Measurement of the Born cross sections for e + e − → D s + D s 1 ( 2460 ) − + c . c . and e + e − → D s * + D s 1 ( 2460 ) − + c . c .
Not Available
72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
SEARCH · Engineering Papers
Results for “C”
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Search for ϒ ( 1 S , 2 S ) → Z c + Z c ( ′ ) − and e + e − → Z c + Z c ( ′ ) − at s = 10.52 , 10.58, and 10.867 GeV
Not Available
43 PARTICLE ACCELERATORS↗
Evidence of the h c → K S 0 K + π − + c . c . decay
Based on ( 2.712 ± 0.014 ) × 10 9 ψ ( 3686 ) events collected by the BESIII Collaboration, evidence of the hadronic decay h c → K S 0 K + π − + c . c . is found with a significance of 4.3 σ in the ψ ( 3686 ) → π 0 h c process. The branching fraction of h c → K S 0 K + π − + c . c . is measured to be ( 7.3 ± 1.8 ± 0.8 ) × 10 − 4 , where the first and second uncertainties are statistical and systematic, respectively. Combining with the exclusive decay width of η c → K K ¯ π , our result indicates inconsistencies with both pQCD and NRQCD predictions. Published by the American Physical Society 2024
Ablikim, M.↗
A Metal‐Organic Framework with Nonpolar Pore Surfaces for the One‐Step Acquisition of C 2 H 4 from a C 2 H 4 and C 2 H 6 Mixture
Abstract Because C 2 H 4 plays an essential role in the chemical industry, economical and energy‐efficient separation of ethylene (C 2 H 4 ) from ethane (C 2 H 6 ) is extremely important. With the exception of energy‐intensive cryogenic distillation, there are few one‐step methods to obtain polymer‐grade (≥99.95 % pure) C 2 H 4 from C 2 H 4 /C 2 H 6 mixtures. Here we report a highly stable metal‐organic‐framework (MOF) FJI‐H11‐Me(des) (FJI‐H=Hong's group in Fujian Institute of Research on the Structure of Matter) which features one‐dimensional hexagonal nonpolar pore surfaces constructed by aromatic rings and alkyl groups. This FJI‐H11‐Me(des) adsorbs C 2 H 6 rather than C 2 H 4 between 273 and 303 K. Practical breakthrough experiments with C 2 H 4 containing 1 % C 2 H 6 have shown that FJI‐H11‐Me(des) can realize the acquisition in one‐step of polymer‐grade, 99.95 % pure C 2 H 4 under various conditions including different gas flow rates, temperatures and relative humidity.
Di, Zhengyi↗
Inclusive and exclusive measurements of B decays to χ c 1 and χ c 2 at Belle
We report inclusive and exclusive measurements for χ c1 and χ c2 production in B decays. We measure B(B→ χc1 X) = (3.03 ± 0.05(stat) ± 0.24(syst)) × 10 –3 and B(B→χ c2 X) = (0.70 ± 0.06(stat) ± 0.10(syst)) × 10 –3 . For the first time, χ c2 production in exclusive B decays in the modes B 0 →χ c2 π – K + and B + →χ c2 π + π – K + has been observed, along with first evidence for the B + →χ c2 π + K$^{0}_{S}$ decay mode. For χ c1 production, we report the first observation in the B + →χ c1 π + π – K + , B 0 →χ c1 π + π – K$^{0}_{S}$ and B 0 →χ c1 π 0 π – K + decay modes. Using these decay modes, we observe a difference in the production mechanism of χ c2 in comparison to χ c1 in B decays. In addition, we report searches for X(3872) and χ c1 (2P) in the B + →(χ c1 π + π – )K + decay mode. In conclusion, the reported results use 772 × 10 6 BB¯ events collected at the Υ(4S) resonance with the Belle detector at the KEKB asymmetric-energy e + e – collider.
72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
Search for the rare decays J / ψ → D 0 e + e - + c . c . and ψ ( 3686 ) → D 0 e + e - + c . c .
