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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 91 records · Page 5
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Effect of Polymer Chain Length on the Superlattice Assembly of Functionalized Gold Nanoparticles

We report on the assembly of gold nanoparticle (AuNPs) superlattices at the liquid/vapor interface and in the bulk of their suspensions. Interparticle distances in the assemblies are achieved on multiple length scales by varying chain lengths of surface grafted AuNPs by polyethylene glycol (PEG) with molecular weights in the range 2000–40,000 Da. Crystal structures and lattice constants in both 2D and 3D assemblies are determined by synchrotron-based surface-sensitive and small-angle X-ray scattering. Here, assuming knowledge of grafting density, we show that experimentally determined interparticle distances are adequately modeled by spherical brushes close to the θ point (Flory–Huggins parameter, x ≈ 1/2) for 2D superlattices at a liquid interface and a nonsolvent (χ = ∞) for the 3D dry superlattices.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Protein-Mimetic Self-Assembly with Synthetic Macromolecules

Protein-mimetic amphiphiles have significant promise as a platform to access the complex functions of natural biological materials and incorporate the tunability and environmental resilience of synthetic materials. The fields of polymer chemistry and chemical biology have concurrently approached the development of biomimetic amphiphiles with materials ranging from random amphiphilic copolymers to peptide–lipid conjugates. In this Perspective, we incorporate strategies from diverse chemical arenas for controlling assembled morphologies and dynamics of protein-mimetic synthetic macromolecules. An overview of significant advances in peptide amphiphiles and single-chain polymer nanoparticles provides the foundation for comparing recent advances in the implementation of multiple intermolecular interactions and computational strategies to fine-tune the assembled structures. We aim to bridge these fields, combining insights from multiple disciplines to inspire new approaches for the development of protein-mimetic materials, as these assemblies have far-reaching applications including in the development of new sensors, catalysts, and therapeutics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

Self-Assembled Bilayers as an Anchoring Strategy: Catalysts, Chromophores, and Chromophore-Catalyst Assemblies

Anchoring strategies for immobilization of molecular catalysts, chromophores, and chromophore-catalyst assemblies on electrode surfaces play an important role in solar energy conversion devices such as dye-sensitized solar cells and dye-sensitized photoelectrosynthesis cells. They are also important in interfacial studies with surface-bound molecules including electron-transfer dynamics and mechanistic studies related to small molecule activation catalysis. Significant progress has been made in this area, but many challenges remain in terms of stability, synthetic complexity, and versatility. We report here a new anchoring strategy based on self-assembled bilayers. This strategy takes advantage of noncovalent interactions between long alkyl chains chemically bound to a metal-oxide electrode surface and long alkyl chains on the molecule being anchored. Here, the new methodology is applicable to the heterogenization of both catalysts and chromophores as well as to the in situ “synthesis” of chromophore-catalyst assemblies on the electrode surface.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1993

Minimum accommodation for aerobrake assembly. Phase 2: Structural concepts for a lunar transfer vehicle aerobrake which can be assembled on orbit

A multidisciplinary conceptual study was conducted to define a reusable lunar transfer vehicle (LTV) aerobrake which could be launched on a Space Shuttle of Titan 4 and assembled on orbit at Space Station Freedom. A major objective was to design an aerobrake, with integrated structure and thermal protection systems, which has a mass less than 20 percent (9040 lb) of the LTV lunar return mass. The aerobrake segmentation concepts, the structural concepts, a joint concept for assembly, and a structural design with analysis of the aerobrake are described. Results show that a 50-foot diameter LTV aerobrake can be designed for on-orbit assembly which will achieve the 20 percent mass budget.

