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Observations of high-time-resolution and size-resolved aerosol chemical composition and microphysics in the central Arctic: implications for climate-relevant particle properties

Abstract. Aerosols play a critical role in the Arctic's radiative balance, influencing solar radiation and cloud formation. Limited observations in the central Arctic leave gaps in understanding aerosol dynamics year-round, affecting model predictions of climate-relevant aerosol properties. Here, we present the first annual high-time-resolution observations of submicron aerosol chemical composition in the central Arctic during the Arctic Ocean 2018 (AO2018) and the 2019–2020 Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expeditions. Seasonal variations in the aerosol mass concentrations and chemical composition in the central Arctic were found to be driven by typical Arctic seasonal regimes and resemble those of pan-Arctic land-based stations. Organic aerosols dominated the pristine summer, while anthropogenic sulfate prevailed in autumn and spring under haze conditions. Ammonium, which impacts aerosol acidity, was consistently less abundant, relative to sulfate, in the central Arctic compared to lower latitudes of the Arctic. Cyclonic (storm) activity was found to have a significant influence on aerosol variability by enhancing emissions from local sources and the transport of remote aerosol. Local wind-generated particles contributed up to 80 % (20 %) of the cloud condensation nuclei population in autumn (spring). While the analysis presented herein provides the current central Arctic aerosol baseline, which will serve to improve climate model predictions in the region, it also underscores the importance of integrating short-timescale processes, such as seasonal wind-driven aerosol sources from blowing snow and open leads/ocean in model simulations. This is particularly important, given the decline in mid-latitude anthropogenic emissions and the increase in local ones.

Heutte, Benjamin (ORCID:0000000173727460)↗

Heat Pump Retrofits for Central Plant Hydronic Heating Systems: A Software Toolkit for Screening and Design

Retrofitting existing central plants with high-efficiency heat pump technologies can play a crucial role in achieving long-term planning goals. Modern heat pump technologies are able to use waste heat recovery to meet a building's heating demand, but there is a lack of accessible tools designed for non-HVAC experts, such as building owners, to quickly and easily conduct what-if analysis, e.g., estimating retrofit costs and payback period for their partial or full equipment replacement. This paper introduces an open-source software toolkit designed to facilitate the initial screening and decision-making of heat pump retrofits in existing central plants using a building's yearly load profile from metered or utility bill data. The toolkit evaluates the technical and economic viability of replacing traditional central plant equipment with various options including water-to-water or air-to-water heat pumps, which can provide efficient and lower-cost heating and cooling. It allows users to compare current central plant configurations with retrofit scenarios, assessing energy consumption, life-cycle costs, and environmental impact. The toolkit offers (1) a web-based tool designed for user-friendly access by a broad audience and (2) Python-based source code for researchers and engineers conducting parametric studies and design parameter optimization. The toolkit compares a typical central plant configuration to a configuration that uses a heat pump to supply hydronic heating and cooling. The output metrics include energy consumption and output of each equipment, life-cycle cost analyses and metrics, and environmental impact of the system.

Excell, L↗

Algebraic Algorithms for Betweenness and Percolation Centrality

Abstract In this paper, we explored different ways to write the algebraic version of betweenness centrality algorithm. Particularly, we focused on Brandes' algorithm. We aimed for algebraic betweenness centrality that can be parallelized easily. We proposed 3-tuple geodetic semiring as an extension to the usual geodetic semiring with 2-tuples. Using the 3-tuple geodetic semiring, Dijkstra's and Brandes' algorithm, we wrote more concise and general algebraic betweenness centrality (ABC) algorithm which is valid for weighted and directed graphs. We also proposed an alternative version of ABC using the usual geodetic semiring with 2-tuple where we used a simple way to construct shortest path tree after computing shortest path distances in the usual geodetic semiring. This allows us to avoid computational complexity of ABC implementation using 3-tuple geodetic semiring. We used numba to optimize and parallelize ABC. We evaluated the performance of ABC using 2-tuple geodetic semiring as compared to NetworkX, a common python package for graph algorithms. We did scalability experiments on parallel ABC and showed its total speedup. We also showed that with small modification, ABC can be adapted to algebraicly compute other centrality measures such as percolation centrality.

