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NASA NTRS2008

Nanocomposites with high thermoelectric figures of merit

The present invention is generally directed to nanocomposite thermoelectric materials that exhibit enhanced thermoelectric properties. The nanocomposite materials include two or more components, with at least one of the components forming nano-sized structures within the composite material. The components are chosen such that thermal conductivity of the composite is decreased without substantially diminishing the composite's electrical conductivity. Suitable component materials exhibit similar electronic band structures. For example, a band-edge gap between at least one of a conduction band or a valence band of one component material and a corresponding band of the other component material at interfaces between the components can be less than about 5k.sub.BT, wherein k.sub.B is the Boltzman constant and T is an average temperature of said nanocomposite composition.

Chen, Gang↗

NASA NTRS2012

Nanocomposites with high thermoelectric figures of merit

Chen, Gang↗

NASA NTRS2015

Nanocomposites with High Thermoelectric Figures of Merit

The present invention is generally directed to nanocomposite thermoelectric materials that exhibit enhanced thermoelectric properties. The nanocomposite materials include two or more components, with at least one of the components forming nano-sized structures within the composite material. The components are chosen such that thermal conductivity of the composite is decreased without substantially diminishing the composite's electrical conductivity. Suitable component materials exhibit similar electronic band structures. For example, a band-edge gap between at least one of a conduction band or a valence band of one component material and a corresponding band of the other component material at interfaces between the components can be less than about 5k(sub B)T, wherein k(sub B) is the Boltzman constant and T is an average temperature of said nanocomposite composition.

Chen, Gang↗

NASA NTRS1986

Simulations of gravity waves in frontal zones

Recent observations of frontal systems passing over the PROFS network in Colorado by Shapiro (1984) indicate the horizontal scale of some fronts can be on the order of a few kilometers or less. Motivated by Shapiros results, esearchers re-ran an earlier numerical simulation of frontogenesis by Williams (1972) (where a very simple stretching deformation forcing of a front is considered) using as high a resolution in both the vertical and horizontal as was possible. Highest resolution that we considered consisted of a grid with a vertical spacing of 32 meters and a horizontal spacing of 260 meters in the immediate vicinity of the surface front. The purpose was to examine development of the frontal structures as the scale of the front became very small. Two sources for banded structures in clouds were found: (1) in the stationary waves above the front and (2) in waves propagating upward from breaking waves under the front.

Gall, R.↗

NASA NTRS1996

Electronic Structure of TIBa(sub 2)CaCu(sub 2)O(sub 7-delta)

The core levels of TIBa(sub 2)CaCu(sub 2)O(sub 7-delta) epitaxial films have been measured with x-ray photoelectron spectroscopy (XPS). The valence electronic structure has been determined using the full-potential linear muffin tin orbital band structure method and measured with XPS.

Epitaxial films van Hove Fermi level↗

NASA NTRS1996

Comparison of Non-Parabolic Hydrodynamic Simulations for Semiconductor Devices

Parabolic drift-diffusion simulators are common engineering level design tools for semiconductor devices. Hydrodynamic simulators, based on the parabolic band approximation, are becoming more prevalent as device dimensions shrink and energy transport effects begin to dominate device characteristic. However, band structure effects present in state-of-the-art devices necessitate relaxing the parabolic band approximation. This paper presents simulations of ballistic diodes, a benchmark device, of Si and GaAs using two different non-parabolic hydrodynamic formulations. The first formulation uses the Kane dispersion relationship in the derivation of the conservation equations. The second model uses a power law dispersion relation {(hk)(exp 2)/2m = xW(exp Y)}. Current-voltage relations show that for the ballistic diodes considered. the non-parabolic formulations predict less current than the parabolic case. Explanations of this will be provided by examination of velocity and energy profiles. At low bias, the simulations based on the Kane formulation predict greater current flow than the power law formulation. As the bias is increased this trend changes and the power law predicts greater current than the Kane formulation. It will be shown that the non-parabolicity and energy range of the hydrodynamic model based on the Kane dispersion relation are limited due to the binomial approximation which was utilized in the derivation.

