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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
NASA NTRS1998

Atmospheric Aerosol Chemical Composition Measurements for the Subsonic Aircraft: Contrail and Cloud Effects Special Study (SUCCESS)

We received funding to provide measurements of the chemical composition of aerosols aboard the NASA Ames DC-8 research aircraft during the SUCCESS mission. These measurements were successfully completed and the final data resides in the Cloud I computer archive at NASA Ames Research Center. The interpretation of the data obtained on this mission over the central United States has been published in special issues of Geophysical Research Letters. The papers with the University of New Hampshire as first author constitute this report and summarize the salient features of our data. The paper by Talbot et al. discusses the impact of vertical transport on free tropospheric chemistry over the the central USA in springtime. This transport was a dominant feature of the aerosol chemistry during SUCCESS. The paper by Dibb et al. discusses aerosol chemistry specifically as it related to free tropospheric sulfate related to jet exhaust and surface sources. Somewhat surprisingly, we found that surface sources appeared to dominant the distribution of aerosol sulfate in the free troposphere. In addition to these first authored papers, researchers from the University of New Hampshire were co-authors on numerous other companion papers in the special issues.

Talbot, Robert W.↗
NASA NTRS1973

The average chemical composition of the lunar surface

The available analytical data from twelve locations on the moon are used to estimate the average amounts of the principal chemical elements (O, Na, Mg, Al, Si, Ca, Ti, and Fe) in the mare, the terra, and the average lunar surface regolith. These chemical elements comprise about 99% of the atoms on the lunar surface. The relatively small variability in the amounts of these elements at different mare (or terra) sites, and the evidence from the orbital measurements of Apollo 15 and 16, suggest that the lunar surface is much more homogeneous than the surface of the earth. The average chemical composition of the lunar surface may now be known as well as, if not better than, that of the solid part of the earth's surface.

Turkevich, A. L.↗
NASA NTRS1974

Chemical composition of cosmic rays with Z greater than or equal to 30 and E greater than or equal to 325 MeV/N

Results are presented on the chemical composition of VVH cosmic rays from a series of six high-altitude balloon flights of a large-area, high-resolution electronic detector. The charge composition in the 32 less than or equal to Z less than or equal to 45 interval is found to be inconsistent with S-process nucleosynthesis. The energy spectrum of particles with Z greater than or equal to 32 between 600 and 1500 MeV/N at the top of the atmosphere is measured and is found to be consistent with the 25 less than or equal to Z less than or equal to 27 group within experimental error.

Binns, W. R.↗
NASA NTRS1978

Relative toxicity of pyrolysis gases from materials - Effects of chemical composition and test conditions

Relative toxicity test data on 270 materials are presented, based on test procedures developed at the University of San Francisco. The effects of chemical composition, using data on 13 types of synthetic polymers and eight types of fabrics, are discussed. Selected materials were evaluated using nine test conditions with the USF method, and using methods developed at the FAA Civil Aeromedical Institute, Douglas Aircraft Company and San Jose State University.

Hilado, C. J.↗
DOE OSTI2024

Chemical compositions of semiregular variable red giants

ABSTRACT A sample of warm, low-level semiregular variables chosen from the General Catalogue of Variable Stars is studied for their chemical compositions by analysing high-resolution optical spectra. The abundance ratios from Na/Fe to Eu/Fe displayed by these and previously analysed semiregular variables are quite similar to ratios displayed by normal red giants across the Galactic thin and thick discs and halo populations in the solar neighbourhood, suggesting from this perspective that the variables may be among the more photometrically active red giants.

Pozhath, Ramya↗
NASA NTRS1975

The relation between the chemical composition of solar cosmic rays and the duration spectrum of radiosplashes

The comparison of durations of the centimeter and meter components of the radiosplashes corresponding to the chromospheric flares with the known chemical composition of the radiated nuclei has shown a greater duration of the centimeter component for the splashes wherein protons are dominating, and vice versa. A conclusion is made about the interrelation of heavy nucleus emission and the processes which occur in the upper layers of the solar corona.

Tsimakhovich, N. P.↗
NASA NTRS1985

RR Lyrae stars and the distant Galactic halo - Distribution, chemical composition, kinematics, and dynamics

Published observational data on 29 outer-Galactic-halo RR Lyr stars (Saha, 1984, and Saha and Oke, 1984) and from other surveys are analyzed to characterize the mass distribution, chemical composition, kinematics, and dynamics of the outer Galaxy (up to galactocentric radius R = 40 kpc). The results are presented in graphs and tables and discussed. Findings reported include a rapid fall-off of RR Lyr density at R = 25 kpc, Fe/H varying from -1.0 to -2.2 (with two stars at -0.5), no net Fe/H gradient in the far halo, and Galactic mass (from dynamical computations) about 3 x 10 to the 11th solar mass within R = 25 kpc.

