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At least 91 records · Page 5

FEP encapsulated N/P silicon solar cells after simulated micrometeoroid exposure.

The effects of simulated micrometeoroid exposure on the performance of N/P silicon solar cells encapsulated for their protection in fluorinated ethylene propylene were determined in a shock tube. It was found that the short-circuit current decreased after exposure to the simulated micrometeoroid particles. The shape of the curve remained the same and was simply translated downward with a concomitant drop in open-circuit voltage.

Mirtich, M. J.↗

Negative streamer development in FEP teflon

A computational model is developed which describes the evolution and propagation of an ionizing front (negative streamer) in solid materials. The ionization front consists of drifting avalanching electrons moving self-consistently under the influence of their own space-charge field together with an applied external field. The required input information for the model consists of the functional dependence of the macroscopic transport coefficients on the local electric field, the initial conditions for beginning the calculation, and the strength of the applied field. A computational approach for specifying the transport coefficients and initional conditions is also described. The approach has been implemented by constructing three computer codes which sequentially interface, beginning with single electron scattering, and ending with streamer development. Computational results are presented for model calculations in Teflon. The overall model is perceived to provide a picture of the initiation phase of a propagating discharge in electron-irradiated dielectrics.

Beers, B. L.↗

Preventing Delamination of Silverized FEP Films

Edge treatment inhibits attack by moisture. New technique prevents delamination by sealing edges where delamination starts. Samples of aluminum/FEP/silver laminate survive humidity tests and other environmental tests when edges of layers are covered by epoxy bead. Untreated laminates, in contrast, deteriorated seriously during such tests.

Domnikov, L.↗

Thermal testing by internal IR heating of the FEP module

A spacecraft module, to be integrated with the FLTSATCOM spacecraft, was tested in a simulated orbit environment separate from the host spacecraft. Thermal vacuum testing of the module was accomplished using internal IR heating rather than conventional external heat sources. For this configuration, the technique produced boundary conditions expected for flight to enable verification of system performance and thermal design details.

Nathanson, D. M.↗

An ESR study of the UV degradation of FEP

Spacecraft in low earth orbit are subjected to significant levels of high energy radiation, including ultraviolet (UV) and visible ultraviolet (VUV) wavelengths. The effects of UV radiation are enhanced over those at the surface of the earth, where the only incident wavelengths are greater than 290 nm. In low earth orbit the incident UV wavelengths extend below 290 nm into the VUV region, where the Lyman alpha-emissions of atomic hydrogen occur at 121 nm. In addition to electromagnetic radiation, in low earth orbit polymer materials may also be subjected to atomic oxygen particle radiation, which will result in direct oxidation of the polymer.

George, G. A.↗

An investigation of the degradation of Fluorinated Ethylene Propylene (FEP) copolymer thermal blanketing materials aboard LDEF in the laboratory

Samples of fluorinated ethylene propylene copolymer thermal blanketing material, recovered from the Long Duration Exposure Facility (LDEF), were investigated to determine the nature and the extent of degradation due to exposure to the low-Earth-orbit environment. Samples recovered from the ram-facing direction of LDEF, which received vacuum-ultraviolet (VUV) radiation and atomic-oxygen impingement, and samples from the trailing edge, which received almost exclusively VUV exposure, were investigated by scanning electron microscopy and atomic force microscopy. The most significant result of this investigation was found on samples that received only VUV exposure. These samples possessed a hard, embrittled surface layer that was absent from the atomic-oxygen exposed sample and from unexposed control samples. This surface layer is believed to be responsible for the 'synergistic' effect between VUV and atomic oxygen. Overall, the investigation revealed dramatically different morphologies for the two samples. The sample receiving both atomic-oxygen and VUV exposure was deeply eroded and had a characteristic 'rolling' surface morphology, while the sample that received only VUV exposure showed mild erosion and a surface morphology characterized by sharp high-frequency peaks. The morphologies observed in the LDEF samples, including the embrittled surface layer, were successfully duplicated in the laboratory.