Smith, A. W.↗

NASA NTRS1997

Electronic Structure of TlBa2CaCu2O(7-Delta)

The core levels of TlBa2CaCu2O(7-delta) (Tl-1212) epitaxial films have been measured with X-ray photoelectron spectroscopy (XPS). The valence electronic structure has been determined using the full-potential linear muffin-tin-orbital band-structure method and measured with XPS. The calculations show that a van Hove singularity (VHS) lies above the Fermi level (E(sub F)) for the stoichiometric compound (delta = 0.5), while for 50% oxygen vacancies in the Tl-O layer (delta = 0.5) E(sub F) is in close proximity to the VHS. Samples annealed in nitrogen (to reduce the hole overdoping by the removal of oxygen) exhibit higher core-level binding energies and a higher T(sub c), consistent with a shift of E(sub F) closer to the VHS. Comparisons are made to the core levels and valence bands of Tl2Ba2CaCu2O(8 + delta)(Tl-2212) and HgBa2CaCu2O)6 + delta) (Hg- 1212). The similarity of the Cu 2p(sub 3/2) spectra for Tl-1212 and Tl-2212 indicates that the number of Tl-O layers has little effect on the Cu-O bonding. However, the Tl-1212 and Hg-1212 Cu 2p(sub 3/2) signals exhibit differences which suggest that the replacement of T(sup 3+) with Hg(sup 2+) results in a decrease in the O 2p right arrow Cu 3d charge-transfer energy and differences in the probabilities of planar vs apical oxygen charge transfer and/or Zhang-Rice singlet-state formation. Differences between the Tl-1212 and the Tl-2212 and Hg-1212 measured valence bands are consistent with the calculated Cu 3d and (Tl,Hg) 6s/5d partial densities of states.

Vasquez, R. P.↗

NASA NTRS1986

Semiconductor superlattice photodetectors

Technical progress made in the study of superlattice photoconductors is summarized and papers submitted for publication are listed. Since the quantum-well regions may contain several subbands, each of which may be occupied by electrons depending on the doping concentrations, it is important to include the multi-subbands in calculating the impact ionization rate. The electrons occupying the higher subbands require a smaller amount of energy to get out of the quantum well; thus, those higher level subband electrons contribute significantly to the impact ionization rate. The results of the subbands have been calculated. Results concerning the nonparabolicity effect of the band structure, the effect of the quantum-well size, and the effect of the band-edge discontinuity and doping are also summarized.

Chuang, S. L.↗

NASA NTRS1992

Raman spectra of seven interplanetary dust particles

The Raman shift spectra of seven interplanetary dust particles, U2034(F10), U2034(F8), U2022(B1), W7074 18, W7074 C15, W7074 C3 and W7074 A7, were measured with a Spex-1403 Raman spectrograph. The exciting radiations were the 488 nm and 514 nm line of a 5W argon ion laser. All seven spectra exhibit the 1350 and 1600 Delta/cm arbon bands, implying that the Interplanetary dust particles were coated with hydrocarbon and incompletely crystallized carbon, the part of which may be the residue of hydrocarbon contents in the particles after water loss by the heating during their entry into the earth's atmosphere. A weak band structure in the 520-610/cm range could be caused by cyclosilicates, and a weak band at 2900/cm is tentatively identified as due to hydrocarbon molecules.

Xu, Yin-Lin↗

NASA NTRS1990

Resonant tunneling IR detectors

Researchers propose a novel semiconductor heterojunction photodetector which would have a very low dark current and would be voltage tunable. A schematic diagram of the device and its band structure are shown. The two crucial components of the device are a cathode (InGaAs) whose condition band edge is below the conduction band edge of the quantum wells and a resonant tunneling filter (GaAs-AlGaAs). In a standard resonant tunneling device the electrodes are made of the same material as the quantum wells, and this device becomes highly conducting when the quantum levels in the wells are aligned with the Fermi level in the negatively biased electrode. In contrast, the researchers device is essentially non-conducting under the same bias conditions. This is because the Fermi Level of the cathode (InGaAs) is still well below the quantum levels so that no resonant transport occurs and the barriers (AlGaAs) effectively block current flow through the device. However, if light with the same photon energy as the conduction-band discontinuity between the cathode and the quantum wells, E sub c3-E sub c1, is shone on the sample, free carriers will be excited to an energy corresponding to the lowest quantum level in the well closest to the cathode (hv plue E sub c1 = E sub o). These electrons will resonantly tunnel through the quantum wells and be collected as a photocurrent in the anode (GaAs). To improve the quantum efficiency, the cathode (InGaAs) should be very heavily doped and capped with a highly reflective metal ohmic contact. The thickness of the device should be tailored to optimize thin film interference effects and afford the maximum absorption of light. Because the device relies on resonant tunneling, its response should be very fast, and the small voltages needed to change the responsivity should allow for very high frequency modulation of the photocurrent. In addition, the device is tuned to a specific photon energy so that it can be designed to detect a fairly narrow range of wavelengths. This selectivity is important for reducing the photocurrent due to spurious light sources.

