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We have developed a theory for the electrical double layer of salt-in-ionic liquids accounting for the thermoreversible association of ions into Cayley tree aggregates. We find that the solution becomes more aggregated at moderate positive voltages.
Various mechanisms for driving double layers (DLs) in plasmas are described, including applied potential drops, currents, contact potentials, and plasma expansions. Somne dynamic features of the DLs are discussed; and it is demonstrated that DLs and the currents through them undergo slow oscillations, determined by the ion transit time across an effective length of the system in which the DLs form. It is shown that a localized potential dip forms at the low potential end of a DL, which interrupts the electron current through it according to the Langmuir criterion whenever the ion flux into the DL is disrupted. Also considered is the generation of electric fields perpendicular to the ambient magnetic field by contact potentials.
In recent years, a number of papers have been concerned with 'ion-acoustic' double layers. In the present investigation, results from numerical simulations are presented to show that the shapes and forms of current-driven double layers evolve dynamically with the fluctuations in the current through the plasma. It is shown that double layers with a potential dip can form even without the excitation of ion-acoustic modes. Double layers in two-and one-half-dimensional simulations are discussed, taking into account the simulation technique, the spatial and temporal features of plasma, and the dynamical behavior of the parallel potential distribution. Attention is also given to double layers in one-dimensional simulations, and electrical field strengths predicted by two-and one-half-dimensional simulations.
A computer simulation is applied to the production of strong electric potential double layers (DL) in a triple plasma device. The simulation is intended to represent DL in the low magnetosphere above the auroral zones. The DL are described as standing electrostatic shocks with different energy coefficients in their strong and weak forms. The strong DL was generally found to be unstable, but stability could be imparted if a population of trapped electrons was presented. Stability increased with the length of the system. A schematic for the system is presented, and a phase-space plot of electrons (indicating system stability) is graphed.
Reducing contact interface thermal and electrical resistances is in great demand across various industries, particularly in the semiconductor industry. This study introduces an approach using double-sided copper nanowire (Cu NW) arrays on copper sheets as both thermal and electrical interfacial layers, designed to effectively accommodate the topographical inconsistencies between contact surfaces. Further, experimental outcomes reveal a significant reduction in thermal contact resistance (TCR), with a value of 2.5 mm 2 K W –1 , thereby exceeding the efficiency of reported nanostructural thermal interface materials (TIMs). Additionally, when utilized as an electrical interfacial layer, these double-sided Cu NWs arrays dramatically reduced electrical contact resistance (ECR), outperforming traditional conductive grease in applications necessitating separable bonding, though showing comparable performance to costly silver-based conductive epoxies required for permanent, inseparable bonds. The promising results of the double-sided Cu NWs arrays in reducing both TCR and ECR, confirmed by finite element simulation, highlight their substantial potential in advancing TIMs and electrical interconnection applications across various sectors.
An effort to extend the low-temperature operational limit of supercapacitors is currently underway. At present, commercially available non-aqueous supercapacitors are rated for a minimum operating temperature of -40 C. A capability to operate at lower temperatures would be desirable for delivering power to systems that must operate in outer space or in the Polar Regions on Earth. Supercapacitors (also known as double-layer or electrochemical capacitors) offer a high power density (>1,000 W/kg) and moderate energy density (about 5 to 10 Wh/kg) technology for storing energy and delivering power. This combination of properties enables delivery of large currents for pulsed applications, or alternatively, smaller currents for low duty cycle applications. The mechanism of storage of electric charge in a supercapacitor -- at the electrical double-layer formed at a solid-electrode/liquid-electrolyte interface -- differs from that of a primary or secondary electrochemical cell (i.e., a battery) in such a manner as to impart a long cycle life (typically >10(exp 6) charge/discharge cycles).
Polar cap boundary layer waves are ELF/VLF electric and magnetic waves detected on field lines just adjacent to the polar cap. Intense waves are present at this location essentially all (96%) of the time.
A genuine two-fluid model of plasmas with collisions permits the calculation of dynamic (not necessarily static) electric fields and double layers inside of plasmas including oscillations and damping. For the first time a macroscopic model for coupling of electromagnetic and Langmuir waves was achieved with realistic damping. Starting points were laser-produced plasmas showing very high dynamic electric fields in nonlinear force-produced cavitous and inverted double layers in agreement with experiments. Applications for any inhomogeneous plasma as in laboratory or in astrophysical plasmas can then be followed up by a transparent hydrodynamic description. Results are the rotation of plasmas in magnetic fields and a new second harmonic resonance, explanation of the measured inverted double layers, explanation of the observed density-independent, second harmonics emission from laser-produced plasmas, and a laser acceleration scheme by the very high fields of the double layers.
