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At least 91 records · Page 5

Raman Spectroscopy as an ortho-para diagnostic of liquid hydrogen moderators

The intense radiation environment of a neutron moderator provides a mechanism for significant up-conversion of parahydrogen to orthohydrogen inside the moderator, as well as intrinsically catalyzing relaxation of orthohydrogen to parahydrogen. It is plausible that the steady-state orthohydrogen fraction of a moderator in a radiation environment such as at the Spallation Neutron Source (SNS) or the European Spallation Source (ESS) is as high as 30 % without supplemental catalysis. Direct measurement of the orthohydrogen fraction in the liquid hydrogen flow itself is essential to predict and monitor moderator performance, especially for thick or flat moderator concepts such as the ones that have been proposed for the ESS and for upgrades to the SNS. Raman spectroscopy provides a well-known method for directly measuring the hydrogen make-up in an unambiguous way. We describe our tests of Raman spectroscopy for application to the measurement of the orthohydrogen fraction of the hydrogen moderators at SNS and at the ESS. As part of this work, we have additionally developed a sample holder that has been used to perform simultaneous Raman and neutron vibrational spectroscopy on the VISION spectrometer at SNS. We discuss our plans to incorporate such a system as a diagnostic for liquid hydrogen moderators at SNS and at the ESS.

Gillis, Robert Chad↗

Edge states of α-bismuthene nanostructures

We present a systematic investigation of the edge states (ESs) of two-dimensional α-bismuthene (α-Bi) structures self-assembled on highly oriented pyrolytic graphite substrates, using scanning tunnelling microscopy and scanning tunnelling spectroscopy. The measurements are carried out for 3ML, 5ML and 7ML thick Bi structures. Our spectroscopy studies reveal clear features at the edges of the 5ML and 7ML thick structures, and the positions of the ESs coincide with the topographical step edges. In contrast, in 3ML structures the ESs appear to be absent and instead new states are sometimes observed, far from the topographical edge. These states are associated with a moiré pattern and result from strain-induced modulation of the topology. Our observations demonstrate the impact on the ESs of coupling to adjacent structures.

2D materials↗

Impact of Uncertainty on Energy Storage Operation Decisions: Motivation and Framework

Energy Storage Systems (ESSs) are gaining great attention, as they can help operate grid power grids more reliably. The ESS acquisition and operation is motivated by the economics revolving around its provided services and revenue streams. These economics are greatly impacted by uncertainties in predicting the parameters which influence the ESS operation. The main goal of this paper is in addressing these uncertainties. We organize sources of uncertainties which directly impact the value-driven operation of the ESS and propose a framework which combines the uncertain requirements from processes both internal and external to ESS.

Hanif, Sarmad↗

Renewable Integration in Hybrid ac-dc Systems using Multi-port Autonomous Reconfigurable Solar power plant (MARS)

To increase inertia and improve primary frequency response of future grids, grid-forming inverters connecting PV to grid and energy storage systems (ESSs) are likely to play an important role. Moreover, high-voltage direct current (HVdc) links will also be an enabler to transfer remote PV generation and for improved grid stability. That is, with increased penetration of PV, discrete development of PV and ESS connecting to transmission ac grid and HVdc links is one of the solutions for stable operation of grid. Here, an integrated concept for integration of PV and ESS to transmission ac grid and HVdc links is proposed that is named as multi-port autonomous reconfigurable solar power plant (MARS). The proposed integrated development reduces the cost associated with respect to discrete development of PV-ESS systems connecting to transmission ac grid and HVdc links. The integrated development incorporates advanced control methods to provide inertial and primary frequency response, reactive power support, and transient stability to manage PV and ESS resources. In this paper, high-fidelity switched system model of the integrated system and grids are developed and detailed simulation results are provided to showcase the stable operation of the integrated system and provision of grid support functions.

