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Fine-scale application of WRF-CAM5 during a dust storm episode over East Asia: Sensitivity to grid resolutions and aerosol activation parameterizations

An advanced online-coupled meteorology and chemistry model WRF-CAM5 has been applied to East Asia using triple-nested domains at different grid resolutions (i.e., 36-, 12-, and 4-km) to simulate a severe dust storm period in spring 2010. Analyses are performed to evaluate the model performance and investigate model sensitivity to different horizontal grid sizes and aerosol activation parameterizations and to examine aerosol-cloud interactions and their impacts on the air quality. A comprehensive model evaluation of the baseline simulations using the default Abdul-Razzak and Ghan (AG) aerosol activation scheme shows that the model can well predict major meteorological variables such as 2-m temperature (T2), water vapor mixing ratio (Q2), 10-m wind speed (WS10) and wind direction (WD10), and shortwave and longwave radiation across different resolutions with domain-average normalized mean biases typically within±15%. The baseline simulations also show moderate biases for precipitation and moderate-to-large underpredictions for other major variables associated with aerosol-cloud interactions such as cloud droplet number concentration (CDNC), cloud optical thickness (COT), and cloud liquid water path (LWP) due to uncertainties or limitations in the aerosol-cloud treatments. The model performance is sensitive to grid resolutions, especially for surface meteorological variables such as T2, Q2, WS10, and WD10, with the performance generally improving at finer grid resolutions for those variables. Comparison of the sensitivity simulations with an alternative (i.e., the Fountoukis and Nenes (FN) series scheme) and the default (i.e., AG scheme) aerosol activation scheme shows that the former predicts larger values for cloud variables such as CDNC and COT across all grid resolutions and improves the overall domain-average model performance for many cloud/radiation variables and precipitation. Sensitivity simulations using the FN series scheme also have large impacts on radiations, T2, precipitation, and air quality (e.g., decreasing O3) through complex aerosol-radiation-cloud-chemistry feedbacks. The inclusion of adsorptive activation of dust particles in the FN series scheme has similar impacts on the meteorology and air quality but to lesser extent as compared to differences between the FN series and AG schemes. Compared to the overall differences between the FN series and AG schemes, impacts of adsorptive activation of dust particles can contribute significantly to the increase of total CDNC (~45%) during dust storm events and indicate their importance in modulating regional climate over East Asia.

WRF-CAM5, Aerosol activation, adsorptive activatio↗

Potential human exposure to halogenated flame-retardants in elevated surface dust and floor dust in an academic environment

Most households and workplaces all over the world possess furnishings and electronics, all of which contain potentially toxic flame retardant chemicals to prevent fire hazards. Indoor dust is a recognized repository of these types of chemicals including polybrominated diphenyl ethers (PBDEs) and non-polybrominated diphenyl ethers (non-PBDEs). However, no previous U.S. studies have differentiated concentrations from elevated surface dust (ESD) and floor dust (FD) within and across microenvironments. We address this information gap by measuring twenty-two flame-retardant chemicals in dust on elevated surfaces (ESD; n=10) and floors (FD; n=10) from rooms on a California campus that contain various concentrations of electronic products. We hypothesized a difference in chemical concentrations in ESD and FD. Secondarily, we examined whether or not this difference persisted: (a) across the studied microenvironments and (b) in rooms with various concentrations of electronics. A Wilcoxon signed-rank test demonstrated that the ESD was statistically significantly higher than FD for BDE-47 (p=0.01), BDE-99 (p=0.01), BDE-100 (p=0.01), BDE-153 (p=0.02), BDE-154 (p=0.02), and 3 non-PBDEs including EH-TBB (p=0.02), BEH-TEBP (p=0.05), and TDCIPP (p=0.03). These results suggest different levels and kinds of exposures to flame-retardant chemicals for individuals spending time in the sampled locations depending on the position of accumulated dust. Therefore, further research is needed to estimate human exposure to flame retardant chemicals based on how much time and where in the room individuals spend their time. Such sub-location estimates will likely differ from assessments that assume continuous unidimensional exposure, with implications for improved understanding of potential health impacts of flame retardant chemicals. - Highlights: • Brominated flame retardants used in electronic products accumulate in room dust • Various chemical moieties of flame retardants leach differently into room dust • Flame retardant concentrations in dust differ in elevated surfaces compared to floors.