97 MATHEMATICS AND COMPUTING↗

Central station market development strategies for photovoltaics

Federal market development strategies designed to accelerate the market penetration of central station applications of photovoltaic energy system are analyzed. Since no specific goals were set for the commercialization of central station applications, strategic principles are explored which, when coupled with specific objectives for central stations, can produce a market development implementation plan. The study includes (1) background information on the National Photovoltaic Program, photovoltaic technology, and central stations; (2) a brief market assessment; (3) a discussion of the viewpoints of the electric utility industry with respect to solar energy; (4) a discussion of commercialization issues; and (5) strategy principles. It is recommended that a set of specific goals and objectives be defined for the photovoltaic central station program, and that these goals and objectives evolve into an implementation plan that identifies the appropriate federal role.

Source record↗

Power conditioning subsystems for photovoltaic central-station power plants - Technology and performance

Central-Station (CS) Photovoltaic (PV) systems have the potential of economically displacing significant amounts of centrally generated electricity. However, the technical viability and, to some extent, the economic viability of central-station PV generation technology will depend upon the availability of large power conditioners that are efficient, safe, reliable, and economical. This paper is an overview of the technical and cost requirements that must be met to develop economically viable power conditioning subsystems (PCS) for central-station power plants. The paper also examines various already commercially available PCS hardware that may be suitable for use in today's central PV power stations.

Krauthamer, S.↗

Central star formation in S0 galaxies

As a class, S0 galaxies are characterized by a lack of resolved bright stars in the disk. However, several lines of evidence support the hypothesis that a high rate of star formation is occurring at the centers of some S0 galaxies. Many of the warmest, most powerful far infrared sources in nearby bright galaxies occur in S0 galaxies. (Dressel 1988, Ap. J., 329, L69). The ratios of radio continuum flux to far infrared flux for these S0 galaxies are comparable to the ratios found for spiral galaxy disks and for star-burst galaxies. Very Large Array (VLA) maps of some of these S0 galaxies show that the radio continuum emission originates in the central few kiloparsecs. It is diffuse or clumpy, unlike the radio sources in active S0 galaxies, which are either extremely compact or have jet-lobe structures. Imaging of some of these galaxies at 10.8 microns shows that the infrared emission is also centrally concentrated. Many of the infrared-powerful S0 galaxies are Markarian galaxies. In only one case in this sample is the powerful ultraviolet emission known to be generated by a Seyfert nucleus. Optical spectra of the central few kiloparsecs of these S0 galaxies generally show deep Balmer absorption lines characteristic of A stars, and H beta emission suggestive of gas heated by O stars. A key question to our understanding of these galaxies is whether they really are S0 galaxies, or at least would have been recognized as S0 galaxies before the episode of central star formation began. Some of Nilson's classifications (used here) have been confirmed by Sandage or de Vaucouleurs and collaborators from better plates; some of the galaxies may be misclassified Sa galaxies (the most frequent hosts of central star formation); some are apparently difficult to classify because of mixed characteristics, faint non-S0 features, or peculiarities. More optical imaging is needed to characterize the host galaxies and to study the evolution of their star-forming regions.

Dressel, L. L.↗

An investigation of several NACA 1-series nose inlets with and without protruding central bodies at high-subsonic Mach numbers and at a Mach number of 1.2

An investigation of three NACA 1-series nose inlets, two of which were fitted with protruded central bodies, was conducted in the Langley 8-foot high-speed tunnel. An elliptical-nose body, which had a critical Mach number approximately equal to that of one of the nose inlets, was also tested. Tests were made near zero angle of attack for a Mach number range from 0.4 to 0.925 and for the supersonic Mach number of 1.2. The inlet-velocity-ratio range extended from zero to a maximum value of 1.34. Measurements included pressure distribution, external drag, and total-pressure loss of the internal flow near the inlet. Drag was not measured for the tests at the supersonic Mach number. Over the range of inlet-velocity ratio investigated, the calculated external pressure-drag coefficient at a Mach number of 1.2 was consecutively lower for the nose inlets of higher critical Mach number, and the pressure-drag coefficient of the longest nose inlet was in the range of pressure-drag coefficient for two solid noses of fineness ratio 2.4 and 6.0. For Mach numbers below the Mach number of the supercritical drag rise, extrapolation of the test data indicated that the external drag of the nose inlets was little affected by the addition of central bodies at or slightly below the minimum inlet-velocity ratio for unseparated central-body flow. The addition of central bodies to the nose inlets also led to no appreciable effects on either the Mach number of the supercritical drag rise, or, for inlet-velocity ratios high enough to avoid a pressure peak at the inlet lip, on the critical Mach number. The total-pressure recovery of the inlets tested, which were of a subsonic type, was sensibly unimpaired at the supersonic Mach number of 1.2 Low-speed measurements of the minimum inlet-velocity ratio for unseparated central-body flow appear to be applicable for Mach numbers extending to 1.2.