Stiegman, A. E.↗

Erosion Data from the MISSE 8 Polymers Experiment After 2 Years of Space Exposure on the International Space Station

The Polymers Experiment was exposed to the low Earth orbit (LEO) space environment for 2.14 and 2.0 years as part of the Materials International Space Station Experiment 8 (MISSE 8) and the Optical Reflector Materials Experiment-III (ORMatE-III), respectively. The experiment contained 42 samples, which were flown in either ram, wake, or zenith orientations. The primary objective was to determine the effect of solar exposure on the atomic oxygen erosion yield (Ey) of fluoropolymers. This paper provides an overview of the experiment with details on the polymers flown, the characterization techniques used, the atomic oxygen fluence for each exposure orientation, and the LEO Ey results. The Ey values for the fluoropolymers range from 1.45 x 10(exp -25) cm(exp 3)/atom for white Tedlar Registered Trademark (polyvinyl fluoride with white titanium dioxide pigment) flown in the ram orientation to 6.32 x 10(exp -24) cm(exp 3)/atom for aluminized-Teflon Registered Trademark fluorinated ethylene propylene (Al-FEP) flown in the zenith orientation. Erosion yield data for FEP flown in ram, wake and zenith orientations are compared, and the Ey was found to be highly dependent on orientation, hence environmental exposure. Teflon FEP had an order of magnitude higher Ey when flown in the zenith direction (6.32 x10(exp -24) cm(exp3)/atom) as compared to the ram direction (2.37 x 10(exp -25) cm(exp 3)/atom). The Ey of FEP was found to increase with a direct correlation to the solar exposure/AO fluence ratio showing the effect of solar radiation and/or heating due to solar exposure on FEP erosion. In addition, back-surface carbon painted FEP (C-FEP) flown in the zenith orientation had a significantly higher Ey than clear FEP or Al-FEP further indicating that heating has a significant impact on the erosion of FEP, particularly in the zenith orientation.

Solar radiation↗

Effect of Air and Vacuum Storage on the Degradation of X-Ray-Exposed Aluminized-Teflon Investigated

Metalized Teflon FEP (fluorinated ethylene propylene, DuPont), a common thermal control material, has been found to degrade in the low-Earth-orbit space environment. The aluminized-FEP (Al-FEP) exterior layer on the Hubble Space Telescope has become extremely embrittled, with extensive cracking occurring on all sides of the telescope. This embrittlement has been primarily attributed to radiation exposure (x-rays from solar flares, electron/proton radiation, and possibly near-ultraviolet radiation) combined with thermal cycling. Limited samples of FEP tested after long-term exposure to low Earth orbit on the Hubble Space Telescope and on the Long Duration Exposure Facility indicated that there might be continued degradation in tensile properties over time. An investigation was conducted at the NASA Glenn Research Center to evaluate the effect of air and vacuum storage on the mechanical properties of x-ray-exposed FEP. Aluminized-FEP (5-mil-thick) tensile samples were x-ray exposed with 15.3-kV copper xrays for 2 hr, reducing the percent elongation to failure by approximately 50 percent in comparison to that for pristine Al-FEP. X-ray-exposed samples were stored in air or under vacuum for various time periods to see the effect of storage on tensile properties. Tensile results indicated that samples stored in air had larger decreases in tensile properties than samples stored under vacuum had, as seen in the graph. Samples stored under vacuum (for up to 400 hr) showed no further decrease in tensile properties over time, whereas samples stored in air (for up to 900 hr) appeared to show decreases in tensile properties over time. X-ray-exposed samples stored in air developed a hazy appearance in the exposed area, as seen in the photographs. When the source of the haziness was evaluated using scanning electron microscopy and atomic force microscopy, it was found to reside at the Al/FEP interface as witnessed by an increased surface roughness of the aluminized side of the material and a dramatic decrease in the adhesion between the Al and FEP. Optical properties of air-stored irradiated samples showed an increase in the diffuse reflectance, which is consistent with observed roughening that was characterized by AFM. These findings indicate that air exposure helps degrade x-ray-irradiated FEP. These results indicate that proper sample handling and storage is necessary with space-retrieved materials and with those exposed to ground-based irradiation simulation exposures.

