Vapor-filled thermionic converters final report
Cesium vapor diode thermionic converter - electrode surface properties, space charge neutralization, plasma studies on arc drop
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Cesium vapor diode thermionic converter - electrode surface properties, space charge neutralization, plasma studies on arc drop
Cs seeding effect on bound-free UV photoabsorption of Cs-H plasma at constant electron density and energies below H ionization
A 20-megawatt linear plasma accelerator facility, a steady flow, Faraday-type plasma accelerator facility for high velocity aerodynamic testing, was constructed, developed, and brought to an operational status. The accelerator has a 63.5-mm-square and 0.5-meter-long channel and utilizes nitrogen-seeded with 2 % mole fraction of cesium vapor. Modification of the original accelerator design characteristics and the improvements necessary to make the arc heater a suitable plasma source are described. The measured accelerator electrode current distribution and the electrode-wall potential distributions are given. The computed and the measured values are in good agreement. Measured pitot pressure indicates that an accelerator exit velocity of 9.2 km/sec, is obtained with 30 of the 36 electrode pairs powered and corresponds to a velocity increase to about 2 1/4 times the computed entrance velocity. The computed stagnation enthalpy at the accelerator exit is 92 MJ/kg, and the mass density corresponds to an altitude of about 58 km. The 92 MJ/kg stagnation enthalpy corresponds to a kinetic energy content at low temperature equivalent to a velocity of 13.6 km/sec.
The need for protective coatings on critical optical surfaces, such as halide crystal windows or lenses used in spectroscopy, has long been recognized. It has been demonstrated that thin, one micron, organic coatings produced by polymerization of flourinated monomers in low temperature gas discharge (plasma) exhibit very high degrees of moisture resistence, e.g., hundreds of hours protection for cesium iodide vs. minutes before degradation sets in for untreated surfaces. The index of refraction of these coatings is intermediate between that of the halide substrate and air, a condition for anti-reflection, another desirable property of optical coatings. Thus, the organic coatings not only offer protection, but improved transmittance as well. The polymer coating is non-absorbing over the range 0.4 to 40 microns with an exception at 8.0 microns, the expected absorption for C-F bonds.
Lanthanum hexaboride electrodes in 1700 K cesium diodes may triple power outputs compared with those demonstrated for nuclear thermionic space applications. Still greater relative gains seem possible for emitters below 1700 K. Further improvements in cesium diode performance should result from the lower collector temperatures allowed for earth and low power space duties. Decreased temperatures will lessen thermal transport losses that attend thermionic conversion mechanisms. Such advantages will add to those from collector Carnot and electrode effects. If plasma ignition difficulties impede diode temperature reductions, recycling small fractions of the output power could provide ionization. So high efficiency, low temperature cesium diodes with lanthanum hexaboride electrodes appear feasible.
A theory of the plasmatron was developed. Also, a wide range of measurements were obtained with two versatile, research devices. To gain insight into plasmatron performance, the experimental results are compared with calculations based on the theoretical model of plasmatron operation. Results are presented which show that the plasma arc drop of the conventional arc (ignited) mode converter can be suppressed by use of an auxiliary ion source. The improved performance, however, is presently limited to low current densities because of voltage losses due to plasma resistance. This resistance loss could be suppressed by an increase in the plasma electron temperature or a decrease in spacing. Plasmatron performance characteristics for both argon and cesium are reported. The argon plasmatron has superior performance. Results are also presented for magnetic cutoff effects and for current distributing effects. These are shown to be important factors for the design of practical devices.
A detailed theoretical study of a heat-driven lamp has been performed. This lamp uses a plasma produced in a thermionic diode. The light is produced by the resonance transition of cesium. An important result of this study is that up to 30% of the input heat is predicted to be converted to light in this device. This is a major improvement over ordinary thermionic energy converters in which only approx. 1% is converted to resonance radiation. Efficiencies and optimum inter-electrode spacings have been found as a function of cathode temperature and the radiative escape factor. The theory developed explains the operating limits of the device.