Pendley, Robert E↗

Differential scaling: Implications for central structures in large lunar craters

The change in morphology of central structures with crater size on the terrestrial planets has been studied by many investigators. While the progression of morphological change essentially follows the same basic pattern, the appearance of central peaks, and the transitions from single to multiple peaks and peaks to peak rings occur at crater diameters that appear to be dependent on parameters associated with the target planet. Statistical data, morphological information, and model results exist for central structures in large craters, but the amount of 'ground truth' is comparatively meager. What, for instance, is the amount of stratigraphic uplift in craters? Answers to questions such as this will provide useful constraints on models of origin for central structures and would help in interpretation of remote-sensing data. This contribution uses terrestrial information and model calculations to estimate the amount of stratigraphic uplift for central-peak craters on the Moon--the only planet other than Earth for which sufficient topographic data are available.

Cintala, M. J.↗

Effects of Shocks on Emission from Central Engines of Active Galactic Nuclei. I

In this paper we show that perturbations of the accretion flow within the central engines of some active galactic nuclei (AGNS) are likely to form shock waves in the accreting plasma. Such shocks, which may be either collisional or collisionless, can contribute to the observed high-energy temporal and spectral variability. Our rationale is the following: Observations show that the continuum emission probably originates in an optically thin, hot plasma in the AGN central engine. The flux and spectrum from this hot plasma varies significantly over light crossing timescales. Several authors have suggested that macroscopic perturbations contained within this plasma are the sources of this variability. In order to produce the observed emission the perturbations must be radiatively coupled with the optically thin hot matter and must also move with high velocities. We suggest that shocks, which can be very effective in randomizing the bulk motion of the perturbations, are responsible for this coupling. Shocks should form in the central engine, because the temperatures and magnetic fields are probably reduced below their virial values by radiative dissipation. Perturbations moving at Keplerian speeds, or strong non-linear excitations, result in supersonic and super-Alfvenic velocities leading to shock waves within the hot plasma. We show that even a perturbation smaller than the emitting region can form a shock that significantly modifies the continuum emission in an AGN, and that the spectral and temporal variability from such a shock generally resembles those of radio-quiet AGNS. As an example, the shock inducing perturbation in our model is a small main-sequence star, the capturing and eventual accretion of which are known to be a plausible process. We argue that shocks in the central engine may also provide a natural triggering mechanism for the "cold" component of Guilbert & Rees two-phase medium and an efficient mecha- nism for angular momentum transfer. Current and future missions, such as ASCA, XTE, XMM, AXAF, and ASTRO-E may determine the importance of shock-related emission from the central engines of AGNS.