deGroh, Kim K.↗

Erosion Results of the MISSE 8 Polymers Experiment After 2 Years of Space Exposure on the International Space Station

Polymers and other oxidizable materials on the exterior of spacecraft in the low Earth orbit (LEO) space environment can be eroded due to reaction with atomic oxygen (AO). Therefore, in order to design durable spacecraft, it is important to know the LEO AO erosion yield (E(sub y), volume loss per incident oxygen atom) of materials susceptible to AO reaction. A spaceflight experiment, called the Polymers Experiment, which contained 42 samples, was developed to determine the effect of solar exposure on the AO E(sub y) of fluoropolymers flown in ram, wake, or zenith orientations. The Polymers Experiment was exposed to the LEO space environment on the exterior of the International Space Station (ISS) as part of the Materials International Space Station Experiment 8 (MISSE 8) mission. The MISSE 8 mission included samples flown in a zenith/nadir orientation for 2.14 years in the MISSE 8 Passive Experiment Container (PEC), and samples flown in a ram/wake orientation for 2.0 years in the Optical Reflector Materials Experiment-III (ORMatEIII) tray. The experiment included Kapton H (Registered Trademark) witness samples for AO fluence determination in each orientation. This paper provides an overview of the MISSE 8 mission, a description of the flight experiment with details on the polymers flown, the characterization techniques used, the AO fluence for each exposure orientation, and the LEO E(sub y) results. The E(sub y) of Teflon fluorinated ethylene propylene (FEP) samples flown in ram, wake, and zenith orientations have been compared, and the E(sub y) was found to be highly dependent on orientation and therefore environmental exposure. The FEP E(sub y) was found to directly correlate with the solar exposure/AO fluence ratio showing the effect of solar radiation and/or heating due to solar exposure on FEP erosion. In addition, back-surface carbon painted FEP (C-FEP) flown in the zenith orientation had a significantly higher E(sub y) than clear FEP or Al-FEP further indicating that heating has a significant impact on the erosion of FEP. This experiment provides valuable LEO flight data on the erosion of Teflon FEP, a commonly used spacecraft thermal insulation.

Teflon↗

Thermal Contributions to the Degradation of Ground-Laboratory- and Space-Irradiated Teflon Investigated

The Hubble Space Telescope (HST) is covered with two primary types of thermal control materials, radiators and multilayer insulation blankets, which passively control temperatures during orbit. Both of these thermal control materials utilize back-surface metalized Teflon FEP (DuPont, fluorinated ethylene propylene) as the exterior (spacefacing) layer because of its excellent optical properties (low solar absorptance and high thermal emittance). The aluminized-FEP (Al-FEP) outermost layer of the multilayer insulation blankets on the HST has become embrittled while in space, resulting in severe on-orbit cracking (see the photographs). During the second servicing mission, an extremely embrittled piece of Al-FEP was retrieved that had curled, exposing the backsurface aluminum to space (see the photograph on the right). Because the aluminum surface has a lower thermal emittance than the FEP, this curled piece reached 200 C during orbit, 150 C higher than the nominal temperature extreme. To better understand the effect of temperature on the rate of degradation, and on the mechanism of degradation, of this insulation material in the low-Earth-orbit environment, researchers at the NASA Glenn Research Center conducted experiments to determine the effect of heating on the degradation of FEP that has been irradiated in a ground laboratory facility or in space on the HST. For this study, Teflon FEP retrieved from the HST during the third servicing mission after 9.7 years of space exposure was provided to Glenn by the NASA Goddard Space Flight Center.

deGroh, Kim K.↗

Contamination Results of MISSE 8 Wake and Nadir Samples After 2 Years of Space Exposure on the International Space Station

