Corrosion of high-temperature materials in alkali metals.
Corrosion by liquid alkali metals of high temperature materials in space reactors
HIGH TEMPERATURE MATERIAL↗
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A preliminary systems-engineering study of an advanced nuclear-electrolytic hydrogen-production facility
An advanced nuclear-electrolytic hydrogen-production facility concept was synthesized at a conceptual level with the objective of minimizing estimated hydrogen-production costs. The concept is a closely-integrated, fully-dedicated (only hydrogen energy is produced) system whose components and subsystems are predicted on ''1985 technology.'' The principal components are: (1) a high-temperature gas-cooled reactor (HTGR) operating a helium-Brayton/ammonia-Rankine binary cycle with a helium reactor-core exit temperature of 980 C, (2) acyclic d-c generators, (3) high-pressure, high-current-density electrolyzers based on solid-polymer electrolyte technology. Based on an assumed 3,000 MWt HTGR the facility is capable of producing 8.7 million std cu m/day of hydrogen at pipeline conditions, 6,900 kPa. Coproduct oxygen is also available at pipeline conditions at one-half this volume. It has further been shown that the incorporation of advanced technology provides an overall efficiency of about 43 percent, as compared with 25 percent for a contemporary nuclear-electric plant powering close-coupled contemporary industrial electrolyzers.
Escher, W. J. D.↗
The importance of Soret transport in the production of high purity silicon for solar cells
Temperature-gradient-driven diffusion, or Soret transport, of silicon vapor and liquid droplets is analyzed under conditions typical of current production reactors for obtaining high purity silicon for solar cells. Contrary to the common belief that Soret transport is negligible, it is concluded that some 15-20 percent of the silicon vapor mass flux to the reactor walls is caused by the high temperature gradients that prevail inside such reactors. Moreover, since collection of silicon is also achieved via deposition of silicon droplets onto the walls, the Soret transport mechanism becomes even more crucial due to size differences between diffusing species. It is shown that for droplets in the 0.01 to 1 micron diameter range, collection by Soret transport dominates both Brownian and turbulent mechanisms.
Srivastava, R.↗
Direct thermal water splitting by concentrated solar radiation for hydrogen production. Phase O: Proof of concept experiment
The direct production of hydrogen from water and solar energy concentrated into a high temperature aperture is described. A solar powered reactor able to dissociate water vapor and to separate the reaction product at high temperature was developed, and direct water splitting has been achieved in a laboratory reactor. Water vapor and radiative heating from a carbon dioxide laser are fed into the reactor, and water vapor enriched in hydrogen and water vapor enriched in oxygen are produced. The enriched water vapors are separated through a separation membrane, a small disc of zirconium dioxide heated to a range of 1800 k to 2800 k. To avoid water vapor condensation within the reactor, the total pressure within the reactor was limited to 0.15 torr. A few modifications would enable the reactor to be operated at an increased pressure of a few torrs. More substantial modifications would allow for a reaction pressure of 0.1 atmosphere.
Genequand, P.↗
Status of the Nuclear-Induced Conductivity Experiment (NICE) Project
Nuclear-based magnetohydrodynamic (MHD) energy conversion has been pursued in various forms since the 1950's. The majority of this work was motivated by the compatibility of MHD generators with the high temperature achievable with a nuclear reactor and the associated potential for very high cycle efficiency. As a result of this perspective, methods for enhancing the electrical conductivity of the MHD flow have primarily focused on traditional thermal ionization processes, especially those utilizing alkali metal seeds. However, electrical conductivity enhancement via thermal interactions imposes significant limitations on the flow expansion through the generator, and hence on the ultimate power density. Furthermore, the introduction of an alkali metal seed into the flow significantly complicates the engineering design and increases the potential for system failures due to plating of the evaporated metal on cold surfaces.
Bitteker, Leo↗
Physics and potentials of fissioning plasmas for space power and propulsion
Fissioning uranium plasmas are the nuclear fuel in conceptual high-temperature gaseous-core reactors for advanced rocket propulsion in space. A gaseous-core nuclear rocket would be a thermal reactor in which an enriched uranium plasma at about 10,000 K is confined in a reflector-moderator cavity where it is nuclear critical and transfers its fission power to a confining propellant flow for the production of thrust at a specific impulse up to 5000 sec. With a thrust-to-engine weight ratio approaching unity, the gaseous-core nuclear rocket could provide for propulsion capabilities needed for manned missions to the nearby planets and for economical cislunar ferry services. Fueled with enriched uranium hexafluoride and operated at temperatures lower than needed for propulsion, the gaseous-core reactor scheme also offers significant benefits in applications for space and terrestrial power. They include high-efficiency power generation at low specific mass, the burnup of certain fission products and actinides, the breeding of U-233 from thorium with short doubling times, and improved convenience of fuel handling and processing in the gaseous phase.
