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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

New Chemical, Bio-Optical and Physical Observations of Upper Ocean Response to the Passage of a Mesoscale Eddy off Bermuda

A mesoscale eddy advected across the Bermuda Testbed Mooring site over a 30-day period centered on July 14, 1995. Temperature and current measurements along with biogeochemical measurements were used to characterize the biological response of the upper ocean associated with the introduction of nitrate into the euphoric layer due to the doming of isotherms associated with the eddy. Complementary shipboard data showed an anomalous water mass, which extended from a depth of approximately 50 to 1000 m, manifesting as a cold surface expression and warm anomaly at depth. Although mesoscale eddies are frequently observed in the Sargasso Sea, the present observations are particularly unique because of the high-temporal-resolution measurements of the new instrumentation deployed on the mooring. Analyzers that measure nitrate plus nitrite were placed at depths of 80 and 200 m and bio-optical sensors were located at depths of 20, 35, 45, 71, and 86 m. Peak nitrate values of nearly 3.0 microns at 80 m and chlorophyll alpha values of 1.4 mg/cu m at 71 m were observed, as well as a 25- to 30-meter shoaling of the 1% light level depth. A Doppler shift from the inertial period (22.8 hours) to 25.2 hours was observed in several time series records due to the movement of the eddy across the mooring. Inertial pumping brought cold, nutrient-rich waters farther into the euphotic zone than would occur solely by isothermal lifting. Silicic acid was depleted to undetectable levels owing to the growth of diatoms within the eddy. The chlorophyll alpha values associated with the eddy appear to be the largest recorded during the 8 years of the ongoing U.S. JGOFS Bermuda Atlantic Time Series Study (BATS) program.

McNeil, J. D.↗
NASA NTRS1996

Electrical double layers at the oil/water interface

This review presents the historical development and current status of the theory of the electrical double layer at a liquid/liquid interface. It gives rigorous thermodynamic definitions of all basic concepts related to liquid interfaces and to the electrical double layer. The difference between the surface of a solid electrode and the interface of two immiscible electrolyte solutions (ITIES) is analyzed in connection to their electrical properties. The most important classical relationships for the electrical double layer are presented and critically discussed. The generalized adsorption isotherm is derived. After a short review of the classical Gouy-Chapman and Verwey-Niessen models, more recent developments of the double layer theory are presented. These include effects of variable dielectric permittivity, nonlocal electrostatics, hydration forces, the modified Poisson-Boltzmann equation and the ion-dipole plasma. The relative merits of different theories are estimated by comparing them with computer simulation of the ITIES and electrical double layer. Special attention is given to the structure of ITIES and its variation due to adsorption of ions and amphiphilic molecules.

Non-NASA Center↗
DOE OSTI2024

Unraveling the multi-step crystallization mechanism of polytetrafluoroethylene, modified polytetrafluoroethylene, and their nanocomposites with boron nitride nanobarbs: Experimental insights and theoretical analysis

The non-isothermal crystallization behavior and kinetics of polytetrafluoroethylene (PTFE) composites with boron nitride nanobarb (BNNB), a new generation nanostructure with unique surface morphology and mechanical “barbs” have been analyzed, understanding these properties is essential for their high-end applications as thermal interface materials (TIM) for microwave, 5G and microelectronic devices. The analysis of the crystallization parameters includes crystallization onset, peak and end temperatures, crystallization half-life and overall crystallinity of PTFE, modified PTFE and their BNNB composites. The results were further analyzed using theoretical models such as the combined Avrami-Ozawa model. It was found that BNNB supports crystallization in the modified PTFE but shows minimal effect on the crystallization of PTFE. Due to the limitation of the classical theoretical models used above in fully characterizing the multi-step crystallization process of PTFE, an in-depth analysis using the model-free advanced isoconversional computation was used to characterize the PTFE crystallization based on the evolution of activation energy with fractional crystallinity and for the first time with temperature. Three kinetic regions were identified in the crystallization mechanism. Here, this study investigated the molecular organization and microstructural evolution of PTFE, modified PTFE and their composites during non-isothermal crystallization using advanced X-ray scattering measurements. An insight into the changes undergone by the material's microstructural units including crystallite size and morphology, lamellar thickness and lamellar interfacial layer thickness, and crystallographic phase dynamics during non-isothermal cooling from the melt, was provided here in this work. The effect of copolymer modification of PTFE and the inclusion of pristine and functionalized BNNB (a thermally conductive and electrically insulating ceramic) are both new investigations that provide valuable knowledge for the development of materials with strong matrix-nanofiller interaction and guidance for optimizing sintering and cooling cycles, two key steps in PTFE processing that largely affect the material microstructural features. Overall, the result of the three-part investigation demonstrates that BNNB supports crystallization in the modified PTFE up to 20 wt% concentration and at low and high cooling rates typically used in the industrial processing of PTFE.