Saha, A.↗
NASA NTRS1974

Chemical composition of boulder-2 rocks and soils, Apollo 17, Station 2

The bulk and trace element composition of five small samples from four rocks is remarkably similar. This result indicates that the metaclastic rocks studied are relatively uniform in their chemical composition. The elemental abundances found in the study are presented in two tables and the implications of the data are considered, giving attention to siderophiles, atmophile elements, and questions of element correlations. The 'dark mantle' valley soil 75081 at Camelot Crater is low in siderophiles. Since the soil is low in alkalis, a derivation from low-alkali mare basalt is suggested. The identical volatile contents in the surface soil 72461 and the 4 cm depth soil 72441 under a 0.7 m boulder argue against any surficial volatization by galactic and solar particles.

Laul, J. C.↗
NASA NTRS1986

Ultraviolet spectrum and probable chemical composition of the high-excitation planetary nebula M1-1

Data obtained with the IUE and with the image-tube scanner on the Shane 3-m telescope at the Lick Observatory were used to determine the possible chemical composition of the high excitation nebula, M1-1. Though N may be enhanced, the composition of M1-1 does not seem to differ significantly from that of the sun, in contrast to NGC 6537. M1-1 abundances do not appear to differ by more than about a factor of two from those of the mean planetaries or the sun. NGC 6537 and NGC 6302 show large effects of nuclear processing in C, N, and possibly O, while M1-1, in spite of its high excitation and presumed origin from a relatively massive star, shows insignificant effects of nuclear processing.

Aller, L. H.↗
NASA NTRS1979

Study of mass flow distribution and chemical composition of comets from solar induced X-ray fluorescence

The expected performance of an X-ray detector as an instrument aboard a mission to a comet was evaluated. The functions of the detector are both nondispersive analysis of chemical composition and measurement of mass flow from the comet nucleus. Measurements are to be carried out at a distance from the comet. The approach distances considered are of the order of 1000 km and 100 km. A new type of X-ray detector, a proportional scintillation detector, is considered as an X-ray counter for nondispersive elemental analysis.

Gorenstein, P.↗
NASA NTRS1989

Extraterrestrial spherules in glacial sediment from the Transantarctic Mountains, Antarctica - Structure, mineralogy, and chemical composition

The morphological, mineralogical, and chemical characteristics of silicate and glassy spherules from a number of new localities in the Transantarctic Mountains were determined. The results indicate that these Antarctic spherules are of extraterrestrial origin. It is concluded that they, most likely, represent individual micrometeorites that melted during passage through the atmosphere; alternatively, they may be ablation spherules.

Koeberl, Christian↗
DOE OSTI2025

Transferable predictions of energetic and structural properties for refractory solid solution alloys across chemical compositions

We present a data-efficient approach to train graph neural networks (GNNs) on density functional theory (DFT) data for accurate and transferable predictions of energetic and structural properties of refractory solid solution alloys in the niobium-tantalum-vanadium (Nb-Ta-V) chemical space. We start by training the GNN model only on DFT data that describes refractory binary alloys niobium-tantalum (Nb-Ta), niobium-vanadium (Nb-V), and tantalum-vanadium (Ta-V) to predict formation enthalpy and root mean squared displacement. Once trained, the GNN predictions are tested on DFT data describing refractory ternary alloys Nb-Ta-V. While, unsurprisingly, direct transferability from binary to ternary is not sufficiently accurate, augmenting the training with only 1% of the available ternary data (uniformly distributed across the entire range of chemical compositions) improves significantly the quality of the GNN predictions. For comparison, we assess the transferability in the opposite direction by training GNN models on ternary Nb-Ta-V data and making predictions on binaries Nb-Ta, Nb-V, and Ta-V, which exhibits notably higher predictive errors. The proposed methodology, which favors transferability from lower-component to higher-component alloys, offers an efficient path towards avoiding the curse of dimensionality incurred when collecting DFT data for discovery and design of multi-component disordered alloys.