In this study, we investigated the effects of laser shock peening (LSP) on the corrosion resistance of lightweight metal alloys, specifically AA6061 and AZ31. LSP was performed underwater, using a nanosecond pulse laser and without using a protective coating or layer on the workpiece. The corrosion behaviors of these alloys were analyzed through electrochemical tests, including open circuit potential, electrochemical impedance spectroscopy, and potentiodynamic polarization measurements. The results demonstrated that LSP significantly improved the polarization resistance, and higher laser power intensities led to increased corrosion resistance and reduced corrosion rates. This enhancement in anti-corrosion performance is attributed to the formation of a protective oxide layer on the surface, acting as a barrier against corrosion. In conclusion, the findings underscore the potential of laser surface treatment as a viable technique for enhancing the corrosion resistance of lightweight metal alloys.
A pore-resolved modeling framework is developed to quantify how pore-scale transport affects the intrinsic microkinetics of CO 2 -to-CO on Au. A DFT-informed microkinetic model is coupled self-consistently to a Generalized-Modified Poisson–Nernst–Planck (GMPNP) transport description in a single, electrolyte-filled cylindrical pore, allowing local concentrations and potential to feed back into site-specific reaction rates. FIB-SEM is used to determine pore sizes within realistic electrode materials. Across pore diameters, d p = 10–6000 nm, the surface-averaged CO 2 reduction rate is systematically reduced relative to the ideal microkinetic baseline where mass transport is not accounted for; the effectiveness factor 𝜂 𝑠,CO 2 , which quantifies this ratio, decreases rapidly at more negative potentials and is about 1% near −1.0 V vs SHE due to reactant depletion. Spatial maps reveal pore-bulk alkalization that emerges at higher cathodic bias, with a small, near-wall pH dip due to electrostatic repulsion of hydroxide at the cathode interface. For a fixed aspect ratio L p /d p , narrower pores exhibit larger 𝜂 𝑠,CO 2 by shortening diffusion paths, whereas variations in the aspect ratio L p /d p play a secondary role. A dimensionless analysis (surface/bulk Damköhler numbers) delineates operating regimes. In conclusion, this work offers a concept for incorporating microkinetic models into homogenized porous-electrode models through effectiveness factors and pore-size distribution.
Electrical double-layer capacitors (EDLCs) are of increasing importance in energy storage from renewable sources. The properties of the electrode and electrolyte materials influence the energy and power densities of EDLCs. We examined the specific capacitance and ion dynamics of a protic ionic liquid confined in pre-intercalated Ti 3 C 2 T x MXene. Our electrochemical measurements demonstrated that the creation of a protic ionic liquid, 1-butyl-3-H-imidazolium bis(trifluoromethanesulfonyl)imide (BuIMH-NTf2), using a mixture of ionic liquid, 1-butyl imidazole (BuIM), and salt, bis(trifluoromethanesulfonyl)imide (HNTf2), in a ratio of 0.8:0.2 led to the optimal capacitance. Remarkably, quasi-elastic neutron scattering measurements revealed increased particle mobility at this composition, attributed to the more efficient accumulation of BuIMH + on the electrode surface. This deposit of additional ions results in fewer BuIM molecules away from the surface, enhancing their mobility due to reduced crowding. This composition-dependent electrochemical behavior will guide the formulation of more efficient protic ionic liquid systems, enabling faster ion transport in energy storage devices.
Models of electrohydrodynamic processes involving liquids with poorly ionized solutes at high (applied) field strengths were developed and tested. Extant theories which account for the details of physico-chemical processes associated with charged interfaces deal mainly with low field strengths and fully ionized solutes. The model used to describe processes at high field strengths--the leaky dielectric--omits consideration of electric double-layers, adsorption at interfaces, and chemical processes involved in the dissociation and recombination of solute species. Thus, even though the model depicts some features associated with bulk fluid motion, it fails to give a comprehensive picture. One example of the shortcomings of both the classical model of eletrokinetics at low field strengths and the leaky-dielectric model for high field strengths is found in the field strength dependence of the mobility of small particles in apolar liquids. The research will provide a more general model of electrohydrodynamic phenomena capable of application in diverse circumstances.