Dorsey, John T.↗
NASA NTRS2010

Development of an Advanced Recycle Filter Tank Assembly for the ISS Urine Processor Assembly

Recovering water from urine is a process that is critical to supporting larger crews for extended missions aboard the International Space Station. Urine is collected, preserved, and stored for processing into water and a concentrated brine solution that is highly toxic and must be contained to avoid exposure to the crew. The brine solution is collected in an accumulator tank, called a Recycle Filter Tank Assembly (RFTA) that must be replaced monthly and disposed in order to continue urine processing operations. In order to reduce resupply requirements, a new accumulator tank is being developed that can be emptied on orbit into existing ISS waste tanks. The new tank, called the Advanced Recycle Filter Tank Assembly (ARFTA) is a metal bellows tank that is designed to collect concentrated brine solution and empty by applying pressure to the bellows. This paper discusses the requirements and design of the ARFTA as well as integration into the urine processor assembly.

Link, Dwight E., Jr.↗
NASA NTRS2011

Assessment of Gamma Radiation Resistance of Spores Isolated from the Spacecraft Assembly Facility During MSL Assembly

Spore forming bacteria, a common inhabitant of spacecraft assembly facilities, are known to tolerate extreme environmental conditions such as radiation, desiccation, and high temperatures. Since the Viking era (early 1970's), spores have been utilized to assess the degree and level of microbiological contamination on spacecraft and their associated spacecraft assembly facilities. There is a growing concern that desiccation and extreme radiation resistant spore forming microorganisms associated with spacecraft surfaces can withstand space environmental conditions and subsequently proliferate on another solar body. Such forward contamination would certainly jeopardize future life detection or sample return technologies. It is important to recognize that different classes of organisms are critical while calculating the probability of contamination, and methods must be devised to estimate their abundances. Microorganisms can be categorized based on radiation sensitivity as Type A, B, C, and D. Type C represents spores resistant to radiation (10% or greater survival above 0.8 mRad gamma radiation). To address these questions we have purified 96 spore formers, isolated during planetary protection efforts of Mars Science Laboratory assembly for gamma radiation resistance. The spores purified and stored will be used to generate data that can be used further to model and predict the probability of forward contamination.

extreme environments↗
DOE OSTI2020

Nozzle assembly and method for forming nozzle assembly

A nozzle assembly is disclosed, including a CMC nozzle shell, a nozzle spar, and an endwall. The CMC nozzle shell includes a CMC composition and an interior cavity. The nozzle spar is partially disposed within the interior cavity and includes a metallic composition, a cross-sectional conformation, a plurality of spacers protruding from the cross-sectional conformation, the plurality of spacers contacting the CMC nozzle shell, and a spar cap. The endwall includes at least one surface in lateral contact with the spar cap and maintains a lateral orientation of the CMC nozzle shell and the nozzle spar relative to the endwall. The lateral orientation maintains a predetermined throat area of the nozzle assembly. A method for forming the nozzle assembly includes inserting the nozzle spar into the interior cavity, rotating the CMC nozzle shell and the nozzle spar laterally relative to the endwall, and maintaining the lateral orientation.

Hafner, Matthew Troy↗
DOE OSTI2023

Assemblies, riveted assemblies, methods for affixing substrates, and methods for mixing materials to form a metallurgical bond

Riveted assemblies are provided that can include a substrate extending between two ends to define opposing substrate surfaces having a first opening extending between the opposing substrate surfaces; a metal-comprising substrate extending between two ends to define opposing metal-comprising substrate surfaces having a second opening extending between the opposing metal-comprising substrate surfaces. The riveted assemblies can further provide that the first and second openings complement one another when the substrate and metal-comprising substrate are engaged; and a rivet shaft extends through the openings and engages the substrate with the rivet head and the metal-comprising substrate with the rivet stop head, at least a portion of the stop head being mixed with, and forming a metallurgical bond with the metal-comprising substrate. Assemblies are provided that can include a rivet stop head mixed with, and metallurgically bonded with a metal-comprising substrate.Methods for affixing substrates to one another are also provided. The methods can include providing a substrate defining an opening configured to receive a rivet shaft; providing a metal-comprising substrate defining a complimentary opening; operatively engaging the substrates with the rivet shaft; and forming a stop head from the rivet shaft to affix the substrates. The method further includes that the stop head mixes with, and forms a metallurgical bond with the metal-comprising substrate. Methods for mixing materials to form a metallurgical bond are also provided. The methods can include forming a metallurgical bond between a stop head of a rivet and a metal-comprising substrate.