Woodall, Jerry M.↗

NASA NTRS1988

Striated spectral activity in Jovian and Saturnian radio emission

Examination of high time resolution frequency-time spectrograms of radio emission measured near the Voyager 1 and 2 encounters with Jupiter reveals occasional striation patterns within the normally diffuse hectometric radiation. The patterns are characterized by distinctive banded structures of enhanced intensity meandering in frequency over time scales of minutes to tens of minutes. This banded form of striated spectral activity (SSA) has an occurrence probability of the order of 5 percent during the three weeks before and after Jupiter encounters. Plots of single 6-s frequency sweeps often exhibit a slow rise in intensity followed by a sharp drop-off in each band as frequency decreases. Banded SSA is often preceded or followed by chaotic SSA in which banding of the emission becomes discontinuous or unrecognizable, although the intensity modulation is still evident. Although SSA normally occurs in the frequency range of roughly 0.2-1.0 MHz, similar but longer-lasting patterns have been found occasionally in decametric emission above 10 MHz. Analogous modulation has also been observed in the Saturnian radio emission, suggesting that SSA may be a common feature intrinsic to the radio emission at both planets.

Thieman, James R.↗

NASA NTRS1990

Ion cyclotron bands in VLF saucers

In the wideband VLF data obtained by the polar orbiting DE-1 satellite over the polar night ion trough region of the upper ionosphere, conspicuous frequency-band structures are found to occur both in absorption and emission, particularly associating with VLF saucers. The attenuation bands indicate that the ions of atomic hydrogen from the polar ionosphere are accelerated by the ac electric fields of VLF waves oscillating normal to the static magnetic field, analogous to a cyclotron accelerator. The observed frequencies of the cyclotron harmonics suggest that the acceleration is taking place in the layer below the satellite at a geocentric distance of less than about 1.5 earth radii. This example indicates the existence of upward propagating hiss at those altitudes inside the auroral zone. On the other hand, the frequency shifts of the emission bands are attributed to a combination of two different types of Doppler shift, one due to the orbital motion of the satellite and the other due to the upward motion of the medium at the emission source. This indicates the existence of an upward plasma flow at the source, with a velocity of the order of 20 km/s inside the saucer. The amount of this frequency shift decreases with increasing harmonic order, indicating a higher phase velocity for the electrostatic waves of higher harmonic order.

Maeda, Kaichi↗

NASA NTRS1993

The atmospheric SO2 budget for Pinatubo derived from NOAA-11 SBUV/2 spectral data

Spectral scan data from the NOAA-11 SBUV/2 instrument were used to derive SO2 for three days following the eruption of Mt. Pinatubo - June 19, July 1, and July 17, 1991. Band structure between 300 and 310 nm observed in the backscattered albedo uniquely identifies the presence of SO2. Band ratios are used to infer SO2 amounts to better accuracy (10-20 percent) and sensitivity (about 0.5 milli-atm-cm of SO2) than the TOMS retrieval, but with relatively poor spatial coverage because the measurement is nadir only. Only 7 scans showed detectable SO2 on June 19 when the cloud was still very localized. On July 1 there were 29 scans between 35N and 12S with SO2, with the highest concentration detected over the Atlantic, and on July 17 SO2 was detected in 30 scans around the world, but in decreased concentration. Estimates of the total SO2 budget made after the cloud had spread sufficiently for the sparse SBUV/2 sampling to be adequate indicated that there were 8.4 million metric tons (MMT) of SO2 in the stratosphere on July 1, 1991, and 4.1 MMT remaining on July 17. This corresponds to an e-folding time of about 24 days for the conversion of SO2 to aerosol, and is consistent with an initial injection into the stratosphere of 12-15 MMT of SO2.

Mcpeters, Richard D.↗

NASA NTRS2012

Effect of Rare Earth Elements (Er, Ho) on Semi-Metallic Materials (ScN) in an Applied Electric Field

The development of materials and fabrication technology for field-controlled spectrally active optics is essential for applications such as membrane optics, filters for LIDARs, windows for sensors, telescopes, spectroscopes, cameras and flat-panel displays. The dopants of rare earth elements, in a host of optical systems, create a number of absorption and emission band structures and can easily be incorporated into many high quality crystalline and amorphous hosts. In wide band-gap semiconductors like ScN, the existing deep levels can capture or emit the mobile charges, and can be ionized with the loss or capture of the carriers which are the fundamental basis of concept for smart optic materials. The band gap shrinkage or splitting with dopants supports the possibility of this concept. In the present work, a semi-metallic material (ScN) was doped with rare earth elements (Er, Ho) and tested under an applied electric field to characterize spectral and refractive index shifts by either Stark or Zeeman Effect. These effects can be verified using the UV-Vis spectroscopy, the Hall Effect measurement and the ellipsometric spectroscopy. The optical band gaps of ScN doped with Er and doped with Ho were experimentally estimated as 2.33eV and 2.24eV ( 0.2eV) respectively. This is less than that of undoped ScN (2.5 0.2eV). The red-shifted absorption onset is a direct evidence for the decrease of band gap energy (Eg), and the broadening of valence band states is attributable to the doping cases. A decrease in refractive index with an applied field was observed as a small shift in absorption coefficient using a variable angle spectroscopic ellipsometer. In the presence of an electric field, mobile carriers are redistributed within the space charge region (SCR) to produce this electro-refractive effect. The shift in refractive index is also affected by the density and location of deep potential wells within the SCR. In addition, the microstructure change was observed by a TEM analysis. These results give an insight for future applications for the field-controlled spectrally active material systems.

