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At least 91 records · Page 5

Europium anomaly in plagioclase feldspar - Experimental results and semiquantitative model.

The partition of europium between plagioclase feldspar and magmatic liquid is considered in terms of the distribution coefficients for divalent and trivalent europium. A model equation is derived giving the europium anomaly in plagioclase as a function of temperature and oxygen fugacity. The model explains europium anomalies in plagioclase synthesized under controlled laboratory conditions as well as the variations of the anomaly observed in natural terrestrial and extraterrestrial igneous rocks.

Weill, D. F.↗

Pressure distribution of a twin-engine upper-surface blown jet-flap model

An investigation has been made to determine the chordwise and spanwise pressure distributions of a small-scale upper-surface blown jet-augmented flap STOL model. The model was powered by two simulated high-bypass-ratio turbofan engines mounted ahead of and above an unswept-untapered wing in a nacelle having a rectangular nozzle. The results of the investigation are presented as tabulated and plotted chordwise pressure distribution coefficients for nine spanwise stations.

Smith, C. C., Jr.↗

Lunar rock types - The role of plagioclase in non-mare and highland rock types

Some nonmare and highland rock types (14310 type KREEP and very high Al2O3 basalts) have the internal chemical variations expected for a plagioclase-liquid system. The observed Eu variations in these rock types suggest a D(Eu) 1/p of 0.6 to 0.7. The Sr variations suggest a D(Sr) 1/p of about 0.6, with values as low as 0.35 suggested for some materials from sample 14063. Common Apollo 14 KREEP and Apollo 15 KREEP do not show internal Sr, Eu, Al2O3 variations consistent with the D(Eu, Sr) 1/p values derived for 14310 type KREEP. Major element and experimental data indicate that olivine or pyroxene is a large, perhaps dominant, controller of chemical variations within common Apollo 14 KREEP. The application of these distribution coefficients to pure anorthosites like 15415 yields the model dependent conclusion that the silicate liquids with which such anorthosites may have been chemically equilibrated have not yet been analyzed and perhaps not directly sampled.

Hubbard, N. J.↗

The distribution of Sr and REE between diopside and silicate liquid

Experimental determination of the distribution coefficients in diopside-liquid pairs for strontium and nine rare-earth elements in the system CaMgSi2O6-NaAlSi3O8-CaAl2Si2O8. In experiments in air at 1265 C it is found that most of the Sr(2+), Eu(2+), and RE(3+) ions substitute for Ca(2+) and, in addition, a coupled substitution of Al(3+) for Si(4+) occurs. All of the trace ions considered are found to be excluded from the diopside lattice relative to the liquid. In the case of the trivalent ions the exclusion is much more pronounced for La and Ce, which have ionic radii larger than that of Ca(2+) in 8-fold oxygen coordination. Divalent Sr and Eu with even larger radii are also strongly excluded.

Grutzeck, M.↗

Modeling the evolution of Sm and Eu abundances during lunar igneous differentiation

The current work presents models for the evolution of europium and samarium abundances during lunar igneous processes. The effect of probable variations in lunar temperature and oxygen fugacity, mineral-liquid distribution coefficients, and the crystallization or melting progression are considered in the model calculations. Changes in the proportions of crystallizing phases strongly influence the evolution of trace element abundances during fractional crystallization, and models must include realistic estimates of the major phase equilibria during crystallization. The results are applied to evaluating the possibility of generating KREEP-rich materials by lunar igneous processes.

Weill, D. F.↗

An investigation of airflow over the aft portions of a variable sweep fighter configuration

An investigation of air flow over the aft portions of a variable sweep fighter aircraft configuration was made. Tests conducted in the unitary plan wind tunnel at Mach number 2.16 included measurements of forces, moments, and local static pressures as well as visual recordings of the air flow. An aerodynamic analytical prediction method was evaluated when used in data comparison at angles of attack of 0, 5, and 15 degrees. The results indicate that in supersonic flow the typical outboard located twin vertical tail arrangement tends to provide a more positive increment in normal-force on the afterbody fuselage and the horizontal tail than a single center-mounted vertical tail of similar planform shape. In addition, the results indicate that a method for aerodynamic analysis of wing-body-tail configurations currently available can provide reasonable estimates of pressure coefficient distributions on configurations in regions of complex supersonic flow. At this time, however, the available analytical method cannot adequately replace experimental wind tunnel tests for determining the supersonic flow environment of a given configuration.

Graves, E. B.↗

Investigation of very low blockage ratio boattail models in the Langley 16-foot transonic tunnel

An investigation at an angle of attack of 0 deg was conducted in a 16 foot transonic tunnel at Mach numbers from 0.4 to 1.05 to determine the limits in Mach number at which valid boattail pressure drag data may be obtained with very low blockage ratio bodies. Extreme care was exercised when examining any data taken at subsonic Mach numbers very near 1.0 and lower than the supersonic Mach number at which shock reflections miss the model. Boattail pressure coefficient distributions did not indicate any error, but when integrated boattail pressure drag data was plotted as a function of Mach number, data which were in error were identified.