Density functional theory calculations↗
NASA NTRS2004

Aerosol Optical Properties Measured Onboard the Ronald H. Brown During ACE Asia as a Function of Aerosol Chemical Composition and Source Region

During the ACE Asia intensive field campaign conducted in the spring of 2001 aerosol properties were measured onboard the R/V Ronald H. Brown to study the effects of the Asian aerosol on atmospheric chemistry and climate in downwind regions. Aerosol properties measured in the marine boundary layer included chemical composition; number size distribution; and light scattering, hemispheric backscattering, and absorption coefficients. In addition, optical depth and vertical profiles of aerosol 180 deg backscatter were measured. Aerosol within the ACE Asia study region was found to be a complex mixture resulting from marine, pollution, volcanic, and dust sources. Presented here as a function of air mass source region are the mass fractions of the dominant aerosol chemical components, the fraction of the scattering measured at the surface due to each component, mass scattering efficiencies of the individual components, aerosol scattering and absorption coefficients, single scattering albedo, Angstrom exponents, optical depth, and vertical profiles of aerosol extinction. All results except aerosol optical depth and the vertical profiles of aerosol extinction are reported at a relative humidity of 55 +/- 5%. An over-determined data set was collected so that measured and calculated aerosol properties could be compared, internal consistency in the data set could be assessed, and sources of uncertainty could be identified. By taking into account non-sphericity of the dust aerosol, calculated and measured aerosol mass and scattering coefficients agreed within overall experimental uncertainties. Differences between measured and calculated aerosol absorption coefficients were not within reasonable uncertainty limits, however, and may indicate the inability of Mie theory and the assumption of internally mixed homogeneous spheres to predict absorption by the ACE Asia aerosol. Mass scattering efficiencies of non-sea salt sulfate aerosol, sea salt, submicron particulate organic matter, and dust found for the ACE Asia aerosol are comparable to values estimated for ACE 1, Aerosols99, and INDOEX. Unique to the ACE Asia aerosol was the large mass fractions of dust, the dominance of dust in controlling the aerosol optical properties, and the interaction of dust with soot aerosol.

Quinn, P. K.↗
NASA NTRS2003

Mantle Metasomatism in Mars: Evidence from Bulk Chemical Compositions of Martian Basalts

Bulk compositions of martian meteorite basalts suggest that they formed from a highly depleted mantle that was variably metasomatised and enriched in incompatible elements. These results are consistent with radio-isotope results. Bulk chemical compositions of basaltic rocks retain clues and tracers to their origins and histories. Interpretations of bulk compositions are not so straight-forward as once envisioned, because real-world magmatic processes can be far from theoretical simple models like one-stage partial melting or closed-system fractional crystallization. Yet, bulk chemistry can shed a broad (if dim) light on Martian basalt petrogenesis that complements the sharply focussed illumination of radio-isotope systematics.

Treiman, A. H.↗
NASA NTRS1973

Unusual chemical compositions of noctilucent-cloud particle nuclei

Two sounding rocket payloads were launched from the ESRO range in Sweden during a noctilucent cloud display. Large numbers of submicron particles were collected, most of which appear to be made up of a high density material coated with a low density material. Typical electron micrographs are shown. Particle chemical compositions have been measured by use of dispersive X-ray analysis equipment attached to an electron microscope and have revealed that most of the high density particle nuclei have atomic weights greater than iron.

Hemenway, C. L.↗
NASA NTRS1994

Chemical compositions of primitive solar system particles

Chemical studies of micrometeorites are of fundamental importance primarily because atmospheric entry selection effects (such as destruction of friable objects) are less significant than those for conventional meteorites. As a result, particles that have experienced very little postaccretional processing have a significant chance of surviving the Earth encounter and subsequent collection. Thus, chemical analyses of these relatively unaltered micrometeorites may lead to a better understanding of the compositions of the most primitive materials in the solar system and thereby constrain the conditions (physical and chemical) that existed in the early solar nebula. Micrometeorites have been collected from the stratosphere, polar ices, and ocean sediments, but the stratospheric collection is the best source for the most unaltered material because they are small and are not heated to their melting points. Despite the fact that the stratospheric micrometeorites have masses in the nanogram range, a variety of microanalytical techniques have been applied to bulk chemical analyses with part-per-million sensitivity. In some cases, multi-disciplinary studies (e.g., chemistry and mineralogy) have been performed on individual particles. The first-order conclusion is that the chondrite-like particles are chemically similar to carbonaceous chondrites but in detail are distinct from members of the conventional meteorite collection. The purpose of this paper is to provide an overview of the results to date and identify important areas for further study.

Sutton, Steve R.↗