54 ENVIRONMENTAL SCIENCES↗

DUST PROPERTIES OF LOCAL DUST-OBSCURED GALAXIES WITH THE SUBMILLIMETER ARRAY

We report Submillimeter Array observations of the 880 μm dust continuum emission for four dust-obscured galaxies (DOGs) in the local universe. Two DOGs are clearly detected with S{sub ν}(880 μm) =10-13 mJy and S/N > 5, but the other two are not detected with 3σ upper limits of S{sub ν}(880 μm) =5-9 mJy. Including an additional two local DOGs with submillimeter data from the literature, we determine the dust masses and temperatures for six local DOGs. The infrared luminosities and dust masses for these DOGs are in the ranges of 1.2-4.9 × 10{sup 11}(L{sub ☉}) and 4-14 × 10{sup 7}(M{sub ☉}), respectively. The dust temperatures derived from a two-component modified blackbody function are 23-26 K and 60-124 K for the cold and warm dust components, respectively. Comparison of local DOGs with other infrared luminous galaxies with submillimeter detections shows that the dust temperatures and masses do not differ significantly among these objects. Thus, as argued previously, local DOGs are not a distinctive population among dusty galaxies, but simply represent the high-end tail of the dust obscuration distribution.

79 ASTRONOMY AND ASTROPHYSICS↗

Direct measurements of dust attenuation in z ∼ 1.5 star-forming galaxies from 3D-HST: Implications for dust geometry and star formation rates

The nature of dust in distant galaxies is not well understood, and until recently few direct dust measurements have been possible. We investigate dust in distant star-forming galaxies using near-infrared grism spectra of the 3D-HST survey combined with archival multi-wavelength photometry. These data allow us to make a direct comparison between dust around star-forming regions (A {sub V,} {sub H} {sub II}) and the integrated dust content (A {sub V,} {sub star}). We select a sample of 163 galaxies between 1.36 ≤ z ≤ 1.5 with Hα signal-to-noise ratio ≥5 and measure Balmer decrements from stacked spectra to calculate A {sub V,} {sub H} {sub II}. First, we stack spectra in bins of A {sub V,} {sub star}, and find that A {sub V,} {sub H} {sub II} = 1.86 A {sub V,} {sub star}, with a significance of σ = 1.7. Our result is consistent with the two-component dust model, in which galaxies contain both diffuse and stellar birth cloud dust. Next, we stack spectra in bins of specific star formation rate (log SSFR), star formation rate (log SFR), and stellar mass (log M {sub *}). We find that on average A {sub V,} {sub H} {sub II} increases with SFR and mass, but decreases with increasing SSFR. Interestingly, the data hint that the amount of extra attenuation decreases with increasing SSFR. This trend is expected from the two-component model, as the extra attenuation will increase once older stars outside the star-forming regions become more dominant in the galaxy spectrum. Finally, using Balmer decrements we derive dust-corrected Hα SFRs, and find that stellar population modeling produces incorrect SFRs if rapidly declining star formation histories are included in the explored parameter space.

79 ASTRONOMY AND ASTROPHYSICS↗

DUST AND GAS IN THE MAGELLANIC CLOUDS FROM THE HERITAGE HERSCHEL KEY PROJECT. I. DUST PROPERTIES AND INSIGHTS INTO THE ORIGIN OF THE SUBMILLIMETER EXCESS EMISSION