Thom, K.↗
The Use of Immersion Rigs for High Temperature Hydrogen Exposure Testing Within the Nuclear Thermal Rocket Element Environmental Simulator (NTREES): NTREES-5 Hydrogen Heat Exchanger (N5HHX-01)
The Nuclear Thermal Rocket Element Environmental Simulator (NTREES) facility at NASA’s Marshall Space Flight Center (MSFC) subjects materials and components typically found on nuclear thermal propulsion (NTP) systems to non-nuclear simulations of prototypic NTP reactor thermohydraulic environments. With 1.2 MW of inductive power available, the currently employed methods to simulate nuclear heating in NTREES consist of 1) inductively heating a test specimen, which typically cannot be performed on ceramic materials, or 2) heating gas that envelops the test specimen. The latter of these has provided a basis for developing so-called “immersion rigs” to be used in NTREES. Furthermore, immersion rigs are especially useful in the case of smaller, technically challenging test specimens. One such device, the “NTREES-5 Hydrogen Heat Exchanger” (N5HHX-01), designed and deployed to test small material coupons to ~0.5 g/s of 2800 K, 500 psi Hydrogen, is discussed herein. To achieve this desired delivery temperature level, the most suitable material for the N5HHX’s construction was pure tungsten, which imposed budgetary and manufacturing challenges. Also discussed in this paper is the design of the N5HHX rig’s sample container, which became the first iteration of improving NTREES small material coupon test operations by permitting rapid changeout of different material samples.
Reactor Testing↗
Review of Rover fuel element protective coating development at Los Alamos
The Los Alamos Scientific Laboratory (LASL) entered the nuclear propulsion field in 1955 and began work on all aspects of a nuclear propulsion program with a target exhaust temperature of about 2750 K. A very extensive chemical vapor deposition coating technology for preventing catastrophic corrosion of reactor core components by the high temperature, high pressure hydrogen propellant gas was developed. Over the 17-year term of the program, more than 50,000 fuel elements were coated and evaluated. Advances in performance were achieved only through closely coupled interaction between the developing fuel element fabrication and protective coating technologies. The endurance of fuel elements in high temperature, high pressure hydrogen environment increased from several minutes at 2000 K exit gas temperature to 2 hours at 2440 K exit gas temperature in a reactor test and 10 hours at 2350 K exit gas temperature in a hot gas test. The purpose of this paper is to highlight the rationale for selection of coating materials used (NbC and ZrC), identify critical fuel element-coat interactions that had to be modified to increase system performance, and review the evolution of protective coating technology.
Wallace, Terry C.↗
Emerging High Temperature Sensors and Electronics for Future Lunar-Martian Reactors
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integrated↗
Hydrogen production from coal using a nuclear heat source
A strong candidate for hydrogen production in the intermediate time frame of 1985 to 1995 is a coal-based process using a high-temperature gas-cooled reactor (HTGR) as a heat source. Expected process efficiencies in the range of 60 to 70% are considerably higher than all other hydrogen production processes except steam reforming of a natural gas. The process involves the preparation of a coal liquid, hydrogasification of that liquid, and steam reforming of the resulting gaseous or light liquid product. A study showing process efficiency and cost of hydrogen vs nuclear reactor core outlet temperature has been completed, and shows diminishing returns at process temperatures above about 1500 F. A possible scenario combining the relatively abundant and low-cost Western coal deposits with the Gulf Coast hydrogen users is presented which provides high-energy density transportation utilizing coal liquids and uranium.
Quade, R. N.↗
Application of Analytical Hierarchy Process for Narrowing Down Nep Candidate Reactor Designs
Nuclear electric propulsion (NEP)-powered vehicles have been contemplated for human Mars missions. The nuclear power system contemplates using a high temperature light-weight nuclear reactor for the production of electrical power in the range of 2-5 MWe with a 3-10 year service life. A myriad of technology options exist for achieving these mission objectives. The analytic hierarchy process (AHP), a multi-attribute decision method, is being used to narrow down the candidate designs. The AHP is a structured decision process that fuses model-supplied quantitative data with subjective assessments to facilitate decisions that involve multiple competing criteria. Proven end-to-end nuclear design and systems analysis tools will be used to provide quantitative performance data such as end-to-end system reliability, system robustness to recover from off-normal conditions, system specific weight (α in kg/kWe), and the ability to meet the service life-time and power level requirements. Three high assay low enriched uranium (HALEU) reactor concepts, namely, gas-, heat pipe- and pumped liquid-cooled nuclear cores coupled to a He/Xe gas or supercritical CO2- Brayton power conversion system are being modeled using the AHP to understand the trade-offs associated with these design combinations. In addition to the reactor and power conversion options, there are a myriad of additional components and subsystems – e.g., radiators, heat exchangers, and recuperators – that also figure into the evaluation process. The choice of the right overall system is a multidimensional problem that has to include not only quantitative data, but also the so called “external factors”, examples of which include the component and subsystem Technology Readiness Levels (TRLs), the associated Advancement Degrees of Difficulty (AD2), the cost and schedule required to achieve a technical maturity consistent with mission infusion, alignment with the priorities of NASA’s Space Nuclear Propulsion program, and alignment with other ongoing government and commercial investments in micro reactors. Focused expert elicitations form the basis for qualitative data set. As a final step, decision-makers individually express their opinions regarding the relative importance of the criteria and preferences among the alternatives through pairwise comparisons. The paper will describe the AHP approach, progress to-date applying it to the NEP human Mars mission problem, and preliminary results. Use of AHP provides sufficient flexibility for incorporating industry input at different stages as the technologies evolve through additional research and development. It is expected that the decision process will be ongoing and expanded to examine additional options and technology choices, culminating in a defensible set of candidate reactor concepts that will form the basis for developing a multi-year NEP technology maturation strategy. .