The thermoelectronic laser energy converter (TELEC), was studied as a method of converting a 10.6 mm CO2 laser beam into electric power. The calculated characteristics of a TELEC seem to be well matched to the requirements of a spacecraft laser energy conversion system. The TELEC is a high power density plasma device which absorbs an intense laser beam by inverse bremsstrahlung with the plasma electrons. In the TELEC process, electromagnetic radiation is absorbed directly in the plasma electrons producing a high electron temperature. The energetic electrons diffuse out of the plasma striking two electrodes which are in contact with the plasma at the boundaries. These two electrodes have different areas: the larger one is designated as the collector, the smaller one is designated as the emitter. The smaller electrode functions as an electron emitter to provide continuity of the current. Waste heat is rejected from the collector electrode. An experiment was carried out with a high power laser using a cesium vapor TELEC cell with 30 cm active length. Laser supported plasma was produced in the TELEC device during a number of laser runs over a period of several days. Electric power from the TELEC was observed with currents in the range of several amperes and output potentials of less than 1 volt. The magnitudes of these electric outputs were smaller than anticipated but consistent with the power levels of the laser during this experiment.
Lanthanum-hexaboride electrodes in 1700 K cesium diodes may triple power outputs compared with those demonstrated for nuclear thermionic space applications. Still greater relative gains seem possible for emitters below 1700 K. Further improvements in cesium-diode performance should result from the lower collector temperatures allowed for earth and low-power-space duties. Decreased temperatures will lessen thermal-transport losses that attend thermionic-conversion mechanisms. Such advantages will add to those from collector-Carnot and electrode effects. If plasma ignition difficulties impede diode temperature reductions, recycling small fractions of the output power could provide ionization. So high-efficiency, low-temperature cesium diodes with lanthanum-hexaboride electrodes appear feasible.
Inert gases, particularly argon and xenon, are of interest as possible alternatives to the usual electric thruster propellants of mercury and cesium. Hollow cathode data were obtained for a wide range of operating conditions. Some test conditions gave plasma coupling voltages at or below the sputtering threshold, hence should permit long operating lifetimes. All observations of hollow cathode operation were consistent with a single theory of operation, in which a significant amount of the total electron emission is from localized areas within the orifice. This mode of emission is also supported by scanning electron microscope photographs that indicate local temperatures at or near the melting temperature of the tungsten tip. Experimental hollow cathode performance was correlated for two orifice diameters, three inert gas propellants, and a range of flow rates for each propellant. The basic theory for the production of doubly ionized argon and xenon was completed. Experimental measurements of the doubly ionized fraction agree with theory within about plus or minus 20 percent. High voltage isolators were studied for the propellant feed line. The breakdown voltage per segment ranged from 300 to over 500 V with argon.
A pulse detonation research engine (MSFC (Marshall Space Flight Center) Model PDRE (Pulse Detonation Rocket Engine) G-2) has been developed for the purpose of examining integrated propulsion and magnetohydrodynamic power generation applications. The engine is based on a rectangular cross-section tube coupled to a converging-diverging nozzle, which is in turn attached to a segmented Faraday channel. As part of the shakedown testing activity, the pressure wave was interrogated along the length of the engine while running on hydrogen/oxygen propellants. Rapid transition to detonation wave propagation was insured through the use of a short Schelkin spiral near the head of the engine. The measured detonation wave velocities were in excess of 2500 m/s in agreement with the theoretical C-J velocity. The engine was first tested in a straight tube configuration without a nozzle, and the time resolved thrust was measured simultaneously with the head-end pressure. Similar measurements were made with the converging-diverging nozzle attached. The time correlation of the thrust and head-end pressure data was found to be excellent. The major purpose of the converging-diverging nozzle was to configure the engine for driving an MHD generator for the direct production of electrical power. Additional tests were therefore necessary in which seed (cesium-hydroxide dissolved in methanol) was directly injected into the engine as