Sivron, R.↗

Prototype Local Data Integration System and Central Florida Data Deficiency

This report describes the Applied Meteorology Unit's (AMU) task on the Local Data Integration System (LDIS) and central Florida data deficiency. The objectives of the task are to identify all existing meteorological data sources within 250 km of the Kennedy Space Center (KSC) and the Eastern Range at Cape Canaveral Air Station (CCAS), identify and configure an appropriate LDIS to integrate these data, and implement a working prototype to be used for limited case studies and data non-incorporation (DNI) experiments. The ultimate goal for running LDIS is to generate products that may enhance weather nowcasts and short-range (less than 6 h) forecasts issued in support of the 45th Weather Squadron (45 WS), Spaceflight Meteorology Group (SMG), and the Melbourne National Weather Service (NWS MLB) operational requirements. The LDIS has the potential to provide added value for nowcasts and short term forecasts for two reasons. First, it incorporates all data operationally available in east central Florida. Second, it is run at finer spatial and temporal resolutions than current national-scale operational models. In combination with a suitable visualization tool, LDIS may provide users with a more complete and comprehensive understanding of evolving fine-scale weather features than could be developed by individually examining the disparate data sets over the same area and time. The utility of LDIS depends largely on the reliability and availability of observational data. Therefore, it is important to document all existing meteorological data sources around central Florida that can be incorporated by it. Several factors contribute to the data density and coverage over east central Florida including the level in the atmosphere, distance from KSC/CCAS, time, and prevailing weather. The central Florida mesonet consists of existing surface meteorological and hydrological data available from the Tampa NWS and data servers at Miami and Jacksonville. However the utility of these data for operational use is limited, mainly because there are relatively few additional meteorological observations within 50 km of KSC/CCAS to supplement existing METAR and KSC/CCAS tower reports.

Manobianco, John↗

Evaluating Ultraviolet Radiation Exposures Determined from TOMS Satellite Data at Sites of Amphibian Declines in Central and South America

Many amphibian species have experienced substantial population declines, or have disappeared altogether, during the last several decades at a number of amphibian census sites in Central and South America. This study addresses the use of satellite-derived trends in solar ultraviolet-B (UV-B; 280-320 nm) radiation exposures at these sites over the last two decades, and is intended to demonstrate a role for satellite observations in determining whether UV-B radiation is a contributing factor in amphibian declines. UV-B radiation levels at the Earth's surface were derived from the Total Ozone Mapping Spectrometer (TOMS) satellite data, typically acquired daily since 1979. These data were used to calculate the daily erythemal (sunburning) UV-B, or UV-B(sub ery), exposures at the latitude, longitude, and elevation of each of 20 census sites. The annually averaged UV-B(sub ery) dose, as well as the maximum values, have been increasing in both Central and South America, with higher levels received at the Central American sites. The annually averaged UV-B(sub ery) exposures increased significantly from 1979-1998 at all 11 Central American sites examined (r(exp 2) = 0.60 - 0.79; P<=0.015), with smaller but significant increases at five of the nine South American sites (r(exp 2) = 0.24-0.42; P<=0.05). The contribution of the highest UV-B(sub ery) exposure levels (>= 6750 J/sq m*d) to the annual UV-B(sub ery) total has increased from approx. 5% to approx. 15% in Central America over the 19 year period, but actual daily exposures for each species are unknown. Synergy among UV-B radiation and other factors, especially those associated with alterations of water chemistry (e.g., acidification) in aqueous habitats is discussed. These findings justify further research concerning whether UV-B(sub ery) radiation plays a role in amphibian population declines and extinctions.

Middleton, Elizabeth M.↗

The UV Scattering Halo of the Central Source Associated with Eta Carinae

Eta Carinae is one of the most massive and luminous stars within our galaxy. It consists of a compact central source which suffers circumstellar and interstellar extinction, local dense knots which emit strong narrow nebular-like emission lines, and an outer dusty nebula called the Homunculus. The optical spectrum of the central star, first observed directly and without obvious nebular contamination by the HST, can be modeled successfully using a hot star with a radius (at the wind sonic point) of 60\,R\odot. The central star is losing mass, via a dense stellar wind, at the prodigious rate of 10(exp -3)\,M\odot/yr. Its effective temperature is low (< 10,000\,K), and is determined entirely by the wind properties. Until now the UV spectrum has not been explained. We show that HST UV spectrum, and the FUSE FUV spectrum, can both be understood using the same underlying model that explains the optical spectrum. To do so, however, it is necessary to take into account the occultation of the central source by dust. It is also important to realize that in the UV, the HST is partially resolving the central source. Due to strong mass loss, the wind is optically thick in UV resonance lines even at large radii. The UV resonance lines are responsible for the UV halo seen around Eta Carinae, and provide a partial explanation of why Eta Carinae can even be seen at UV wavelengths.