The dynamic aspects of auroral current structures are reviewed with emphasis on consequences for models of microscopic turbulence (MT). A number of models of MT are introduced into a large-scale model of Alfven wave propagation to determine the effect of various models on the overall structure of auroral currents. The effect of a double layer (DL) electric field which scales with the plasma temperature and the Debye length is compared with the effect of anomalous resistivity due to electrostatic ion cyclotron turbulence in which the electric field scales with the magnetic field strength. It is shown that the DL model is less diffusive than the resistive model, indicating the possibility of narrow intense current structures.
Recent satellite observations at high altitudes (greater than 5000 km) in the auroral zone have shown the existence of hybrid or bimodal ion beam distributions that are evidence of both parallel and perpendicular ion acceleration. Acceleration parallel to the magnetic field is most likely due to quasi-static electric fields (double layers) which can create outflowing ion beams; since ions of different mass will have different drift speeds due to this acceleration, a plasma configuration unstable to the ion-ion two-stream acoustic mode develops. When the net drift velocity (U) between the two ion species is greater than the sound speed (C(sub 0)), the ion-ion instability has maximum growth at oblique wave propagation. To study the nonlinear effects of the ion-ion instability in terms of plasma heating, a numerical simulation parametric study has been performed. It was found that the parallel acceleration that forms the ion beams occurs on a time scale faster than ion- ion wave growth at low drifts; thus ion-ion wave growth is expected to occur primarily for higher drift speeds (U greater than C(sub 0)) which results in strong oblique heating of the ions (both hydrogen and oxygen) forming elevated ion conics (sometimes called 'bowl' distributions). Also, strong parallel electron heating in the direction of the ion beams can occur, and electrons near the top of the acceleration region may attain a net upward drift along with the elevated ion conics. Variation of the oxygen density greatly affects the ion heating due to the ion-ion instability; as the oxygen density decreases, oxygen heating increases, in agreement with observations (Collin et al., 1987). Ion-ion electrostatic wave properties and the plasma heating that results over a wide range of auroral zone parameters are included.
Batteries keep devices working by utilizing high energy density, however, they can run down and take tens of minutes to hours to recharge. For rapid power delivery and recharging, high-power density devices, i.e., supercapacitors, are used. The electrochemical processes which occur in batteries and supercapacitors give rise to different charge-storage properties. In lithium ion (Li+) batteries, the insertion of Li+, which enables redox reactions in bulk electrode materials, is diffusion controlled and can be slow. Supercapacitor devices, also known as electrical double-layer capacitors (EDLCs) store charge by adsorption of electrolyte ions onto the surface of electrode materials. No redox reactions are necessary, so the response to changes in potential without diffusion limitations is rapid and leads to high power. However, the charge in EDLCs is confined to the surface, so the energy density is lower than that of batteries.
Non-linear rectification of the RF electric fields excited in a convectively amplifying electron beam-plasma interaction results in a dc electric field, and a corresponding ponderomotive force acting on the charged particles to produce a space-charge separation, i.e. a type of plasma double-layer. This paper analyses the effect, taking into account plasma electron temperature and electron-neutral collisions. To measure such double-layers, an electron beam probe constitutes a convenient non-perturbing diagnostic technique, but great care is required in its calibration. An analysis is presented taking into account significant non-linear effects which had been neglected in previous work. The paper concludes with some preliminary experimental results illustrating the use of the technique in a beam-plasma interaction for which a weak double-layer electric field is predicted.
Plasma processes dealing with ac and dc electric fields, the formation of ion beams and conics, and electron acceleration are considered, and similarities between simulation results and satellite-based observations are discussed. Electrostatic shock-type electric fields are found to occur near the current sheet edges, and double layers having upward electric fields form inside the sheet and are distinguishable from the large perpendicular electric fields only in wide sheets with thicknesses much greater than the ion Larmor radius. It is found that the most energetic ions have pitch angles near 90 deg, indicating a large perpendicular acceleration of the ions, and that the downward accelerating electrons inside the sheet are neither monoenergetic nor perfectly field aligned.
The characteristics of ion beams and conics as seen in two-dimensional numerical simulations in which the plasmas are driven by current sheets of a finite thickness are described. It is shown that the most energetic ions in the simulations have pitch angles near 90 deg, implying a large perpendicular acceleration of the ions. Large perpendicular electric fields, similar to those measured in electrostatic shocks, are mainly confined near the edges of the current sheets, where E-perpendicular is much larger than E-parallel. Double layers with E-perpendicular about equal to, and spatially separated from, E-parallel form in the interior of wide current sheets. Such double layers have upward electric fields in the region of the upward current. Downward electric fields develop outside the current sheet.