36 MATERIALS SCIENCE↗
DOE OSTI2022

High concentrations of ice: Investigations using polarimetric radar observations combined with in situ measurements and cloud modeling (Final Report)

This DOE-funded joint project had the over-arching goal of understanding the reasons for observed size distributions of ice particles in cold clouds. Its approach involves the use of cloud models and field observations by radar and aircraft of real storms. The project addresses three major research objectives: (1) Utilize a novel polarimetric radar technique to retrieve size distributions and amounts of ice from radar data collected during the previous DOE ARM field campaigns; (2) Evaluate the results of ice microphysical retrievals using available in situ aircraft measurements and other remote sensors (e.g., vertically pointing cloud radars and wind profilers); (3) Improve the treatment of microphysical processes leading to cloud glaciation and ice multiplication in numerical cloud models. The study was performed by three research organizations: University of Oklahoma, The Hebrew University of Jerusalem, Israel, and Lund University, Sweden. The Israel and Swedish partners were funded by the sub-awards from the University of Oklahoma. Cloud modeling studies have been performed by the research teams at The Hebrew University of Jerusalem (HUJ) and Lund University to identify the origins of high concentrations of cloud ice in areas of high ice water content (HIWC). The Hebrew University Cloud Model (HUCM) with full spectral bin microphysics and the Lund University aerosol-cloud (AC) model with a hybrid bin / bulk microphysics scheme complementing HUCM were utilized for simulations. Both research teams had particular focus on secondary ice production (SIP) as one of the possible sources of enhanced ice concentration. The HUJ group suggested a novel concept of ice multiplication during droplet freezing. It is assumed that splintering and droplet fragmentation during droplet freezing takes place because of dendritic growth within a supercooled drop. The resulting simulations of SIP generated small ice in concentrations exceeding hundreds per liter similar to what was observed in the HIWC regions of the tropical storms. The Lund team explored the SIP mechanisms such as breakup of ice particles due to ice-ice collisions and ice sublimation that are expected to dominate the continental storms. They also quantified the impact of homogeneous nucleation of cloud droplets on the total number concentration of ice at very low temperatures near the tops of the clouds. Additionally, the Lund AC model is able to simulate the effect of aerosols of various types (including biological) on the cloud life cycle and the corresponding ice production. The HUCM / AC model was used to simulate one of the “golden” cases of the DOE MC3E campaign on 20 May 2011. The model output was converted into the fields of polarimetric radar variables using the polarimetric radar forward operator developed at the University of Oklahoma and compared with radar observations and in situ microphysical measurements onboard research aircraft. It was demonstrated that specific differential phase KDP is the best radar parameter to identify the HIWC areas and quantify the corresponding ice parameters. For the first time, the shape of the vertical profile of KDP was realistically reproduced by the cloud model with the KDP maximum in the dendritic growth layer (DGL) centered at the -15°C isotherm. The University of Oklahoma team has developed a methodology for polarimetric radar retrievals of such microphysical parameters of ice as ice water content (IWC), mean volume diameter (Dm), and total number concentration (Nt) of ice particles. These retrievals have been validated using in situ aircraft measurements during 6 field campaigns and proved to be quite robust and reliable. This allowed to build the first climatology of the vertical profiles of polarimetric radar variables and retrieved microphysical parameters for the three types of weather systems: continental MCSs, maritime MCSs, and tropical cyclones / hurricanes (Hu and Ryzhkov 2022). The data were collected by a multitude of the WSR-88D radars in 13 continental and 10 maritime MCSs and 11 landfalling hurricanes. The HIWC areas were identified within the examined storms and the corresponding “HIWC statistics” was compared with the “background” one without HIWC. An overarching conclusion of the study is that maritime tropical storms (MCSs and hurricanes) are characterized by smaller size ice in higher concentration compared to the continental MCSs. High ice water content in the HIWC areas is primarily caused by a strong jump in a number concentration of ice particles rather than the increase of their size compared to the “background” environment. This may point to the homogeneous nucleation of excessive amounts of supercooled droplets and / or secondary ice production as the possible origins of HIWC. Such a climatology provides a good observational reference for the modelers to evaluate the performance of their models. As an example, the in-depth analysis of the 20 May 2011 MC3E case shows that the advanced cloud models developed in the course of this study still tend to underestimate the number concentration of ice in the HIWC areas although they succeed in reproducing realistically looking vertical profiles of IWC and Nt. The results of the project research are summarized in 13 journal papers.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1977