The dust properties in the Large and Small Magellanic clouds (LMC/SMC) are studied using the HERITAGE Herschel Key Project photometric data in five bands from 100 to 500 μm. Three simple models of dust emission were fit to the observations: a single temperature blackbody modified by a power-law emissivity (SMBB), a single temperature blackbody modified by a broken power-law emissivity (BEMBB), and two blackbodies with different temperatures, both modified by the same power-law emissivity (TTMBB). Using these models, we investigate the origin of the submillimeter excess, defined as the submillimeter emission above that expected from SMBB models fit to observations <200 μm. We find that the BEMBB model produces the lowest fit residuals with pixel-averaged 500 μm submillimeter excesses of 27% and 43% for the LMC and SMC, respectively. Adopting gas masses from previous works, the gas-to-dust ratios calculated from our fitting results show that the TTMBB fits require significantly more dust than are available even if all the metals present in the interstellar medium (ISM) were condensed into dust. This indicates that the submillimeter excess is more likely to be due to emissivity variations than a second population of colder dust. We derive integrated dust masses of (7.3 ± 1.7) × 10{sup 5} and (8.3 ± 2.1) × 10{sup 4} M {sub ☉} for the LMC and SMC, respectively. We find significant correlations between the submillimeter excess and other dust properties; further work is needed to determine the relative contributions of fitting noise and ISM physics to the correlations.

79 ASTRONOMY AND ASTROPHYSICS↗

AN INFRARED CENSUS OF DUST IN NEARBY GALAXIES WITH SPITZER (DUSTiNGS). II. DISCOVERY OF METAL-POOR DUSTY AGB STARS

The DUSTiNGS survey (DUST in Nearby Galaxies with Spitzer) is a 3.6 and 4.5 μm imaging survey of 50 nearby dwarf galaxies designed to identify dust-producing asymptotic giant branch (AGB) stars and massive stars. Using two epochs, spaced approximately six months apart, we identify a total of 526 dusty variable AGB stars (sometimes called ''extreme'' or x-AGB stars; [3.6]-[4.5] > 0.1 mag). Of these, 111 are in galaxies with [Fe/H] < –1.5 and 12 are in galaxies with [Fe/H] < –2.0, making them the most metal-poor dust-producing AGB stars known. We compare these identifications to those in the literature and find that most are newly discovered large-amplitude variables, with the exception of ≈30 stars in NGC 185 and NGC 147, 1 star in IC 1613, and 1 star in Phoenix. The chemical abundances of the x-AGB variables are unknown, but the low metallicities suggest that they are more likely to be carbon-rich than oxygen-rich and comparisons with existing optical and near-IR photometry confirm that 70 of the x-AGB variables are confirmed or likely carbon stars. We see an increase in the pulsation amplitude with increased dust production, supporting previous studies suggesting that dust production and pulsation are linked. We find no strong evidence linking dust production with metallicity, indicating that dust can form in very metal-poor environments.

79 ASTRONOMY AND ASTROPHYSICS↗

Dust and Gas in the Magellanic Clouds from the Heritage Herschel Key Project. I. Dust Properties and Insights into the Origin of the Submm (Submillimeter) Excess Emission

The dust properties in the Large and Small Magellanic Clouds are studied using the HERITAGE Herschel Key Project photometric data in five bands from 100 to 500 micromillimeters. Three simple models of dust emission were fit to the observations: a single temperature blackbody modified by a powerlaw emissivity (SMBB), a single temperature blackbody modified by a broken power-law emissivity (BEMBB), and two blackbodies with different temperatures, both modified by the same power-law emissivity (TTMBB). Using these models we investigate the origin of the submillimeter excess; defined as the submillimeter (submm) emission above that expected from SMBB models fit to observations < 200 micromillimeters. We find that the BEMBB model produces the lowest fit residuals with pixel-averaged 500 micromillimeters submillimeter excesses of 27% and 43% for the Large and Small Magellanic Clouds, respectively. Adopting gas masses from previous works, the gas-to-dust ratios calculated from our fitting results show that the TTMBB fits require significantly more dust than are available even if all the metals present in the interstellar medium (ISM) were condensed into dust. This indicates that the submillimeter excess is more likely to be due to emissivity variations than a second population of colder dust. We derive integrated dust masses of (7.3 plus or minus 1.7) x 10 (sup 5) and (8.3 plus or minus 2.1) x 10 (sup 4) solar masses for the Large and Small Magellanic Clouds, respectively. We find significant correlations between the submillimeter excess and other dust properties; further work is needed to determine the relative contributions of fitting noise and ISM physics to the correlations.