14 SOLAR ENERGY↗

Convex Relaxation of Grid-Connected Energy Storage System Models With Complementarity Constraints in DC OPF

Including complementarity constraints in energy storage system (ESS) models in optimization problems ensure an optimal solution will not produce a physically unrealizable control strategy where there is simultaneous charging and discharging. However, the current approaches to impose complementarity constraints require the use of non-convex optimization methods. Here, we propose a convex relaxation for a common ESS model that has terms for both charging and discharging based on a penalty reformulation for use in a model predictive control (MPC) based optimal power flow (DC OPF) problem. In this approach, the complementarity constraints are omitted and a penalty term is added to the optimization objective function. For the DC OPF problem, we provide analysis for the conditions under which the convex relaxation of the complementarity constraint ensures that a solution with simultaneous ESS charging and discharging operation is suboptimal. Simulation results demonstrating ESS behavior with and without the penalty reformulation are provided for an MPC-based DC OPF problem on multiple IEEE test systems.

25 ENERGY STORAGE↗

Control and Size Energy Storage for Managing Energy balance of Variable Generation Resources

This paper presents control algorithms and sizing strategies for using energy storage to manage energy balance for variable generation resources. The control objective is to minimize the hourly generation imbalance between the actual and the scheduled generation of the wind farm. Three control algorithms are compared: tracking power imbalance, post-compensation, and pre-compensation. Measurement data from a wind farm located in South-central Washington State are used in the study. The results show that tracking power imbalance yields the best performance by keeping the hourly energy imbalances zero. However, the energy storage system (ESS) will be significantly oversized. Post-compensation reduces power rating of the ESS but the hourly imbalance may not be kept as zero when large and long-lasting energy imbalances occur. A linear regression forecasting algorithm is developed for the pre-compensation algorithm to pre-charge or pre-discharge the ESS based on predicted energy imbalances. The performance comparison shows that the pre-compensation method significantly reduces the size of the ESS while maintaining satisfactory performance.

ENERGY MANAGEMENT↗

Sizing SiC Storage Inverters for Fast Grid Frequency Support

As wind and solar displace synchronous generators whose inertia stabilizes the AC grid frequency on fast time scales, it has been proposed to use energy storage systems (ESSs) to mitigate frequency transient events. Such events require a rapid surge of power from the ESS, but they occur only rarely. The high temperature tolerance of SiC MOSFETs and diodes presents an opportunity for innovative ESS inverter designs. Herein we investigate a SiC ESS inverter design such that the SiC device ratings are obeyed during mild frequency events but are exceeded during rare, major events, for a potentially more economical inverter design. In support of this proposal we present: 1. An analysis of four years of grid frequency events in the U.S. Western Interconnection. 2. A switch-level ESS inverter simulation using SiC devices with detailed loss estimates. 3. Thermal analysis of the SiC power modules during a worst-case frequency event, showing that the modules can likely withstand the brief overcurrent. This analysis supports the conclusion that it may be advantageous for economical designs (acknowledging the increased risks) to undersize the SiC switches when designing inverters to perform active power control for grid frequency support. Such a strategy may result in SiC-based designs being more competitive with less costly silicon IGBT-based designs.

24 POWER TRANSMISSION AND DISTRIBUTION↗

The UCAR Africa Initiative: Recent insights, challenges, and opportunities to foster collaborative research for environmental sustainability

Africa is increasingly being exposed to the negative impacts of climate and environmental change, while having less capacity to respond compared to other continents. The vulnerability partially results from unprecedented demographic growth, urbanization, and industrialization. However, the continent has still largely been underserved by the broader Earth System Science (ESS) community, as evidenced by the limited amount of ESS data and research that cover Africa compared to other areas of the world. Here we present the recent University Corporation for Atmospheric Research (UCAR) Africa Initiative that aims to enhance environmental sustainability in Africa by fostering international collaborative research partnerships co-led by African scientists. Specifically, we outline urgent challenges and opportunities identified through an international workshop in six areas of ESS namely (1) air quality and health, (2) weather, (3) climate, (4) land and water, (5) social science perspectives, and (6) developing equitable collaboration and sustainable infrastructure. We highlight examples of successful partnerships and conclude with recommendations to advance collaborative, actionable ESS research that addresses Africa’s critical environmental challenges.

African weather and land variability↗

Inventory of Safety-related Codes and Standards for Energy Storage Systems with some Experiences related to Approval and Acceptance

The purpose of this document is to identify laws, rules, model codes, codes, standards, regulations, specifications (CSR) related to safety that could apply to stationary energy storage systems (ESS) and experiences to date securing approval of ESS in relation to CSR. This information is intended to assist in securing approval of ESS under current CSR and to identification of new CRS or revisions to existing CRS and necessary supporting research and documentation that can foster the deployment of safe ESS.