Studies of heat-source driven natural convection: A numerical investigation

Thermal convection driven by uniform volumetric energy sources was studied in a horizontal fluid layer bounded from above by a rigid, isothermal surface and from below by a rigid, zero heat-flux surface. The side walls of the fluid domain were assumed to be rigid and perfectly insulating. The computations were formally restricted to two-dimensional laminar convection but were carried out for a range of Rayleigh numbers which spans the regimes of laminar and turbulent flow. The results of the computations consists of streamline and isotherm patterns, horizontally averaged temperature distributions, and horizontally averaged Nusselt numbers at the upper surface. Flow and temperature fields do not exhibit a steady state, but horizontally averaged Nusselt numbers reach limiting, quasi-steady values for all Rayleigh numbers considered. Correlations of the Nusselt number in terms of the Rayleigh and Prandtl numbers were determined.

Emara, A. A.↗
NASA NTRS1985

A two-layer diagnostic model of the long-term physical evolution of warm-core ring 82B

The present shipboard data in the 1982 time series on a single Gulf Stream warm core ring are composited on a cylindrical coordinate system following ring motion; 10 C-isotherm depth measurements are used in a two-layer model of the ring's structure to compute gradient current, kinetic energy, available potential energy (APE), and potential vorticity. The ring's evolution can be divided into two periods: April-late June, while the ring is isolated from strong Gulf Stream interaction, during which the ring loses APE at a low rate, and from July onward, following ring interactions with the Gulf Stream and topography with much higher energy loss. Within measurement errors, the potential vorticity at the center of the ring is conserved from April through August, implying nearly inviscid dynamics.

Olson, D. B.↗
DOE OSTI2020

On the pressure and temperature dependence of adsorption densities and other thermodynamic properties in gas shales

Black shale source rocks have become a key natural gas resource in the US and China. Unlike in conventional hydrocarbon reservoirs, a significant fraction of the gas in shales is adsorbed onto the inordinate specific surface areas (SSA) of micropores inside organic matter with densities exceeding those of bulk gas by an order of magnitude. Yet, the distribution of adsorbed versus bulk gas remains poorly understood. Experiments measure excess adsorption isotherms, which are corrected to absolute adsorption amounts by a factor that involves the density, ρ abs , of the adsorption layer(s). Constant values of ρ abs are widely used in the literature but, we argue, are inconsistent with the pressure- and temperature-dependence of adsorption behavior. In this work, we propose a more reliable approach that assumes a constant volume of each adsorption layer that can be determined from the SSA of the substrate. We measure nine high-pressure methane excess adsorption isotherms up to 15 MPa for three shale samples from China and Germany at temperatures of 65, 75, and 95 °C, and low-pressure carbon dioxide and nitrogen isotherms to estimate the SSA. We also investigate another 24 isotherms at 35, 50, and 60° C or 8 Chinese shale samples and 3 isotherms at 60, 90, and 120° C for an Argentinian shale sample from the literature. A new variation of the multi-layer Ono-Kondo lattice model is introduced to derive the temperature and pressure dependent adsorption layer densities, which are subsequently used to obtain the absolute adsorption isotherms of interest. Finally, this practical methodology has the potential to significantly improve our estimates of shale gas-in-place resources, and adsorption modeling more broadly.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1999

Blade Heat Transfer Measurements and Prediction in a Transonic Turbine Cascade

Detailed heat transfer measurements and predictions are given for a turbine rotor with 136 deg of turning and an axial chord of 12.7 cm. Data were obtained for inlet Reynolds numbers of 0.5 and 1.0 x 10(exp 6), for isentropic exit Mach numbers of 1.0 and 1.3, and for inlet turbulence intensities of 0.25% and 7.0%. Measurements were made in a linear cascade having a highly three-dimensional flow field resulting from thick inlet boundary layers. The purpose of the work is to provide benchmark quality data for three-dimensional CFD code and model verification. Data were obtained by a steady-state technique using a heated, isothermal blade. Heat fluxes were determined from a calibrated resistance layer in conjunction with a surface temperature measured by calibrated liquid crystals. The results show the effects of strong secondary vortical flows, laminar-to-turbulent transition, shock impingement, and increased inlet turbulence on the surface heat transfer.

Giel, P. W.↗
NASA NTRS1951

Sideslip in a viscous compressible gas

By an analysis of the Navier-Stokes equations it is shown that the aerodynamic coefficients of an infinite rectangular swept wing in an isothermal or adiabatic flow of a compressible gas can be determined from the aerodynamic coefficients of the unswept wing. When the flow is neither isothermal nor adiabatic, a three-dimensional boundary layer theory is developed and applied to the special case of a swept flat plate.