Magellanic↗

Lunar Dust and Dust Mitigation Testing

Lunar dust was one of the most persistent problems for the Apollo astronauts due to its’ abrasiveness and strong adherence to surfaces. With the Artemis program, NASA is planning longer stays on the lunar surface, with more activities that have the potential to put the astronauts and equipment in contact with greater quantities of lunar dust. The success of these missions will depend on our understanding of material interactions with lunar dust and the development of ways to mitigate dust effects. This is particularly true in cases where exposure to dust will lead to failure of components, unacceptable loss of power or thermal control, unacceptable loss of visibility, or health issues. Lunar dust, issues with lunar dust, and ground testing with lunar simulant will be discussed as well as the development of and planned flight testing of optically transparent work function matching coatings to reduce adhesion of dust on the lunar surface.

Lunar dust↗

Twentieth century dust lows and the weakening of the westerly winds over the Tibetan Plateau: Dust and the Westerlies over the TP

Understanding past atmospheric dust variability is necessary to put modern atmospheric dust into historical context and assess the impacts of dust on the climate. In Asia, meteorological data of atmospheric dust is temporally limited, beginning only in the 1950s. High-resolution ice cores provide the ideal archive for reconstructing pre-instrumental atmospheric dust concentrations. Using a ~500-year (1477-1982AD) annually resolved calcium (Ca) dust proxy from a Tibetan Plateau (TP) ice core, we demonstrate the lowest atmospheric dust concentrations in the past ~500 years during the latter 20th century. Declines in late 19th-20th century Ca concentrations significantly correspond with regional zonal wind trends from two reanalysis models, suggesting that the Ca record provides a proxy for the westerlies. Twentieth century warming and attendant atmospheric pressure reductions over northern Asia have potentially reduced temperature/pressure gradients resulting in lower zonal wind velocities and associated dust entrainment/transport in the past ~500 years over the TP.

58 GEOSCIENCES↗

Modeling Dust Production, Growth, and Destruction in Reionization-era Galaxies with the CROC Simulations. II. Predicting the Dust Content of High-redshift Galaxies

Abstract We model the interstellar dust content of the reionization era with a suite of cosmological, fluid-dynamical simulations of galaxies with stellar masses ranging from ∼10 5 to 10 9 M ⊙ in the first 1.2 Gyr of the Universe. We use a post-processing method that accounts for dust creation and destruction processes, allowing us to systematically vary the parameters of these processes to test whether dust-dependent observable quantities of galaxies at these epochs could be useful for placing constraints on dust physics. We then forward model observable properties of these galaxies to compare to existing data. We find that we are unable to simultaneously match existing observational constraints with any one set of model parameters. Specifically, the models that predict the largest dust masses D / Z ≳ 0.1 at z = 5—because of high assumed production yields and/or efficient growth via accretion in the interstellar medium—are preferred by constraints on total dust mass and infrared (IR) luminosities, but these models produce far too much attenuation in the ultraviolet (UV), preventing them from matching observations of β UV . To investigate this discrepancy, we analyze the relative spatial distribution of stars and dust as probed by IR and UV emission, which appear to exhibit overly symmetric morphologies compared to existing data, likely due to the limitations of the stellar feedback model used in the simulations. Our results indicate that the observable properties of the dust distribution in high redshift galaxies are a particularly strong test of stellar feedback.

79 ASTRONOMY AND ASTROPHYSICS↗

Dust Modeling with GEOS-Chem: Evidence for Acidic Uptake on Dust Surfaces during INTEX-B

We use measurements of aerosol ion composition and size made from the DC8 aircraft during the 2006 INTEX-B airborne campaign to identify mineral dust signatures, and look for evidence for interaction of dust with acidic components. Coating of dust with sulfate or nitrate favors the role of dust particles as cloud condensation nucleii, can promote further uptake of SO2 and N2O5, can impact NOx/HNO3 partitioning, and can shift sulfate or nitrate towards larger sizes, affecting atmospheric lifetimes for both aerosol and gas components. Mineral dust had a pervasive presence on flights made during the Northern Pacific deployment of the INTEX-B mission. We use scatter plots of ion mixing ratios with Na+ and Ca(2+) to distinguish sea salt and mineral components of the aerosol distribution, respectively. Positive correlations of non-sea-salt sulfate and nitrate with calcium indicate that the dusty air stream is associated with polluted air masses. Sulfate-ammonium scatter plots indicate sulfate to be primarily in the form of (NH4)2SO4. A positive correlation between Ca(2+) and NO-, but little evidence of NH4NO3, suggests that NO3- may be associated with mineral dust surfaces. 3-d model simulations conducted with the GEOS-Chem chemical transport model indicate that transpacific transport from East Asia was principally responsible for the dust observed from the aircraft over the Pacific. We compare the aerosol component relationships in the model with those observed. Uptake of sulfate and nitrate on the dust is not yet represented in the model.