Reubush, D. E.↗

Fe and Mg in plagioclase

Distribution coefficients for Fe and Mg between plagioclase and basaltic liquids were measured for lunar, terrestrial and synthetic systems. The data obtained imply that lunar anorthosites crystallized from relatively iron-rich liquids, that Fe/Mg zoning in plagioclase is an indicator of crystallization processes in basaltic magmas, and that Fe/Mg heterogeneity in plagioclase is a clue to the recognition of impact melts.

Longhi, J.↗

Compositional interrelationships of mare basalts from bulk chemical and melt inclusion studies

Petrographic and electron microprobe data (355 new analyses) are presented on melt inclusions and their host phases found in a reexamination of the Apollo thin section collection. In addition, occurrences of early armalcolite and ilmenite are described and new data are presented on quench-pyroxene compositions and melt inclusions in chromian ulvospinel. Compositional differences between mare basalt types and their melt inclusions are illustrated with plots of compositions normalized to a terrestrial lava composition, that of the 1965 Makaopuhi lava lake. The plots emphasize the fact that mare basalts are not significantly differentiated relative to the compositions that are possible as defined by the melt inclusion data. Distribution coefficients for Fe and Mg partitioning between trapped melt and host olivine and ilmenite are calculated and show a range about probable equilibrium values. It is suggested that the crystallization sequence olivine-ilmenite-plagioclase-pyroxene defined by the melt inclusion data may be the actual sequence which obtained generally for Apollo 11 and 17 mare basalts just prior to eruption.

Weiblen, P. W.↗

Petrogenesis of KREEP

Solid/liquid distribution coefficients were experimentally determined for a number of trace elements for olivine, orthopyroxene, plagioclase and ilmenite. Major- and trace-element partitioning and relevant phase equilibria are used to study possible parent-daughter relationships between a number of highland samples and highly evolved KREEP-rich materials. A model is proposed in which low-K Fra Mauro basalt type material was produced by fractionation of large amounts of olivine and lesser amounts of plagioclase from undifferentiated lunar material at about 4.4 AE.

Mckay, G. A.↗

Test of a model for trace element partition during closed-system solidification of a silicate liquid

Trace-element concentrations in separated minerals and rock fragments from a coarsely crushed and sieved sample of medium-grained lunar basalt are determined by high-precision instrumental neutron activation analysis for three main purposes. These are: (1) to test a previously proposed model for describing trace-element behavior during solidification of a silicate liquid under conditions of a closed system; (2) to compare trace-element concentrations among different size fractions of a comminuted basalt; and (3) to investigate small-scale heterogeneity within a single medium-grained basalt. It is found that an excellent mass balance for the whole rock is attained in terms of the trace-element concentrations of the component minerals and mesostasis, that the mixing model describing this mass balance yields a superior modal analysis for the whole rock, and that different size fractions of the coarsely crushed basalt vary in mineral composition. The closed-system model is shown to account properly for the average behavior of the trace elements during solidification of the basalt, and values of distribution coefficients are obtained for incompatible elements in that rock.

Haskin, L. A.↗

The effect of temperature and pressure on the distribution of iron group elements between metal and olivine phases in the process of differentiation of protoplanetary material

The distribution patterns of Ni, Co, Mn, and Cr were studied in olivines of various origins: from meteorites (chondrites, achondrites, pallasites), which are likely analogs of the protoplanetary material, to peridotite inclusions in kimberlite pipes, which are analogs of mantle material. According to X-ray microanalysis data, nickel is concentrated in peridotite olivines, while manganese is concentrated in meteoritic olivines. The maximum chromium content was found in ureilites, which were formed under reducing conditions. Experiments at pressures of 20 to 70 kbar and temperatures of 1100 to 2000 C have shown that in a mixture of olivine and Ni metal or NiO, nickel enters the silicate phase, displacing Fe into the metallic phase. Equilibrium temperatures were estimated from the Fe, Ni distribution coefficients between the metal and olivine: 1500 K for pallasites, 1600 K for olivine-bronzite H6 chondrites, 1200 K for olivine-hypersthene L6, 900 K for LL6, and 1900 K for ureilites (at P = 1 atm). The equilibrium conditions of peridotites are close to T = 1800 K and P over 100 kbar. It is concluded that there is a sharp difference between the conditions of differentiation of the protoplanetary material at the time meteorites were formed and the conditions of differentiation of the planets into concentric layers.

Vinogradov, A. P.↗

Passive particle dosimetry

Present methods of dosimetry are reviewed with emphasis on the processes using silver chloride crystals for ionizing particle dosimetry. Differences between the ability of various crystals to record ionizing particle paths are directly related to impurities in the range of a few ppm (parts per million). To understand the roles of these impurities in the process, a method for consistent production of high purity silver chloride, and silver bromide was developed which yields silver halides with detectable impurity content less than 1 ppm. This high purity silver chloride was used in growing crystals with controlled doping. Crystals were grown by both the Czochalski method and the Bridgman method, and the Bridgman grown crystals were used for the experiments discussed. The distribution coefficients of ten divalent cations were determined for the Bridgman crystals. The best dosimeters were made with silver chloride crystals containing 5 to 10 ppm of lead; other impurities tested did not produce proper dosimeters.