Using the data samples of (1310.6 ± 7.2) × 10 6 J / ψ events and (448.1 ± 2.9) × 106 (3686) events collected with the BESIII detector, we search for the rare decays J / ψ → D 0 e + e - + c.c. and (3686) → D 0 e + e - + c.c.. No significant signals are observed and the corresponding upper limits on the branching fractions at the 90% confidence level are determined to be B( J / ψ → D0e+e- + c.c.) < 8.5 × 10 -8 and B( (3686) → D0e+e- + c.c.) < 1.4 × 10 -7 , respectively. Our limit on B( J / ψ → D 0 e + e - + c.c.) is more stringent by two orders of magnitude than the previous results, and the B( (3686) → D 0 e + e - + c.c.) is measured for the first time.
73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
Measurement of the branching fractions of the decays Λ c + → Λ K S 0 K + , Λ c + → Λ K S 0 π + , and Λ c + → Λ K * +
Studies are performed of the Cabibbo-favored decay Λ c + → Λ K S 0 K + and the singly Cabibbo-suppressed decay Λ c + → Λ K S 0 π + , based on a sample of e + e − collision data, corresponding to an integrated luminosity of 4.5 fb − 1 , accumulated at center-of-mass energies between 4599.53 MeV and 4698.82 MeV with the BESIII detector. The decay Λ c + → Λ K S 0 π + is observed for the first time. The branching fractions of Λ c + → Λ K S 0 K + and Λ c + → Λ K S 0 π + are measured to be ( 3.04 ± 0.30 ± 0.16 ) × 10 − 3 and ( 1.73 ± 0.27 ± 0.10 ) × 10 − 3 , respectively, where the first uncertainties are statistical and the second are systematic. These results correspond to the most precise measurement of these quantities for both decays. Evidence of a K * + contribution in the Λ c + → Λ K S 0 π + decay is found with a statistical significance of 4.71 σ . The branching fraction of Λ c + → Λ K * + is calculated under three possible interference scenarios, with the significance increasing to 5.03 σ when interference is taken into account. Published by the American Physical Society 2025
Ablikim, M.↗
A Combined Crossed Molecular Beam and Theoretical Investigation of the Elementary Reaction of Tricarbon (C 3 (X 1 Σ g + )) with Diacetylene (C 4 H 2 (X 1 Σ g + )): Gas Phase Formation of the Heptatriynylidyne Radical ( l -C 7 H(X 2 Π))
An elucidation of the underlying formation pathways to acyclic hydrocarbons such as polyynes (C n H 2 ), cumulenes (C n H 2 ), and linear resonantly stabilized linear radicals (l-C n H) is indispensable to understand the hydrocarbon chemistry in extreme low and high temperature environments. In this study, we exploited the crossed molecular beam technique to investigate the reaction of tricarbon C 3 (X 1 Σ g + ) with diacetylene (butadiyne; HCCCCH; X 1 Σ g + ) at a collision energy of 47 ± 1 kJ mol ⁻1 . The experimental data were merged with ab initio calculations of the singlet C 7 H 2 potential energy surface (PES) revealing that the reaction is initiated via the formation of an initial van der Waals reactant complex in the entrance channel. Subsequent rearrangements lead to various carbene-type and cyclic intermediates via ring-opening, ring-closure, and hydrogen migration processes eventually forming acyclic C 7 H 2 isomers prior to their barrierless unimolecular decomposition to the most stable linear isomer, heptatriynylidyne (C 7 H, X 2 Π) in an overall endoergic reaction (+57 kJ mol ⁻1 ). The reaction exhibits strong similarities to the tricarbon – acetylene (C 3 – C 2 H 2 ). Furthermore, the significant energy threshold suggests that the tricarbon reaction with (poly)acetylenes forming resonantly stabilized linear radicals are open in high-temperature environments such as combustion flames and circumstellar envelopes of carbon stars and planetary nebulae as their descendants; however, these reactions are closed in low-temperature environments as in cold molecular clouds and hydrocarbon-rich atmospheres of planets and their moons such as in Titan.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Distinguishing artificial and essential symmetry breaking in a single determinant: approach and application to the C 60 , C 36 , and C 20 fullerenes