Fairlie, T. Duncan↗

Complex Role of Secondary Electron Emissions in Dust Grain Charging in Space Environments: Measurements on Apollo 11 and 17 Dust Grains

Dust grains in various astrophysical environments are generally charged electrostatically by photoelectric emissions with radiation from nearby sources, or by electron/ion collisions by sticking or secondary electron emissions. Knowledge of the dust grain charges and equilibrium potentials is important for understanding of a variety of physical and dynamical processes in the interstellar medium (ISM), and heliospheric, interplanetary, planetary, and lunar environments. The high vacuum environment on the lunar surface leads to some unusual physical and dynamical phenomena involving dust grains with high adhesive characteristics, and levitation and transportation over long distances. It has been well recognized that the charging properties of individual micron/submicron size dust grains are expected to be substantially different from the corresponding values for bulk materials and theoretical models. In this paper we present experimental results on charging of individual dust grains selected from Apollo 11 and Apollo 17 dust samples by exposing them to mono-energetic electron beams in the 10- 400 eV energy range. The charging rates of positively and negatively charged particles of approximately 0.2 to 13 microns diameters are discussed in terms of the secondary electron emission (SEE) process, which is found to be a complex charging process at electron energies as low as 10-25 eV, with strong particle size dependence. The measurements indicate substantial differences between dust charging properties of individual small size dust grains and of bulk materials.

Abbas, M. M.↗

Dust Destruction in the ISM: A Re-Evaluation of Dust Lifetimes

There is a long-standing conundrum in interstellar dust studies relating to the discrepancy between the time-scales for dust formation from evolved stars and the apparently more rapid destruction in supernova-generated shock waves. Aims. We re-examine some of the key issues relating to dust evolution and processing in the interstellar medium. Methods. We use recent and new constraints from observations, experiments, modelling and theory to re-evaluate dust formation in the interstellar medium (ISM). Results. We find that the discrepancy between the dust formation and destruction time-scales may not be as significant as has previously been assumed because of the very large uncertainties involved. Conclusions. The derived silicate dust lifetime could be compatible with its injection time-scale, given the inherent uncertainties in the dust lifetime calculation. The apparent need to re-form significant quantities of silicate dust in the tenuous interstellar medium may therefore not be a strong requirement. Carbonaceous matter, on the other hand, appears to be rapidly recycled in the ISM and, in contrast to silicates, there are viable mechanisms for its re-formation in the ISM.

Jones, A. P.↗

Transport of Alaskan Dust into the Gulf of Alaska and Comparison with Similar High-Latitude Dust Environments

Transport of Alaskan dust into the Gulf of Alaska and comparison with similar high-latitude dust environments. An airborne flux of the micronutrient iron, derived from dust originating from coastal regions may be an important contributor of iron to the Gulf of Alaska's (GoA) oligotrophic waters. Dust blowing off glacier termini and dry riverbeds is a recurring phenomenon in Alaska, usually occurring in the autumn. Since previous studies assumed that dust originating in the deserts of Asia was the largest source of . airborne iron to the GoA, the budget of aeolian deposition of iron needs to be reassessed. Since late 20 I 0, our group has been monitoring dust activity using satellites over the Copper River Delta (CRD) where the most vigorous dust plumes have been observed. Since 2011, sample aerosol concentration and their composition are being collected at Middleton Island (100km off shore of CRD). This presentation will show a summary of the ongoing dust observations and compare with other similar environments (Patagonia, Iceland) by showing case studies. Common features will be highlighted

Crusium, John↗

The Martian Dust Devil Electron Avalanche: Laboratory Measurements of the E-Field Fortifying Effects of Dust-Electron Absorption