Conover, David R.↗

Lower-Energy Energy Storage System (LEESS) Component Evaluation

Alternate hybrid electric vehicle (HEV) energy storage systems (ESS) such as lithium-ion capacitors (LICs) and electrochemical double-layer capacitor (EDLC) modules have the potential for improved life, superior cold temperature performance, and lower long-term cost projections relative to traditional battery storage systems. If such lower-energy ESS (LEESS) devices can also be shown to maintain high HEV fuel savings, future HEVs designed with these devices could have an increased value proposition relative to conventional vehicles. NREL's vehicle test platform is helping validate the in-vehicle performance capability of alternative LEESS devices and identify unforeseen issues. NREL created the Ford Fusion Hybrid test platform for in-vehicle evaluation of such alternative LEESS devices, bench testing of the initial LIC pack, integration and testing of the LIC pack in the test vehicle, and bench testing and installation of an EDLC module pack. EDLC pack testing will continue in FY15. The in-vehicle LIC testing results suggest technical viability of LEESS devices to support HEV operation. Several LIC configurations tested demonstrated equivalent fuel economy and acceleration performance as the production nickel-metal-hydride ESS configuration across all tests conducted. The lowest energy LIC scenario demonstrated equivalent performance over several tests, although slightly higher fuel consumption on the US06 cycle and slightly slower acceleration performance. More extensive vehicle-level calibration may be able to reduce or eliminate these performance differences. The overall results indicate that as long as critical attributes such as engine start under worst case conditions can be retained, considerable ESS downsizing may minimally impact HEV fuel savings.

25 ENERGY STORAGE↗

Sample Results from the Interim Salt Disposition Program Macrobatch 8 Tank 21H Qualification Samples

Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 8 for the Interim Salt Disposition Program (ISDP). An Actinide Removal Process (ARP) and several Extraction-Scrub- Strip (ESS) tests were also performed. This document reports characterization data on the samples of Tank 21H as well as simulated performance of ARP and the Modular Caustic Side Solvent Extraction (CSSX) Unit (MCU). No issues with the projected Salt Batch 8 strategy are identified. A demonstration of the monosodium titanate (MST) (0.2 g/L) removal of strontium and actinides provided acceptable average decontamination factors for plutonium of 2.62 (4 hour) and 2.90 (8 hour); and average strontium decontamination factors of 21.7 (4 hour) and 21.3 (8 hour). These values are consistent with results from previous salt batch ARP tests. The two ESS tests also showed acceptable performance with extraction distribution ratios (D(Cs)) values of 52.5 and 50.4 for the Next Generation Solvent (NGS) blend (from MCU) and NGS (lab prepared), respectively. These values are consistent with results from previous salt batch ESS tests. Even though the performance is acceptable, SRNL recommends that a model for predicting extraction behavior for cesium removal for the blended solvent and NGS be developed in order to improve our predictive capabilities for the ESS tests.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Sample results from the Interim Salt Disposition Program Macrobatch 8 Tank 21H qualification samples

Savannah River National Laboratory (SRNL) analyzed samples from Tank 21H in support of qualification of Macrobatch (Salt Batch) 8 for the Interim Salt Disposition Program (ISDP). An Actinide Removal Process (ARP) and several Extraction-Scrub-Strip (ESS) tests were also performed. This document reports characterization data on the samples of Tank 21H as well as simulated performance of ARP and the Modular Caustic Side Solvent Extraction (CSSX) Unit (MCU). No issues with the projected Salt Batch 8 strategy are identified. A demonstration of the monosodium titanate (MST) (0.2 g/L) removal of strontium and actinides provided acceptable average decontamination factors for plutonium of 2.62 (4 hour) and 2.90 (8 hour); and average strontium decontamination factors of 21.7 (4 hour) and 21.3 (8 hour). These values are consistent with results from previous salt batch ARP tests. The two ESS tests also showed acceptable performance with extraction distribution ratios (D (Cs) ) values of 52.5 and 50.4 for the Next Generation Solvent (NGS) blend (from MCU) and NGS (lab prepared), respectively. These values are consistent with results from previous salt batch ESS tests. Even though the performance is acceptable, SRNL recommends that a model for predicting extraction behavior for cesium removal for the blended solvent and NGS be developed in order to improve our predictive capabilities for the ESS tests.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Determination of Duty Cycle for Energy Storage Systems in a PV Smoothing Application