Hillier, D. J.↗

A Comparison of Groundwater Storage Using GRACE Data, Groundwater Levels, and a Hydrological Model in Californias Central Valley

The Gravity Recovery and Climate Experiment (GRACE) measures changes in total water storage (TWS) remotely, and may provide additional insight to the use of well-based data in California's agriculturally productive Central Valley region. Under current California law, well owners are not required to report groundwater extraction rates, making estimation of total groundwater extraction difficult. As a result, other groundwater change detection techniques may prove useful. From October 2002 to September 2009, GRACE was used to map changes in TWS for the three hydrological regions (the Sacramento River Basin, the San Joaquin River Basin, and the Tulare Lake Basin) encompassing the Central Valley aquifer. Net groundwater storage changes were calculated from the changes in TWS for each of the three hydrological regions and by incorporating estimates for additional components of the hydrological budget including precipitation, evapotranspiration, soil moisture, snow pack, and surface water storage. The calculated changes in groundwater storage were then compared to simulated values from the California Department of Water Resource's Central Valley Groundwater- Surface Water Simulation Model (C2VSIM) and their Water Data Library (WDL) Geographic Information System (GIS) change in storage tool. The results from the three methods were compared. Downscaling GRACE data into the 21 smaller Central Valley sub-regions included in C2VSIM was also evaluated. This work has the potential to improve California's groundwater resource management and use of existing hydrological models for the Central Valley.

Department of Water Resources↗

Characteristics of Precipitation Features and Annual Rainfall during the TRMM Era in the Central Andes

The central Andes extends from 7 deg to 21 deg S, with its eastern boundary defined by elevation (1000m and greater) and its western boundary by the coastline. The authors used a combination of surface observations, reanalysis, and the University of Utah Tropical Rainfall Measuring Mission (TRMM) precipitation features (PF) database to understand the characteristics of convective systems and associated rainfall in the central Andes during the TRMM era, 1998-2012. Compared to other dry (West Africa), mountainous (Himalayas), and dynamically linked (Amazon) regions in the tropics, the central Andes PF population was distinct from these other regions, with small and weak PFs dominating its cumulative distribution functions and annual rainfall totals. No more than 10% of PFs in the central Andes met any of the thresholds used to identify and define deep convection (minimum IR cloud-top temperatures, minimum 85-GHz brightness temperature, maximum height of the 40-dBZ echo). For most of the PFs, available moisture was limited (less than 35mm) and instability low (less than 500 J kg(exp -1)). The central Andes represents a largely stable, dry to arid environment, limiting system development and organization. Hence, primarily short-duration events (less than 60 min) characterized by shallow convection and light to light-moderate rainfall rates (0.5-4.0 mm h(exp -1)) were found.

Andes Mountains↗

Entropy Stable Method for the Euler Equations Revisited: Central Differencing via Entropy Splitting and SBP

The two decades old high order central differencing via entropy splitting and summation-by-parts (SBP) difference boundary closure of Ols- son & Oliger (1994), Gerritsen & Olsson (1996), and Yee et al. (2000) is revisited. The entropy splitting is a form of skew-symmetric splitting of the nonlinear Euler flux derivatives. Central differencing applied to the entropy splitting form of the Euler flux derivatives together with SBP difference operators will, hereafter, be referred to as entropy split schemes. This study is prompted by the recent growing interest in numerical methods for which a discrete entropy conservation law holds, a discrete global entropy conservation can be proved and/or the numerical method possesses a stable entropy in the framework of SBP difference operators and L2-energy norm estimate. The objective of this paper is to recast the entropy split scheme as the re- cent definition of an entropy stable method for central differencing with SBP operators for both periodic and non-periodic boundary conditions for non- linear Euler equations. Standard high order spatial central differencing as well as high order central spatial DRP (dispersion relation preserving) spatial differencing is part of the entropy stable methodology framework. Long time integration of 2D and 3D test cases is included to show the comparison of this efficient entropy stable method with the Tadmor-type of entropy conservative methods. Studies also include the comparison among the three skew-symmetric splittings on their nonlinear stability and accuracy performance without added numerical dissipations for smooth flows. These are, namely, entropy splitting, Ducros et al. splitting and the Kennedy & Grub- ber splitting.

