the quadrupolar magnetic excitations in Y 2 BaNiO 5 show a remarkable dual nature of collective dispersion. While one component propagates as non-interacting entities, the other behaves as a bound quadrupolar magnetic wave. This result highlights the rich and largely unexplored physics of higher-order magnetic excitations.

36 MATERIALS SCIENCE↗

An isotropic zero thermal expansion alloy with super-high toughness

Zero thermal expansion (ZTE) alloys with high mechanical response are crucial for their practical usage. Yet, unifying the ZTE behavior and mechanical response in one material is a grand obstacle, especially in multicomponent ZTE alloys. Herein, we report a near isotropic zero thermal expansion (α l = 1.10 × 10 -6 K -1 , 260–310 K) in the natural heterogeneous LaFe 54 Co 3.5 Si 3.35 alloy, which exhibits a super-high toughness of 277.8 ± 14.7 J cm -3 . Chemical partition, in the dual-phase structure, assumes the role of not only modulating thermal expansion through magnetic interaction but also enhancing mechanical properties via interface bonding. The comprehensive analysis reveals that the hierarchically synergistic enhancement among lattice, phase interface, and heterogeneous structure is significant for strong toughness. Our findings pave the way to tailor thermal expansion and obtain prominent mechanical properties in multicomponent alloys, which is essential to ultra-stable functional materials.

36 MATERIALS SCIENCE↗

Data-driven learning of Mori–Zwanzig operators for isotropic turbulence

Developing reduced-order models for turbulent flows, which contain dynamics over a wide range of scales, is an extremely challenging problem. In statistical mechanics, the Mori–Zwanzig (MZ) formalism provides a mathematically exact procedure for constructing reduced-order representations of high-dimensional dynamical systems, where the effects due to the unresolved dynamics are captured in the memory kernel and orthogonal dynamics. Turbulence models based on MZ formalism have been scarce due to the limited knowledge of the MZ operators, which originates from the difficulty in deriving MZ kernels for complex nonlinear dynamical systems. In this work, we apply a recently developed data-driven learning algorithm, which is based on Koopman's description of dynamical systems and Mori's linear projection operator, on a set of fully resolved isotropic turbulence datasets to extract the Mori–Zwanzig operators. With data augmentation using known turbulence symmetries, the extracted Markov term, memory kernel, and orthogonal dynamics are statistically converged and the generalized fluctuation–dissipation relation can be verified. The properties of the memory kernel and orthogonal dynamics, and their dependence on the choices of observables are investigated to address the modeling assumptions that are commonly used in MZ-based models. A series of numerical experiments are then constructed using the extracted kernels to evaluate the memory effects on prediction. The results show that the prediction errors are strongly affected by the choice of observables and can be further reduced by including the past history of the observables in the memory kernel.

97 MATHEMATICS AND COMPUTING↗