a spray. The exhaust plume was then interrogated with a microwave interferometer in an attempt to characterize the plasma conditions, and emission spectroscopy measurements were also acquired. Data reduction efforts indicate that the plasma exhaust is very highly ionized, although there is some uncertainty at this time as to the relative abundance of negative OH ions. The emission spectroscopy data provided some indication of the species in the exhaust as well as a measurement of temperature. A 24-electrode-pair segmented Faraday channel and 0.6 Tesla permanent magnet assembly were then installed on Marshall Space Flight Center's (MSFC's) rectangular channel pulse detonation research engine. Magnetohydrodynamic (MHD) electrical power extraction experiments were carried out for a range of load impedances in which cesium hydroxide seed (dissolved in methanol) was sprayed into the gaseous oxygen/hydrogen propellants. Positive power extraction was obtained, but preliminary analysis of the data indicated that the plasma electrical conductivity is lower than anticipated and the near-electrode voltage drop is not negligible. It is believed that the electrical conductivity is reduced due to a large population of negative OH ions. This occurs because OH has a strong affinity for capturing free electrons. The effect of near-electrode voltage drop is associated with the high surface-to-volume ratio of the channel (1-inch by 1-inch cross-section) where surface effects play a dominant role. As usual for MHD devices, higher performance will require larger scale devices. Overall, the gathered data is extremely valuable from the standpoint of understanding plasma behavior and for developing empirical scaling laws.
Plasma sheath-boundary interactions, analyzing emission, reflection and surface ionization effects on current densities and heat fluxes for cesium and argon
It is shown that it is possible to controllably and continuously elevate the electron temperature in the plasmatron thermionic energy converter from the emitter temperature to the maintenance electron temperature for the diode arc mode. This ability and the apparent validity of an elementary analytical model of the plasma should make possible the optimization and evaluation of operation under strong ionization conditions for which the plasma resistance should be acceptably low. Measurement of the vacuum space charge arising from the emission from a surface in cesium vapor indicates the presence of a substantial negative ion emission current. Apparatus has been constructed for identifying and directly measuring the flux of positive, negative and neutral species emitted from an electrode surface in a cesium vapor diode. The primary purpose of the investigation is to determine the influence of negative ion emission on the effective work function of thermionic converter electrodes. Initial data indicate the presence of H(-), Cs(-) and possibly C(-) and CH(-).
Line widths of the Ca(II) 3968 A and Na(I) 5890 A resonance lines broadened by electric microfields in a plasma were measured. A pressure-driven shock tube was used as the light source. Radiation from the equilibrium region behind the reflected shock wave was studied using a rapid scanning Fabry-Perot interferometer. Electron and argon atom densities of about 8 x 10 to the 16th and 1 x 10 to the 19th/cu cm, respectively, were achieved at the relatively low temperature of around 7500 K by vaporizing a cesium powder that had been added to the shock tube as a solid aerosol in argon gas. The measured line widths were predominantly Stark broadened by the electrons and ions in the plasma, although Doppler, van der Waals, instrument function and optical depth effects had to be taken into account.
In this study, the performance of a current-regulated arc modulator was investigated with a focus on its role in initiating and sustaining plasma discharge within the Magnetron Body of the LINAC system. The analysis centered on how switching components, circuit topology, and feedback loop architecture influence critical factors such as energy efficiency, discharge stability, and long-term plasma containment. Particular attention was given to variations in pulse termination behavior, as observed through oscilloscope traces, which revealed inconsistencies affecting the duty factor and cathode temperature. These fluctuations have downstream effects on the cesium-coated cathode surface, thereby impacting H⁻ ion production and beam reliability. Simulation-based testing in LTspice was used to evaluate noise suppression techniques and arc current regulation schemes, revealing how optimized snubber networks, improved pulse shaping, and feedback stability can mitigate modulator-induced noise. The results identified hardware level parameters that significantly enhance discharge repeatability and improve overall plasma performance under operational conditions.