Analogous to terrestrial dust devils, charged dust in Mars dust devils should become vertically stratified in the convective features, creating large scale E-fields. This E-field in a Martian-like atmosphere has been shown to stimulate the development of a Townsend discharge (electron avalanche) that acts to dissipate charge in regions where charge build-up occurs. While the stratification of the charged dust is a source of the electrical energy, the uncharged particulates in the dust population may absorb a portion of these avalanching electrons, thereby inhibiting dissipation and leading to the development of anomalously large E-field values. We performed a laboratory study that does indeed show the presence of enhanced E-field strengths between an anode and cathode when dust-absorbing filaments (acting as particulates) are placed in the avalanching electron flow. Further, the E-field threshold condition to create an impulsive spark discharge increases to larger values as more filaments are placed between the anode and cathode. We conclude that the spatially separated charged dust creates the charge centers and E-fields in a dust devil, but the under-charged portion of the population acts to reduce Townsend electron dissipation currents, further fortifying the development of larger-than-expected E-fields.

Farrell, W. M.↗

Following the Dust: Satellite Perspectives of Dust Sources, Transport, Deposition, and Impacts

Mineral dust is an integral component in the Earth system that interacts with the system's many other components involving the energy, water, and carbon cycles. Dust also degrades air quality and adversely affects human health. These interactions and impacts are not contained in regions nearby dust sources, but can reach very far because of the long-range transport on intercontinental and global scales. Satellite's routine sampling and extensive coverage in time and space makes it an ideal platform to follow the dust from sources to sinks and assess its impacts along the long journey. Dust particles are unique in their coarse size and irregular shape, which makes it feasible to distinguish them from other aerosol particles using remote sensing techniques. This talk will provide an overview of what we have learned from analyzing advanced satellite remote sensing measurements during the EOS-era supplemented by in situ observations and model simulations, including dust source characterization, seasonal and interannual variability, trans-Pacific and trans-Atlantic transport and deposition, and dust influences on the radiation budget, air quality, and ecosystems. The talk will also discuss challenges and opportunities to further improve the dust characterization and assessment of the impacts via remote sensing techniques.

Yu, Hongbin↗

Large Dust Aerosol Sizes Seen During the 2018 Martian Global Dust Event by the Curiosity Rover

Mars' atmosphere typically supports dust aerosol with an effective radius near 1.5 μm, varying from ~1 μm during low dust times near northern summer solstice to ~2 μm during higher dust times in southern spring and summer. After global dust events, size variations outside this range have not previously been observed. We report on imaging and spectral observations by the Curiosity rover through the 2018 global dust event. These observations show that the dust effective radius was seasonally normal prior to the local onset of increased opacity, increased rapidly above 4 μm with increasing opacity, remained above 3 μm over a period of ~50 Martian solar days, then returned to seasonal values before the opacity did so. This demonstrates lifting and regional‐scale transport of a dust population ~3 times the size of typical dust aerosol.

Lemmon, M. T.↗

The roles of non-extensivity and dust concentration as bifurcation parameters in dust-ion acoustic traveling waves in magnetized dusty plasma

Dust ion-acoustic traveling waves are studied in a magnetized dusty plasma in presence of static dust and non-extensive distributed electrons in the framework of Zakharov-Kuznesstov-Burgers (ZKB) equation. System of coupled nonlinear ordinary differential equations is derived from ZKB equation, and equilibrium points are obtained. Nonlinear wave phenomena are studied numerically using fourth order Runge-Kutta method. The change from unstable to stable solution and consequently to asymptotic stable of dust ion acoustic traveling waves is studied through dynamical system approach. It is found that some dramatical features emerge when the non-extensive parameter and the dust concentration parameters are varied. Behavior of the solution of the system changes from unstable to stable and stable to asymptotic stable depending on the value of the non-extensive parameter. It is also observed that when the dust concentration is increased the solution pattern is changed from oscillatory shocks to periodic solution. Thus, non-extensive and dust concentration parameters play crucial roles in determining the nature of the stability behavior of the system. Thus, the non-extensive parameter and the dust concentration parameters can be treated as bifurcation parameters.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