Spacecraft in low Earth orbit (LEO) are subjected to harsh environmental conditions, including radiation (cosmic rays, ultraviolet, x-ray and charged particle radiation), micrometeoroids and orbital debris, temperature extremes, thermal cycling, and atomic oxygen. In addition, on-orbit spacecraft contamination is a serious spaceflight issue, with silicone contamination being a particular concern. In an effort to understand on-orbit contamination of Materials International Space Station Experiment 8 (MISSE 8) flight samples and other International Space Station (ISS) payloads, contamination studies were conducted post-flight on retrieved Teflon fluorinated ethylene propylene (FEP) samples flown in the wake and nadir orientations on MISSE 8. The wake sample was Teflon FEP (M8-W11) flown as part of the Glenn MISSE 8 Polymers Experiment on the Optical Reflector Materials Experiment-III Ram/Wake (ORMatE-III R/W) tray and exposed to the LEO wake environment for 2.0 years. The nadir samples were silver-Teflon FEP radiator pieces taken from the MISSE 8 Single Events Upset Xilinx-Sandia Experiment II (SEUXSE II) Power Box and exposed to the LEO nadir environment for 2.14 years. The Teflon FEP flight materials were analyzed for changes in surface morphology and chemistry as compared to pristine control samples. The wake samples were also analyzed for changes in optical properties. There was no evidence of a molecular contamination layer present on the surface of the MISSE 8 wake or nadir facing Teflon FEP flight samples, although both the wake and nadir flight samples contained particulate contamination in some regions. The analyzed nadir particles were primarily zinc rich. The majority of analyzed wake particles were comprised of oxidized aluminum with small amounts of zinc and magnesium. The wake particles appear to have arrived early in the mission (or pre-flight) during a single event. This paper provides details of the MISSE 8 sample contamination analyses.

Erosion↗

Irradiation and measurements of fluorinated ethylene-propylene-A on silicon solar cells in vacuum

Silicon monoxide (SiO) coated silicon solar cells covered with fluorinated ethylene-propylene-A (FEP-A) were irradiated by 1-MeV electrons in vacuum. The effect of irradiation on the light transmittance of FEP-A was checked by measuring the short-circuit current of the cells while in vacuum after each dose increment, immediately after the irradiation, and again after a minimum elapsed time of 16 hr. The results indicated no apparent loss in transmission due to irradiation of FEP-A and no delamination from the SiO surface while the cells were in vacuum, but embrittlement of FEP-A occurred at the accumulated dose.

Marsik, S. J.↗

Operating system for a real-time multiprocessor propulsion system simulator

The success of the Real Time Multiprocessor Operating System (RTMPOS) in the development and evaluation of experimental hardware and software systems for real time interactive simulation of air breathing propulsion systems was evaluated. The Real Time Multiprocessor Operating System (RTMPOS) provides the user with a versatile, interactive means for loading, running, debugging and obtaining results from a multiprocessor based simulator. A front end processor (FEP) serves as the simulator controller and interface between the user and the simulator. These functions are facilitated by the RTMPOS which resides on the FEP. The RTMPOS acts in conjunction with the FEP's manufacturer supplied disk operating system that provides typical utilities like an assembler, linkage editor, text editor, file handling services, etc. Once a simulation is formulated, the RTMPOS provides for engineering level, run time operations such as loading, modifying and specifying computation flow of programs, simulator mode control, data handling and run time monitoring. Run time monitoring is a powerful feature of RTMPOS that allows the user to record all actions taken during a simulation session and to receive advisories from the simulator via the FEP. The RTMPOS is programmed mainly in PASCAL along with some assembly language routines. The RTMPOS software is easily modified to be applicable to hardware from different manufacturers.

Cole, G. L.↗

Initial operating capability for the hypercluster parallel-processing test bed

The NASA Lewis Research Center is investigating the benefits of parallel processing to applications in computational fluid and structural mechanics. To aid this investigation, NASA Lewis is developing the Hypercluster, a multi-architecture, parallel-processing test bed. The initial operating capability (IOC) being developed for the Hypercluster is described. The IOC will provide a user with a programming/operating environment that is interactive, responsive, and easy to use. The IOC effort includes the development of the Hypercluster Operating System (HYCLOPS). HYCLOPS runs in conjunction with a vendor-supplied disk operating system on a Front-End Processor (FEP) to provide interactive, run-time operations such as program loading, execution, memory editing, and data retrieval. Run-time libraries, that augment the FEP FORTRAN libraries, are being developed to support parallel and vector processing on the Hypercluster. Special utilities are being provided to enable passage of information about application programs and their mapping to the operating system. Communications between the FEP and the Hypercluster are being handled by dedicated processors, each running a Message-Passing Kernel, (MPK). A shared-memory interface allows rapid data exchange between HYCLOPS and the communications processors. Input/output handlers are built into the HYCLOPS-MPK interface, eliminating the need for the user to supply separate I/O support programs on the FEP.