Dasari V Rao↗
Use of tungsten-184 as a thermal flux monitor at high temperatures
Tungsten-184 used as thermal flux monitor at high temperatures in Plum Brook reactor
Ball, L. L.↗
International Symposium on Combustion, 14th, Pennsylvania State University, University Park, Pa., August 20-25, 1972, Proceedings.
Some elementary steps for the formation and destruction of nitric oxide in the H-N-O system, high-temperature oxidation of hydrogen by nitrous oxide in shock waves, and high-temperature fast-flow reactor studies of metal-atom oxidation kinetics are among the topics covered in papers concerned with elementary reactions in combustion. Other areas covered include oscillatory, turbulent, and supersonic combustion; flames in furnaces and combustors; and pollutant formation and destruction in flames. Individual items are announced in this issue.
Source record↗
Applications of plasma core reactors to terrestrial energy systems
Plasma core reactors offer several new options for future energy needs in addition to space power and propulsion applications. Power extraction from plasma core reactors with gaseous nuclear fuel allows operation at temperatures higher than conventional reactors. Highly efficient thermodynamic cycles and applications employing direct coupling of radiant energy are possible. Conceptual configurations of plasma core reactors for terrestrial applications are described. Closed-cycle gas turbines, MHD systems, photo- and thermo-chemical hydrogen production processes, and laser systems using plasma core reactors as prime energy sources are considered. Cycle efficiencies in the range of 50 to 65 percent are calculated for closed-cycle gas turbine and MHD electrical generators. Reactor advantages include continuous fuel reprocessing which limits inventory of radioactive by-products and thorium-U-233 breeder configurations with about 5-year doubling times.-
Latham, T. S.↗
Simplified Heat-Source/Thermionic Converter
Radiation coupling of heat from heat-source cylinder to converter cylinder through vacuum gap eliminates need for high-temperature electrical insulators between reactor heat pipes and thermionic converters. In addition no radiatior heat pipe is necessary because collectors of thermionic converters from which excess heat must be removed radiate directly to space. New design concept is also applicable to terrestrial and non-nuclear thermionic power supplies.
Shimada, K.↗
Modeling and Testing of Non-Nuclear, Highpower Simulated Nuclear Thermal Rocket Reactor Elements
When the President offered his new vision for space exploration in January of 2004, he said, "Our third goal is to return to the moon by 2020, as the launching point for missions beyond," and, "With the experience and knowledge gained on the moon, we will then be ready to take the next steps of space exploration: human missions to Mars and to worlds beyond." A human mission to Mars implies the need to move large payloads as rapidly as possible, in an efficient and cost-effective manner. Furthermore, with the scientific advancements possible with Project Prometheus and its Jupiter Icy Moons Orbiter (JIMO), (these use electric propulsion), there is a renewed interest in deep space exploration propulsion systems. According to many mission analyses, nuclear thermal propulsion (NTP), with its relatively high thrust and high specific impulse, is a serious candidate for such missions. Nuclear rockets utilize fission energy to heat a reactor core to very high temperatures. Hydrogen gas flowing through the core then becomes superheated and exits the engine at very high exhaust velocities. The combination of temperature and low molecular weight results in an engine with specific impulses above 900 seconds. This is almost twice the performance of the LOX/LH2 space shuttle engines, and the impact of this performance would be to reduce the trip time of a manned Mars mission from the 2.5 years, possible with chemical engines, to about 12-14 months.
Kirk, Daniel R.↗
Experimental Studies of NaK in a Simulated Space Environment
Space fission power systems are being developed at the National Aeronautics and Space Administration (NASA) and Department of Energy (DOE) with a short term goal of building a full scale, non-nuclear, Technology Demonstration Unit (TDU) test at NASA's Glenn Research Center. Due to the geometric constraints, mass restrictions, and fairly high temperatures associated with space reactors, liquid metals are typically used as the primary coolant. A eutectic mixture of sodium (22 percent) and potassium (78 percent), or NaK, has been chosen as the coolant for the TDU with a total system capacity of approximately 55 L. NaK, like all alkali metals, is very reactive, and warrants certain safety considerations. To adequately examine the risk associated with the personnel, facility, and test hardware during a potential NaK leak in the large scale TDU test, a small scale experiment was performed in which NaK was released in a thermal vacuum chamber under controlled conditions. The study focused on detecting NaK leaks in the vacuum environment as well as the molecular flow of the NaK vapor. This paper reflects the work completed during the NaK experiment and provides results and discussion relative to the findings.
Gibons, Marc↗
Silicon Carbide Microsystems Technology for Extreme Environments: Opportunities for Nuclear Applications
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silicon carbide↗