Sjogreen, Bjorn↗

The synergistic effects of central core size and end group engineering on performance of narrow bandgap nonfullerene acceptors

Understanding the relationship between the molecular structure and photoelectric properties of fused-ring non-fullerene acceptors (NFAs) is of far-reaching significance to the development of organic solar cells (OSCs). Herein, six NFAs based on multiple thiophenes (4 T, 6 T and 8 T) are employed to systematically probe the synergistic effects of extending central core size and terminal fluorination. The absorption results manifest that the molecular absorption is comprehensively affected by molecular crystallinity, planarity, conjugation length and intramolecular electron push–pull effect, simultaneously. The intensity of electron push–pull effect is not only related to the electron-donating ability of central core and the electron-withdrawing ability of end group, but also may be related to the distance between the positive and negative centers. The extension of central core leads to the more planar backbone and stronger crystallinity of NFAs, and less energy loss (E loss ) in its based OSC. Compared with the extension of central core, terminal fluorination has a greater impact on molecular photoelectric properties. The terminal fluorination significantly enhances the push–pull effect, lowers the energy levels, and slightly increases the vibrational relaxation. As a result, the strongest crystallinity and coplanarity of 8TIC-4F lead to a low vibrational relaxation of 0.18 eV, which makes PTB7-Th:8TIC-4F device exhibit a small E loss of 0.51 eV and a high efficiency of 10.4%. In addition, the fluorinated 6TIC-4F with suitable core size exhibits suitable energy level, absorption, crystallization, and phase separation morphology, making its as-cast device up to 11.61% efficiency. Finally, to the best of the authors’ knowledge, the PCE of 11.61% for PTB7-Th:6TIC-4F based device without any treatment is one of the highest values reported for the NAFs with over 1000 nm absorption.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

How does urbanization affect CO 2 emissions of central heating systems in China? An assessment of natural gas transition policy based on nighttime light data

Understanding the different impacts of urbanization on sectorial carbon dioxide (CO 2 ) emissions at different spatial scales is of great importance for the evaluation of energy transition policies and reduction of environmental inequality. However, how urbanization affects the CO 2 emissions of central heating systems at high spatial resolution in China has not been fully studied before. Based on satellite-observed NPP-VIIRS nighttime light (NTL) data, we develop a 5 km x 5 km annual CO 2 emission inventory for coal boilers, thermal power plants (TPPs), and natural gas boilers in China's central heating systems for the period 2012-2017 by using the geographical and temporally weighted regression (GTWR) model. It is observed that nonurban areas generated 2-4 times the CO 2 emissions of coal boilers in urban areas. The largest increments of CO 2 emissions of gas boilers are observed in urban areas of the eastern (6.80 times) and central regions (2.86 times) in 2013-2014, due to the clean heating policy in the "2 + 26" cities in China. The effects of urbanization on CO 2 emissions from natural gas boilers are approximately 2-3 times those of coal boilers, and the differences are largest in western cities with only minor differences in northeastern cities. Overall, our results will aid in designing low-carbon development goals and provide micro-level information on central heating facilities in urbanized and less developed regions.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Directional Laplacian Centrality for Cyber Situational Awareness

Cyber operations is drowning in diverse, high-volume, multi-source data. To get a full picture of current operations and identify malicious events and actors, analysts must see through data generated by a mix of human activity and benign automated processes. Although many monitoring and alert systems exist, they typically use signature-based detection methods. We introduce a general method rooted in spectral graph theory to discover patterns and anomalies without a priori knowledge of signatures. We derive and propose a new graph-theoretic centrality measure based on the derivative of the graph Laplacian matrix in the direction of a vertex. To build intuition about our measure, we show how it identifies the most central vertices in standard network datasets and compare to other graph centrality measures. Finally, we focus our attention on studying its effectiveness in identifying important IP addresses in network flow data. Using both real and synthetic network flow data, we conduct several experiments to test our measure’s sensitivity to two types of injected attack profiles and show that vertices participating in injected attack profiles exhibit noticeable changes in our centrality measures, even when the injected anomalies are relatively small, and in the presence of simulated network dynamics.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