Cole, Gary L.↗

HST Multi Layer Insulation Failure Review Board Findings

The mechanical and optical properties of the thermal control materials on the Hubble Space Telescope (HST) have degraded over the nearly seven years the telescope has been in orbit. Astronaut observations and photographs from the Second Servicing Mission (SM2) revealed large cracks in the metallized Teflon fluorinated ethylene propylene (FEP), the outer layer of the multi-layer insulation (MLI), in many locations around the telescope. Also, the absorptance of the bonded metallized Teflon FEP radiator surfaces of the telescope has increased over time. A Failure Review Board was established to determine the damage mechanism and to identify a replacement material. Samples of the top layer of the MLI and radiator material were retrieved during SM2, and a thorough investigation into the degradation followed in order to determine the primary cause of the damage. Mapping of the cracks on HST and the ground testing showed that thermal cycling with deep-layer damage from electron and proton radiation are necessary to cause the observed embrittlement. Further, strong evidence was found indicating that chain scission (reduced molecular weight) is the dominant form of damage to the metallized Teflon FEP. Given the damage to the outer layer of the multi-layer insulation (MLI) that was apparent during the second servicing mission (SM2), the decision was made to replace the outer layer during subsequent servicing missions. The replacement material had to meet the stringent thermal requirements of the spacecraft and maintain structural integrity for at least ten years. Ten candidate materials were exposed to simulated orbital environments and a replacement material was selected. This presentation will summarize the FRB results, in particular, the analysis of the retrieved specimens, the results of the simulated environmental exposures, and the selection of the replacement material. The NASA Space Environments and Effects community needs to hear these results because they reveal that Teflon (FEP) films should not be used in LEO as routinely as they are today.

Townsend, Jacqueline↗

Analysis of Ag/FEP Thermal Control Blanket Performance From Multiple Satellites

Materials performance data from operational spacecraft and spacecraft experiments has slowly accumulated over the years. Much of this data is obtained indirectly by analyzing temperature measurements telemetered to ground. Due to the Space Transportation System (STS) program, materials performance data has also been obtained by flying materials on satellites, or on the Space Shuttle itself, for limited periods of time, and then returning the materials to ground for post-flight examination. During the course of NASA contract NAS8-98213, the authors have extended the analysis of data reported for selected materials flown on a variety of spacecraft over the past 30 years. In this paper we discuss changes in two properties of silver- or aluminum-backed (metallized) FEP Teflon due to exposure to specific environmental factors on-orbit. First, the change in solar absorptance (alpha(sub s)) of metallized FEP Teflon as a function of particulate radiation will be discussed. Data providing the change in solar absorptance of metallized FEP as a function of days on orbit has been published for NTS-2 satellite, several NavStar Global Positioning Satellites (GPS), the SCATHA experiment, and the ML-101 satellite. The unique approach that we have taken is to calculate the absorbed radiation dose within the Ag/FEP for the various satellite orbits, and to plot the change in solar absorptance, alpha(sub s), as a function of the dose; the behavior agrees with the same data from laboratory tests. Second, the variation of the atomic oxygen induced material recession rate of metallized FEP will be discussed. Data from certain Space Shuttle flights, a Lockheed experiment [approximately 105 days in low Earth orbit (LEO)], and the Long Duration Exposure Facility allows the variation of the material recession rate of Ag/FEP to be estimated under conditions that include atomic oxygen exposure.