We present a thorough analysis of symmetry breaking observed in Hartree–Fock (HF) solutions of the C 60 , C 36 , and C 20 fullerenes in order to characterize the nature of electron correlation in them. Our analysis is based on (1) the critical regularization strength to restore symmetry breaking in the recently developed regularized orbital optimized second-order Møller–Plesset perturbation theory (κ-OOMP2), (2) singlet–triplet gaps from various MP2 methods, and (3) natural orbital occupation numbers from restricted coupled-cluster with singles and doubles (RCCSD) and coupled-cluster valence bond with singles and doubles (CCVB-SD). Based on these three independent probes, we conclude that C 36 (D6h) exhibits genuine strong correlation and symmetry breaking whereas C 60 exhibits artificial HF symmetry breaking and is not strongly correlated. Investigating the critical regularization strength, we discuss strong correlation in C 20 at the Jahn–Teller distorted geometries (C 2h , D 2h , C i , and D 3h ) and the Ih geometry. Only C 20 (I h ) was found to be strongly correlated while others exhibit artificial HF symmetry breaking. This analysis highlights a useful feature of the recommended κ-OOMP2 method. It is an electronic structure method that describes dynamic correlation, and attenuates strong correlation in MP2 towards zero by regularization. Therefore, κ-OOMP2 will exhibit symmetry breaking in its reference determinant only when correlation is strong (i.e., essential symmetry breaking). Furthermore, artificial symmetry breaking (arising in HF due to neglect of dynamic correlation) thus appears to be removed in κ-OOMP2.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
C–O cleavage of diphenyl ether followed by C–C coupling reactions over hydrophobized Pd/HY catalysts
The catalytic conversion of diphenyl ether (DPE), a dimeric model compound representing 4-O-5 lignin linkages, has been investigated using a hydrophobized bifunctional Pd/HY catalyst since the hydrophobicity of the catalyst significantly improved conversion and carbon balance. Partial hydrogenation of DPE was found to be an essential step before C–O bond cleavage and C–C bond formation, which are the target reactions in this study. The main products resulting from the C–O cleavage are phenol and cyclohexanone, which subsequently can undergo C–C coupling via alkylation and aldol condensation. In conclusion, the balance between hydrogenation activity of the metal and the acidic function of zeolite was found to play an important role for maximizing the yield of C–C coupling products, which are desirable in the upgrading of lignin-derived compounds to fuel components.
09 BIOMASS FUELS↗
Cleavage of C-O and C-C Bonds in Lignin-Derived Compounds to Produce Aromatics Using Molybdenum-Containing MFI Zeolites
Lignin, the most abundant source of renewable arenes, is a viable feedstock for the production of aromatic compounds. However, the prevalence of resilient C-C bonded oligomeric fragments in lignin-derived streams can compromise monomer yields during reductive catalytic fractionation (RCF). To address this issue, we developed a bifunctional molybdenum-containing MFI (Mo/H-MFI) zeolite catalyst capable of cleaving both C-O and C-C bonds in lignin-derived molecules to produce aromatic monomers. Using propylguaiacol as a model compound, we demonstrated the importance of proximity between metallic molybdenum carbide sites and the Bronsted acid sites in the zeolite in achieving high carbon yields (~80%) of benzene, toluene, propylbenzene, and phenol while maintaining catalyst stability (>98% stable conversion for 20 h). A reaction network involving both C-O and C-C bond cleavage pathways was proposed based on kinetic studies using key intermediates as feeds. Finally, we successfully depolymerized partially deoxygenated lignin oil obtained from the RCF of poplar using a continuous, two-pass catalytic process. This work highlights the potential of the bifunctional Mo/H-MFI catalyst in upgrading complex lignin feedstocks and provides a methodological approach for converting lignin-derived compounds into platform aromatic chemicals.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Study of excited Ξ c states decaying into Ξ c 0 and Ξ c + baryons
Here, with a data sample of 980 fb - 1 of e + e - annihilation data taken with the Belle detector operating at the KEKB asymmetric-energy e + e - collider, we discuss the results of a study of excited Ξ c states that decay, via the emission of photons and/or charged pions, into Ξ c 0 or Ξ c + ground state charmed-strange baryons. We present new measurements of the masses of all members of the Ξ c ' , Ξ c ( 2645 ) , Ξ c ( 2790 ) , Ξ c ( 2815 ) , and Ξ c ( 2980 ) isodoublets, measurements of the intrinsic widths of those that decay strongly, and evidence of previously unknown transitions.