THEORIES - WINGS, SWEEPBACK & SWEEPFORWARD↗
NASA NTRS2002

Path-Integrated Attenuation from Airborne X-Band Radar and Passive Radiometer Measurements: Implication for Rainfall Measurements

This study compares path-integrated attenuation (PIA), in precipitation over the ocean, derived from a single-frequency X-band radar, using the surface reference technique (SRT), with that deduced from a radiometer also operating at X band. The data were collected during TRMM field campaigns. The PIA derived from radar using the SRT does not involve any assumptions regarding the precipitation but it assumes that the cross-section of the surface is stable, that is, it is not significantly altered by factors such as surface roughness. The PIA deduced from the radiometer, however, involves assumptions regarding the temperature and emissivity of the surface and absorption and scattering by the intervening precipitation, which in turn depend upon the size, concentration and composition of the precipitation particles. The comparison of the PIA from the two instruments serves not only as a check between the radar and the radiometer but also may yield insights into the structure of the intervening precipitation. Such study can provide valuable information for TRMM in which both radar and radiometers are used for rain measurements. The radiometer PIA was first deduced from the brightness temperature using a simple one-layer radiative transfer model assuming no scattering, an isothermal atmosphere. The initial results show a general agreement between the PIAs deduced from the two instruments. Largo disagreement was found at high values of PIAs that may have been caused saturation of the X-band brightness temperature or by uncertainties in wind roughening of the sea surface that affects the SRT. Further results including the effects of scattering and a non-isothermal atmosphere will be shown at the conference.

Tian, Lin↗
NASA NTRS1996

Microstructural Development during Directional Solidification of Peritectic Alloys

A thorough understanding of the microstructures produced through solidification in peritectic systems has yet to be achieved, even though a large number of industrially and scientifically significant materials are in this class. One type of microstructure frequently observed during directional solidification consists of alternating layers of primary solid and peritectic solid oriented perpendicular to the growth direction. This layer formation is usually reported for alloy compositions within the two-phase region of the peritectic isotherm and for temperature gradient and growth rate conditions that result in a planar solid-liquid interface. Layered growth in peritectic alloys has not previously been characterized on a quantitative basis, nor has a mechanism for its formation been verified. The mechanisms that have been proposed for layer formation can be categorized as either extrinsic or intrinsic to the alloy system. The extrinsic mechanisms rely on externally induced perturbations to the system for layer formation, such as temperature oscillations, growth velocity variations, or vibrations. The intrinsic mechanisms approach layer formation as an alternative type of two phase growth that is inherent for certain peritectic systems and solidification conditions. Convective mixing of the liquid is an additional variable which can strongly influence the development and appearance of layers due to the requisite slow growth rate. The first quantitative description of layer formation is a model recently developed by Trivedi based on the intrinsic mechanism of cyclic accumulation and depiction of solute in the liquid ahead of the interface, linked to repeated nucleation events in the absence of convection. The objective of this research is to characterize the layered microstructures developed during ground-based experiments in which external influences have been minimized as much as possible and to compare these results to the current the model. Also, the differences between intrinsic and externally influenced layer formation were explored. The choice of alloy system is critical to a study of the formation of layered microstructures. The ideal system would have a well-characterized phase diagram, equal densities of both elements in the liquid state to minimize compositionally-driven convective flows, a low peritectic temperature to simplify directional solidification and the achievement of a high temperature gradient in the liquid, a broad composition range for the peritectic reaction, and a reasonable hardness at room temperature to facilitate handling and metallographic preparation. The In-Sn system was selected initially due to a very low peritectic temperature and the nearly equal densities of In and Sn in the liquid state. Since the In-rich peritectic reaction had apparently not been utilized previously for solidification research, experiments were conducted to check the phase diagram in the region of interest. The alloys in this system proved to be difficult to handle and prepare in bulk form with the equipment available, so experiments were initiated with the Sn-Cd system. Layered microstructures had been observed previously in Sn-Cd.

Lograsso, Thomas A.↗
NASA NTRS1983

The influence of coastal shape on winter mesoscale air-sea interaction

In cold air outbreaks, the combination of coastal shape and sea surface isotherms has a profound effect in the establishment of mesoscale atmospheric circulation, due to differential heating resulting from both overwater path length and underlying sea surface temperature (SST) variations. Where coastal effects are dominant, a mesoscale front forms downstream of the point which marks the major bend in the coastline's orientation. The strength of the induced mesoscale circulation depends on the original contrast between the land air temperature and the SST. It is noted that where the coastline and the isotherm pattern are approximately normal to the mean boundary layer flow, and thermal contrast is sufficiently large, the cloud streets formed downstream will be convective in nature, and oriented with the axis of roll vortices along the wind direction.