This report supplements the document, "Protocol for Uniformly Measuring and Expressing the Performance of Energy Storage Systems," issued in a revised version in April 2016 (see [4]), which will include the photovoltaic (PV) smoothing application for an energy storage system (ESS). This report provides the background and documentation associated with the determination of a duty cycle for an ESS operated in a PV smoothing application for the purpose of measuring and expressing ESS performance in accordance with the ESS performance protocol. ACKNOWLEDGEMENTS The authors gratefully acknowledge the support of Dr. Imre Gyuk, program manager for the DOE Energy Storage Systems Program. The authors would also like to express their appreciation to all the stakeholders who participated as members of the PV Smoothing Subgroup. Without their thoughtful input and recommendations, the definitions, metrics, and duty cycle provided in this report would not have been possible. A complete listing of members of the PV Smoothing Subgroup appears in the first chapter of this report. Special recognition should go to the staffs at Pacific Northwest National Laboratory (PNNL) and Sandia National Laboratories (SNL) in collaborating on this effort. In particular, Mr. David Conover and Dr. Vish Viswanathan of PNNL and Dr. Summer Ferreira of SNL were especially helpful in their suggestions for the determination of a duty cycle for the PV Smoothing application.

25 ENERGY STORAGE↗

Protocol for Uniformly Measuring and Expressing the Performance of Energy Storage Systems

This Protocol provides a set of “best practices” for characterizing energy storage systems (ESSs) and measuring and reporting their performance. It serves as a basis for assessing how an ESS will perform with respect to key performance attributes relevant to different applications. It is intended to provide a valid and accurate basis for the comparison of different ESSs. By achieving the stated purpose, the Protocol will enable more informed decision-making in the selection of ESSs for various stationary applications. The Protocol identifies general information and technical specifications relevant in describing an ESS and also defines a set of test, measurement, and evaluation criteria with which to express the performance of ESSs that are intended for energy-intensive and/or power-intensive stationary applications. An ESS includes a storage device, battery management system, and any power conversion systems installed with the storage device. The Protocol is agnostic with respect to the storage technology and the size and rating of the ESS. The Protocol does not apply to single-use storage devices and storage devices that are not coupled with power conversion systems, nor does it address safety, security, or operations and maintenance of ESSs, or provide any pass/fail criteria.

25 ENERGY STORAGE↗

Determination of Duty Cycle for Energy Storage Systems in a Renewables (Solar) Firming Application

This report supplements the document, “Protocol for Uniformly Measuring and Expressing the Performance of Energy Storage Systems,” issued in a revised version in April 2016, which will include the renewables (solar) firming application for an energy storage system (ESS). This report provides the background and documentation associated with the determination of a duty cycle for an ESS operated in a renewables (solar) firming application for the purpose of measuring and expressing ESS performance in accordance with the ESS performance protocol.

25 ENERGY STORAGE↗

Building a Cyberinfrastructure for Environmental System Science: Modeling Frameworks, Data Management, and Scientific Workflows, Workshop Report, Potomac, Maryland, April 30-May 1, 2015