72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
Identification of a small tetraheme cytochrome c and a flavocytochrome c as two of the principal soluble cytochromes c in Shewanella oneidensis strain MR1
Two abundant, low-redox-potential cytochromes c were purified from the facultative anaerobe Shewanella oneidensis strain MR1 grown anaerobically with fumarate. The small cytochrome was completely sequenced, and the genes coding for both proteins were cloned and sequenced. The small cytochrome c contains 91 residues and four heme binding sites. It is most similar to the cytochromes c from Shewanella frigidimarina (formerly Shewanella putrefaciens) NCIMB400 and the unclassified bacterial strain H1R (64 and 55% identity, respectively). The amount of the small tetraheme cytochrome is regulated by anaerobiosis, but not by fumarate. The larger of the two low-potential cytochromes contains tetraheme and flavin domains and is regulated by anaerobiosis and by fumarate and thus most nearly corresponds to the flavocytochrome c-fumarate reductase previously characterized from S. frigidimarina to which it is 59% identical. However, the genetic context of the cytochrome genes is not the same for the two Shewanella species, and they are not located in multicistronic operons. The small cytochrome c and the cytochrome domain of the flavocytochrome c are also homologous, showing 34% identity. Structural comparison shows that the Shewanella tetraheme cytochromes are not related to the Desulfovibrio cytochromes c(3) but define a new folding motif for small multiheme cytochromes c.
Cytochrome c Group/chemistry/genetics/metabolism↗
Carbonation of C–S–H and C–A–S–H samples studied by {sup 13}C, {sup 27}Al and {sup 29}Si MAS NMR spectroscopy
Synthesized calcium silicate hydrate (C–S–H) samples with Ca/Si ratios of 0.66, 1.0, and 1.5 have been exposed to atmospheric CO{sub 2} at room temperature and high relative humidity and studied after one to 12 weeks. {sup 29}Si NMR reveals that the decomposition of C–S–H caused by carbonation involves two steps and that the decomposition rate decreases with increasing Ca/Si ratio. The first step is a gradual decalcification of the C–S–H where calcium is removed from the interlayer and defect sites in the silicate chains until Ca/Si = 0.67 is reached, ideally corresponding to infinite silicate chains. In the seconds step, calcium from the principal layers is consumed, resulting in the final decomposition of the C–S–H and the formation of an amorphous silica phase composed of Q{sup 3} and Q{sup 4} silicate tetrahedra. The amount of solid carbonates and of carbonate ions in a hydrous environment increases with increasing Ca/Si ratio for the C–S–H, as shown by {sup 13}C NMR. For C–A–S–H samples with Ca/Si = 1.0 and 1.5, {sup 27}Al NMR demonstrates that all aluminium sites associated with the C–S–H are consumed during the carbonation reactions and incorporated mainly as tetrahedral Al(–OSi){sub 4} units in the amorphous silica phase. A small amount of penta-coordinated Al sites has also been identified in the silica phase.