Atlas, D.↗
NASA NTRS1988

Numerical models of thermally and mechanically coupled two-layer convection of highly viscous fluids

Thermal convection in the earth mantle is investigated by means of numerical simulations. The mantle models comprise two horizontal layers of viscous incompressible fluid (with identical or differing properties) separated by a fixed horizontal interface; an isothermal, fixed-heat-flux, or insulating lower boundary; and heat supplied either from below or internally (in the lower layer only, equally in both layers, or primarily in the upper layer). The mathematical formulation of the models is explained, and results for linear stability and finite-amplitude convection are presented in extensive tables and graphs and discussed in detail. Particular attention is given to the presence of thermal coupling without interface distortion in many cases, the predominance of long-wavelength cells in the finite-amplitude models, and the large (50 percent) temperature difference across the interface in all cases.

Ellsworth, Kirk↗
DOE OSTI2020

Nonclassical Behavior in Competitive Ion Adsorption at a Charged Solid–Water Interface

Ion adsorption at solid-water interfaces is commonly described by interactions between specific surface sites and adsorbed ions in classical models. However, energetic contributions from non-site-specific ion-ion interactions have not been explored systematically. Here, we report non-classical behaviors observed during competitive adsorption between Sr 2+ and Na + /Rb + at the negatively-charged muscovite mica (001)-water interface, revealing apparent controls of adsorbed ion speciation over the interfacial reactivity. In the absence of competing cations, Sr 2+ adsorbs in approximately equivalent proportions of inner-sphere and outer-sphere complexes, whereas it adsorbs predominantly as an outer-sphere complex in the presence of Na + /Rb + . This transformation of adsorbed Sr 2+ speciation significantly decreases its adsorption strength, as indicated by ~15-fold shift in the Sr 2+ adsorption edge concentration, compared to that calculated from a classical Langmuir isotherm model developed based on site-specific interactions. Finally, these observations highlight the importance of non-site-specific interactions in controlling the energetics of chemical reactions at the charged interface.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1971

One dimensional lunar ash flow with and without heat transfer

The characteristics of lunar ash flow are discussed in terms of the two phase flow theory of a mixture of a gas and small solid particles. A model is developed to present the fundamental equations and boundary conditions. Numerical solutions for special ash flow with and without heat transfer are presented. In the case of lunar ash flow with small initial velocity, the effect of the heat transfer makes the whole layer of ash flow more compacted together than the corresponding isothermal case.

Pai, S. I.↗
NASA NTRS1977

Structure of the atmosphere of Mars in summer at mid-latitudes

Instruments onboard Viking 1 and 2 landers were used to measure the structure of Mars' atmosphere in situ from near the surface to an altitude of 120 km. Atmospheric structure was found to be well defined by the instruments and relatively similar at the two sites. Viking 1 and 2 surface pressures were 7.62 and 7.81 mbar, and temperatures were 238 K and 236 K, respectively, with pressures at the elevation of the reference ellipsoid of 6.74 and 6.30 mbar. Mean temperature was found to decrease with a lapse rate of about 1.6 K/km (significantly subadiabatic) from above the boundary layer to about 40 km. The temperature was then near isothermal with a large-amplitude wave superimposed (attributed to the diurnal thermal tide). It is suggested that the mean profile is governed by radiative equilibrium. The obtained density data are found to merge well with those obtained by an upper-atmosphere spectrometer (at 200 km). The temperature wave is found to continue above 100 km while increasing in wavelength and amplitude.

Seiff, A.↗
NASA NTRS1974

Studies of heat source driven natural convection

Natural convection energy transport in a horizontal layer of internally heated fluid with a zero heat flux lower boundary, and an isothermal upper boundary, has been studied. Quantitative information on the time-mean temperature distribution and the fluctuating component of temperature about the mean temperature in steady turbulent convection are obtained from a small thermocouple inserted into the layer through the upper bounding plate. Data are also presented on the development of temperature at several vertical positions when the layer is subject to both a sudden increase and to a sudden decrease in power input. For changes of power input from zero to a value corresponding to a Rayleigh number much greater than the critical linear stability theory value, a slight hysteresis in temperature profiles near the upper boundary is observed between the heat-up and cool-down modes.

Kulacki, F. A.↗