The Environmental System Science (ESS) activity within the Department of Energy’s (DOE) Office of Biological and Environmental Research (BER) seeks to advance a robust, predictive understanding of terrestrial environments, extending from bedrock to the top of the vegetative canopy and from molecular to global scales, through an iterative cycle of model-driven experimentation and observation dubbed MODEX. Considerable progress has been made toward achieving this overarching goal, but widely recognized is the fragmentation across projects and disciplines of the relevant modeling and simulation capabilities, observational and experimental data, analysis algorithms, and workflow tools. This fragmentation creates significant challenges for studying impacts and feedbacks in these complex multiscale systems. These challenges are further exacerbated by ongoing disruptive changes in high-performance computational architectures and the exponential growth in the types and volume of data that render obsolete the conventional approaches to software development and data management. Overcoming these challenges will require the development of a BER Climate and Environmental Sciences Division (CESD)–wide enabling cyberinfrastructure to support data management, cross-domain modeling, data analysis, and collaborative research. To explore the potential for working groups to initiate and guide a more integrated and community-based cyberinfrastructure, BER held the ESS Workshop on Model-Data Integration: Modeling Frameworks, Data Management, and Scientific Workflows on April 30-May 1, 2015, following the ESS Principal Investigator Meeting in Potomac, Maryland. Participants included model developers, software engineers, and data management specialists from eight national laboratories, which represented a wide range of projects and programs from CESD as well as cross-cutting projects from DOE’s Office of Advanced Scientific Computing Research (ASCR; both BER and ASCR are operated from within DOE’s Office of Science). A series of plenary talks provided background information and clarified the workshop’s three objectives: (1) develop requirements for this community-based cyberinfrastructure to ensure enhanced scientific productivity of the community as a whole; (2) identify challenges associated with developing this new cyberinfrastructure using a phased approach guided by project-driven use cases; and, given these requirements and challenges, (3) chart a path forward for ESS working groups to lead the phased development of the new cyberinfrastructure.

54 ENVIRONMENTAL SCIENCES↗

Energy Storage and Decarbonization Analysis for Energy Regulators: Technical Analysis for the Illinois Commerce Commission

Jurisdictions around the world are enacting and enforcing an increasing number of policies to fight climate change, leading to higher penetration of variable renewable energy (VRE) and energy storage systems (ESSs) in the power grid. One of the biggest challenges associated with this process is the evaluation of the appropriate amount of ESS required to mitigate the variability of the VREs and achieve decarbonization goals of a particular jurisdiction. This report presents methodologies developed and results obtained for determining the minimum amount of ESS required to adequately serve load in a system where fossil fueled generators are being replaced by VREs over the next two decades. This technical analysis is performed by Sandia National Laboratories for the DOE Office of Electricity Energy Storage Program in collaboration with the Illinois Commerce Commission (ICC). The Illinois MISO Zone 4 is used as a case study. Several boundary conditions are investigated in this analysis including capacity adequacy and energy adequacy to determine the quantity of ESS required for MISO Zone 4. Multiple scenarios are designed and evaluated to incorporate the impact of varying capacity values of VREs and on the resource adequacy of the system. Several retirement scenarios involving fossil-fueled assets are also considered. Based on the current plans of new additions and retirements of generating assets, the results of the technical analysis indicate that Illinois MISO Zone 4 will require a significant quantity of ESS to satisfy their electricity demand over the next two decades.

25 ENERGY STORAGE↗

Considerations for Fire Service Response to Residential Battery Energy Storage System Incidents

Renewable energy sources (e.g., rooftop photovoltaics, wind turbines) are capable of addressing our grid-level energy challenges by reducing environmental impacts, increasing resiliency, and increasing the supply of input energy. However, renewable energy sources alone are not a complete solution. The generation of power from major renewable energy sources fluctuates with the weather, creating significant challenges in matching electrical power generation to electrical power consumption. The value of renewable power generation sources is multiplied when paired with battery energy storage systems (ESS), which can store excess power generated from renewable energy sources when it is not consumed and deliver that power later when demand exceeds base power generation. Residential ESS units are frequently installed to support renewable energy initiatives by storing energy from intermittent sources such as photovoltaic panels. Residential ESS units also offer an alternative to gas-powered generators or other backup power means. Lithium-ion batteries are the most common residential ESS technology due to their affordability and energy density. Though lithium-ion systems come with benefits, there is also a risk of thermal runaway within this technology which can result in flammable gas release, fire, and explosion. As the installations of these products increase, the frequency of response to fire incidents involving these products will increase. In response to this new and evolving hazard, UL Solutions (ULS) and UL Fire Safety Research Institute (FSRI) have partnered with the International Association of Fire Fighters (IAFF) to conduct a series of large-scale tests sponsored by the US Department of Energy to characterize the challenges for fire fighters responding to fires involving residential energy storage systems. The project focuses on developing size-up and tactical considerations to support the fire service in navigating the evolving modern fireground.

25 ENERGY STORAGE↗