Childs, C. B.↗

Tungsten in iron meteorites

Tungsten concentrations have been determined by instrumental neutron activation in 104 iron meteorites, and range from 0.07 to 5 microg/g. In individual groups, concentrations vary by factors of between 1.5 and 8, but there are negative W-Ni correlations in 8 groups: IAB, IC, IIAB, IID, IIE, IIIAB, IIICD, and IIIF. The lowest W concentrations are found in groups IAB and IIICD, which also have the smallest slopes on a W-Ni plot. Eighteen anomalous irons have W concentrations between 5 microg/g (Butler) and 0.11 microg/g (Rafrueti). The distribution of W in irons shows similarities to that of other refractory sideophilic elements (except Mo), but is closest to the distribution of Ru and Pt. Assuming that chemical trends in group IIIAB were produced by fractional crystallization, a value of 1.6 can be deduced for the distribution coefficient of W between solid and liquid metal, as compared with 0.89 for Mo. Experimental evidence in support of these values is tenuous.

Scott, E. R. D.↗

KREEP petrogenesis revisited

An experimentally determined crystallization sequence for a composition similar to the LKFM breccias and experimentally determined crystal/liquid distribution coefficients are used to calculate the evolution of the abundances of several key elements during the crystallization of LKFM liquids. Results indicate that the LKFM breccias are not themselves precursors to Apollo 15 igneous KREEP, but that compositions slightly poorer in Ti and Fe might be. Consideration of the evolution of Ti and Sm abundances during the differentiation of proposed whole-moon compositions suggests that it may be necessary to appeal to 'unorthodox' mechanisms such as magma hybridization or interaction of magma with genetically unrelated minerals within the lunar crust to produce KREEP-rich liquids having the observed Ti/Sm. It is concluded that the compositions of samples with Sm contents greater than those in LKFM are dominated by igneous processes, while samples with lower Sm contents may be mixtures of an anorthositic component, a Mg-rich Sm-poor component, and a component similar in composition to LKFM.

Mckay, G. A.↗

Fuselage ventilation due to wind flow about a postcrash aircraft

Postcrash aircraft fuselage fire development, dependent on the internal and external fluid dynamics is discussed. The natural ventilation rate, a major factor in the internal flow patterns and fire development is reviewed. The flow about the fuselage as affected by the wind and external fire is studied. An analysis was performend which estimated the rates of ventilation produced by the wind for a limited idealized environmental configuration. The simulation utilizes the empirical pressure coefficient distribution of an infinite circular cylinder near a wall with its boundary later flow to represent the atmospheric boundary layer. The resulting maximum ventilation rate for two door size openings, with varying circumferential location in a common 10 mph wind was an order of magnitude greater than the forced ventilation specified in full scale fire testing. The parameter discussed are: (1) fuselage size and shape, (2) fuselage orientation and proximity to the ground, (3) fuselage-openings size and location, (4) wind speed and direction, and (5) induced flow of the external fire plume is recommended. The fire testing should be conducted to a maximum ventilation rate at least an order of magnitude greater than the inflight air conditioning rates.

Stuart, J. W.↗

An implicit algorithm for the transonic full-potential equation in conservative form

A fast, implicit approximate factorization algorithm for the solution of the conservative full-potential equation for transonic flow in two and three dimensions is presented. Stability in supersonic regions is maintained by the use of an upwind evaluation of the density coefficient along all coordinate directions, providing an effective upwind difference of the streamwise terms for any orientation of the velocity vector and thereby enhancing the reliability of the algorithm. The algorithm is shown to provide rapid convergence for the computation of certain difficult two-dimensional test cases, including cases with fishtail shock patterns, demonstrating the reliability and efficiency of the procedure. Surface pressure coefficient distributions obtained by the present method are also found to be in good agreement with those computed by successive-line overrelaxation and a hybrid direct-solver/successive-line overrelaxation scheme, with significant reductions in CPU time required. A three-dimensional solution for a swept wing mounted between parallel walls is also presented which demonstrates the high convergence rate of the algorithm in three dimensions as well as two.

Holst, T.↗

Noble gas trapping by laboratory carbon condensates

Trapping of noble gases by carbon-rich matter was investigated by synthesizing carbon condensates in a noble gas atmosphere. Laser evaporation of a solid carbon target yielded submicron grains which proved to be efficient noble gas trappers (Xe distribution coefficients up to 13 cu cm STP/g-atm). The carbon condensates are better noble gas trappers than previously reported synthetic samples, except one, but coefficients inferred for meteoritic acid-residues are still orders of magnitude higher. The trapped noble gases are loosely bound and elementally strongly fractionated, but isotopic fractionations were not detected. Although this experiment does not simulate nebular conditions, the results support the evidence that carbon-rich phases in meteorites may be carriers of noble gases from early solar system reservoirs. The trapped elemental noble gas fractionations are remarkably similar to both those inferred for meteorites and those of planetary atmospheres for earth, Mars and Venus.

Niemeyer, S.↗