Pippin, Gary↗

Solar Effects on Tensile and Optical Properties of Hubble Space Telescope Silver-Teflon(Registered Trademark) Insulation

A section of the retrieved Hubble Space Telescope (HST) solar array drive arm (SADA) multilayer insulation (MLI), which experienced 8.25 years of space exposure, was analyzed for environmental durability of the top layer of silver-Teflon (DuPont) fluorinated ethylene propylene (Ag-FEP). Because the SADA MLI had solar and anti-solar facing surfaces and was exposed to the space environment for a long duration, it provided a unique opportunity to study solar effects on the environmental degradation of Ag-FEP, a commonly used spacecraft thermal control material. Data obtained included tensile properties, solar absorptance, surface morphology and chemistry. The solar facing surface was found to be extremely embrittled and contained numerous through-thickness cracks. Tensile testing indicated that the solar facing surface lost 60% of its mechanical strength and 90% of its elasticity while the anti-solar facing surface had ductility similar to pristine FEP. The solar absorptance of both the solar facing surface (0.155 plus or minus 0.032) and the anti-solar facing surface (0.208 plus or minus 0.012) were found to be greater than pristine Ag-FEP (0.074). Solar facing and anti-solar facing surfaces were microscopically textured, and locations of isolated contamination were present on the anti-solar surface resulting in increased localized texturing. Yet, the overall texture was significantly more pronounced on the solar facing surface indicating a synergistic effect of combined solar exposure and increased heating with atomic oxygen erosion. The results indicate a very strong dependence of degradation, particularly embrittlement, upon solar exposure with orbital thermal cycling having a significant effect.

deGroh, Kim, K.↗

Composite-Material Tanks with Chemically Resistant Liners

Lightweight composite-material tanks with chemically resistant liners have been developed for storage of chemically reactive and/or unstable fluids . especially hydrogen peroxide. These tanks are similar, in some respects, to the ones described in gLightweight Composite-Material Tanks for Cryogenic Liquids h (MFS-31379), NASA Tech Briefs, Vol. 25, No. 1 (January, 2001), page 58; however, the present tanks are fabricated by a different procedure and they do not incorporate insulation that would be needed to prevent boil-off of cryogenic fluids. The manufacture of a tank of this type begins with the fabrication of a reusable multisegmented aluminum mandrel in the shape and size of the desired interior volume. One or more segments of the mandrel can be aluminum bosses that will be incorporated into the tank as end fittings. The mandrel is coated with a mold-release material. The mandrel is then heated to a temperature of about 400 F (approximately equal to 200 C) and coated with a thermoplastic liner material to the desired thickness [typically approxiamtely equal to 15 mils (approximately equal to 0.38 mm)] by thermal spraying. In the thermal-spraying process, the liner material in powder form is sprayed and heated to the melting temperature by a propane torch and the molten particles land on the mandrel. The sprayed liner and mandrel are allowed to cool, then the outer surface of the liner is chemically and/or mechanically etched to enhance bonding of a composite overwrap. The etched liner is wrapped with multiple layers of an epoxy resin reinforced with graphite fibers; the wrapping can be done either by manual application of epoxy-impregnated graphite cloth or by winding of epoxy-impregnated filaments. The entire assembly is heated in an autoclave to cure the epoxy. After the curing process, the multisegmented mandrel is disassembled and removed from inside, leaving the finished tank. If the tank is to be used for storing hydrogen peroxide, then the liner material should be fluorinated ethylene/propylene (FEP), and one or more FEP O ring(s) should be used in the aluminum end fitting(s). This choice of materials is dictated by experimental observations that pure aluminum and FEP are the only materials suitable for long-term storage of hydrogen peroxide and that other materials tend to catalyze the decomposition of hydrogen peroxide to oxygen and water. Other thermoplastic liner materials that are suitable for some applications include nylon 6 and polyethylene. The processing temperatures for nylon 6 are lower than those for FEP. Nylon 6 is compatible with propane, natural gas, and other petroleum-based fuels. Polyethylene is compatible with petroleum- based products and can be used for short-term storage of hydrogen peroxide.

DeLay, Thomas K.↗