Whalen, Scott A.↗
DOE OSTI2018

Facile electrostatic self-assembly of silicon/reduced graphene oxide porous composite by silica assist as high performance anode for Li-ion battery

Silicon(Si)/graphene composite has been regarded as one of the most promising candidates for next generation anode materials with high power and energy density in lithium ion batteries. Introduction of graphene in Si anodes could improve the electronic conductivity, suppress the severe volume expansion of Si, and facilitate the formation of stable solid electrolyte interphase, etc. However, traditionally mechanical mixing of Si and graphene cannot realize uniform distribution of Si particles on the graphene sheets, which would largely weaken the effectiveness of the graphene in the composite. In this work, nano-Si/reduced graphene oxide porous composite (p Si/rGO) has been fabricated by a facile electrostatic self-assembly approach via using SiO2 as the sacrificial template. Compared with the simply mechanically mixed nano-Si and rGO (Si/rGO), the nano-Si particles could be more uniformly dispersed among the rGO sheets in the p Si/rGO, which significantly increases its electronic conductivity. Moreover, the drastic volume expansion of nano-Si during repeated lithiation/delithiation cycles also has been effectively accommodated by the large number of pores left after removing the SiO2 template in the composite. Thus, the p Si/rGO presented largely enhanced electrochemical performances, showing a high reversible capacity up to 1849?mA?h?g-1 at 0.2?A?g-1 with good capacity retention, and high rate capability (535?mA?h?g-1 at 2?A?g-1).

Silicon, Reduced graphene oxide, Electrostatic sel↗
DOE OSTI2019

Self-assembly and metal-directed assembly of organic semiconductor aerogels and conductive carbon nanofiber aerogels with controllable nanoscale morphologies

A versatile and highly tunable synthesis for nanofiber aerogels based on the n-type organic semiconductor perylene tetracarboxylic diimide (PTCDI) is presented. PTCDI nanofiber aerogels are demonstrated to incorporate the organic semiconductor into a high surface area and porous morphology and can also be graphitized to synthesize carbon nanofiber (CNF) aerogels by thermal annealing. Using this approach, CNF aerogels with variable density and crystallinity are synthesized. Furthermore, by incorporating metal salts into the synthesis, metal-directed assembly yields a variety of nanoscale morphologies. The selection of post-synthesis thermal treatment can result in metal-directed assembly of PTCDI aerogels, low crystallinity graphitic aerogels decorated with metal nanoparticles, or highly crystalline graphitic aerogels with controllable nanoscale morphologies. The high surface area and porosity afforded by the aerogel morphology coupled with the intrinsic properties of PTCDI or CNFs is important for improving their performance in a number of applications including energy storage and catalysis.

36 MATERIALS SCIENCE↗
DOE OSTI2018

One-Shot Synthesis and Melt Self-Assembly of Bottlebrush Copolymers with a Gradient Compositional Profile

Morphological control plays a central role in soft materials design. Herein, we report the synthesis of a gradient bottlebrush architecture and its role in directing molecular packing in the solid state. Bottlebrush copolymers with gradient interfaces were prepared via one-shot ring-opening metathesis polymerization of exo- and endo- norbornene-capped macromonomers. Kinetic studies revealed a gradient compositional profile separating the two blocks along the backbone. Side-chain symmetric gradient bottlebrush copolymers exhibited a strong tendency to assemble into cylindrical microstructures, in contrast to their block copolymer analogs with sharp interfaces. Furthermore such exquisite architectural control of the interfacial composition affords a delicate handle to direct macromolecular assembly.

36 MATERIALS SCIENCE↗