Kim, Hyunjung↗

NASA NTRS1995

High-Density Amorphous Ice, the Frost on Interstellar Grains

Most water ice in the universe is in a form which does not occur naturally on Earth and of which only minimal amounts have been made in the laboratory. We have encountered this 'high-density amorphous ice' in electron diffraction experiments of low-temperature (T less than 30 K) vapor-deposited water and have subsequently modeled its structure using molecular dynamics simulations. The characteristic feature of high-density amorphous ice is the presence of 'interstitial' oxygen pair distances between 3 and 4 A. However, we find that the structure is best described as a collapsed lattice of the more familiar low-density amorphous form. These distortions are frozen in at temperatures below 38 K because, we propose, it requires the breaking of one hydrogen bond, on average, per molecule to relieve the strain and to restructure the lattice to that of low-density amorphous ice. Several features of astrophysical ice analogs studied in laboratory experiments are readily explained by the structural transition from high-density amorphous ice into low-density amorphous ice. Changes in the shape of the 3.07 gm water band, trapping efficiency of CO, CO loss, changes in the CO band structure, and the recombination of radicals induced by low-temperature UV photolysis all covary with structural changes that occur in the ice during this amorphous to amorphous transition. While the 3.07 micrometers ice band in various astronomical environments can be modeled with spectra of simple mixtures of amorphous and crystalline forms, the contribution of the high-density amorphous form nearly always dominates.

Jenniskens, P.↗

NASA NTRS1966

Magnetoresistance of semiconducting SrTiO sub 3.

Magnetoresistance of reduced and doped strontium titanate to investigate band structure

MAGNETORESISTANCE↗

NASA NTRS1995

Influence of calcium on transport properties, band spectrum and superconductivity of YBa2Cu3O(y) and YBa(1.5)La(0.5)Cu3O(y)

The comparative investigation of transport phenomena in Y(1-x)Ca(x)Ba2Cu3O(y) (0 is less than x is less than 0.25; 6.96 is greater than y is greater than 6.87 and 6.73 is less than x is less than 6.53); Y(1-x)Ca(x)Ba(1.5)La(0.5)Cu3O(y) (0 is less than x is less than 0.5; 7.12 is greater than y is greater than 6.96) and YBa(2-x)La(x)Cu3O(y) (0 is less than x is less than 0.5; 6.95 is less than y is less than 7.21) systems have been carried out. The temperature dependencies of resistivity and thermopower have been measured. It was found that the S(T) dependencies take some additional features with Ca content increase. The results obtained have been analyzed on the basis of the phenomenological theory of electron transport in the case of the narrow conductive band. The main parameters of the band spectrum (the band filling with electrons degree and the total effective band width) have been determined. The dependencies of these from contents of substituting elements are discussed. Analyzing the results obtained simultaneously with the tendencies in oxygen content and critical temperature change we have confirmed the conclusion that the oxygen sublattice disordering has a determinant effect on band structure parameters and superconductive properties of YBa2Cu3O(y). The results obtained suggest that Ca gives rise to some peculiarities in band spectrum of this compound.

Gasumyants, V. E.↗

NASA NTRS1975

The study of mesoscale phenomena, winter monsoon clouds and snow area

The author has identified the following significant results. The clouds under a moderate winter monsoon situation taken with S190A camera reveal existence of clouds with band structure of various wavelengths. The wavelength ranges from 0.4 to 3.5 kms. There was a good relationship between the longitudinal cloud band and vertical wind shear. There was a distinct difference in size of clouds between the Japan Sea side or upwind side and the Pacific Ocean side or downwind side of the Japanese mainland. Large solid cumulus clusters have the size of 20 x 35 sq km over the Japan Sea off the coast of Hokuriku District. It was found that S190A aerial color pictures showing shadows of fair weather cumuli over the sea could be successfully used in estimating cloud height while S190A station 1 picture was more useful over the land since it could more clearly distinguish shadow from vegetation. The height of fair weather cumuli estimated from shadows agree with the lifted condensation level. It was also found that these pictures were effectively used in delineating snow cover area. S192 data, especially IR channel, were found to be effective in finding topography of nimbostratus.

Tsuchiya, K.↗