The prospects for realizing an integrated pulse detonation propulsion and magnetohydrodynamic (MHD) power system are examined. First, energy requirements for direct detonation initiation of various fuel-oxygen and fuel-air mixtures are deduced from available experimental data and theoretical models. Second, the pumping power requirements for effective chamber scavenging are examined through the introduction of a scavenging ratio parameter and a scavenging efficiency parameter. A series of laboratory experiments were carried out to investigate the basic engineering performance characteristics of a pulse detonation-driven MHD electric power generator. In these experiments, stoichiometric oxy-acetylene mixtures seeded with a cesium hydroxide/methanol spray were detonated at atmospheric pressure in a 1-m-long tube having an i.d. of 2.54 cm. Experiments with a plasma diagnostic channel attached to the end of the tube confirmed the attainment of detonation conditions (p2/p1 approximately 34 and D approximately 2,400 m/sec) and enabled the direct measurement of current density and electrical conductivity (approximately = 6 S/m) behind the detonation wave front, In a second set of experiments, a 30-cm-long continuous electrode Faraday channel, having a height of 2.54 cm and a width of 2 cm, was attached to the end of the tube using an area transition duct. The Faraday channel was inserted in applied magnetic fields of 0.6 and 0.95 T, and the electrodes were connected to an active loading circuit to characterize power extraction dependence on load impedance while also simulating higher effective magnetic induction. The experiments indicated peak power extraction at a load impedance between 5 and 10 Omega. The measured power density was in reasonable agreement with a simple electrodynamic model incorporating a correction for near-electrode potential losses. The time-resolved thrust characteristics of the system were also measured, and it was found that the NM interaction exerted a negligible influence on system thrust and that the measured I(sub sp) of the system (200 see) exceeded that computed for an equivalent nozzleless rocket (120 see).
The prospects for realizing an integrated pulse detonation propulsion and magnetohydrodynamic (MHD) power system are examined. First, energy requirements for direct detonation initiation of various fuel-oxygen and fuel-air mixtures are deduced from available experimental data and theoretical models. Second, the pumping power requirements for effective chamber scavenging are examined through the introduction of a scavenging ratio parameter and a scavenging efficiency parameter. A series of laboratory experiments were carried out to investigate the basic engineering performance characteristics of a pulse detonation-driven MHD electric power generator. In these experiments, stoichiometric oxy-acetylene mixtures seeded with a cesium hydroxide/methanol spray were detonated at atmospheric pressure in a 1-m-long tube having an i.d. of 2.54 cm. Experiments with a plasma diagnostic channel attached to the end of the tube confirmed the attainment of detonation conditions (p(sub 2)/p(sub 1) approx. 34 and D approx. 2,400 m/sec) and enabled the direct measurement of current density and electrical conductivity (=6 S/m) behind the detonation wave front. In a second set of experiments, a 30-cm-long continuous electrode Faraday channel, having a height of 2.54 cm and a width of 2 cm, was attached to the end of the tube using an area transition duct. The Faraday channel was inserted in applied magnetic fields of 0.6 and 0.95 T. and the electrodes were connected to an active loading circuit to characterize power extraction dependence on load impedance while also simulating higher effective magnetic induction. The experiments indicated peak power extraction at a load impedance between 5 and 10 Ohm. The measured power density was in reasonable agreement with a simple electrodynamic model incorporating a correction for near-electrode potential losses. The time-resolved thrust characteristics of the system were also measured, and it was found that the MHD interaction exerted a negligible influence on system thrust and that the measured I(sub sp) of the system (200 sec) exceeded that computed for an equivalent nozzleless rocket (120 sec).
The efficiency with which heat may be converted into resonance radiation in a cesium thermionic diode is investigated theoretically. An analytical model of a thermionic converter is used which combines the coupled effects of line radiation transport, excited-state kinetics, and plasma diffusion. Operating regimes are established for various degrees of optical density in the plasma. The results indicate that monochromatic radiation can be produced with efficiencies on the order of 30 percent, provided that there is an adequate voltage drop across the plasma. A drop of 1 V was used since it can be maintained without any electrical power input to the device. It is found that high efficiencies are ude to the higher interelectrode distances which the solutions accommodate, and that radiation can be generated efficiently, even with optically dense gases.