36 MATERIALS SCIENCE↗
Raman spectroscopy of isotopically pure ({sup 12}C, {sup 13}C) and isotopically mixed ({sup 12.5}C) diamond single crystals at ultrahigh pressures
The Raman scattering by isotopically pure {sup 12}C and {sup 13}C diamond single crystals and by isotopically mixed {sup 12.5}C diamond single crystals is studied at a high accuracy. The studies are performed over a wide pressure range up to 73 GPa using helium as a hydrostatic pressure-transferring medium. It is found that the quantum effects, which determine the difference between the ratio of the Raman scattering frequencies in the {sup 12}C and {sup 13}C diamonds and the classical ratio (1.0408), increase to 30 GPa and then decrease. Thus, inversion in the sign of the quantum contribution to the physical properties of diamond during compression is detected. Our data suggest that the maximum possible difference between the bulk moduli of the {sup 12}C and {sup 13}C diamonds is 0.15%. The investigation of the isotopically mixed {sup 12.5}C diamond shows that the effective mass, which determines the Raman frequency, decreases during compression from 12.38 au at normal pressure to 12.33 au at 73 GPa.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Insights into hydrocarbon chain and aromatic ring formation in the interstellar medium: computational study of the isomers of C{sub 4}H{sub 3}{sup +} C{sub 6}H{sub 3}{sup +} and C{sub 6}H{sub 5}{sup +} and their formation pathways
Small hydrocarbons such as acetylene is present in circumstellar envelopes of carbon-rich stars, but the processes that yield larger molecules, and eventually polycyclic aromatic hydrocarbons (PAHs), remain poorly understood. To gain additional insight into the early steps of such processes, electronic structure calculations were performed on the potential energy surfaces of C{sub 4}H{sub 3}{sup +}, C{sub 6}H{sub 3}{sup +} and C{sub 6}H{sub 5}{sup +}. The results establish reactive pathways from acetylene and its ion to formation of the first aromatic ring. We characterize the stable isomers, their spectroscopic properties, and many of the transition structures that represent barriers to isomerization. The pathways to stabilized C{sub 4}H{sub 3}{sup +} and C{sub 6}H{sub 3}{sup +} are most likely to arise from unimolecular decomposition of hot C{sub 4}H{sub 4}{sup +} and C{sub 6}H{sub 4}{sup +} by H atom elimination. By contrast, we found an ion-molecule pathway to C{sub 6}H{sub 5}{sup +} to be very stable to fragmentation and elimination reactions even without collisional stabilization. This aromatic species is a good nucleation center for the growth of larger PAHs in interstellar conditions.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Optical Properties of Two-Dimensional Perovskite Films of (C 6 H 5 C 2 H 4 NH 3 ) 2 [PbI 4 ] and (C 6 H 5 C 2 H 4 NH 3 ) 2 (CH 3 NH 3 ) 2 [Pb 3 I 10 ]
The temperature dependence of absorption and photoluminescence (PL) spectroscopies were used to study the optical properties of 2D perovskite films, including n = 1 and 3 of (PEA) 2 (CH 3 NH 3 ) n-1 [Pb n I 3n+1 ] (PEA = C 6 H 5 (CH 2 ) 2 NH 3 ). In (PEA) 2 [Pb 1 I 4 ] (PEPI), excitons coupling to optical phonons with an average energy of ~30 meV dominate the photophysics of absorption and PL. (PEA) 2 (CH 3 NH 3 ) 2 [Pb 3 I 10 ] (shortened as PMPI 3 ), nominally prepared as n = 3, actually was a mixture of multiple layered perovskites with various n. In absorption, a PMPI 3 film presents respective n materials' excitonic features, coupling to phonons with an average energy of ~30 meV; in analyzing PL peaked singly at ~1.6 eV and its width as a function of temperature, we found that PMPI 3 behaves like PEPI at around 80 K but like 3D perovskite near room temperature, with three times larger electron-phonon interaction strength compared to that in PEPI.
14 SOLAR ENERGY↗
Tests of C P T symmetry in B 0 - B ¯ 0 mixing and in B 0 → c c ¯ K 0 decays
Here, using the eight time dependences e- Γt (1 + C i cos Δmt + S i sin Δmt) for the decays Y(4S)→B 0 $\bar{B}$ 0 →f j f k , with the decay into a flavor-specific state f j = ± X before or after the decay into a CP eigenstate f k =c$\bar{c}$ K S,L , as measured by the BABAR experiment, we determine the three CPT-sensitive parameters Re(z) and Im(z) in B 0 $\bar{B}$ 0 mixing and |$\bar{A}$/A| in B 0 →c$\bar{c}$ K 0 decays. We find Im(z) = 0.010 ± 0.030 ± 0.013, Re(z) = -0.065 ± 0.028 ± 0.014, and |$\bar{A}$/A|=0.999±0.023±0.01, in agreement with CPT symmetry.
72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